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Results for “exotic materials”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Core 74001/2 - Grain size and petrology as a key to the rate of in-situ reworking and lateral transport on the lunar surface

A suite of samples from the double drive tube 74001/2 has been studied. Material from this core mainly consists of orange and black droplets interpreted to be volcanic pyroclastic ejecta. Grain size analysis indicates that this material is very homogeneous in its grain size properties. It is also the finest and best sorted suite of soil samples in the lunar collection having a mean grain size of 40 microns and a mean standard deviation of 1.75 phi. The upper 5.5 cm of this core has apparently undergone in situ reworking by meteorites over a period of about 10 million years. This reworked zone contains 'exotic' grains including basalt, mineral fragments, vitric breccias, and agglutinates. One type of agglutinate is unique and has been made primarily from orange and black glass droplets melted and welded together by micrometeorite impacts. Other agglutinates are made mainly from basaltic fragments and minerals. The amount of 'exotic' material added to the core combined with an estimate of the location of the source areas for the 'exotic' material allows us to estimate that a maximum of about 0.36 gm per sq cm of regolith surface is added from a radius of about 1 meter in 10 million years. Furthermore, no more than about 0.01 gm per sq cm of regolith surface is added from a radius of about 100 meters in 10 million years.

Mckay, D. S.↗
NASA NTRS1988

Preliminary design of two transpacific high-speed civil transport

Two high-speed civil transport (HSCT) design concepts are presented. Both transports are designed for a 5500-n.m. range with 300 passengers. The first design concept is a Mach 2.5, joined-wing, single-fuselage transport. The second design concept is a Mach-4.0, twin-fuselage, variable-sweep wing transport. The use of conventional hydrocarbon fuels is emphasized to reduce the amount of change required in current airport facilities. Advanced aluminums are used in the designs when possible to reduce material and production costs over more exotic materials. Methods to reduce airport noise, community noise, and fly-over noise are incorporated into the designs. In addition, requirements set forth by the Federal Aviation Regulations (FARs) have been addressed.

Source record↗
NASA NTRS1980

Containerless materials processing in the laboratory

Drop tube makes possible preparation of exotic materials. The 100 foot tube is oriented precisely vertical to prevent free-falling drop from hitting tube walls. Inert-gas supply, evacuation pumps, viewing ports, and flexibility in choice of melt technique allow precise control and monitoring of solidification.

Lacy, L. L.↗
NASA NTRS2016

Moonrise: Sampling the South Pole-Aitken Basin to Address Problems of Solar System Significance

A mission to land in the giant South Pole-Aitken (SPA) Basin on the Moon's southern farside and return a sample to Earth for analysis is a high priority for Solar System Science. Such a sample would be used to determine the age of the SPA impact; the chronology of the basin, including the ages of basins and large impacts within SPA, with implications for early Solar System dynamics and the magmatic history of the Moon; the age and composition of volcanic rocks within SPA; the origin of the thorium signature of SPA with implications for the origin of exposed materials and thermal evolution of the Moon; and possibly the magnetization that forms a strong anomaly especially evident in the northern parts of the SPA basin. It is well known from studies of the Apollo regolith that rock fragments found in the regolith form a representative collection of many different rock types delivered to the site by the impact process (Fig. 1). Such samples are well documented to contain a broad suite of materials that reflect both the local major rock formations, as well as some exotic materials from far distant sources. Within the SPA basin, modeling of the impact ejection process indicates that regolith would be dominated by SPA substrate, formed at the time of the SPA basin-forming impact and for the most part moved around by subsequent impacts. Consistent with GRAIL data, the SPA impact likely formed a vast melt body tens of km thick that took perhaps several million years to cool, but that nonetheless represents barely an instant in geologic time that should be readily apparent through integrated geochronologic studies involving multiple chronometers. It is anticipated that a statistically significant number of age determinations would yield not only the age of SPA but also the age of several prominent nearby basins and large craters within SPA. This chronology would provide a contrast to the Imbrium-dominated chronology of the nearside Apollo samples and an independent test of the timing of the lunar cataclysm.

