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Results for “excess enthalpy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Physical aging and solvent effects on the fracture of LaRC-TPI adhesives

When amorphous materials are quenched below their glass transition temperature, excess enthalpy is trapped in the glassy material because the viscosity is too great to allow the material to remain in volumetric equilibrium. Over time, this excess free volume is reduced as the material slowly approaches its equilibrium configuration. This process, known as physical aging, leads to substantial changes in the constitutive behavior of polymers, as has been widely discussed in the literature. Less is known about the effects of this physical aging process on fracture and fatigue properties of aged materials. The original goal of the summer was to investigate the effects of physical aging on the fracture and fatigue behavior of LaRC-TPI, a thermoplastic polyimide developed at NASA-Langley. Preliminary results are reported, although a lack of equipment availability prevented completion of this task. In the process of making specimens, the current LaRC-TPI was observed to be extremely susceptible to environmental stress cracking. A study of the unique failure patterns resulting from this degradation process in bonded joints was conducted and is also reported herein.

Dillard, David A.↗
NASA NTRS2016

Apatite-Melt Partitioning at 1 Bar: An Assessment of Apatite-Melt Exchange Equilibria Resulting from Non-Ideal Mixing of F and Cl in Apatite

The mineral apatite [Ca5(PO4)3(F,Cl,OH)] is present in a wide range of planetary materials. Due to the presence of volatiles within its crystal structure (X-site), many recent studies have attempted to use apatite to constrain the volatile contents of planetary magmas and mantle sources. In order to use the volatile contents of apatite to precisely determine the abundances of volatiles in coexisting silicate melt or fluids, thermodynamic models for the apatite solid solution and for the apatite components in multi-component silicate melts and fluids are required. Although some thermodynamic models for apatite have been developed, they are incomplete. Furthermore, no mixing model is available for all of the apatite components in silicate melts or fluids, especially for F and Cl components. Several experimental studies have investigated the apatite-melt and apatite-fluid partitioning behavior of F, Cl, and OH in terrestrial and planetary systems, which have determined that apatite-melt partitioning of volatiles are best described as exchange equilibria similar to Fe-Mg partitioning between olivine and silicate melt. However, McCubbin et al. recently reported that the exchange coefficients may vary in portions of apatite compositional space where F, Cl, and OH do not mix ideally in apatite. In particular, solution calorimetry data of apatite compositions along the F-Cl join exhibit substantial excess enthalpies of mixing. In the present study, we conducted apatite-melt partitioning experiments in evacuated, sealed silica-glass tubes at approximately 1 bar and 950-1050 degrees Centigrade on a synthetic Martian basalt composition equivalent to the basaltic shergottite Queen Alexandria Range (QUE) 94201. These experiments were conducted dry, at low pressure, to assess the effects of temperature and apatite composition on the partitioning behavior of F and Cl between apatite and basaltic melt along the F-Cl apatite binary join, where there is non-ideal mixing of F and Cl in apatite.

McCubbin, F. M.↗
NASA NTRS2017

Partitioning of F and Cl Between Apatite and a Synthetic Shergottite Liquid (QUE 94201) at 4 Gpa from 1300 TO 1500 C

