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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Nitric oxide gamma band emission rate factor

Molecular fluorescence emission rate factors for the strong bands of the nitric oxide gamma system have been calculated using recent branching ratios and different temperatures. For the 1-0 gamma band the effects of self-absorption by NO have been taken into account, and effective emission rate factors were calculated for a range of NO column densities at several different temperatures. For column densities near 10 to the 16th/sq cm self-absorption corrections to the emission rate factor can be significant. The emission rate factor for the 1-0 gamma band is 7.19 or 7.68 x 10 to the -6th photons/molecule/sec depending upon the use of experimental or theoretical branching ratios.

Cravens, T. E.↗

Calculated ionization rates, ion densities, and airglow emission rates due to precipitating electrons in the nightside ionosphere of Mars

The calculations presented in this paper clearly establish that the electron fluxes measured by the HARP instrument, carried on board Phobos 2, could cause significant electron impact ionization and excitation in the nightside atmosphere of Mars, if these electrons actually do precipitate. The calculated peak electron densities were found to be about a factor of 2 larger than the mean observed nightside densities, indicating that if a significant fraction of the measured electrons actually precipitate, they could be the dominant mechanism responsible for maintaining the nightside ionosphere. The calculated zenith column emission rates of the O I 5577-A and 6300-A and CO Cameron band emissions, due to electron impact and dissociative recombination mechanisms, were found to be significant.

Haider, S. A.↗

Interactions Between Temperature and Intercellular CO2 Concentration in Controlling Leaf Isoprene Emission Rates

Plant isoprene emissions have been linked to several reaction pathways involved in atmospheric photochemistry. Evidence exists from a limited set of past observations that isoprene emission rate (I(sub s)) decreases as a function of increasing atmospheric CO2 concentration, and that increased temperature suppresses the CO2 effect. We studied interactions between intercellular CO2 concentration (C(sub I)) and temperature as they affect I(sub s) in field-grown hybrid poplar trees in one of the warmest climates on earth - the Sonoran Desert of the southwestern United States. We observed an unexpected midsummer down regulation of I(sub s) despite the persistence of relatively high temperatures. High temperature suppression of the I(sub s):C(sub I) relation occurred at all times during the growing season, but sensitivity of I(sub s) to increased C(sub I) was greatest during the midsummer period when I(subs) was lowest. We interpret the seasonal down regulation of I(sub s) and increased sensitivity of I(sub s) to C(sub I) as being caused by weather changes associated with the onset of a regional monsoon system. Our observations on the temperature suppression of the I(sub s):C(sub I) relation are best explained by the existence of a small pool of chloroplastic inorganic phosphate, balanced by several large, connected metabolic fluxes, which together, determine the C(sub I) and temperature dependencies of phosphoenolpyruvate import into the chloroplast.

Monson, Russell K.↗

A Time-Varying Model for Predicting Formaldehyde Emission Rates in Homes

Recent studies have succeeded in relating emissions of various volatile organic compounds to material mass diffusion transfer using detailed empirical characteristics of each of the individual emitting materials. While significant, the resulting models are often scenario specific and/or require a host of individual component parameters to estimate emission rates. This study developed an approach to estimate aggregated emissions rates based on a wide number of field measurements. We used a multi-parameter regression model based on previous mass transfer models to predict formaldehyde emission rate for a whole dwelling using field-measured, time-resolved formaldehyde concentrations, air exchange rates, and indoor environmental parameters in 63 California single-family houses built between 2011 and 2017. The resulting model provides time-varying formaldehyde emission rates, normalized by floor area, for each study home, assuming a well-mixed mass balance transport model of the home, and a well-mixed layer transport model of indoor surfaces. The surface layer model asserts an equilibrium concentration within the surface layer of the emitted materials that is a function of temperature and RH; the dwelling ventilation rate serves as a surrogate for indoor concentration. We also developed a more generic emission model that is suitable for broad prediction of emission for a population of buildings. This model is also based on measurements aggregated from 27 homes from the same study. We showed that errors in predicting household formaldehyde concentrations using this approach were substantially less than those using a traditional constant emission rate model, despite requiring less unique building information.