Zeigler, R. A.↗
NASA NTRS1990

LWIR HgCdTe: Innovative detectors in an incumbent technology

HgCdTe is the current material of choice for high performance imagers operating at relatively high temperatures. Its lack of technological maturity compared with silicon and wide-band gap III-V compounds is more than offset by its outstanding IR sensitivity and by the relatively benign effect of its materials defects. This latter property has allowed non-equilibrium growth techniques, metal oxide chemical vapor deposition (MOCVD) and molecular beam epitaxy (MBE), to produce device quality long wavelength infrared (LWIR) HgCdTe even on common substrates like GaAs and GaAs/Si. Detector performance in these exotic materials structures is comparable in many ways with devices in equilibrium-grown material. Lifetimes are similar. RoA values at 77K as high as several hundred have been seen in HgCdTe/GaAs/Si with 9.5 micron cut-off wavelength. HgCdTe/GaAs layers with approx. 15 micron cut-off wavelengths have given average 77K RoAs of greater than 2. Hybrid focal plane arrays have been evaluated with excellent operability.

Tennant, William E.↗
NASA NTRS1985

Short-lived nuclides in the early solar system and general isotopic anomalies in meteorites

Evidence for short-lived nuclides in the early solar system is reviewed. The presence of these nuclides requires the addition to the interstellar medium, from which the solar system formed, of freshly synthesized materials just prior to the formation of the solar system. The best evidence is obtained for Al26. The time scale implied by the Al26 effects is equated with the free-fall time for the collapse of the protosolar cloud. From the observation of ratios of short-lived parent to stable isotopes for nuclides with different half-lives, it is apparent that addition of exotic material to the solar system occurred just prior to its formation. Evidence for a diffuse galactic gamma-ray line emission attributed to Al26 provides support for the existence of Al26 in the protosolar cloud. The time scale for isolation of the protosolar cloud would still be restricted on a timescale comparable to tau 1/2 (Al26).

Papanastassiou, D. A.↗
NASA NTRS1985

SSME lifetime prediction and verification, integrating environments, structures, materials: The challenge

The planned missions for the space shuttle dictated a unique and technology-extending rocket engine. The high specific impulse requirements in conjunction with a 55-mission lifetime, plus volume and weight constraints, produced unique structural design, manufacturing, and verification requirements. Operations from Earth to orbit produce severe dynamic environments, which couple with the extreme pressure and thermal environments associated with the high performance, creating large low cycle loads and high alternating stresses above endurance limit which result in high sensitivity to alternating stresses. Combining all of these effects resulted in the requirements for exotic materials, which are more susceptible to manufacturing problems, and the use of an all-welded structure. The challenge of integrating environments, dynamics, structures, and materials into a verified SSME structure is discussed. The verification program and developmental flight results are included. The first six shuttle flights had engine performance as predicted with no failures. The engine system has met the basic design challenges.

Ryan, R. S.↗
NASA NTRS1990

Benzenoid hydrocarbons in space: The evidence and implications

Many different celestial objects emit an infrared spectrum which has been attributed to infrared fluorescence from a family of highly vibrationally excited benzenoid hydrocarbons referred to as polycyclic aromatic hydrocarbons (PAHs). The most intense emitters contain between 20 to 50 carbon atoms, although larger species also contribute to the emission. This assignment is based on a rough resemblance of the interstellar emission spectra to the vibrational spectra of PAHs and related materials such as chars and soots which contain PAH mixtures. The spectroscopic assignments of the features between 3200 and 700/cm are discussed in detail. Much laboratory work on PAHs which are larger than those previously studied, isolated, ionized and dehydrogenated is called for to fully exploit this model. As PAHs are thought to be ubiquitous throughout the interstellar medium and more abundant than all other known polyatomic, interstellar molecules, they possess great potential as important probes of conditions in many different kinds of astronomical objects. Conversely, astronomical observations are extending our knowledge of these exotic materials by probing regions in which some conditions may be impossible to duplicate in the laboratory.