Apatite [Ca5(PO4)3(F,Cl,OH)] is present in a wide range of planetary materials. Due to the presence of volatiles within its crystal structure (Xsite), many recent studies have attempted to use apatite to constrain the volatile contents of planetary magmas and mantle sources. In order to use the volatile contents of apatite to accurately determine the abundances of volatiles in coexisting silicate melt or fluids, thermodynamic models for the apatite solid solution and for the apatite components in multicomponent silicate melts and fluids are required. Although some thermodynamic models for apatite have been developed, they are incomplete. Furthermore, no mixing model is available for all of the apatite components in silicate melts or fluids, especially for F and Cl components. Several experimental studies have investigated the apatite-melt and apatite-fluid partitioning behavior of F, Cl, and OH in terrestrial and planetary systems, which have determined that apatite-melt partitioning of volatiles are best described as exchange equilibria similar to Fe-Mg partitioning between olivine and silicate melt. However, McCubbin et al., recently reported that the exchange coefficients vary in portions of apatite compositional space where F, Cl, and OH do not mix ideally in apatite. In particular, solution calorimetry data of apatite compositions along the F-Cl join exhibit substantial excess enthalpies of mixing, and McCubbin et al. reported substantial deviations in the Cl-F exchange Kd along the F-Cl apatite join that could be explained by the preferential incorporation of F into apatite. In the present study, we assess the effect of apatite crystal chemistry on F-Cl exchange equilibria between apatite and melt at 4 GPa over the temperature range of 1300-1500 C. The goal of these experiments is to assess the variation in the Ap-melt Cl-F exchange Kd over a broad range of F:Cl ratios in apatite. The results of these experiments could be used to understand at what composition apatite shifts from a hexagonal unit cell with space group P63/m to a unit cell with monoclinic symmetry within space group P21/b. We anticipate that this transition occurs at >70% chlorapatite based on solution calorimetry data.

McCubbin, F. M.↗
NASA NTRS1973

The solubility of hydrogen in rhodium, ruthenium, iridium and nickel.

The temperature variation of the solubility of hydrogen in rhodium, ruthenium, iridium, and nickel in equilibrium with H2 gas at 1 atm pressure has been measured by a technique involving saturating the solvent metal with hydrogen, quenching, and analyzing in resultant solid solutions. The solubilities determined are small (atom fraction of H is in the range from 0.0005 to 0.00001, and the results are consistent with the simple quasi-regular model for dilute interstitial solid solutions. The relative partial enthalpy and excess entropy of the dissolved hydrogen atoms have been calculated from the solubility data and compared with well-known correlations between these quantities.

Mclellan, R. B.↗
NASA NTRS1972

High enthalpy hypersonic boundary layer flow

A theoretical and experimental study of an ionizing laminar boundary layer formed by a very high enthalpy flow (in excess of 12 eV per atom or 7000 cal/gm) with allowance for the presence of helium driver gas is described. The theoretical investigation has shown that the use of variable transport properties and their respective derivatives is very important in the solution of equilibrium boundary layer equations of high enthalpy flow. The effect of low level helium contamination on the surface heat transfer rate is minimal. The variation of ionization is much smaller in a chemically frozen boundary layer solution than in an equilibrium boundary layer calculation and consequently, the variation of the transport properties in the case of the former was not essential in the integration. The experiments have been conducted in a free piston shock tunnel, and a detailed study of its nozzle operation, including the effects of low levels of helium driver gas contamination has been made. Neither the extreme solutions of an equilibrium nor of a frozen boundary layer will adequately predict surface heat transfer rate in very high enthalpy flows.

Yanow, G.↗
NASA NTRS1974

Measurement techniques for supersonic combustion testing

Measurement techniques used during nine years of intensive research in supersonic combustion are presented. The tests employed a number of combustor and injector configurations, which were directly connected to a Mach 3.2 supersonic nozzle, and both gaseous hydrogen and storable liquid fuels. Nominal plenum conditions for the arc-heated air were 3000 to 4500 R and 30 atm. Measurements included wall surface pressures, wall temperatures, heat flux, skin friction, instream cone-static and pitot pressures, and gas samples. Measurement and analysis techniques have been developed for determining total enthalpy of an airstream containing NO concentrations in excess of equilibrium using the two-throat technique, bulk combustion efficiency using steam calorimetry, radial gradients of fluid properties in the combustor exit plane using a stream tube method, and wall shear from measurements of heat transfer in a reacting supersonic flow using Reynolds analogy.

