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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Onboard Inert Gas Generation System/Onboard Oxygen Gas Generation System (OBIGGS/OBOGS) Study: Gas Separation Technology--State of the Art - Part 2

This purpose of this contract study task was to investigate the State of the Art in Gas Separation Technologies utilized for separating air into both nitrogen and oxygen gases for potential applications on commercial aircraft. The intended applications included: nitrogen gas for fuel tank inerting, cargo compartment fire protection, and emergency oxygen for passenger and crew use in the event of loss of cabin pressure. The approach was to investigate three principle methods of gas separation: Hollow Fiber Membrane (HFM), Ceramic Membrane (CM), and liquefaction: Total Atmospheric Liquefaction of Oxygen and Nitrogen (TALON). Additional data on the performance of molecular sieve pressure swing adsorption (PSA) systems was also collected and discussed. Performance comparisons of these technologies are contained in the body of the report.

Reynolds, Thomas L.↗

Onboard Inert Gas Generation System/Onboard Oxygen Gas Generation System (OBIGGS/OBOGS) Study: Aircraft System Requirements - Part 1

The purpose of this technology assessment is to define a multiphase research study program investigating Onboard Inert Gas Generation Systems (OBIGGS) and Onboard Oxygen Generation Systems (OBOGS) that would identify current airplane systems design and certification requirements (Subtask 1); explore state-of-the-art technology (Subtask 2); develop systems specifications (Subtask 3); and develop an initial system design (Subtask 4). If feasible, consideration may be given to the development of a prototype laboratory test system that could potentially be used in commercial transport aircraft (Subtask 5). These systems should be capable of providing inert nitrogen gas for improved fire cargo compartment fire suppression and fuel tank inerting and emergency oxygen for crew and passenger use. Subtask I of this research study, presented herein, defines current production aircraft certification requirements and design objectives necessary to meet mandatory FAA certification requirements and Boeing design and performance specifications. These requirements will be utilized for baseline comparisons for subsequent OBIGGS/OBOGS application evaluations and assessments.

Reynolds, Thomas L.↗

Flammable Gas Generation and Control at the Idaho Completion Project Legacy Combustible Gas Generation - 20191

On April 11, 2018, four drums containing transuranic waste at the Idaho National Laboratory underwent over-pressurization, ejecting their lids and spreading radiological waste within a facility. An investigation has found that waste in the drums generated methane gas, which contributed to the event. Subsequent to the investigation, the potential for drums to have methane and other flammable analytes whose concentrations could approach or exceed the lower flammability limit (LFL) and the adequacy of the controls to prevent or mitigate a possible deflagration was evaluated. An extensive review of the historical records was performed to determine how many drums exceed the LFL. The historical record identified a small quantity of drums that exceeded the LFL for xylene, hydrogen, and methane. The primary codified applicable code or standard for handling drums is 29 CFR 1910.120 (j) 'Handling Drums and Containers.' It is used throughout the commercial and government sector. This code is integrated throughout the Fluor Idaho safety management programs and procedures to control the Standard Industrial Hazards (SIHs) associated with drum and container handling. Example requirements include: - Drums and containers are inspected, and their integrity assured prior to being moved. - Site operations are organized to minimize the amount of drum or container movement. - When there is a reasonable possibility of flammable atmospheres being present, material handling equipment and hand tools are of the type to prevent sources of ignition. Drums and containers under pressure, as evidenced by bulging or swelling, are not moved until the cause for excess pressure is determined and appropriate containment procedures have been implemented to protect employees from explosive relief of the drum. Drums which exceed the WIPP FGA limit have NCRs associated with them. Once a drum fails flammable gas sampling, an NCR is initiated. The NCR drives placement into NCR dense pack rows. A standing order drives placement of the FGA failures to a single planer segregation location. These drums are not allowed for further processing or shipment until the NCR has been cleared. Once in the single planer rows, follow-up FGA testing is performed by CCP. The NCR is dispositioned by follow-up sampling occurring after adequate time has been provided for the gas to diffuse through the filter assembly, or, in some cases, the drums are repackaged into additional drums to reduce the source term. To date, the ICP project has performed approximately 1.5 million drums moves without a deflagration event due to combustible gas generation. Flammable gas generation in a transuranic waste drum is not unique to the ICP but is common across the DOE complex. Based on the experience at Idaho, application of industry standards is sufficient to control the risk of drum deflagration due to drum movements. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Gas Generation in Lithium Cells with High-Nickel Cathodes and Localized High-Concentration Electrolytes

