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At least 19 records

Low Temperature Flux Growth of 2H-SiC and Beta-Gallium Oxide

We present brief overview of our study on the low temperature flux growth of two very important novel wide bandgap materials 2H-SiC and Beta-gallium oxide (Beta-Ga2O3). We have synthesized and grown 5 millimeter to 1 centimeter size single crystals of Beta-gallium oxide (Beta-Ga2O3). We used a flux and semi wet method to grow transparent good quality crystals. In the semi-wet method Ga2O3 was synthesized with starting gallium nitrate solution and urea as a nucleation agent. In the flux method we used tin and other metallic flux. This crystal was placed in an alumina crucible and temperature was raised above 1050 degrees Centigrade. After a time period of thirty hours, we observed prismatic and needle shaped crystals of gallium oxide. Scanning electron microscopic studies showed step growth morphology. Crystal was polished to measure the properties. Bandgap was measured 4.7electronvolts using the optical absorption curve. Another wide bandgap hexagonal 2H-SiC was grown by using Si-Al eutectic flux in the graphite crucible. We used slight AlN also as the impurity in the flux. The temperature was raised up to 1050 degrees Centigrade and slowly cooled to 850 degrees Centigrade. Preliminary characterization results of this material are also reported.

Singh, N. B.↗

What makes active regions grow.

A study of magnetic flux growth or growth failure in over 100 active regions is shown to indicate that most growth is connected with the emergence of a large batch of flux in the shape of a new arch filament system (AFS). During the recent sunspot maximum, new AFSs appeared at a rate of nearly one per day over the entire sun. Evidence is presented for two proposed hypotheses, namely: (1) a twist in the flux tubes of new AFSs is a key factor in determining which new AFSs will grow; and (2) this twist is related to the well-known asymmetry of sunspot groups.

Weart, S.↗

Effect of Processing on Morphology of Hydroxyapatites: Bioactive Glasses and Crystalline Composites

Recent studies on multinary oxides for applications as laser hosts and high dielectric capacitors have shown that processing at high temperature provides glassy or crystalline materials based on thermal treatments and cooling rates. Since hydroxyapatites are now subject of great interests due to their bioactivity, interest in producing soft and hard materials with glassy and crystalline nature by processing parameters has become very important. Crystalline materials by using Bridgman, Czochralski and flux growth methods are costly and require huge investment. We have observed that even low temperature solidification in organic flux produced oriented fibers. This organic treated material has different characteristics than in situ oxide materials prepared by sintering and grain growth. Examples of phosphate and silicate-based systems will be presented to demonstrate soft and hard materials. Effect of TiO2 and other hardening elements will be also reported.

McAdams, Joel↗

Bulk Crystal Growth of Piezoelectric PMN-PT Crystals Using Gradient Freeze Technique for Improved SHM Sensors

There has been a growing interest in recent years in lead based perovskite ferroelectric and relaxor ferroelectric solid solutions because of their excellent dielectric, piezoelectric and electrostrictive properties that make them very attractive for various sensing, actuating and structural health monitoring (SHM) applications. We are interested in the development of highly sensitive and efficient PMN-PT sensors based on large single crystals for the structural health monitoring of composite materials that may be used in future spacecrafts. Highly sensitive sensors are needed for detection of defects in these materials because they often tend to fail by distributed and interacting damage modes and much of the damage occurs beneath the top surface of the laminate and not detectable by visual inspection. Research is being carried out for various combinations of solid solutions for PMN-PT piezoelectric materials and bigger size crystals are being sought for improved sensor applications. Single crystals of this material are of interest for sensor applications because of their high piezoelectric coefficient (d33 greater than 1700 pC/N) and electromechanical coefficients (k33 greater than 0.90). For comparison, the commonly used piezoelectric ceramic lead zirconate titanate (PZT) has a d33 of about 600 pC/N and electromechanical coefficients k33 of about 0.75. At the present time, these piezoelectric relaxor crystals are grown by high temperature flux growth method and the size of these crystals are rather small (~3x4x5 mm(exp 3). In the present paper, we have attempted to grow bulk single crystals of PMN-PT in a 2 inch diameter platinum crucible and successfully grown a large size crystal of 67%PMN-33%PT using the vertical gradient freeze technique with no flux. Piezoelectric properties of the grown crystals are investigated. PMN-PT plates show excellent piezoelectric properties. Samples were poled under an applied electric field of 5 kV/cm. Dielectric properties at a frequency of 1 kHz are examined. The grown PMN-PT crystals show typical relaxor dielectric properties. Additionally, the thermal properties of the sample are tested. The results are in good agreement with those found in the literature and some are reported for the first time.