Orth, R. C.↗
NASA NTRS1989

Use of an expansion tube to examine scramjet combustion at hypersonic velocities

Combustion testing at total enthalpy conditions corresponding to flight Mach numbers in excess of 12 requires the use of impulse facilities. The expansion tube is the only operational facility of its size which can provide these conditions without excessive oxygen dissociation or driver gas contamination. Expansion tube operation is described herein and the operational parameters having the largest impact on its performance are determined. These are: driver-to-intermediate chamber pressure ratio, driver gas molecular weight and specific heat ratio, and driver gas temperature. Increases in the last-named parameter will markedly affect the test section static pressure. Preliminary calibration tests are discussed and test gas conditions which have been achieved are presented. Calculated and experimental test times are compared and the parameters affecting test time are discussed. The direction of future work using this important experimental tool is indicated.

Rizkalla, O.↗
NASA NTRS1989

Use of an Expansion Tube to Examine Scramjet Combustion at Hypersonic Velocities

Combustion testing at total enthalpy conditions corresponding to flight Math numbers in excess of 12 requires the use of impulse facilities. The expansion tube is the only operational facility of its size which can provide these conditions without excessive oxygen dissociation or driver gas contamination. Expansio tube operation is described herein and the operational parameters having the largest impact on its performance are determined. These are: driver-to-intermediate chamber pressure ratio, driver gas molecular weight and specific heat ratio, and driver gas temperature. Increases in the lase named parameter will markedly affect the test section static pressure. Preliminary calibration tests are discussed and test gas conditions which have been achieved are presented. Calculated and experimental test times are compared and the parameters affecting test time are discussed. The direction of future work using this important experimental tool is indicated.

Rizkalla, Oussama↗
NASA NTRS1992

Estimation of excitation energy of diatomic molecules in expanding nonequilibrium flows

The energy contained in the highly excited vibrational and rotational states in a diatomic gas in a thermochemical nonequilibrium state during expansion is estimated. The estimation is made on the assumption that the populations of the vibrational and rotational states, when normalized by their respective equilibrium values, are describable by simple functions containing no more than four arbitrary parameters. A cubic polynomial, a logarithmic-cubic polynomial, and a bimodal step function are used for this purpose. The four parameters are determined by imposing conditions known at the ground state and the dissociation limit and the mass conservation law. The energy in excess of that accounted for by assuming a Boltzmann distribution of these states, defined here as excess excitation energy, is calculated for N2, O2, NO, CO, OH, and H2. A calculation made for a typical nozzle flow shows that the excess energy may reach 6 percent of the total enthalpy of the flow, and that the flow velocity may decrease by as much as 4 percent due to the nonequilibrium excitation phenomenon.

Park, Chul↗
NASA NTRS1995

The Superorbital Expansion Tube concept, experiment and analysis

In response to the need for ground testing facilities for super orbital re-entry research, a small scale facility has been set up at the University of Queensland to demonstrate the superorbital expansion tube concept. This unique device is a free piston driven, triple diaphragm, impulse shock facility which uses the enthalpy multiplication mechanism of the unsteady expansion process and the addition of a secondary shock driver to further heat the driver gas. The pilot facility has been operated to produce quasi-steady test flows in air with shock velocities in excess of 13 km/s and with a usable test flow duration of the order of 15 micro sec. an experimental condition produced in the facility with total enthalpy of 108 MJ/kg and a total pressure of 335 MPa is reported. A simple analytical flow model which accounts for non-ideal rupture of the light tertiary diaphragm and the resulting entropy increase in the test gas is discussed. It is shown that equilibrium calculations more accurately model the unsteady expansion process than calculations assuming frozen chemistry. This is because the high enthalpy flows produced in the facility can only be achieved if the chemical energy stored in the test flow during shock heating of the test gas is partially returned to the flow during the process of unsteady expansion. Measurements of heat transfer rates to a flat plate demonstrate the usability of test flow for aerothermodynamic testing and comparison of these rates with empirical calculations confirms the usable accuracy of the flow model.

