Performance of Airborne Imaging Spectrometers for Carbon Dioxide Detection and Emission Quantification
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Jinsol Kim↗
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Spatial and Temporal Variability of Carbon Dioxide Using Structure Functions in Urban Areas: Insights for Future Active Remote CO2 Sensors
High resolution in-situ CO2 measurements were recorded onboard the NASA P-3B during the DISCOVER-AQ (Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality) Field Campaigns during July 2011 over Washington DC/Baltimore, MD; January-February 2013 over the San Joaquin Valley, CA; September 2013 over Houston, TX; and July-August 2014 over Denver, CO. Each of these campaigns have approximately two hundred vertical soundings of CO2 within the lower troposphere (surface to about 5 kilometers) at 6-8 different sites in each of the urban areas. In this study, we used structure function analysis, which is a useful way to quantify spatial and temporal variability, by displaying differences with average observations, to evaluate the variability of CO2 in the 0-2 kilometers range (representative of the planetary boundary layer). These results can then be used to provide guidance in the development of science requirements for the future ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons) mission to measure near-surface CO2 variability in different urban areas. We also compare the observed in-situ CO2 variability with the variability of the CO2 column-averaged optical depths in the 0-1 kilometer and 0-3.5 kilometers altitude ranges in the four geographically different urban areas, using vertical weighting functions for potential future ASCENDS lidar CO2 sensors operating in the 1.57 and 2.05 millimeter measurement regions. In addition to determining the natural variability of CO2 near the surface and in the column, radiocarbon method using continuous CO2 and CO measurements are used to examine the variation of emission quantification between anthropogenic and biogenic sources in the DC/Maryland urban site.
Choi, Yonghoon↗
Assessing the Needs of NASA's Near Real-Time Earth Observation Products
"The 2017-2027 Decadal Survey for Earth Science and Applications from Space stated that NASA's Earth Science with planned implementation of applications provides sustained earth observations for societal benefits [1]. The Decadal Survey indicated that data latency is invaluable for time-sensitive applications including disaster risk reduction, wildland fire carbon emissions quantification, real-time measurements of the state of the hydrologic systems and many more. Data latency refers to the time between earth observation and data products available to users. During the past 13 years, NASA's Land, Atmosphere Near Real-Time Capability for Earth Observing Systems (LANCE) continues to provide free access to earth observation products that are made available much quicker than routine processing allows. The latency of most LANCE data products is Near Real-time (NRT) which is defined as less than three hours from satellite observations [2]. LANCE is managed by the Earth Science Data and Information System (ESDIS) Project at NASA Goddard Space Flight Center [3], and a User Working Group (UWG) is responsible for providing guidance to LANCE. LANCE data are used by direct users and brokers who add value to the data [4]. NASA Earth Applied Sciences Program (ASP) is one of the primary users of LANCE, which collaborates with partner organizations and provides support to scientists to solve problems in applications of earth observations. ASP promotes the use of LANCE NRT data products to demonstrate applications in decision making, facilitates end-user feedback to the science team to improve data products, and provides information on future demands for research. LANCE supports applications that need a rapid response including detecting wildland fires and volcanic eruptions, tracking smoke, ash and dust plumes, monitoring air quality and tracking extreme weather events such as hurricanes, landslides, and floods. To gather feedback regarding the availability, accessibility and actionability of NASA's NRT data products for societal benefit, three surveys and a few discussions with experts involved in the topic within ASP were conducted from the perspective of users. Feedback has been collected from users who are interested in using low latency NASA data within application communities of agriculture, disasters, water resources, health and air quality, ecological conservation, wildland fires and capacity building. Analysis-ready NRT data products in a variety of formats have been mentioned many times in the collected feedback, especially for applied users with little to no experience using research-grade earth observation products. Users prefer to have products that can be easily integrated into their existing workflows and take their analysis to the data. HDF5 is a commonly used data format for research, but typically requires some conversion to a more friendly format for applications and regular use in decision-making. Users prefer the GeoTIFF data format that can be directly ingested into a GIS mapping software and platform for