Allamandola, Louis J.↗
NASA NTRS1990

A New Approach to Fibrous Composite Laminate Strength Prediction

A method of predicting the strength of cross-plied fibrous composite laminates is based on expressing the classical maximum-shear-stress failure criterion for ductile metals in terms of strains. Starting with such a formulation for classical isotropic materials, the derivation is extended to orthotropic materials having a longitudinal axis of symmetry, to represent the fibers in a unidirectional composite lamina. The only modification needed to represent those same fibers with properties normalized to the lamina rather than fiber is a change in axial modulus. A mirror image is added to the strain-based lamina failure criterion for fiber-dominated failures to reflect the cutoffs due to the presence of orthogonal fibers. It is found that the combined failure envelope is now identical with the well-known maximum-strain failure model in the tension-tension and compression-compression quadrants but is truncated in the shear quadrants. The successive application of this simple failure model for fibers in the 0/90 degree and +/- 45 degree orientations, in turn, is shown to be the necessary and sufficient characterization of the fiber-dominated failures of laminates made from fibers having the same tensile and compressive strengths. When one such strength is greater than the other, the failure envelope is appropriately truncated for the lesser direct strain. The shear-failure cutoffs are now based on the higher axial strain to failure since they occur at lower strains than and are usually not affected by such mechanisms as microbuckling. Premature matrix failures can also be covered by appropriately truncating the fiber failure envelope. Matrix failures are excluded from consideration for conventional fiber/polymer composites but the additional features needed for a more rigorous analysis of exotic materials are covered. The new failure envelope is compared with published biaxial test data. The theory is developed for unnotched laminates but is easily shrunk to incorporate reductions to allow for bolt holes, cutouts, reduced compressive strength after impact, and the like.

Hart-Smith, L. J.↗
NASA NTRS1972

Mineralogy and origin of Fra Mauro fines and breccias.

Textural features, glassy spherule and glassy aggregate contents, and size-frequency distributions of lithic components of the regolith fines indicate that the Fra Mauro regolith of the smooth terrain is a highly reworked accumulation of debris derived primarily by impact comminution of annealed breccias. Analyses of the glassy spherules suggest that mare-derived debris must amount to less than 5% of the regolith, but exotic materials having the composition of the Fra Mauro breccias (highland-like) cannot be recognized. Breccia samples from the Fra Mauro site include (1) regolith breccias derived by lithification of local regolith material, (2) texturally and compositionally unique white rock breccias that may have been derived from ancient ejecta buried beneath the Fra Mauro formation, and (3) annealed breccias that are excavated samples of the Fra Mauro formation. The latter were deposited as heated impact ejecta, probably by avalanches produced by the Imbrian event and were annealed in situ in a thermal regime perhaps equivalent to that responsible for the pyroxene-hornfels facies of metamorphism in terrestrial rocks.

Quaide, W.↗
NASA NTRS1987

O-16 excesses in Murchison and Murray hibonites - A case against a late supernova injection origin of isotopic anomalies in O, Mg, Ca, and Ti

Ion probe measurements of the oxygen isotopic composition of seven hibonite samples from the CM chondrites Murchison and Murray are reported. All samples show large O-16 excesses relative to terrestrial oxygen. The data for all samples plot along the carbonaceous chondrite O-16-rich mixing line and show no evidence for isotopic mass fractionation effects characteristic of FUN inclusions. These hibonites have the largest Ca-48 and Ti-50 isotopic anomalies found to date; thus there is no intrinsic relationship between anomalies of a nucleosynthetic origin and isotopic mass fractionation effects. The large O-16 excess seen in the sample with the largest measured Ca-48 and Ti-50 depletions argues against a late injection of exotic material from a nearby supernova as a source for the isotopic anomalies.