54 ENVIRONMENTAL SCIENCES↗

Calculated emission rates for barium releases in space

The optical emissions from barium releases in space are caused by resonance and fluorescent scattering of sunlight. Emission rates for the dominant ion and neutral lines are calculated assuming the release to be optically thin and the barium to be in radiative equilibrium with the solar radiation. The solar spectrum has deep Fraunhofer absorption lines at the primary barium ion resonances. A velocity component toward or away from the sun will Doppler shift the emission lines relative to the absorption lines and the emission rates will increase many-fold over the rest value. The Doppler brightening is important in shaped charge or satellite releases where the barium is injected at high velocities. Emission rates as a function of velocity are calculated for the 4554, 4934, 5854, 6142 and 6497 A ion emission lines and the dominant neutral line at 5535 A. Results are presented for injection parallel to the ambient magnetic field, B, and for injection at an angle to B.

Stenbaek-Nielsen, H. C.↗

Reconciling Assumptions in Bottom-up and Top-down Approaches for Estimating Aerosol Emission Rates from Wildland Fires using Observations from FIREX-AQ

Accurate fire emissions inventories are crucial to predict the impacts of wildland fires on air quality and atmospheric composition. Two traditional approaches are widely used to calculate fire emissions: a satellite-based top-down approach and a fuels-based bottom-up approach. However, these methods often considerably disagree on the amount of particulate mass emitted from fires. Previously available observational datasets tended to be sparse, and lacked the statistics needed to resolve these methodological discrepancies. Here, we leverage the extensive and comprehensive airborne in situ and remote sensing measurements of smoke plumes from the recent Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign to statistically assess the skill of the two traditional approaches. We use detailed campaign observations to calculate and compare emission rates at an exceptionally high-resolution using three separate approaches: top-down, bottom-up, and a novel approach based entirely on integrated airborne in situ measurements. We then compute the daily average of these high-resolution estimates and compare with estimates from lower resolution, global top-down and bottom-up inventories. We uncover strong, linear relationships between all of the high-resolution emission rate estimates in aggregate, however no single approach is capable of capturing the emission characteristics of every fire. Global inventory emission rate estimates exhibited weaker correlations with the high-resolution approaches and displayed evidence of systematic bias. The disparity between the low resolution global inventories and the high-resolution approaches is likely caused by high levels of uncertainty in essential variables used in bottom-up inventories and imperfect assumptions in top-down inventories. Plain Language Summary Smoke emitted by wildland fires is dangerous to human health and contributes to climate change.To predict and evaluate the impacts of fires, we need to know how much smoke is emitted into the atmosphere. There are two state-of-the-art methods used to estimate the mass of smoke emitted by fires, but they often disagree. In this study, we use unusually detailed measurements collected using an aircraft that flew within wildland fire smoke plumes to calculate the amount ofsmoke emitted from fires in the Western United States. We compare emission rates derived from the exceptionally high spatial and temporal resolution approach to the two traditional, lower resolution approaches to understand why they sometimes diverge

E B Wiggins↗

Long-Run Marginal CO 2 e Emission Rates for End-Use Electricity Consumption in the State of Washington [Slides]

This analysis contains an estimate of the long-run marginal emission rate for the electric sector in the state of Washington. The long-run marginal emission rate is an estimate of the rate of emissions that would be either induced or avoided by a long-term (i.e., more than several years) change in electrical demand. The metric explicitly takes into account both the underlying evolution of the electric grid, as well as the potential for an incremental change in electrical demand to influence the structural evolution of the grid (i.e., the building and retiring of capital assets, such as generators and transmission lines). It is therefore distinct from the more-commonly-known short-run marginal, which also identifies a marginal emission rate but treats the grid assets as fixed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Long-run Marginal Emission Rates for Electricity - Workbooks for 2021 Cambium Data

