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At least 19 records

Flocculation of colloidal sols: Diffusion-controlled vs agitation-induced flocculation

A proposal for carrying out flocculation experiments in microgravity is presented. These experiments might allow a correlation between theory and experiment. First, all particles, whether single primary particles or aggregates of primary particles would not settle or cream at any agitation rate, or even in the absence of agitation. This failure to separate would keep all aggregates active, still serving as centers for diffusion-controlled flocculation. Keeping all particles suspended would allow the possibility of determining the total number of particles as a function of time from beginning to end of flocculation. Finally, the experiments would allow a definite separation diffusion-controlled and agitation-induced flocculation by studying diffusion-controlled flocculation with and without agitation.

Source record↗

Star formation in grand design and flocculent spiral galaxies

An examination is conducted of the colors and neutral hydrogen contents of spiral galaxies which have been classified in the Elmegreen and Elmegreen arm morphology system. Using these data, possible differences between the star formation activity in spiral galaxies with and without classic spiral arms are delineated. At the same revised Hubble type, spiral galaxies with regular global arm patterns (the grand design spirals) are bluer than spiral galaxies lacking such patterns (the flocculent spirals) by a small, but statistically significant amount (approximately 0.05 in B-V and approximately 0.15 in U-V). The neutral hydrogen contents of the two groups are roughly similar, implying the star formation rate averaged over a Hubble time has been approximately the same in grand design and flocculent systems. The color differences can be explained either by using an initial mass function in the flocculent spiral galaxies which is deficient in massive stars by a factor of 2 compared with the grand design systems, or by a decrease of 30 percent in the ratio of recent to past star formation rates in flocculent galaxies. The possibility is discussed that systematic Hubble type misclassifications significantly affect these conclusions.

Romanishin, W.↗

Flocculation and aggregation in a microgravity environment (FAME)

An experiment to study flocculation phenomena in the constrained microgravity environment of a space shuttle or space station is described. The small size and light weight experiment easily fits in a Spacelab Glovebox. Using an integrated fiber optic dynamic light scattering (DLS) system we obtain high precision particle size measurements from dispersions of colloidal particles within seconds, needs no onboard optical alignment, no index matching fluid, and offers sample mixing and shear melting capabilities to study aggregation (flocculation and coagulation) phenomena under both quiescent and controlled agitation conditions. The experimental system can easily be adapted for other microgravity experiments requiring the use of DLS. Preliminary results of ground-based study are reported.

Ansari, Rafat R.↗

Dewatering of contaminated river sediments

Dewatering of slurries has been successfully accomplished by the proper use of polymers in flocculating the fine particulate matter suspended in mineral processing streams. The U.S. Bureau of Mines (USBM) entered into a cooperative research effort with the U.S. Army Corps of Engineers (Corps) for the purpose of testing and demonstrating the applicability of mining flocculation technology to dredging activities associated with the removal of sediments from navigable waterways. The Corps has the responsibility for maintaining the navigable waterways in the United States. Current technology relies primarily on dredging operations which excavate the material from the bottom of waterways. The Corps is testing new dredging technology which may reduce resuspension of sediments by the dredging operation. Pilot plant dredging equipment was tested by the Corps which generated larger quantities of water when compared to conventional equipment, such as the clam shell. The transportation of this 'excess' water adds to the cost of sediment removal. The process developed by the USBM consists of feed material from the barge being pumped through a 4-in line by a centrifugal pump and exiting through a 4-in PVC delivery system. A 1,000-gal fiberglass tank was used to mix the polymer concentrate. The polymer was pumped through a 1-in line using a variable speed progressive cavity pump and introduced to the 4-in feed line prior to passing through a 6-in by 2-ft static mixer. The polymer/feed slurry travels to the clarifying tank where the flocculated material settled to the bottom and allowed 'clean' water to exit the overflow. A pilot scale flocculation unit was operated on-site at the Corps' 'Confined Disposal Facility' in Buffalo, NY.