Fahey, A. J.↗
NASA NTRS1996

Investigation of Machine Design for Friction Stir Welding

The process of joining two pieces of metal together has not significantly changed over the last few decades. The basic idea used is to bring the pieces together and apply enough heat to melt the metal at the interface. The molten metal mixes and after cooling forms a strong joint. This process is called the fusion process. The most significant difference between the many fusion processes is how the heat is generated and applied. The Welding Institute (TWI), in Great Britain, has recently patented an innovative application of mechanical friction. TWI designed a tool and process called Friction Stir Welding (FSW) that uses friction to heat the metal to within a few hundred degrees Fahrenheit of melting, just to the point of being plastic-like. The tool then stirs the plasticized metal together forming a joint that has been shown to be as good or better than an equivalent fusion joint. The FSW process is well suited for the joining of the aluminum alloys used in the aerospace industry. The relatively low melting point of aluminum eliminates the requirements for exotic materials for pin tool design. The FSW process has been successfully used to join alloys such as 7075 which were before considered "unweldable", and aluminum-lithium 2195 which exhibits many problems when fusion welded. The objective this summer was to investigate the design of a FSW system that could take this process from the laboratory to the manufacturing floor. In particular, it was the goal of my NASA colleague to develop a concept for applying the FSW process to the manufacturing of aluminum cryogenic oxygen and hydrogen tanks, of the sort used to make the Shuttle External Tank.

Romine, Peter L.↗
NASA NTRS2000

Lightweight Lidar Telescopes for Space Applications

NASA is intent on exploiting the unique perspective of space-based remote optical instruments to observe and study large-scale environmental processes. Emphasis on smaller and more affordable missions continues to force the remote sensing instruments to find innovative ways to reduce the size, weight, and cost of the sensor package. This is a challenge because many of the proposed instruments incorporate a high quality meter-class telescope that can be a significant driver of total instrument costs. While various methods for telescope weight reduction have been achieved, many of the current approaches rely on exotic materials and specialized manufacturing techniques that limit availability or substantially increase costs. A competitive lightweight telescope technology that is especially well suited to space-based coherent Doppler wind lidar has been developed through a collaborative effort involving NASA Marshall Space Flight Center (MSFC) through the Global Hydrology and Climate Center (GHCC) and the University of Alabama in Huntsville (UAH) at the Center for Applied Optics (CAO). The new lightweight optics using metal alloy shells and surfaces (LOMASS) fabrication approach is suitable for high quality metal mirrors and meter-class telescopes. Compared to alternative materials and fabrication methods the new approach promises to reduce the areal density of a meter-class telescope to less than 15-kg/sq m; deliver a minimum VIO-RMS surface optical quality; while using commercial materials and equipment to lower procurement costs. The final optical figure and finish is put into the mirrors through conventional diamond turning and polishing techniques. This approach is especially advantageous for a coherent lidar instrument because the reduced telescope weight permits the rotation of the telescope to scan the beam without requiring heavy wedges or additional large mirrors. Ongoing investigations and preliminary results show promise for the LOMASS approach to be successful in demonstrating a novel alternative approach to fabricating lightweight mirrors with performance parameters comparable with the Space Readiness Coherent Lidar Experiment (SPARCLE). Development and process characterization is continuing with the design and fabrication of mirrors for a 25-cm telescope suitable for a lidar instrument.