Aggarwal, Mohan D.↗

Diffusive-convective vapor transport across horizontal and inclined rectangular enclosures

The enhancement of vapor transport across horizontal and inclined rectangular (two-dimensional) enclosures by expansive convection is studied numerically for a range in Grashof number that extends up to boundary layer flow. Comparison is made with predictions of the simplifying model and resulting analytical treatment of Klosse and Ullersma (1973) for various aspect ratios of the enclosure. The influence of varying Schmidt and Prandtl numbers is investigated. Solutions for interfacial (growth) flux and temperature distributions are given, showing practically important nonuniformities.

Markham, B. L.↗

Interaction of surface radiation with convection in crystal growth by physical vapor transport

Growth of single crystals from vapor in closed ampoules is governed by an intricate interplay between mass, momentum and heat transfer processes. The objective of this study is to examine and isolate the effects of surface radiation heat transfer on the vapor transport process using a mathematical model. The model consists of a set of coupled nonlinear partial differential equations for conservation of mass, momentum, energy and species, and the integrodifferential equations which represent radiative exchange. It depends on five important physical parameters. These are Grashof number, Prandtl number, Schmidt number, aspect ratio and the radiation-conduction number. The effects of these dimensionless groupings are systematically investigated. From the cases examined, it is concluded that surface radiation can change the flow structure appreciably. This is especially true in microgravity environment where radiation competes primarily with conduction in modifying the thermal profiles. The numerical results also show that in the presence of radiation, the top heating configuration (source on top) is no longer stable and that near the growing crystal, radiation-induced vortices can introduce significant nonuniformities in the growth flux.

Kassemi, Mohammad↗

Design and Characteristics of Hydroxyapatites: Effect of Radiation

Hydroxyapatites single crystals have been investigated their applications as the laser host material. Czochralksi and flux growth methods have been utilized to achieve single crystals. Because of their bioactivities with tissues these have attracted interest for bone applications. For low temperature processing we have used several techniques. We utilized some organic melt and oriented the grains by the directional solidification method. This organic treated material has different characteristics than coarsened oxide materials. Our approach involved low temperature processing using nano-engineered powders of the material system MgO-Na2O-K2O-CaO-SrO-SiO2 and also borates were processed by sintering and grain growth. Our results indicate that substitution of calcium and strontium with some other elements such as gallium and magnesium have great potential to improve the mechanical properties of bones.

Bhavsar, Jayati↗

Effect of Radiation on Biologically Active Glasses

Multifunctional hydroxyapatites single crystals have been studied for their applications as the laser host material since past several decades. It is only recently their potential has been evaluated for bioactive materials. In the past researches, Czochralski and flux growth methods have been utilized to achieve single crystals. We have used low temperature processing techniques for synthesis. Organic melt was used to achieve oriented fibers by the directional solidification method. This organic treated material has different characteristics than coarsened oxide materials. Our approach involved low temperature processing using nano engineered powders of the material system Na2O-K2O-CaO- MgO-SrO-SiO2. Also, borates were processed by sintering and grain growth. Effect of -ray was studied by measuring the electrical characteristics of radiated samples. Our experiments to further improve mechanical characteristics indicate that substitution of calcium with some other elements such as gallium have great potential to improve the radiation hardening and mechanical properties of bones.

Tufail, Areeba↗

Turbulent spectra, fluxes, stability and growth of the mixed layer in the boundary layer of Mars

Spectra of wind and temperature from high frequency measurements in the atmospheric surface layer of Mars are presented for the first time. Heat and momentum fluxes, and stability are calculated for early spring from estimates of the surface temperature and mean Viking Lander 2 temperature and wind at 44 degrees N, using similarity theory. This study provides the first estimates of (1) the height of the mixed layer, (2) spectra of wind and temperature, (3) the validity of similarity theories on Mars, and (4) bounds of effective measuring height and surface roughness. It confirms and extends the universiality of model wind spectra. Finally and more important, we provide the ability to estimate and determine the self-consistency of Martian atmospheric mixed layer fluxes, stability and heights on a diurnal and annual basis. This can be used to initialize and validate the various models, which previously could only be compared with each other or the efforts of Sutton, Leovy and Tillman: these were restricted in season and limited by the results from the surface temperature model available at that time. Analysis of additional data can better estimate z(sub 0) values directly from the measurements and provide the parameters necessary to calculate the vertical profiles of wind and temperature on a daily, seasonal and annual basis.