data analysis and visualization. For example, LANCE’s fire, flood, SO2 and Black Marble Nighttime Blue/Yellow Composite data products have been integrated into NASA Disasters Mapping Portal, which is an GIS-based open data portal, for users in the disaster management community. There are 291 LANCE NRT layers available through GIBS and Worldview, where users can download a snapshot in GeoTIFF format. Operational users expect data to be processed as close to the user as possible. The collected feedback indicates that LANCE fire products within 3 hours latency would meet the needs of the wildland fire community. The ideal latency for volcanic application is 10-15 minutes. Users in Volcanic Ash Advisory Centers (VAAC) reported that the first forecast volcanic product should be issued within 75 minutes from the volcano eruption [5]. Overall, for disaster applications, data latency within 3 hours is useful while latency greater than 12 hours is not timely enough for operational use. Capacity building and training are critical for users to be able to access, interpret and use data products and tools for their decision making, especially for applied users with limited experience using earth observation products. LANCE data products have been used in a number of capacity building projects domestically and internationally [6]. As LANCE continues to bring new products into the system, users request training to utilize LANCE new and upcoming data products and capabilities in their applications. Due to the limitation of bandwidth and downstream flow paths, users in some developing countries need tools to select and download data for a specific area of interest instead of bulk downloads. The collected feedback also shows the lack of available SAR satellite low latency data products. The advantages of SAR to monitor conditions and changes on the ground through darkness, clouds, volcanic ash, and other atmospheric conditions, are appealing to low latency users. For example, terabytes of low latency but cloudy optical images are not helpful in rapidly identifying the extent of flood or fire impacts. LANCE could be complemented with low latency measurements via the upcoming NASA-ISRO Synthetic Aperture Radar (NISAR) mission [7]. Requests for higher spatial resolution products are expressed. A user from the wildland fire management community reported that products with 30-m spatial resolution could be used to detect small fires. The 30-m Landsat OLI fire data is now part of NASA’s Fire Information for Resource Management System (FIRMS) US/Canada [8]. Within the open and free NASA resources, LANCE disseminates NRT data products in a manner that allows them to be accessible and understandable to both scientific and applied users. In many application areas, latency plays an important or even decisive role where low latency earth observations help people to observe areas of interest, detect and track changes in the environment and make timely decisions. NASA’s Earth Applied Sciences Program promotes the use of LANCE NRT products and builds a bridge between application users and research teams. The collected feedback indicates data latency within 3 hours is useful for most of the applications, and shows the needs of user-friendly, analysis-ready products, and requests training on LANCE’s new and upcoming data products. User feedback has been provided to LANCE UWG for guidance and recommendations, and for translating findings into something actionable.
Tian Yao↗
Evaluation of GHGSat Methane Emission Estimations of South Side Landfill in Indianapolis, Indiana
As global methane (CH4) continues to grow, accurate quantification of CH4 emission sources has become a high priority for climate management. Urban CH4 emissions in the US could potentially account close to 20% of the national CH4 anthropogenic emissions. While isolated insitu urban CH4 emissions quantification projects have been successful, they require sophisticated planning and prolonged analyses. Such studies are imperative, but they cannot easily operate in every city. An ability to quantify the magnitude of CH4 point sources in a variety of cities with a satellite could support wide scale urban CH4 emissions quantification. Whole-earth scanning satellite instruments such as the TROPOMI and GOSAT are too coarse and noisy to provide meaningful measurements over cities with mid-strength emissions and most point-source emissions in general. It may be possible to address this deficiency utilizing a product with the high spatial resolution of 30-50 m from a private company GHGSat Inc. These sensors are specifically designed to identify and quantify CH4 emissions from diverse types of point sources of varying intensities. In this work we analyze a year (05/2023-05/2024) of GHGSat scans over South Side Landfill in downtown Indianapolis, Indiana and assess the instruments’ accuracy and precision with respect to prior estimations. The results indicate that the data are helpful for estimating landfill’s emissions (~750 kg/hr ± 200 kg/hr) over months-to-a-year time frame but may not be appropriate for identifying daily or even seasonal variations with any trustable degree of certainty, at least not in an urban environment.