High-nickel layered-oxide cathodes (LiNi x Mn y Co 1-x-y O 2 , x ≥ 0.8) exhibit high capacities, but also experience rapid capacity fade during cycling, and are susceptible to heat generation and gas release. Advanced electrolytes, such as localized high-concentration electrolytes (LHCE), substantially stabilize the cathode during cycling and have lower flammability than conventional electrolytes, but gas generation with these electrolytes is yet to be assessed. We demonstrate here that gas generation from a high-nickel cathode in an LHCE is half as much as in a conventional electrolyte at 4.4 V. The gas generation in LHCE is further reduced at 4.3 V, but the LHCE generates a similar amount of gas as the conventional electrolyte at 4.6 V. Neither electrolyte can prevent gas generation after cycling; cathodes after 200 cycles generate similar amounts of gas as pristine cathodes during high-voltage hold. Finally, it is shown that in both electrolytes, oxygen from the cathode lattice plays a critical role in gas generation.

25 ENERGY STORAGE↗

Design study of an advanced gas generator

A gas generator which can be ignited reliably during the initial start-up period and offers fairly uniform gas temperature at the exit was studied numerically. Various sizes and shapes of the mixing enhancement devices and their positions were examined to evaluate the uniformity of the exit gas temperature and the change of internal pressure drop incurred by introducing the mixing enhancement devices. By introducing a turbulence ring and a splash plate with an appropriate size and position, it was possible to obtain fairly uniform gas temperature distributions and a maximum gas temperature that is within the design limit temperature of 1600 R at the generator exit. However, with the geometry studied, the pressure drop across the generator was great, approximately 1150 psi, to satisfy the assigned design limit temperature. If the design limit temperature is increased to 1650 R, the pressure drop across the generator could be lowered by as much as 350 psi.

Kim, S.↗

Fastrac Gas Generator Testing

A rocket engine gas generator component development test was recently conducted at the Marshall Space Flight Center. This gas generator is intended to power a rocket engine turbopump by the combustion of Lox and RP-1. The testing demonstrated design requirements for start sequence, wall compatibility, performance, and stable combustion. During testing the gas generator injector was modified to improve distribution of outer wall coolant and the igniter boss was modified to investigate the use of a pyrotechnic igniter. Expected chamber pressure oscillations at longitudinal acoustic mode were measured for three different chamber lengths tested. High amplitude discrete oscillations resulted in the chamber-alone configurations when chamber acoustic modes coupled with feed-system acoustics modes. For the full gas generator configuration, which included a turbine inlet manifold, high amplitude oscillations occurred only at off-design very low power levels. This testing led to a successful gas generator design for the Fastrac 60,000 lb thrust engine.

Nesman, Tomas E.↗

Fastrac Gas Generator Testing

A rocket engine gas generator component development test was recently conducted at the Marshall Space Flight Center. This gas generator was intended to power a rocket engine turbopump by the combustion of Lox and RP-1. The testing demonstrated design requirements for start sequence, wall compatibility, performance, and stable combustion. During testing the gas generator injector was modified to improve distribution of outer wall coolant and the igniter boss was modified to investigate the use of a pyrotechnic igniter, Expected chamber pressure oscillations at longitudinal acoustic modes were measured for three different chamber lengths tested. High amplitude discrete oscillations occurred in the chamber-alone configurations when chamber acoustic modes coupled with feed-system acoustics modes. For the full gas generator configuration, which included the turbine inlet manifold simulator, high amplitude oscillations occurred only at off-design very low power levels. This testing led to a successful gas generator design for the Fastrac 60,000 lb thrust engine.

