Large-Scale Volcanic Provinces on Venus: Implications for Plains Emplacement
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Small, modular aircraft are an emerging technology with a goal to maximize flexibility and enable multi-mission support. This reports the progress of an unmanned aerial system (UAS) project conducted at the NASA Ames Research Center (ARC) in 2016. This interdisciplinary effort builds upon the success of the 2014 FrankenEye project to apply rapid prototyping techniques to UAS, to develop a variety of platforms to host remote sensing instruments. In 2016, ARC received AeroVironment RQ-11A and RQ-11B Raven UAS from the US Department of the Interior, Office of Aviation Services. These aircraft have electric propulsion, a wingspan of roughly 1.3m, and have demonstrated reliability in challenging environments. The Raven airframe is an ideal foundation to construct more complex aircraft, and student interns using 3D printing were able to graft multiple Raven wings and fuselages into FrankenRaven aircraft. Aeronautical analysis shows that the new configuration has enhanced flight time, payload capacity, and distance compared to the original Raven. The FrankenRaven avionics architecture replaces the mil-spec avionics with COTS technology based upon the 3DR Pixhawk PX4 autopilot with a safety multiplexer for failsafe handoff to 2.4 GHz RC control and 915 MHz telemetry. This project demonstrates how design reuse, rapid prototyping, and modular subcomponents can be leveraged into flexible airborne platforms that can host a variety of remote sensing payloads and even multiple payloads. Modularity advances a new paradigm: mass-customization of aircraft around given payload(s). Multi-fuselage designs are currently under development to host a wide variety of payloads including a zenith-pointing spectrometer, a magnetometer, a multi-spectral camera, and a RGB camera. After airworthiness certification, flight readiness review, and test flights are performed at Crows Landing airfield in central California, field data will be taken at Kilauea volcano in Hawaii and other locations.
Reports from the session, "Mars Volcanology and Tectonics" include:Martian Shield Volcanoes; Estimating the Rheology of Basaltic Lava Flows; A Model for Variable Levee Formation Rates in an Active Lava Flow; Deflections in Lava Flow Directions Relative to Topography in the Tharsis Region: Indicators of Post-Flow Tectonic Motion; Fractal Variation with Changing Line Length: A Potential Problem for Planetary Lava Flow Identification; Burfellshraun:A Terrestrial Analogue to Recent Volcanism on Mars; Lava Domes of the Arcadia Region of Mars; Comparison of Plains Volcanism in the Tempe Terra Region of Mars to the Eastern Snake River Plains, Idaho with Implications for Geochemical Constraints; Vent Geology of Low-Shield Volcanoes from the Central Snake River Plain, Idaho: Lessons for Mars and the Moon; Field and Geochemical Study of Table Legs Butte and Quaking Aspen Butte, Eastern Snake River Plain, Idaho: An Analog to the Morphology of Small Shield Volcanoes on Mars; Variability in Morphology and Thermophysical Properties of Pitted Cones in Acidalia Planitia and Cydonia Mensae; A Volcano Composed of Light-colored Layered Deposits on the Floor of Valles Marineris; Analysis of Alba Patera Flows: A Comparison of Similarities and Differences Geomorphologic Studies of a Very Long Lava Flow in Tharsis, Mars; Radar Backscatter Characteristics of Basaltic Flow Fields: Results for Mauna Ulu, Kilauea Volcano, Hawaii;and Preliminary Lava Tube-fed Flow Abundance Mapping on Olympus Mons.
This paper presents preliminary results from a subset of work carried out as part of a multinational research project entitled DErisking Exploration for multiple geothermal Plays in magmatic ENvironments (DEEPEN), supported by the U.S. Department of Energy (DOE) and Geothermica, a joint effort by EU member states and associated countries. The DEEPEN project will develop a customized approach to exploration for supercritical and superhot geothermal plays in magmatic systems, which will be applied to two demonstration sites. This paper summarizes field activities carried out at the U.S. demonstration site, Newberry Volcano in central Oregon. The objective of this work effort is to refine the subsurface model of Newberry Volcano, with special focus on deeper zones including the magmatic plumbing system and other key geologic elements. New data collection included gravity and wideband magnetotelluric (MT) surveys, as well as reinstallation of a seismic network. The National Renewable Energy Laboratory (NREL) and Enthalpion Energy LLC (Enthalpion) worked with the Deschutes National Forest Fort Rock District to use a low ground disturbance method of MT deployment to collect MT data inside the caldera and other restricted areas inside the National Volcanic Monument. This opened these areas to geophysical exploration for the first time in decades. Sites along and adjacent to the south rim of the volcano constituted the primary survey objectives. A team from Lawrence Berkeley National Laboratory (LBNL), the U.S. Geological Survey (USGS), and AltaRock also began the process of reinstalling the seismic network from the AltaRock enhanced geothermal system (EGS) demonstration in anticipation of further development activities at the site. The data ingestion, reduction, and analysis phase of the project is ongoing. We are currently processing the MT and gravity data and are developing a new, highly GPU-accelerated, 3D joint MT and gravity inversion to better localize the south rim/south flank conductive target and better understand its relationship to deep heat, fluid sources, and surface extrusive features. Joint inversions, which have not yet been undertaken at Newberry, will allow us to obtain constraints on the geologic model that cannot be determined from each method in isolation, improving our ability to image key geologic features at depth.