Neely, A. J.↗
NASA NTRS1992

Large-scale flows and solar luminosity variations

The influence of a variation of the large-scale flows present in the solar convection zone on solar luminosity is examined. The convection zone is modeled as a plane-parallel fluid layer through which heat is transported by small-scale convection as described by the mixing-length theory, and the large-scale flow is treated as a small perturbation superposed on the layer. The excess energy transported by the flow is calculated and is found to depend critically on the mixing length. The excess luminosity is found to be carried as small-scale convective heat flow rather than bulk enthalpy transport throughout all but the top few percent of the convection zone. The results are applied to the specific examples of supergranules and giant cells.

Arendt, S.↗
NASA NTRS1946

An Investigation of the Icing and Heated-air De-icing Characteristics of the R-2600-13 Induction System

A laboratory investigation was made on a Holley 1685-HB carburetor mounted on an R-2600-13 supercharger assembly to determine the icing characteristics and the heated-air de-icing requirements of this portion of the B-25D airplane induction system. Icing has been found to be most prevalent at relatively small throttle openings and, consequently, all runs were made at simulated 60-percent normal rated power condition. Icing characteristics were determined during a series of 15-minute runs over a range of inlet-air conditions. For the de-icing investigation severe impact ice was allowed to form in the induction system and the time required for the recovery of 95 percent of the maximum possible air flow at the original throttle setting was then determined for a range of wet-bulb temperatures. Results of these runs showed that ice on the walls of the carburetor adapter and on the rim of the impeller-shroud portion of the supercharger diffuser plate did not affect engine operation at 60-percent normal rated power. Ice that adversely affected the air flow and the fuel-air ratio was formed only on the central web of the carburetor and then only when the inlet air was saturated or contained free moisture in excess of saturation. No serious ice formations were observed at inlet-air temperatures above 66 0 F or with an inlet-air enthalpy greater than 34 Btu per pound. The maximum temperature at. which any trace of icing could be detected was 1110 F with a relative humidity of approximately 28 percent, The air-flow recovery time for emergency de-icing was 0.3 minute for.an enthalpy of 35 Btu per pound or wet-bulb temperature of 68 0 F. Further increase in enthalpy and wet-bulb temperature above these values resulted in very slight improvement in recovery time. The fuel-air ratio restored by a 5-Minute application of heated air was approximately 7 percent less than the initial value for cold-air conditions.

Chapman, Gilbert E.↗
NASA NTRS1991

High enthalpy, hypervelocity flows of air and argon in an expansion tube

An expansion tube with a free piston driver has been used to generate quasi-steady hypersonic flows in argon and air at flow velocities in excess of 9 km/s. Irregular test flow unsteadiness has limited the performance of previous expansion tubes, and it has been found that this can be avoided by attention to the interaction between the test gas accelerating expansion and the contact surface in the primary shock tube. Test section measurements of pitot pressure, static pressure and flat plate heat transfer are reported. An approximate analytical theory has been developed for predicting the velocities achieved in the unsteady expansion of the ionizing or dissociating test gas.

Neely, A. J↗
NASA NTRS1988

A high heat flux experiment for verification of thermostructural analysis

A major concern in advancing the state of the art technologies for hypersonic vehicles is the development of an aeropropulsion system capable of handling the high heat fluxes during flight. The leading edges of such systems must not only tolerate the maximum heating rates, but must also minimize distortions to the flow field due to excessive blunting and/or thermal warping of the compression surface to achieve the high inlet performance required. A combined analytical and experimental effort to study the aerothermodynamic loads on actively cooled structures for hypersonic applications was established. A hydrogen/oxygen rocket engine was modified to establish a high enthalpy high heat flux environment. The facility provides heat flux levels from about 200 up to 10000 Btu/sq ft/sec. Cross flow and parallel flow regeneratively cooled model can be tested and analyzed by using cooling fluids of water and hydrogen. Results are presented of the experiment and the characteristics of the Hot Gas Test Facility. The predicted temperature results of the cross flow model are compared with the experimental data on the first monolithic specimens and are found to be in good agreement. Thermal stress analysis results are also presented.