Church, Ronald H.↗

Method of reducing the green density of a slip cast article

The method disclosed in this specification is one of reducing the green density of an article cast in a slip casting operation. The article is cast from a casting slip containing silicon metal particles, yttrium containing particles, and a small amount of a fluoride salt which is effective to suppress flocculation of the silicon metal particles by y.sup.+3 ions derived from the yttrium containing particles. The method is characterized by the following step. A small amount of compound which produces a cation which will partly flocculate the particles of silicon metal is added to the casting slip. The small amount of this compound is added so that when the casting slip is slip cast into a casting mold, the partly flocculated particles of silicon will interrupt an otherwise orderly packing of the particles of silicon and particles of yttrium. In this manner, the green density of the slip cast article is reduced and the article may be more easily nitrided.

Mangels, John A.↗

Method of forming a relatively stable slip of silicon metal particles and yttrium containing particles

The method concerns forming a relatively stable slip of silicon metal particles and yttrium containing particles. In one embodiment, a casting slip of silicon metal particles is formed in water. Particles of a yttrium containing sintering aid are added to the casting slip. The yttrium containing sintering aid is a compound which has at least some solubility in water to form Y.sup.+3 ions which have a high potential for totally flocculating the silicon metal particles into a semiporous solid. A small amount of a fluoride salt is added to the casting slip which contains the yttrium containing sintering aid. The fluoride salt is one which will produce fluoride anions when dissolved in water. The small amount of the fluoride anions produced are effective to suppress the flocculation of the silicon metal particles by the Y.sup.+3 ions so that all particles remain in suspension in the casting slip and the casting slip has both an increased shelf life and can be used to cast articles having a relatively thick cross-section. The pH of the casting slip is maintained in a range from 7.5 to 9. Preferably, the fluoride salt used is one which is based on a monovalent cation such as sodium or ammonia. The steps of adding the yttrium containing sintering aid and the fluoride salt may be interchanged if desired, and the salt may be added to a solution containing the sintering aid prior to addition of the silicon metal particles.

Dickie, Ray A.↗

The Transformation and Export of Organic Carbon Across an Arctic River-Delta-Ocean Continuum

The Arctic Ocean is surrounded by land that feeds highly seasonal rivers with water enriched in high concentrations of dissolved and particulate organic carbon (DOC and POC). Explicit estimates of the flux of organic carbon across the land-ocean interface are difficult to quantify and many interdependent processes makes source attribution difficult. A high-resolution 3-D biogeochemical model was built for the lower Yukon River and coastal ocean to estimate biogeochemical cycling across the land-ocean continuum. The model solves for complex reactions related to organic carbon transformation, including mechanistic photodegradation and multi-reactivity microbial processing, DOC to POC flocculation, and phytoplankton dynamics. The baseline DOC and POC flux out of the delta from April to September 2019, was 977 and 536 Gg C (~80% of the annual total), but only 50% of the DOC and 25% of the POC exited the plume across the 10 m isobath. Microbial breakdown of DOC accounted for a net loss of 168 Gg C (17% of delta export) within the plume and photodegradation accounted for a net loss of 46.6 Gg C DOC (5% of delta export) in 2019. Flocculation decreased the total organic carbon flux by only 6.4 Gg C (~1%), while POC sinking accounted for 63.3 Gg C (10%) settling in the plume. The loss of chromophoric dissolved organic matter (CDOM) due to photodegradation increased the light available for phytoplankton growth throughout the coastal ocean, demonstrating the secondary effects that organic carbon reactions can have on biological processes and the net coastal carbon flux.

Land-Ocean Continuum↗

Polyelectrolytes with high charge density

Polymers can be used as flocculants to clarify residential and industrial water supplies and as bactericidal and fungicidal agents. They can be used in preparation of electroconductive photocopy papers, to improve living cell adhesion to glass or plastic, and as anticancer agents.

Rembaum, A.↗

Wash water solids removal system study

During wash water purification, surfactants tend to precipitate and foul the RO membranes, causing water flux decline and loss of salt rejection. The use of 165 to 190 ppm ferric chloride and optionally 0.25 to 1.0 ppm polymeric flocculate precipitates 92 to 96 percent of the surfactant from an Olive Leaf Soap based wash water. Crossflow filtration and pressure filtration yield good soap rejection at high water flux rates. Post-treatment of the chemically pretreated and filtered wash water with activated charcoal removes the residual soap down to an undetectable level.