These workbooks contain modeled estimates of long-run marginal emission rates (LRMER) for the contiguous United States. The LRMER is an estimate of the rate of emissions that would be either induced or avoided by a long-term (i.e., more than several years) change in electrical demand. It incorporates both the projected changes to the electric grid, as well as the potential for an incremental change in electrical demand to influence the structural evolution of the grid (i.e., the building and retiring of capital assets, such as generators and transmission lines). It is therefore distinct from the more-commonly-known short-run marginal, which treats grid assets as fixed. The Levelized LRMER worksheet within each workbook is set up to produce a levelized long-run marginal emission rate based on user-provided inputs. These levelized LRMER values are intended for analysts to use when estimating the emissions induced (or avoided) by a long-term change in end-use electricity demand. There are two workbooks that supply the data at two different geographic resolutions: states and GEA regions (20 regions that are similar to, but not exactly the same as, the US EPA's eGRID regions). For more data underlying these emissions factors, see the Cambium 2021 project at https://cambium.nrel.gov/. For more details on the inputs into the scenarios available in the workbooks, see the Standard Scenarios 2021 Report (https://www.nrel.gov/docs/fy22osti/80641.pdf). This data was produced as part of the Cambium project. For more details about the methodology, see the Cambium Documentation: Version 2021 (https://www.nrel.gov/docs/fy22osti/81611.pdf). This data is planned to be updated annually. Information on the latest versions can be found at https://www.nrel.gov/analysis/cambium.html.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Long-run Marginal Emission Rates for Electricity - Workbooks for 2022 Cambium Data

These workbooks contain modeled estimates of long-run marginal emission rates (LRMER) for the contiguous United States. A LRMER is an estimate of the rate of emissions that would be either induced or avoided by a change in electric demand, taking into account how the change could influence both the operation as well as the structure of the grid (i.e., the building and retiring of capital assets, such as generators and transmission lines). It is therefore distinct from the more-commonly-known short-run marginal, which treat grid assets as fixed. Long-run marginal emissions rates are generally appropriate to use when trying to comprehensively estimate the impact of a long-lived (i.e., more than several years) intervention. There are two workbooks that supply the data at two different geographic resolutions: states and GEA regions (20 regions that are similar to, but not exactly the same as, the US EPA's eGRID regions). For more data underlying these emissions factors, see the Cambium 2022 project at https://scenarioviewer.nrel.gov/. For more details on input assumptions and methodology see the associated report (Cambium 2022 Scenario Descriptions and Documentation, https://www.nrel.gov/docs/fy23osti/84916.pdf). This data is planned to be updated annually. Information on the latest versions can be found at https://www.nrel.gov/analysis/cambium.html.

01 COAL, LIGNITE, AND PEAT↗

Observed Barium Emission Rates

The barium releases from the CRRES satellite have provided an opportunity for verifying theoretically calculated barium ion and neutral emission rates. Spectra of the five Caribbean releases in the summer of 1991 were taken with a spectrograph on board a U.S. Air Force jet aircraft. Because the line of sight release densities are not known, only relative rates could be obtained. The observed relative rates agree well with the theoretically calculated rates and, together with other observations, confirm the earlier detailed theoretical emission rates. The calculated emission rates can thus with good accuracy be used with photometric observations. It has been postulated that charge exchange between neutral barium and oxygen ions represents a significant source for ionization. If so. it should be associated with emissions at 4957.15 A and 5013.00 A, but these emissions were not detected.

Stenbaek-Nielsen, H. C.↗

Characterization of Neutron Emission Rates of Commercial 252 Cf Sources

Accurate knowledge of 252 Cf neutron emission rates is critical for modeling and fast-neutron experiments, yet commercial sources are often supplied without traceable calibration or uncertainty estimates. This report describes a method to characterize 252 Cf sources using a pulse-shape-discrimination (PSD) scintillator. The scintillator was efficiency-calibrated against a time-tagged 252 Cf fission chamber manufactured at ORNL over 40 years ago. Isotopic evolution of the calibration source was modeled using Bateman equations to account for changes in the effective average neutrons per fission at the time of measurement. The calibrated scintillator was then used to measure absolute emission rates of several commercial 252 Cf sources, revealing deviations of up to 12% from nominal manufacturer values. This methodology provides a practical approach for establishing uncertainty-quantified 252 Cf neutron emission rates, improving fidelity in simulations and supporting the accurate interpretation of measurements.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Tidal influence on O(1S) airglow emission rate distributions at the geographic equator as observed by WINDII