Nesman, Tomas E.↗

Liquid propellant gas generators

The design of gas generators intended to provide hot gases for turbine drive is discussed. Emphasis is placed on the design and operation of bipropellant gas generators because of their wider use. Problems and limitations involved in turbine operation due to temperature effects are analyzed. Methods of temperature control of gas turbines and combustion products are examined. Drawings of critical sections of gas turbines to show their operation and areas of stress are included.

Source record↗

Spin Start Line Effects on the J2X Gas Generator Chamber Acoustics

The J2X Gas Generator engine design has a spin start line connected near to the turbine inlet vanes. This line provides helium during engine startup to begin turbomachinery operation. The spin start line also acts as an acoustic side branch which alters the chamber's acoustic modes. The side branch effectively creates 'split modes' in the chamber longitudinal modes, in particular below the first longitudinal mode and within the frequency range associated with the injection-coupled response of the Gas Generator. Interaction between the spin start-modified chamber acoustics and the injection-driven response can create a higher system response than without the spin start attached to the chamber. This work reviews the acoustic effects of the spin start line as seen throughout the workhorse gas generator test program. A simple impedance model of the spin start line is reviewed. Tests were run with no initial spin start gas existing in the line, as well as being initially filled with nitrogen gas. Tests were also run with varying spin start line lengths from 0" to 40". Acoustic impedance changes due to different spin start gas constituents and line lengths are shown. Collected thermocouple and static pressure data in the spin start line was used to help estimate the fluid properties along the line length. The side branch impedance model was coupled to a chamber impedance model to show the effects on the overall chamber response. Predictions of the spin start acoustic behavior for helium operation are shown and compared against available data.

Kenny, R. Jeremy↗

Evaluation of Start Transient Oscillations with the J-2X Engine Gas Generator Assembly

During development of the gas generator for the liquid oxygen/liquid hydrogen propellant J-2X rocket engine, distinctive and oftentimes high-amplitude pressure oscillations and hardware vibrations occurred during the start transient of nearly every workhorse gas generator assembly test, as well as during many tests of engine system hardware. These oscillations appeared whether the steady-state conditions exhibited stable behavior or not. They occurred similarly with three different injector types, and with every combustion chamber configuration tested, including chamber lengths ranging over a 5:1 range, several different nozzle types, and with or without a side branch line simulating a turbine spin start gas supply line. Generally, two sets of oscillations occurred, one earlier in the start transient and at higher frequencies, and the other almost immediately following and at lower frequencies. Multiple dynamic pressure measurements in the workhorse combustion chambers indicated that the oscillations were associated with longitudinal acoustic modes of the combustion chambers, with the earlier and higher frequency oscillation usually related to the second longitudinal acoustic mode and the later and lower frequency oscillation usually related to the first longitudinal acoustic mode. Given that several early development gas generator assemblies exhibited unstable behavior at frequencies near the first longitudinal acoustic modes of longer combustion chambers, the start transient oscillations are presumed to provide additional insight into the nature of the combustion instability mechanisms. Aspects of the steadystate oscillations and combustion instabilities from development and engine system test programs have been reported extensively in the three previous JANNAF Liquid Propulsion Subcommittee meetings (see references below). This paper describes the hardware configurations, start transient sequence operations, and transient and dynamic test data during the start transient. The implications of these results on previous analyses and understanding of the combustion instability observed during steady-state conditions, especially the effects of injector influences, is discussed.