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Process for preparation of large-particle-size monodisperse latexes

Monodisperse latexes having a particle size in the range of 2 to 40 microns are prepared by seeded emulsion polymerization in microgravity. A reaction mixture containing smaller monodisperse latex seed particles, predetermined amounts of monomer, emulsifier, initiator, inhibitor and water is placed in a microgravity environment, and polymerization is initiated by heating. The reaction is allowed to continue until the seed particles grow to a predetermined size, and the resulting enlarged particles are then recovered. A plurality of particle-growing steps can be used to reach larger sizes within the stated range, with enlarge particles from the previous steps being used as seed particles for the succeeding steps. Microgravity enables preparation of particles in the stated size range by avoiding gravity related problems of creaming and settling, and flocculation induced by mechanical shear that have precluded their preparation in a normal gravity environment.

Vanderhoff, J. W.↗

Purification of Solar Ponds

Flocculatory agents added to solar saltponds remove turbidity to increase solar-energy collection efficiency. Flocculating agent or bacteriocide used to remove micro-organisms sprayed onto pond from airplane and allowed to settle to bottom of pond.

Carpenter, S.↗

The role of water in slip casting

Slips and casting are considered in terms of physical and colloidal chemistry. Casting slips are polydisperse suspensions of lyophobic particles in water, whose degree of coagulation is controlled by interaction of flocculating and deflocculating agents. Slip casting rate and viscosity are functions of temperature. Slip rheology and response to deflocculating agents varies significantly as the kinds and amounts of colloid modifiers change. Water is considered as a raw material. Various concepts of water/clay interactions and structures are discussed. Casting is a de-watering operation in which water moves from slip to cast to mold in response to a potential energy termed moisture stress. Drying is an evaporative process from a free water surface.

Mccauley, R. A.↗

The colloidal chemistry of ceramic clays

The colloidal chemistry and mineralogy of two argil minerals were studied. Deposits of kaolin and of ceramic clays in the United States and England are discussed for the probable mechanism of formation. The structural modifications of the bed, original material associated with the clays and the proper use of flocculants are discussed.

Phelps, G. W.↗

Kinetics of successive seeding of monodisperse polystyrene latexes. I - Initiation via potassium persulfate. II - Azo initiators with and without inhibitors

The polymerization kinetics of monodisperse polystyrene latexes with diameters of 1 micron are studied. The monodisperse latexes were prepared by the successive seeding method using 1 mM K2S2O8 with an 8 percent emulsifier surface coverage and 0.5 mM K2S2O8 with a 4 percent emulsifier surface coverage, and the kinetics were measured in a piston/cylinder dialometer. The data reveal that the polymerization rate decreases with increasing particle size; and the surface charge decreases with increasing particle size. The effects of initiators (AIBN and AMBN) and inhibitors (NH24SCN, NaNO2, and hydroquinone) on the product monodispersity and polymerization kinetics of latexes with diameters greater than 1 micron are investigated in a second experiment. It is observed that hydroquinone combined with AMBN are most effective in reducing nucleation without causing flocculation. It is noted that the kinetic transition from emulsion to bulk is complete for a particle size exceeding 1 micron in which the polymerization rate is independent of the particle size.

Sudol, E. D.↗

Sampling the oxidative weathering products and the potentially acidic permafrost on Mars

Large areas of Mars' surface are covered by oxidative weathering products containing ferric and sulfate ions having analogies to terrestrial gossans derived from sulfide mineralization associated with iron-rich basalts. Chemical weathering of such massive and disseminated pyrrhotite-pentlandite assemblages and host basaltic rocks in the Martian environment could have produced metastable gossaniferous phases (limonite containing poorly crystalline hydrated ferric sulfates and oxyhydroxides, clay silicates and opal). Underlying groundwater, now permafrost on Mars, may still be acidic due to incomplete buffering reactions by wall-rock alteration of unfractured host rock. Such acidic solutions stabilize temperature-sensitive complex ions and sols which flocculate to colloidal precipitates at elevated temperatures. Sampling procedures of Martian regolith will need to be designed bearing in mind that the frozen permafrost may be corrosive and be stabilizing unique complex ions and sols of Fe, Al, Mg, Ni and other minor elements.