Peters, Bruce R.↗
NASA NTRS1997

Machine Phase Fullerene Nanotechnology: 1996

NASA has used exotic materials for spacecraft and experimental aircraft to good effect for many decades. In spite of many advances, transportation to space still costs about $10,000 per pound. Drexler has proposed a hypothetical nanotechnology based on diamond and investigated the properties of such molecular systems. These studies and others suggest enormous potential for aerospace systems. Unfortunately, methods to realize diamonoid nanotechnology are at best highly speculative. Recent computational efforts at NASA Ames Research Center and computation and experiment elsewhere suggest that a nanotechnology of machine phase functionalized fullerenes may be synthetically relatively accessible and of great aerospace interest. Machine phase materials are (hypothetical) materials consisting entirely or in large part of microscopic machines. In a sense, most living matter fits this definition. To begin investigation of fullerene nanotechnology, we used molecular dynamics to study the properties of carbon nanotube based gears and gear/shaft configurations. Experiments on C60 and quantum calculations suggest that benzyne may react with carbon nanotubes to form gear teeth. Han has computationally demonstrated that molecular gears fashioned from (14,0) single-walled carbon nanotubes and benzyne teeth should operate well at 50-100 gigahertz. Results suggest that rotation can be converted to rotating or linear motion, and linear motion may be converted into rotation. Preliminary results suggest that these mechanical systems can be cooled by a helium atmosphere. Furthermore, Deepak has successfully simulated using helical electric fields generated by a laser to power fullerene gears once a positive and negative charge have been added to form a dipole. Even with mechanical motion, cooling, and power; creating a viable nanotechnology requires support structures, computer control, a system architecture, a variety of components, and some approach to manufacture. Additional information is contained within the original extended abstract.

Globus, Al↗
NASA NTRS1999

Aerogel Composites: Strong and Waterproof

Aerogels are exotic materials having superior thermal and physical properties with great potential for both space and industrial uses. Although aerogels are excellent low-density insulators with unique acoustic and optical properties, their commercialization potential is currently limited by moisture absorption, fragility, and cost. This paper describes useful, easily scaled-up solutions to the first two of these three problems. The waterproofing and water-repellent method described here is a cheaper and simpler improvement over previous permanent methods.

White, Susan↗
NASA NTRS2003

Search for Near-Earth Objects with Small Aphelion Distances

An essential component of our ability to efficiently find NEOs at small solar elongation is a focal reducer, whose construction is being separately funded by a grant from NSF. This focal reducer will increase the field of view of the 8k CCD mosaic camera from 19 arc min to about 32 arc min at the Cassegrain focus of the University of Hawaii 2.24-m telescope. As of January, all but one of the lenses for the focal reducer were in hand. The final lens had been delayed due to problems with the availability of the rather exotic material out of which the manufacturer was to fabricate the lens. Perhaps as a result of their rush to deliver that final lens, it developed a crack during the annealing process at the manufacturer, thus they had to start over. The total delay in delivery of that last lens was nearly ten months, and therefore the focal reducer was not completed on schedule and could not be used on the telescope this semester. A postdoctoral research associate was recruited to handle the day-to-day operations. The closing date for applications was 2002 December 3 1, and seven were received. One applicant was not qualified, and two were marginal. Of the four qualified candidates, Fabrizio Bernardi stood out as being best qualified. He was a student of Andrea Carusi and had worked on the CINEOS project in Italy, which includes a component of searching for NEOs at small solar elongations.

Tholen, David J.↗
NASA NTRS2016

Investigation of Miniaturized Radioisotope Thermionic Power Generation for General Use

Radioisotope thermoelectric generators (RTGs) running off the radioisotope Pu238 are the current standard in deep space probe power supplies. While reliable, these generators are very inefficient, operating at only approx.7% efficiency. As an alternative, more efficient radioisotope thermionic emission generators (RTIGs) are being explored. Like RTGs, current RTIGs concepts use exotic materials for the emitter, limiting applicability to space and other niche applications. The high demand for long-lasting mobile power sources would be satisfied if RTIGs could be produced inexpensively. This work focuses on exposing several common materials, such as Al, stainless steel, W, Si, and Cu, to elevated temperatures under vacuum to determine the efficiency of each material as inexpensive replacements for thermoelectric materials.

Duzik, Adam J.↗