Nikolay Balashov↗
Uncertainty Quantification of Global Net Methane Emissions From Terrestrial Ecosystems Using a Mechanistically Based Biogeochemistry Model
Quantification of methane (CH4) emissions from wetlands and its sinks from uplands is still fraught with large uncertainties. Here, a methane biogeochemistry model was revised, parameterized, and verified for various wetland ecosystems across the globe. The model was then extrapolated to the global scale to quantify the uncertainty induced from four different types of uncertainty sources including parameterization, wetland type distribution, wetland area distribution, and meteorological input. We found that global wetland emissions are 212 ± 62 and 212 ± 32 Tg CH4 year−1 (1Tg = 1012 g) due to uncertain parameters and wetland type distribution, respectively, during 2000–2012. Using two wetland distribution data sets and three sets of climate data, the model simulations indicated that the global wetland emissions range from 186 to 212 CH4 year−1 for the same period. The parameters were the most significant uncertainty source. After combining the global methane consumption in the range of −34 to −46 Tg CH4 year−1, we estimated that the global net land methane emissions are 149–176 Tg CH4 year−1 due to uncertain wetland distribution and meteorological input. Spatially, the northeast United States and Amazon were two hotspots of methane emission, while consumption hotspots were in the Eastern United States and eastern China. During 1950–2016, both wetland emissions and upland consumption increased during El Niño events and decreased during La Niña events. This study highlights the need for more in situ methane flux data, more accurate wetland type, and area distribution information to better constrain the model uncertainty.
wetland methane emission↗
Distances of Galactic WC stars from emission-line fluxes and a quantification of the WC classification
The extent to which later-type WC stars in the Galaxy show constant flux in the carbon lines is assessed. It is found the the WC stars are an extremely 'well-behaved' sequence in terms of quantitative spectroscopic properties. The two classification parameters are closely correlated with a scatter of the order of uncertainty. There appear to be natural breaks in the sequence between subclasses, except between WC5 and 6. The classification is quantified using the C IV 5808 A/C III 5696 A ratio as the principal defining parameter for WC7-9 stars and the C III 5696 A/O V 5590 A ratio as the principal defining parameter for WC4-6 stars. Preliminary calibration of the line fluxes indicate that the flux of C IV 5808 A in Galactic WC stars is constant at F(0) 5808 = -log F(0)(5808) = 8.1 at 1 kpc for subclasses WC5-7. The intrinsic line flux ratio C(0) = log f(0)(5808/4650) is a smooth function of subclass number, decreasing from -0.22 dex for WC4 stars to -0.56 dex for WC9 stars.
Smith, Lindsey F.↗
Development of a sparging technique for volatile emissions from potato (Solanum tuberosum)
Accumulation of volatile emissions from plants grown in tightly closed growth chambers may have allelopathic or phytotoxic properties. Whole air analysis of a closed chamber includes both biotic and abiotic volatile emissions. A method for characterization and quantification of biogenic emissions solely from plantlets was developed to investigate this complex mixture of volatile organic compounds. Volatile organic compounds from potato (Solanum tuberosum L. cv. Norland) were isolated, separated and identified using an in-line configuration consisting of a purge and trap concentrator with sparging vessels coupled to a GC/MS system. Analyses identified plant volatile compounds: transcaryophyllene, alpha-humulene, thiobismethane, hexanal, cis-3-hexen-1-ol, and cis-3-hexenyl acetate.
Berdis, Elizabeth↗
Pulling Results Out of Thin Air: Four Years of Ozone and Greenhouse Gas Measurements by the Alpha Jet Atmospheric Experiment (AJAX)
The Alpha Jet Atmospheric eXperiment (AJAX) has been measuring atmospheric ozone, carbon dioxide, methane and meteorological parameters from near the surface to 8000 m since January 2011. The main goals are to study photochemical ozone production and the impacts of extreme events on western US air quality, provide data to support satellite observations and aid in the quantification of emission sources e.g. wildfires, urban outflow, diary and oil and gas. The aircraft is based at Moffett Field and flies multiple times a month to sample vertical profiles at selected sites in California and Nevada, providing long-term data records at these sites. AJAX is also uniquely positioned to launch with short notice sampling flights in rapid response to extreme events e.g. the 2013 Yosemite Rim fire. This talk will focus on the impacts of vertical transport on surface air quality, and investigation of emission sources from diaries and wildfires.