Tyrrhena and Hadriaca Paterae are low-relief central-vent volcanoes with shallowly sloping flanks dissected by radial channels. We present results of our investigations of channel formation, the Tyrrhena Patera lava flow field, and the relation between Hesperia Planum and Tyrrhena Patera. Additional information is contained in the original extended abstract.
Large volcanic rises on Venus have been interpreted as hotspots, or the surface manifestation of mantle upwelling, on the basis of their broad topographic rises, abundant volcanism, and large positive gravity anomalies. Hotspots offer an important opportunity to study the behavior of the lithosphere in response to mantle forces. In addition to the four previously known hotspots, Atla, Bell, Beta, and western Eistla Regiones, five new probable hotspots, Dione, central Eistla, eastern Eistla, Imdr, and Themis, have been identified in the Magellan radar, gravity and topography data. These nine regions exhibit a wider range of volcano-tectonic characteristics than previously recognized for venusian hotspots, and have been classified as rift-dominated (Atla, Beta), coronae-dominated (central and eastern Eistla, Themis), or volcano-dominated (Bell, Dione, western Eistla, Imdr). The apparent depths of compensation for these regions ranges from 65 to 260 km. New estimates of the elastic thickness, using the 90 deg and order spherical harmonic field, are 15-40 km at Bell Regio, and 25 km at western Eistla Regio. Phillips et al. find a value of 30 km at Atla Regio. Numerous models of lithospheric and mantle behavior have been proposed to interpret the gravity and topography signature of the hotspots, with most studies focusing on Atla or Beta Regiones. Convective models with Earth-like parameters result in estimates of the thickness of the thermal lithosphere of approximately 100 km. Models of stagnant lid convection or thermal thinning infer the thickness of the thermal lithosphere to be 300 km or more. Without additional constraints, any of the model fits are equally valid. The thinner thermal lithosphere estimates are most consistent with the volcanic and tectonic characteristics of the hotspots. Estimates of the thermal gradient based on estimates of the elastic thickness also support a relatively thin lithosphere (Phillips et al.). The advantage of larger estimates of the thermal lithospheric thickness is that they provide an explanation for the apparently modest levels of geologic activity on Venus over the last half billion years.
Isolated knobs that are erosional remnants of central volcanoes or of folded rocks occur in several areas of the Altiplano are visible on both optical and images. The optically visible streaks occur in the immediate lee of the knobs, whereas the radar visible streaks occur in the zone downwind between the knobs. Aerial reconnaissance and field studies showed that the optically visible streaks consist of a series of small ( 100 m wide) barchan and barchanoid dunes, intradune sand sheets, and sand hummocks (large shrub coppice dunes) up to 15 m across and 5 m high. On LANDSAT images these features are poorly resolved but combine to form a bright streak. On the radar image, this area also appears brighter than the zone of the radar dark streak; evidently, the dunes and hummocks serve as radar reflectors. The radar dark streak consists of a relatively flat, smooth sand sheet which lacks organized aerolian bedforms, other than occasional ripples. Wind velocity profiles show a greater U value in the optically bright streak zone than in the radar dark streak.
On the Colorado Plateau-Basin and Range transition in Arizona and New Mexico, basaltic volcanism takes two physiographic forms: (1) Major central composite volcanoes (e.g., San Francisco Peaks) in which basaltic magma differentiates at shallow crustal levels to siliceous and members and (2) large numbers of small cinder cones and a few domes that result from numerous discrete magma batches which apparently had little opportunity for differentiation. This study represents the first look at the petrogenesis of Plateau-bounding volcanic fields, based on rigorous stratigraphic controls, in combination with major and trace-element constraints. The emerging pattern of large volcanic constructs associated with shallow fractional crystallization, and numerous cinder cones associated with limited or no shallow differentiation may provide an analogue for interpreting petrogenetic patterns and/or tectonic settings on Mars.