Hulka, J. R.↗

Combustion Stability of the Gas Generator Assembly from J-2X Engine E10001 and Powerpack Tests

Testing of a powerpack configuration (turbomachinery and gas generator assembly) and the first complete engine system of the liquid oxygen/liquid hydrogen propellant J-2X rocket engine have been completed at the NASA Stennis Space Center. The combustion stability characteristics of the gas generator assemblies on these two systems are of interest for reporting since considerable effort was expended to eliminate combustion instability during early development of the gas generator assembly with workhorse hardware. Comparing the final workhorse gas generator assembly development test data to the powerpack and engine system test data provides an opportunity to investigate how the nearly identical configurations of gas generator assemblies operate with two very different propellant supply systems one the autonomous pressure-fed test configuration on the workhorse development test stand, the other the pump-fed configurations on the powerpack and engine systems. The development of the gas generator assembly and the elimination of the combustion instability on the pressure-fed workhorse test stand have been reported extensively in the two previous Liquid Propulsion Subcommittee meetings 1-7. The powerpack and engine system testing have been conducted from mid-2011 through 2012. All tests of the powerpack and engine system gas generator systems to date have been stable. However, measureable dynamic behavior, similar to that observed on the pressure-fed test stand and reported in Ref. [6] and attributed to an injection-coupled response, has appeared in both powerpack and engine system tests. As discussed in Ref. [6], these injection-coupled responses are influenced by the interaction of the combustion chamber with a branch pipe in the hot gas duct that supplies gaseous helium to pre-spin the turbine during the start transient. This paper presents the powerpack and engine system gas generator test data, compares these data to the development test data, and provides additional combustion stability analyses of the configurations.

Hulka, J. R.↗

Design and assembly of a catalyst bed gas generator for the catalytic decomposition of high concentration hydrogen peroxide propellants and the catalytic combustion of hydrocarbon/air mixtures

A method for designing and assembling a high performance catalyst bed gas generator for use in decomposing propellants, particularly hydrogen peroxide propellants, for use in target, space, and on-orbit propulsion systems and low-emission terrestrial power and gas generation. The gas generator utilizes a sectioned catalyst bed system, and incorporates a robust, high temperature mixed metal oxide catalyst. The gas generator requires no special preheat apparatus or special sequencing to meet start-up requirements, enabling a fast overall response time. The high performance catalyst bed gas generator system has consistently demonstrated high decomposition efficiency, extremely low decomposition roughness, and long operating life on multiple test articles.

Lohner, Kevin A.↗

Low-Cost Gas Generator and Ignitor

A gas generator and ignitor assembly for powering a turbine of a turbopump assembly for a rocket engine comprises an injector and a combustion chamber. the injector having a body member including a fuel inlet and an oxidizer inlet spaced one from the other and communicating with respective radially spaced apart annular members in the body member. Three annuli communicate with the fuel inlet and two annuli communicate with the oxidizer inlet. the annuli which communicates with the oxidizer being positioned between pairs of the other annuli, The body member is enclosed by a plate having an array of bores arranged in two series with three radially spaced apart groups of circular rows in each series. The outer series has 28 groups of triplet bores while the inner series has 14 groups of triplet bores. The annuli which communicate with oxidizer feed bores of each series that are between the other bores of a triplet. the latter bores communicating with annuli that communicate with fuel. The inner and outer bores of the triplets of each series are inclined relatively to each other and to the third bore of the triplet so that fuel and oxidizer atomizes as it is sprayed into the inlet of the combustion chamber where the propellants are mixed. and burned. The burning of the propellants is effected by ignition of a plug of solid propellant fuel mounted to communicate with the interior of the combustion chamber.

Henry J Dennis, Jr↗

Pyrotechnically Actuated Gas Generator Utilizing Aqueous Methanol

A gas-generating device was developed to supplement the ram-air inflation of a supersonic ballute. The device is designed to initially pressurize the ballute following deployment, exposing and orienting its ram-air inlets to free-stream air for complete inflation. The supplemental pressurization decreases the total inflation time, and increases the likelihood of a successful inflation. The device contains a reservoir filled with an aqueous mixture of methanol that, when released in to the interior of the ballute, rapidly vaporizes due to the low ambient pressure. Upon activation of the device, a pair of redundant ring mechanisms initiate pyrotechnic charges that pressurize and rupture the reservoir, resulting in ejection of the methanol in to the ballute. In addition to its role in inflation, the device serves as the structural connection to the ballute. Analytical models were developed for the inflation capability of the device, which were verified using vacuum chamber testing of developmental hardware. Static, deployment, and environmental testing demonstrated the functionality of the ring mechanism and reservoir under several temperature and pressure conditions. Finally, the device was successfully operated during the first Supersonic Flight Dynamics Test (SFDT) of NASA's Low Density Supersonic Decelerator (LDSD) project. The design architecture is scalable to accommodate different quantities of gas generation, can be adjusted to operate in a variety of temperature and atmospheric pressure regimes, and provides a robust device that may be installed with minimal risk to personnel or hardware.