AJAX↗
Quantification of CO2 and CH4 emissions over Sacramento, California, based on divergence theorem using aircraft measurements
Emission estimates of carbon dioxide (CO2) and methane (CH4) and the meteorological factors affecting them are investigated over Sacramento, California, using an aircraft equipped with a cavity ring-down greenhouse gas sensor as part of the Alpha Jet Atmospheric eXperiment (AJAX) project. To better constrain the emission fluxes, we designed flights in a cylindrical pattern and computed the emission fluxes from two flights using a kriging method and Gauss’s divergence theorem. Differences in wind treatment and assumptions about background concentrations affect the emission estimates by a factor of 1.5 to 7. The uncertainty is also impacted by meteorological conditions and distance from the emission sources. The vertical layer averaging affects the flux estimate, but the choice of raw wind or mass-balanced wind is more important than the thickness of the vertical averaging for massbalanced wind for both urban and local scales. The importance of vertical mass transfer for flux estimates is examined, and the difference in the total emission estimate with and without vertical mass transfer is found to be small, especially at the local scale. The total flux estimates accounting for the entire circumference are larger than those based solely on measurements made in the downwind region. This indicates that a closed-shape flight profile can better contain total emissions relative to a one-sided curtain flight because most cities have more than one point source and wind direction can change with time and altitude. To reduce the uncertainty of the emission estimate, it is important that the sampling strategy account not only for known source locations but also possible unidentified sources around the city. Our results highlight that aircraft-based measurements using a closed-shape flight pattern are an efficient and useful strategy for identifying emission sources and estimating local- and city-scale greenhouse gas emission fluxes.
Ju-Mee Ryoo↗
Global Carbon Consumption Database for Wildland Fire
Fire plays a significant role on both national and global scales, profoundly impacting landscapes shaped by human activity as well as those left wild. Even though fire can be devastating, wildland fire is a natural and integral force on our landscapes. Fires can also serve to reduce fuels to mitigate wildfire risk and maintain healthy ecosystem functions. However, the smoke produced by fires, regardless of their size or purpose, can pose adverse effects on human health when inhaled downwind. Understanding the influence of smoke on air quality and human well-being necessitates the quantification of emissions that fires release into the atmosphere. In response to this need, we have established a comprehensive global consumption database directly linked to distinct fuels within various fire danger categories. This database, featuring a spatial resolution of approximately 300 meters, builds upon the foundations of the Pettinari, M. Lucrecia (2015) Global Fuelbed database, a global fuel map with standardized Fuel Characteristic Classification System (FCCS) biomass parameters. Consumption is broken down into five Fire Danger categories (Low, Moderate, High, Very High, Extreme), for both ‘new’ and ‘residual’ burning scenarios. We define ‘residual burned area’ as area burning in a region that has burned on a previous day for the same fire season, and ‘new burned area’ as area burning in a region that has not recently burned. This product serves as a valuable tool when used in conjunction with burned area data to rapidly estimate the carbon consumed and released into the atmosphere. Previously, we developed a similar emissions method utilizing satellite information, in conjunction with the FCCS 30-meter United States fuelbed dataset. We implemented this approach on fires, documented during the 2019 Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign to estimate daily carbon emissions. Our emissions estimates were rigorously compared against in-situ measurements of CO2, CO, and black carbon aerosols, revealing a robust agreement between the two datasets.
Emily Gargulinski↗
CONUS and Global Carbon Consumption Database for Wildland Fire
Fire plays a significant role on both national and global scales, profoundly impacting landscapes shaped by human activity as well as wildlands. Even though fire can be devastating, wildland fire is a natural and integral force on our landscapes. Fires can also serve to reduce fuels to mitigate wildfire risk and maintain healthy ecosystem functions. However, the smoke produced by fires, regardless of their size or purpose, can pose adverse effects on human health when inhaled downwind. Understanding the influence of smoke on air quality and human well-being necessitates the quantification of emissions that fires release into the atmosphere. In response to this need, we have developed a carbon consumption database for the Continental United States (CONUS) and are developing a global carbon consumption database, both of which are directly link to distinct fuels within various fire danger categories. Fuel Characteristic Classification System (FCCS) fuels are used to parameterize biomass, and consumption is broken down into five Fire Danger categories (Low, Moderate, High, Very High, Extreme), for both ‘new’ and ‘residual’ burning scenarios. Residual burned area is defined as burning in areas that have recently burned. We implemented the FCCS 30-meter CONUS fuelbed dataset during the 2019 Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign to estimate daily carbon emissions. Our emissions estimates were rigorously compared against in-situ measurements of CO2, CO, and black carbon aerosols, revealing a robust agreement between the two datasets. The 300-meter global database builds upon the foundations of the Pettinari, M. Lucrecia (2015) Global Fuelbed database, a global fuel map with standardized FCCS biomass parameters. These products can serve as valuable tools when used in conjunction with burned area data to rapidly and accurately estimate carbon consumed and released into the atmosphere.