WINDII, the Wind Imaging Interferometer on the Upper Atmosphere Research Satellite, observes winds, temperatures and emission rates in the upper mesosphere and thermosphere. In this paper we report on nighttime observations of the vertical distribution of the O(1S) 557.7 nm emission near the geographic equator for March/April, 1993. The airglow volume emission rate distribution is found to be strongly dependent on local time. Beginning at dusk, an intense airglow emission layer descends from a mean altitude of 95 km, reaching 89 km by midnight after which the emission rapidly decays. Shortly after midnight it reappears weakly at a higher altitude and remains at this level as the emission rate gradually increases towards dawn. This strong local time dependence leads us to conclude that the effect is tidally driven. Comparison with the Forbes (1982a,b) model suggest that total density perturbations and changes in the atomic oxygen mixing ratio may the cause of the changes in emission rate distribution between dusk and midnight. The reappearance of the emission after midnight may be caused by downward winds bringing oxygen-rich air from above.

Shephere, G. G.↗

Enhancement of the photon emission rate near the QCD critical point

We compute photon emission rate enhancement near the QCD critical point using an effective theory of dynamic critical phenomena and derive a universal photon spectrum. The emission rate scales similar to conductivity, increasing with the correlation length (𝜉), diverging at the critical point. The spectrum exhibits 𝜔⁢𝑑⁢𝑁 𝛾 /𝑑 3 ⁢𝑘 ∝ 𝜔 −1/2 in the scaling regime, with the transition occurring at a frequency comparable to shear damping rate 𝜔 ∼ 𝛾 𝜂 /𝜉 2 , reflecting the nonequilibrium properties of the near-critical liquid.

dynamic critical phenomena↗

Long-run Marginal CO2 Emission Rates Workbooks for 2020 Standard Scenarios Cambium Data

This dataset has been superseded by a new set of workbooks that can be found here: https://data.nlr.gov/submissions/183 These workbooks contain modeled estimates of long-run marginal CO2 emission rates (LRMER) for the contiguous United States. The LRMER is an estimate of the rate of emissions that would be either induced or avoided by a long-term (i.e., more than several years) change in electrical demand. It incorporates both the projected changes to the electric grid, as well as the potential for an incremental change in electrical demand to influence the structural evolution of the grid (i.e., the building and retiring of capital assets, such as generators and transmission lines). It is therefore distinct from the more-commonly-known short-run marginal, which treats grid assets as fixed. In addition to year-over-year data, the Levelized LRMER worksheet within each workbook is set up to produce a levelized long-run marginal emission rate based on user-provided inputs. These levelized LRMER values are intended for analysts to use when estimating the emissions induced (or avoided) by a long-term change in end-use electricity demand. Three future scenarios are provided in separate workbooks: A Mid-case (i.e., business-as-usual), and two scenarios with relatively higher or lower renewable energy costs. For more details on these scenarios, see the Standard Scenarios 2020 Report ( https://www.nlr.gov/docs/fy21osti/77442.pdf ). For more data underlying each scenario, see the Standard Scenarios 2020 project (Cambium data) at https://cambium.nlr.gov/ . This data was produced as part of the Cambium project. For more details about the methodology, see the Cambium Documentation: Version 2020 ( https://www.nlr.gov/docs/fy21osti/78239.pdf ). This data is planned to be updated annually. Information on the latest versions can be found at https://www.nlr.gov/analysis/cambium.html .

24 POWER TRANSMISSION AND DISTRIBUTION↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for Mn ions in low-density high-temperature plasmas

The analysis of optically-thin far-ultraviolet and X-ray emission lines of multiply-charged ions is one of the basic methods for determining the temperatures and densities of laboratory and astrophysical plasmas. In addition, the energy balance in these plasmas can be significantly influenced by the emission of radiation from relatively low concentrations of multiple-charged atomic ions. Because the populations of the excited levels are expected to depart substantially from their local thermodynamic equilibrium values a detailed treatment of the elementary collisional and radiative processes must be employed in order to predict the emission line intensities. In this investigation the authors present the results of calculations based on a corona equilibrium model in which a detailed evaluation is made of the dielectronic recombination rate coefficients. The ionization and autoionization following inner-shell electron excitation from each ground state are balanced by direct radiative and dielectronic recombination. The spectral line intensities emitted by the low-lying excited states, which are assumed to undergo spontaneous radiative decay in times that are short compared with the collision time, are evaluated in terms of the corona ionization equilibrium distributions of the ground states and their electron-impact excitation states.

Jacobs, V. L.↗