IA↗

Hydrazine Gas Generator Program

The design and fabrication of a flight gas generator for the space shuttle were investigated. Critical performance parameters and stability criteria were evaluated as well as a scaling laws that could be applied in designing the flight gas generator. A test program to provide the necessary design information was included. A structural design, including thermal and stress analysis, and two gas generators were fabricated based on the results. Conclusions are presented.

Kusak, L.↗

Development of a NASA standard gas generator

The goals of the NASA Standard Gas Generator (NSGG) Program are to create a NASA standard gas generating cartridge, characterize its performance, and make it readily available to users. A cartridge within the same envelope as the NASA Standard Initiator (NSI) has the greatest potential use. This potential use is described in viewgraph form. Our approach for NSGG development and qualification was planned to be conducted in several phases. Test methods were developed to evaluate output performance for a variety of potential applications. A feasibility study using modified NSI's was accomplished. Preliminary and final development will be conducted with a delta qualification to evaluate the effects of manufacturing lots and environments. Feasibility study results, feasibility study conclusions, and future plans are presented.

Bement, Laurence J.↗

Evaluation of Hydrogen Gas Generation and Permeation in the 9979 Type AF Shipping Package

The 9979 Type AF Shipping Packaging is a cost-effective radioactive material package designed by Savannah River National Laboratory (SRNL) that consists of two primary components: a foamed outer drum for structural protection and an inner containment drum. The packaging was designed to transport Highly Enriched Uranium (HEU), Low Enriched Uranium (LEU), and other isotopes not exceeding a Type A quantity. These contents have the potential to generate flammable hydrogen gas during transport due to the degradation of hydrogenous materials (e.g. water vapor, plastics, etc) by high-energy alpha radiation. Since 10 CFR 71.43(h) prohibits the incorporation of packaging features explicitly designed for continuous venting, alternative justification was required to demonstrate that the requirements of 10 CFR 71.43(d) for negligible reactions between packaging components and contents were satisfied. An analysis was performed to demonstrate that the potential for hydrogen gas generation over a one-year period was limited by the effects of permeation through the packaging materials. The rate of hydrogen collection was evaluated for both the inner containment drum and the outer structural drum under 10 CFR 71.71 Normal Conditions of Transport (NCT). The analysis concludes that the Lower Flammability Limit (LFL) for hydrogen gas will not be reached in a one-year shipping period assuming a minimum void volume is maintained within the drum.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Investigation of a catalytic gas generator for the Space Shuttle APU

An investigation was conducted to establish the capability of a monopropellant hydrazine catalytic gas generator to meet the requirements specified for the Space Shuttle APU. Detailed analytical and experimental studies were conducted on potential problem areas including long-term nitriding effects on materials, design variables affecting catalyst life, vehicle vibration effects, and catalyst oxidation/contamination. A full-scale gas generator, designed to operate at a chamber pressure of 750 psia and a flow rate of 0.36 lbm/sec, was fabricated and subjected to three separate life test series. The objective of the first test series was to demonstrate the capability of the gas generator to successfully complete 20 simulated Space Shuttle missions in steady-state operation. The gas generator was then refurbished and subjected to a second series of tests to demonstrate the pulse-mode capability of the gas generator during 20 simulated missions. The third series of tests was conducted with a refurbished reactor to further demonstrate pulse-mode capability with a modified catalyst bed.

Emmons, D. L.↗