Gladden, Herbert J.↗
NASA NTRS1988

A high heat flux experiment for verification of thermostructural analysis

A major concern in advancing the state of the art technologies for hypersonic vehicles is the development of an aeropropulsion system capable of handling the high heat fluxes during flight. The leading edges of such systems must not only tolerate the maximum heating rates, but must also minimize distortions to the flow field due to excessive blunting and/or thermal warping of the conmpression surface to achieve the high inlet performance required. A combined analytical and experimental effort to study the aerothermodynamic loads on actively cooled structures for hypersonic applications was established. A hydrogen/oxygen rocket engine was modified to establish a high enthalpy high heat flux environment. The facility provides heat flux levels from about 200 up to 10000 Btu/sq ft/sec. Cross flow and parallel flow regeneratively cooled model can be tested and analyzed by using cooling fluids of water and hydrogen. Results are presented of the experiment and the characteristics of the Hot Gas Test Facility. The predicted temperature results of the cross flow model are compared with the experimental data on the first monolithic specimens and are found to be in good agreement. Thermal stress analysis results are also presented.

Gladden, H. J.↗
NASA NTRS1974

Microwave interferometry technique for obtaining gas interface velocity measurements in an expansion tube facility

A microwave interferometer technique to determine the front interface velocity of a high enthalpy gas flow, is described. The system is designed to excite a standing wave in an expansion tube, and to measure the shift in this standing wave as it is moved by the test gas front. Data, in the form of a varying sinusoidal signal, is recorded on a high-speed drum camera-oscilloscope combination. Measurements of average and incremental velocities in excess of 6,000 meters per second were made.

Laney, C. C., Jr.↗
NASA NTRS1971

Compression of helium to high pressures and temperatures using a ballistic piston apparatus

Some preliminary experiments are described which were carried out in a high enthalpy laboratory to investigate the compression of helium, a typical shock-tube driver gas, to very high pressures and temperatures by means of a ballistic piston. The purpose of these measurements was to identify any problem areas in the compression process, to determine the importance of real gas effects duDC 47355s process, and to establish the feasibility of using a ballistic piston apparatus to achieve temperatures in helium in excess of 10,000 K.

Roman, B. P.↗
NASA NTRS2018

Acoustic Radiation Pressure

The theoretical foundation of acoustic radiation pressure in plane wave beams is reexamined. It is shown from finite deformation theory and the Boltzmann-Ehrenfest Adiabatic Principle that the Brillouin stress tensor (BST) is the radiation stress in Lagrangian coordinates (not Eulerian coordinates) and that the terms in the BST are not the momentum flux density and mean excess Eulerian stress but are simply contributions to the variation in the wave oscillation period resulting from changes in path length and true wave velocity, respectively, from virtual variations in the strain. It is shown that the radiation stress in Eulerian coordinates is the mean Cauchy stress (not the momentum flux density, as commonly assumed) and that Langevin's second relation does not yield an assessment of the mean Eulerian pressure, since the enthalpy used in the traditional derivations is a function of the thermodynamic tensions - not the Eulerian pressure. It is shown that the transformation between Lagrangian and Eulerian quantities cannot be obtained from the commonly-used expansion of one of the quantities in terms of the particle displacement, since the expansion provides only the difference between the value of the quantity at two different points in Cartesian space separated by the displacement. The proper transformation is obtained only by employing the transformation coefficients of finite deformation theory, which are defined in terms of the displacement gradients. Finite deformation theory leads to the result that for laterally unconfined, plane waves the Lagrangian and Eulerian radiation pressures are equal with the value (1/4)(2K) along the direction of wave propagation, where (K) is the mean kinetic energy density, and zero in directions normal to the propagation direction. This is contrary to the Langevin result that the Lagrangian radiation pressure in the propagation direction is equal to (2K) and the BST result that the Eulerian radiation pressure in that direction is the momentum flux density.

Finite deformation theory↗