A model is presented accounting for many features of the Altiplano-Puna volcanic complex situated in the Central Volcanic Zone of the Andes which contains 50 recently active volcanoes. The dominant elements of the complex are several large nested caldera complexes which are the source structures for the major regionally distributed ignimbrite sheets that characterize the complex. The study of the complex reveals the importance of the intersection of subsidiary axis-oblique tectonic trends related to regional stress fields peculiar to individual oceanic ridge sections with the axis-parallel trends predominant at all spreading centers in localizing hydrothermal discharge zones.
A critical evaluation is presented of the assumptions on which the mathematical model for the geometrical form of a volcano arising from the flow of magma in a porous medium of Lacey et al. (1981) is based. The lack of evidence for an equipotential surface or its equivalent in volcanoes prior to eruption is pointed out, and the preference of volcanic eruptions for low ground is attributed to the local stress field produced by topographic loading rather than a rising magma table. Other difficulties with the model involve the neglect of the surface flow of lava under gravity away from the vent, and the use of the Dupuit approximation for unconfined flow and the assumption of essentially horizontal magma flow. Comparisons of model predictions with the shapes of actual volcanoes reveal the model not to fit lava shield volcanoes, for which the cone represents the solidification of small lava flows, and to provide a poor fit to composite central volcanoes.
A synoptic study of the volcanoes of southern Peru (14-17 deg S), the northernmost part of the Central Volcanic Zone (CVZ 14-28 deg S) of the Andes, was conducted on the basis of Landsat TM images and color photography. The volcanoes were classified and their relative ages determined using subtle glacial-morphological features. Eight of them were postulated as potentially active. These are located in a narrow volcanic zone which probably reflects a steep dip of the Nazca plate through the zone of magma generation. The break in the trend of the volcanic arc possibly reflects the complexity of the crustal stress field above a major segment boundary in the subducting plate. There are also fields of mafic monogenetic centers in this region. In comparison with the southern part of the CVZ, the general paucity of older volcanic edifices north of 17 deg S suggested a more recent onset of volcanism, a possible result of the oblique subduction of the Nazca ridge and the consequent northward migration of its intersection with the Peru-Chile trench. This, together with the lack of any large silicic caldera systems and youthful dacite domes, suggested that there are real differences in the volcanic evolution of the two parts of the CVZ.
Elucidating structure-performance relationships remains a central challenge in field-enhanced catalysis, where nanoparticles exhibit nonuniform surface sites with site-dependent responses to electric fields. Low-coordination sites (edges, corners, and tips) are particularly electric field-sensitive (EF), leading to nonuniform charge distribution, adsorption energies, and catalytic activity. Here, using ammonia decomposition on a ruthenium cluster as a model system, we develop a transferable multiscale framework integrating density functional theory, group additivity (GA), Brønsted-Evans-Polanyi scaling, and microkinetic modeling to predict EF-dependent activity across nonuniform cluster sites. Across sites and fields, the nitrogen adsorption energy (E N ) emerges as the governing descriptor, yielding robust volcano relationships whose optimum shifts systematically with field: negative fields strengthen N binding via electron accumulation, while positive fields weaken N binding via charge depletion, moving the optimal E N toward weaker binding. Microkinetic analysis shows that N≡N bond formation remains the key kinetic bottleneck over most conditions; positive fields lower the effective barrier and, critically, increase the fraction of near-optimal active sites, leading to a net enhancement in overall activity relative to zero-field and negative-field cases. By capturing EF- and site-dependent energetics with high accuracy and low computational cost, this GA-embedded multi-scale simulation workflow provides a physically interpretable route to predict and design field-enhanced nanocatalysis.