FCCS↗
Bias in CMIP6 Models as Compared to Observed Regional Dimming and Brightening
Anthropogenic aerosol emissions have increased considerably over the last century, but climate effects and quantification of the emissions are highly uncertain as one goes back in time. This uncertainty is partly due to a lack of observations in the pre-satellite era, making the observations we do have before 1990 additionally valuable. Aerosols suspended in the atmosphere scatter and absorb incoming solar radiation and thereby alter the Earth's surface energy balance. Previous studies show that Earth system models (ESMs) do not adequately represent surface energy fluxes over the historical era. We investigated global and regional aerosol effects over the time period 1961–2014 by looking at surface downwelling shortwave radiation (SDSR). We used observations from ground stations as well as multiple experiments from eight ESMs participating in the Coupled Model Intercomparison Project Version 6 (CMIP6). Our results show that this subset of models reproduces the observed transient SDSR well in Europe but poorly in China. We suggest that this may be attributed to missing emissions of sulfur dioxide in China, sulfur dioxide being a precursor to sulfate, which is a highly reflective aerosol and responsible for more reflective clouds. The emissions of sulfur dioxide used in the models do not show a temporal pattern that could explain observed SDSR evolution over China. The results from various aerosol emission perturbation experiments from DAMIP, RFMIP and AerChemMIP show that only simulations containing anthropogenic aerosol emissions show dimming, even if the dimming is underestimated. Simulated clear-sky and all-sky SDSR do not differ greatly, suggesting that cloud cover changes are not a dominant cause of the biased SDSR evolution in the simulations. Therefore we suggest that the discrepancy between modeled and observed SDSR evolution is partly caused by erroneous aerosol and aerosol precursor emission inventories. This is an important finding as it may help interpret whether ESMs reproduce the historical climate evolution for the right or wrong reason.
surface downwelling shortwave radiation (SDSR)↗
Simulation of Seasonal Snow Microwave TB Using Coupled Multi-Layered Snow Evolution and Microwave Emission Models
The accurate quantification of SWE has important societal benefits, including improving domestic and agricultural water planning, flood forecasting and electric power generation. However, passive-microwave SWE algorithms suffer from variations in TB due to snow metamorphism, difficult to distinguish from those due to SWE variations. Coupled snow evolution-emission models are able to predict snow metamorphism, allowing us to account for emissivity changes. They can also be used to identify weaknesses in the snow evolution model. Moreover, thoroughly evaluating coupled models is a contribution toward the assimilation of TB, which leads to a significant increase in the accuracy of SWE estimates.
microwave↗
Emissions Estimation from Satellite Retrievals: a Review of Current Capability
Since the mid-1990s a new generation of Earth-observing satellites has been able to detect tropospheric air pollution at increasingly high spatial and temporal resolution. Most primary emitted species can be measured by one or more of the instruments. This review article addresses the question of how well we can relate the satellite measurements to quantification of primary emissions and what advances are needed to improve the usability of the measurements by U.S. air quality managers. Built on a comprehensive literature review and comprising input by both satellite experts and emission inventory specialists, the review identifies several targets that seem promising: large point sources of NOx and SO2, species that are difficult to measure by other means (NH3 and CH4, for example), area sources that cannot easily be quantified by traditional bottom-up methods (such as unconventional oil and gas extraction, shipping, biomass burning, and biogenic sources), and the temporal variation of emissions (seasonal, diurnal, episodic). Techniques that enhance the usefulness of current retrievals (data assimilation, oversampling, multi-species retrievals, improved vertical profiles, etc.) are discussed. Finally, we point out the value of having new geostationary satellites like GEO-CAPE and TEMPO over North America that could provide measurements at high spatial (few km) and temporal (hourly) resolution.
