Search NASA⌕ Search

SEARCH · Search NASA

Results for “graphite crystal”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Graphite crystals in catalytically-graphitized glass-like carbon

Catalytic graphitization of glass-like carbon leads to enhanced growth of micro-sized graphitic crystals with unusual shapes of wires, filaments, tubes, rods, whiskers, and spirals. Similar particles with axial symmetry are also found in pure glass-like carbon heat-treated at high temperatures. Nonetheless, the presence of a graphitization catalyst, Si in this case, in the heat-treatment process supports the transformation of porous, disordered carbon structure towards the graphitic atomic order and the formation of manifold peculiar polyhedral wires and particles of geometry distinct from the plate-like shape typical for conventional graphite. In contrast to conventional carbon nanotubes and fibers, the graphene layers are stacked perpendicular to the tube axis, while the size of the most common tube fibers can reach up to 10 μm in diameter and 100 μm in length. X-ray diffraction, Raman spectroscopy, scanning and transmission electron microscopy, small-angle X-ray scattering combined with complementary techniques have been used to characterize the structure of the glass-like carbon derived from furfuryl alcohol catalytically-graphitized using Si particles at 3000 °C. Finally, since control of graphite shape is vital to achieving the level of performance required in contemporary applications, the obtained results demonstrate that the catalytic graphitization method may be employed to produce filamentous graphite crystals.

36 MATERIALS SCIENCE↗
NASA NTRS1976

The graphite crystal X-ray spectrometer on OSO-8

The large-area graphite crystal X-ray spectrometer aboard the OSO-8 satellite is described. The instrument can be used to measure continuum profiles over the energy band from 2 to 8 keV with a resolution of several tens of electron volts and to detect narrow line emission from strong X-ray sources with a limiting sensitivity (3 sigmas) of the order of 10-eV, equivalent width for a three-day observing period.

Kestenbaum, H. L.↗
NASA NTRS1991

Predicted performance of the lithium scattering and graphite crystal polarimeter for the Spectrum-X-Gamma mission

X-ray scattering from a lithium disk and Bragg reflection from a mosaic graphite crystal can be exploited to measure the linear polarization of radiation emitted from cosmic X-ray sources. The sensitivity is greatly enhanced if these polarimeters are placed at the focus of an X-ray telescope. Such devices form two of the three components of the Stellar X-Ray Polarimeter experiment scheduled to fly on the Spectrum-X-Gamma mission. The experiment will reside at the focus of one of the SODART X-ray telescopes. The expected on-axis performance of these two components of the Stellar X-Ray Polarimeter experiment based on detailed Monte-Carlo simulation is described. Various systematic effects, both external and internal to the experiment, that must be considered in order to properly design and utilize the experiment are also discussed.

Weisskopf, M. C.↗
NASA NTRS1972

A graphite crystal polarimeter for stellar X-ray astronomy.

The first crystal X-ray polarimeter to be used for X-ray astronomy is described. Polarization is measured by modulation of the X rays diffracted at an average 45 deg glancing angle from large, curved graphite crystal panels as these rotate about an axis parallel to the incident X-ray flux. Arrangement of the crystal panels, the design of the detector, and the signal-processing circuitry were optimized to minimize systematic effects produced by off-axis pointing of the rocket and cosmic ray induced events. The in-flight performance of the instrument in relation to the observed background signal is discussed.

Weisskopf, M. C.↗
NASA NTRS1980

Data reduction and analysis for the graphite crystal X-ray spectrometer and polarimeter experiment flown aboard OSO-8 spacecraft

The documentation and software programs developed for the reception, initial processing (quickbook), and production analysis of data obtained by solar X-ray spectroscopy, stellar spectroscopy, and X-ray polarimetry experiments on OSO-8 are listed. The effectiveness and sensitivity of the Bragg crystal scattering instruments used are assessed. The polarization data polarimetric data obtained shows that some X-ray sources are polarized and that a larger polarimeter of this type is required to perform the measurements necessary to fully understand the physics of X-ray sources. The scanning Bragg crystal spectrometer was ideally suited for studying rapidly changing solar conditions. Observations of the Crab Nebula and pulsar, Cyg X-1, Cyg X-2, Cyg X-3, Sco X-1, Cen X-3, and Her X-1 are discussed as well as of 4U1656-53 and 4U1820-30. Evidence was obtained for iron line emission from Cyg X-3.