Tillman, James E.↗

Particle propagation effects on wave growth in a solar flux tube

The evolution of a distribution of electrons is followed after they are injected impulsively at the top of a coronal magnetic loop, with the objective of studying the plasma instabilities which result. At early times the downgoing electrons have beamlike distributions and amplify electrostatic waves via the Cerenkov resonance; the anomalous Doppler resonance is found to be less important. Slightly later, while the electrons are still predominantly downgoing, they are unstable to cyclotron maser generation of z-mode waves with omega(p) much less than Omega, or to second harmonic x-mode waves. The energetics of these instabilities, including saturation effects and heating of the ambient plasma, are discussed. It is suggested that coalescence of two z-mode waves generated by cyclotron maser emission of the downgoing electrons may produce the observed microwave spike bursts.

White, S. M.↗

The morphological evolution of mare-highland contacts - A potential measure of relative mare surface age

The uniform breaks in slopes along many mare-highland contacts may be debris aprons transported primarily by impact erosion at relatively slow rates. Other suggestions, such as the 'high lava mark' hypothesis, appear inadequate to explain all of the unique characteristics of these widespread features. There is a reasonable correlation of overall slope form (profile) and apron distribution with established mare age provinces. Distinctive debris aprons in the younger maria could represent the initial stages of lunar slope degradation produced mainly by the postmare impact flux. The growth of debris aprons must be qualitatively related to the impact flux recorded on adjacent mare surfaces and could provide an approximate means of extrapolating relative mare ages to highland scarps and crater walls. By combining detailed measurements of lunar slopes with development of a realistic model for impact modification of these features, approximate limits for the cumulative lunar flux distribution through time might be derived.

Young, R. A.↗

Vapor Growth of Alloy-Type Semiconductor Crystals

The present effort is part of a continuing research program directed towards the investigation of basic vapor transport phenomena and of crystal growth properties of electronic materials. The primary purpose of ground-based studies is the development and definition of optimum experimental parameters for flight experiments. The ground-based effort includes the investigation of gravity-driven convection effects on mass transport rates and on crystal morphology for different orientations of the density gradient with respect to the gravity vector, and as a function of pressure and of temperature. In addition to the experimental tasks, theoretical efforts involve the quantitative thermodynamic analysis of the systems under investigation, the computation of fluid dynamic parameters, and the consideration of other possible effects on fluid flow under vertical, stabilizing and microgravity conditions. The specific experiments to be performed in a microgravity environment include the investigation of vapor transport and crystal growth phenomena of the GeSe-Xenon system and of the mass flux and growth of bulk and layer-type crystals of Hg sub (1-x) Cd sub x Te using HgI as a transport agent.