Burns, Roger G.↗

Models of the Cartwheel ring galaxy: Spokes and starbursts

Recent observations of this famous ring galaxy, including optical and near-infrared CCD surface photometry, and VLA radio continuum and 21 cm line mapping (Higdon 1992b, in prep.), have inspired a renewed modeling effort. Toomre's (1978, in The Large-scale Structure of the Universe, eds. Longair and Einasto) series of restricted three-body simulations demonstrated how the multiple rings could be produced in a nearly head-on galaxy collision. New models with a halo-dominated potential based on the 21 cm rotation curve are able to reproduce such details as the spacing between rings, ring widths, offset of the nucleus, and several kinematical features, thus providing strong support for the collisional theory. The new observations have shown there are little or no old stars in Cartwheel; it may consist almost entirely of gas and stars produced as a result of compression in the ring wave. To model this process Smooth Particle Hydrodynamics (SPH) simulations of the Cartwheel disk have been performed. Fixed gravitational potentials were used to represent the Cartwheel and a roughly 30 percent mass collision partner. The interaction dynamics was treated as in the usual restricted three-body approximation, and the effects of local self-gravity between disk particles were calculated. We are particularly interested in testing the theory that enhanced star formation in waves is the result of gravitational instability in the compressed region (see e.g. Kennicutt 1989, ApJ 344, 685). The gas surface density in a number of simulations was initialized to a value slightly below the threshold for local gravitational instability throughout most of the disk. The first ring wave produces relatively modest compressions (a factor of order a few), triggering instability in a narrow range of wavelengths. Self-gravity in the disk is calculated over a comparable range of scales. Simulations were run with isothermal, adiabatic, and adiabatic with radiative cooling characterized by a relatively short timescale. The isothermal approximation is good except in the vicinity of the strong second (inner) ring, and several snapshots from one case are shown in the figure below. Flocculent spiral segments are present before the collision, and these are compressed into dense knots in the ring wave. These knots are likely to be sites of vigorous star formation. In the strong rarefaction behind the outer ring most of the knots are radially stretched and sheared, giving rise to spoke-like features. A few dense knots are evidently very tightly bound, because they retain their coherence and are stretched relatively little through the rarefaction. This is in accord with evidence for continuing star formation in some spokes (Marcum, Appleton and Higdon 1992). The number and spacing of spokes is a direct function of the scale of the gravitational instability in the disk. Thus, the gravitational instability theory, together with the hypothesis that massive stars are only formed in dense knots of gas, can account for most of the distinct morphology of the Cartwheel.

Struck-Marcell, Curtis↗

On the distribution of pitch angles in external galactic spirals NGC 1232 and NGC 5457

A numerical method, originally developed to analyze the morphology of global and local structure in prototype galaxies, is modified for analyzing observed disk-shape galaxies. Two digitized spiral galaxies NGC 1232 and NGC 5457 with varying degrees of contrast between arm and interarm regions are analyzed. A synergism of partitioning methods and a geometric mean least-squares regression algorithm serves to isolate local arm segments, spurs, feathers, and secondary features and to measure their pitch angles and lengths. The global arms are actually highly disjointed, with arm segments frequently revealing pitch angles between 30 and 50 deg, certainly greater than those of the parent arms. Prominent spurs tend to exhibit a much greater pitch angle. The automated mathematical algorithm is shown to have negligible numerical biasing and could be applied to any number of spiral galaxies manifesting flocculent structure, either prototype or observed, and could possibly be used as a tool for classification of multiple-armed-type galaxies.

Russell, William S.↗

Transport phenomena of growth-in-gel zeolite crystallization in microgravity

Secondary nucleation (SN) due to crystal sedimentation has been believed to be one of the major effects that causes smaller sizes of final zeolite crystals. The present investigation indicates that, in a reactor, this gravity-induced SN occurs only within a white opaque column termed the gel portion. Under normal gravity this portion shrinks to the bottom of the hydrothermal reactor, leaving a clear portion of solution at the top, due to depletion of the flocculated gel particles. Solution phase nucleation and crystallization is assumed and a correlation for the shrinkage is therefore derived, which shows good agreement with experimental observations. A non-dimensional parameter is suggested as a criterion for the occurrence of SN. Based on the parameter whether or not microgravity is beneficial to zeolite growth is discussed. Also, the growth mechanism and the transport phenomena in the absence of gravity are discussed.

Zhang, H.↗