air quality↗
Regional Impacts of Woodland Expansion on Nitrogen Oxide Emissions from Texas Savannahs: Combining Field, Modeling and Remote Sensing Approaches
Woody encroachment has contributed to documented changes world-wide and locally in the southwestern U.S. Specifically, in North Texas rangelands encroaching mesquite (Prosopis glandulosa var. glandulosa) a known N-fixing species has caused changes in aboveground biomass. While measurements of aboveground plant production are relatively common, measures of soil N availability are scarce and vary widely. N trace gas emissions (nitric and nitrous oxide) flom soils reflect patterns in current N cycling rates and availability as they are stimulated by inputs of organic and inorganic N. Quantification of N oxide emissions from savanna soils may depend upon the spatial distribution of woody plant canopies, and specifically upon the changes in N availability and cycling and subsequent N trace gas production as influenced by the shift from herbaceous to woody vegetation type. The main goal of this research was to determine whether remotely sensible parameters of vegetation structure and soil type could be used to quantify biogeochemical changes in N at local, landscape and regional scales. To accomplish this goal, field-based measurements of N trace gases were carried out between 2000-2001, encompassing the acquisition of imaging spectrometer data from the NASA Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) on September 29, 2001. Both biotic (vegetation type and soil organic N) and abiotic (soil type, soil pH, temperature, soil moisture, and soil inorganic N) controls were analyzed for their contributions to observed spatial and temporal variation in soil N gas fluxes. These plot level studies were used to develop relationships between spatially extensive, field-based measurements of N oxide fluxes and remotely sensible aboveground vegetation and soil properties, and to evaluate the short-term controls over N oxide emissions through intensive field wetting experiments. The relationship between N oxide emissions, remotely-sensed parameters (vegetation cover, and soil type), and physical controls (soil moisture, and temperature) permitted the regional scale quantification of soil N oxides emissions. Landscape scale analysis linking N oxide emissions with cover change revealed an alleviation from N limitation following mesquite invasion. This study demonstrated the advantage of using N trace gases as a measure of ecosystem N availability combined with remote sensing to characterize the spatial heterogeneity in ecosystem parameters at a scale commensurate with field-based measurements of these properties. Woody vegetation encroachment provided an opportunity to capitalize on detection of the remotely-sensible parameter of woody cover as it relates to belowground biogeochemical processes that determine N trace gas production. The first spatially-explicit estimates of NO flux were calculated based on Prosopis fractional cover derived from high resolution remote sensing estimates of fractional woody cover (< 4 m) for a 120 sq km region of North Texas. An assessment of both N stocks and fluxes from the study revealed an alleviation of N limitation at this site experiencing recent woody encroachment. Many arid and semi-arid regions of the world are experiencing woody invasions, often of N-fixing species. The issue of woody encroachment is in the center of an ecological and political debate. Improving the links between biogeochemical processes and remote sensing of ecosystem properties will improve our understanding of biogeochemical processes at the regional scale, thus providing a means to address issues of land-use and land-cover change.
Asner, Gregory P.↗
Conceptual design study of a coal gasification combined-cycle powerplant for industrial cogeneration
A conceptual design study was conducted to assess technical feasibility, environmental characteristics, and economics of coal gasification. The feasibility of a coal gasification combined cycle cogeneration powerplant was examined in response to energy needs and to national policy aimed at decreasing dependence on oil and natural gas. The powerplant provides the steam heating and baseload electrical requirements while serving as a prototype for industrial cogeneration and a modular building block for utility applications. The following topics are discussed: (1) screening of candidate gasification, sulfur removal and power conversion components; (2) definition of a reference system; (3) quantification of plant emissions and waste streams; (4) estimates of capital and operating costs; and (5) a procurement and construction schedule. It is concluded that the proposed powerplant is technically feasible and environmentally superior.
Bloomfield, H. S.↗
Recent spectroscopic measurements of NOx in the lower stratosphere
High resolution (0.02 and 0.06 per cm) Fourier transform airborne systems were used for measurements of long path atmospheric absorption spectra, covering many of the NOx infrared bands. Atmospheric emission measurements with liquid helium cooled grating spectrometer systems at 0.5 per cm resolution were also carried out from different altitudes in the NOx bands region. Analysis of the absorption and emission spectra provides quantification of NOx in the lower stratosphere at different latitudes and seasons, as well as diurnal variability.
Goldman, A.↗