Wiedemeier, H.↗

A Mechanistic Study of Nucleate Boiling Under Microgravity Conditions

The overall objective of this work is to study nucleate boiling heat transfer under microgravity conditions in such a way that while providing basic knowledge of the phenomena, it also leads to development of simulation models and correlations that can be used as design tools for a wide range of gravity levels. In the study a building block type of approach is used and both pool and low velocity flow boiling are investigated. Starting with experiments using a single bubble, the complexity of the experiments is increased to two or three inline bubbles, to five bubbles placed on a two-dimensional grid. Finally, experiments are conducted where a large number of prescribed cavities nucleate on the heater and when a commercial surface is used. So far experiments have been conducted at earth normal gravity and in the reduced gravity environment of the KC-135 aircraft whereas experiments on the space station are planned. Modeling/complete numerical simulation of the boiling process is an integral part of the total effort. Experiments conducted with single bubbles formed on a nucleation site microfabricated on a polished silicon wafer show that for gravity levels (g) varying from 1.5g(sub e) to 0.01g(sub e), the bubble diameter at departure varies approximately as (g(sub e)/g)(exp 1/2) and the growth period as (g(sub e)/g). When bubbles merge either inline or in a plane, the bubble diameter at departure is found to be smaller than that obtained for a single bubble and shows a weaker dependence on the level of gravity. The possible reason is that as the bubbles merge they create fluid circulation around the bubbles, which in turn induces a lift force that is responsible for the earlier departure of the bubbles. The verification of this proposition is being sought through numerical simulations. There is a merger of two inline, three inline, and several bubbles in a plane in the low gravity environment of the KC-135 aircraft. After merger and before departure, a mushroom type of bubble with several stems attached to the heater surface is clearly evident. Local heat fluxes during growth and departure of a single bubble were also measured. It was found that during most of the growth period of the bubble, generally the wall heat flux decreased with time because of the increased dry area under the bubble. However, the heat flux increased rapidly just prior to departure of the bubble because of the transient conduction into the cold liquid rushing to fill the space vacated by the bubble as the bubble base shrinks. The measured heat fluxes at various radial locations are found to be in qualitative agreement with the numerical predictions. Single bubble studies at earth normal gravity have also been performed on surfaces oriented at different angles to the gravitational acceleration with flow parallel to the surface. It is found that in all cases the bubbles slide along the surface before lift-off from the surface. The lift force generated as a result of the relative motion between the sliding bubbles and the imposed flow is found to play an important role when the normal force due to buoyancy is reduced. An experimental apparatus for the study of the bubble behavior with imposed flow under reduced gravity conditions has been developed and will soon be employed for experiments in the KC-135 aircraft.

Dhir, V. K.↗

The boundary layer of Mars: Fluxes, stability, turbulent spectra, and growth of the mixed layer

Spectra of wind from high-frequency measurements in the Martian atmospheric surface layer, along with the diurnal variation of the height of the mixed surface layer, are calculated for the first time for Mars. Heat and momentum fluxes, stability, and z(sub 0) are estimated for early spring from a surface temperature model and from Viking Lander 2 temperatures and winds at 44 deg N, using Monin-Obukhov similarity theory. Flow distortion by the lander is also taken into account. Model spectra for two measuring heights and three surface roughnesses are calculated using the depth of the mixed layer and the surface-layer parameters. These experiments indicate that z(sub 0) probably lies between 1.0 and 3.0 cm, and most likely is closer to 1.0 cm. The spectra are adjusted to simulate aliasing and high-frequency rolloff, the latter caused by both the sensor response and the large Kolmogorov length on Mars. Since the spectral models depend on the surface parameters, including the estimated surface temperature, their agreement with the calculated spectra indicates that the surface-layer estimates are self-consistent. This agreement is especially noteworthy in that the inertial subrange is virtually absent in the Martian atmosphere at this height, due to the large Kolmogorov length scale. These analyses extend the range of applicability of terrestrial results and demonstrate that it is possible to estimate the effects of severe aliasing of wind measurements, to produce models that agree well with the measured spectra. The results show that similarity theory developed for Earth applies to Mars, and that the spectral models are universal.

Tillman, James E.↗

Garnet melt viscosity, surface tension and drainage

Good surface morphology and layer uniformity of LPE-grown Bi YIG films are favored by fast melt removal after growth. Three flux modifying oxides: MoO3, V2O3, and WO3 are compared with respect to their effect on viscosity, surface tension and melt drainage. All three oxides increased the viscosities of Bi-garnet melts, but the viscosities and drainage times of V2O3 and MoO3 modified melts were smaller than those of WO3 modified melts. The liquid-gas surface tension was found to be temperature independent. The drainage process was strongly temperature dependent, 40 to 60 kcal/mol, whereas the viscosities of melts had activation energies of 11 to 16 kcal/mol. Contact angles of 16 + or - 2 deg were measured on frozen melt drops.

Luther, L. C.↗

Analysis of soil and species composition

Measurements were made during May to October, 1987 and June to August, 1989 over a tallgrass prairie near Manhattan, Kansas. Soil at the experimental site is predominantly Dwight silty clay loam. The prairie was burned on 16 April 1987 and on 28 April 1989 to improve the mix of grasses and forbs. The experimental area was not grazed during 1986 - 1989. A summary of results are given for soil moisture and plant growth; momentum flux and canopy aerodynamic characteristics; evapotranspiration, components of energy balance and canopy conductance; modeling canopy stomatal conductance; canopy photosynthesis, photosynthetic efficiency and water use efficiency; modeling canopy photosynthesis; the carbon dioxide budget in a temperate grassland ecosystem; and photosynthesis and stomatal conductance related to reflectance on the canopy scale.

Verma, Shashi B.↗