(25-50 S, 180-210 E) is host to numerous coronae and small volcanic centers (paterae and shield fields), focused (Aditi and Sirona Dorsa) and distributed (penetrative north-south trending wrinkle ridges) contractional deformation, and radial and linear extensional structures, all of which contribute materials to and/or deform the expansive surrounding plains (Nsomeka and Wawalag Planitiae). Regional plains, which are a northern extension of regional plains mapped in the Barrymore Quadrangle V-59 [1], dominate the V-50 quadrangle. Previous mapping divided the regional plains into two members: regional plains, members a and b [2]. A re-evaluation of these members has determined that a continuous and consistent unit contact does not exist; however, the majority of this radar unit or surficial unit will still be displayed on the final map as a stipple pattern as it is a prevalent feature of the quadrangle. With minimal tessera or highland material, much of the quadrangle s oldest materials are plains units (the regional plains). Much of these plains are covered with small shield edifices that exhibit a variety of material contributions (or flows). In the northwest, several flows emerge and flow to the southeast from Diana-Dali Chasmata. Local corona- and mons-fed flows superpose the regional plains; however, earlier stages of volcano-tectonic centers marked by arcuate and radial structural elements, including terrain so heavily deformed that it takes on a new appearance, may have developed prior to or concurrently with the region plains. Northtrending deformation belts disrupt the central portion of the map area and wrinkle ridges parallel these larger belts. Isabella crater, in the northeastern quadrant, is highly asymmetric and displays two prominent ejecta blanket morphologies, which generally correlate with distance from the impact structure suggesting that ejecta block size or ejecta blanket thickness may be the cause. The crater floor is very dark and shows no direct connection with the large outflow to the south, which emphasizes the asymmetry observed. Isabella crater ejecta and outflow materials clearly postdate several small craters in the vicinity.
Synthetic-aperture radar imagery from the Shuttle Imaging Radar - mission B (SIR-B) was collected in October 1984 over the central Andes between 20 deg S and 24 deg S and also south of 42 deg S. Despite signal-strength problems that drastically reduced the signal-to-noise ratio of the images, volcanic features of both areas show up well. In particular, ignimbrite sheets formed by large explosive eruptions stand out as very strong radar reflectors. High backscatter is apparently caused by erosional relief on the ignimbrites at scales ranging from the radar wavelength (23 cm for SIR-B) to the 30-200-m scale of quebradas (gullies and canyons). The consistent regional erosional pattern appears unrelated to the emplacement of the ignimbrites, and is probably caused by preferential eolian erosion in the directions of the prevailing wind. Hand-held space photographs, ground observations, and Landsat Thematic Mapper imagery support the interpretation of the ignimbrite radar signature. The Chilean volcano Michinmahuida was imaged by four radar data takes at different incidence angles, which show tectonic, glacial, and volcanic features of that nearly inaccessible and often cloud-covered region. Stereo viewing of radar images from two data takes greatly enhances the geologic interpretation of this rugged area.
Learning the science of heterogeneous catalysis and electrocatalysis always starts with the simple case of a flat, uniform surface with an ideal adsorbate. It has of course been recognized for a century that real catalysts are more complicated. For the increasingly complex catalysts of the 21st century, this Perspective argues that surface heterogeneity and non-ideal binding isotherms are central features, and their implications need to be incorporated in current thinking. A variety of systems are described herein where catalyst complexity leads to broad, non-Langmuirian surface isotherms for the binding of hydrogen atoms – and this occurs even for ideal, flat Pt(111) surfaces. Modern catalysis employs nanoscale materials whose surfaces have substantial step, edge, corner, impurity, and other defect sites, and they increasingly have both metallic and non-metallic elements M n X m , including metal oxides, chalcogenides, pnictides, carbides, doped carbons, etc. The surfaces of such catalysts are often not crystal facets of the bulk phase underneath, and they typically have a variety of potential active sites. Catalytic surfaces in operando are often non-stoichiometric, amorphous, dynamic, and impure, and often vary from one part of the surface to another. Understanding of the issues that arise at such nanoscale, multi-element catalysts is just beginning to emerge. Yet these catalysts are widely discussed using Brønsted/Bell-Evans-Polanyi (BEP) relations, volcano plots, Tafel slopes, the Butler-Volmer equation, and other linear free energy relations (LFERs), which all depend on the implicit assumption that the active sites are “similar” and that surface adsorption is close to ideal. These assumptions underly the ubiquitous intuition based on the Sabatier Principle, that the fastest catalysis will occur when key intermediates have free energies of adsorption that are not too strong nor too weak. Current catalysis research often aims to minimize the complexity of non-ideal isotherms through experimental and computational design (e.g., the use of single crystal surfaces), and these studies are the foundation of the field. In contrast, this Perspective argues that the heterogeneity of binding sites and binding energies is an inherent strength of these catalysts. Here, this diversity makes many nanoscale catalysts inherently a high-throughput screen wrapped in a tiny package. Only by making the heterogeneity part of the foundation of catalysis models, sorting the types of active sites and dissecting non-ideal binding isotherms, will modern catalysis learn to harness the inherent diversity of real catalysts. Controlling and exploiting diversity rather than avoiding it will help to optimize complex modern catalysts and catalytic conditions.