Novick, R.↗
NASA NTRS1994

Igneous petrology of the new ureilites Nova 001 and Nullarbor 010

The Nova 001 (= Nuevo Mercurio (b)) and Nullarbor 010 meteorites are ureilites, both of which contain euhedral graphite crystals. The bulk of the meteorites are olivine (Fo79) and pyroxenes (Wo9En73Fs18, Wo3En77Fs20), with a few percent graphite and minor amounts of troilite, Ni-Fe metal, and possibly diamond. The rims of olivine grains are reduced (to Fo91) and contain abundant blebs of Fe metal. Silicate mineral grains are equant, anhedral, up to 2 mm across, and lack obvious preferred orientations. Euhedral graphite crystals (to 1 mm x 0.3 mm) are present at silicate grain boundaries, along boundaries and protruding into the silicates, and entirely within silicate mineral grains. Graphite euhedra are also present as radiating clusters and groups of parallel plates grains embedded in olivine; no other ureilite has comparable graphite textures. Minute lumps within graphite grains are possible diamond, inferred to be a result of shock. Other shock effects are limited to undulatory extinction and fracturing. Both ureilites have been weathered significantly. Considering their similar mineralogies, identical mineral compositions, and identical unusual textures, Nova 001 and Nullarbor 010 are probably paired. Based on olivine compositions, Nova 001 and Nullarbor 010 are in Group 1 (FeO-rich) of Berkley et al. (1980). Silicate mineral compositions are consistent with those of others known ureilites. The presence of euhedral graphite crystals within the silicate minerals is consistent with an igneous origin, and suggests that large proportions of silicate magma were present locally and crystallized in situ.

Triman, Allan H.↗
NASA NTRS1956

Energy of Cohesion, Compressibility, and the Potential Energy Functions of the Graphite System

The lattice summations of the potential energy of importance in the graphite system have been computed by direct summation assuming a Lennard‐Jones 6–12 potential between carbon atoms. From these summations, potential energy curves were constructed for interactions between a carbon atom and a graphite monolayer, between a carbon atom and a graphite surface, between a graphite monolayer and a semi‐infinite graphite crystal and between two graphite semi‐infinite crystals. Using these curves, the equilibrium distance between two isolated physically interacting carbon atoms was found to be 2.70 a, where a is the carbon‐carbon distance in a graphite sheet. The distance between a surface plane and the rest of the crystal was found to be 1.7% greater than the interlayer spacing. Theoretical values of the energy of cohesion and the compressibility were calculated from the potential curve for the interaction between two semi‐infinite crystals. They were ΔE c = —330 ergs/cm 2 and β = 3.18×10 —12 cm 2 /dyne, respectively. These compared favorably with the experimental values of ΔE c = —260 ergs/cm 2 and β = 2.97×10 —2 cm 2 /dyne.

L A Girifalco↗
NASA NTRS1992

Electronic and total energy properties of ternary and quaternary semiconductor compounds, alloys, and superlattices: Theoretical study of Cu/graphite bonding

The goals of the research were to provide a fundamental science basis for why the bonding of Cu to graphite is weak, to critically evaluate the previous analysis of the wetting studies with particular regard to the values used for the surface energies of Cu and graphite, and to make recommendations for future experiments or other studies which could advance the understanding and solution of this technological problem. First principles electronic structure calculations were used to study the problem. These are based on density functional theory in the local density approximation and the use of the linear muffin-tin orbital band structure method. Calculations were performed for graphite monolayers, single crystal graphite with the hexagonal AB stacking, bulk Cu, Cu(111) surface, and Cu/graphite superlattices. The study is limited to the basal plane of graphite because this is the graphite plane exposed to Cu and graphite surface energies and combined with the measured contact angles to evaluate the experimental adhesion energy.

Lambrecht, Walter R. L.↗
NASA NTRS1991

Bragg crystal polarimeter for the Spectrum-X-Gamma mission

A Bragg crystal polarimeter for the focal plane of the SODART telescope on the Spectrum-X-Gamma mission is being designed. A mosaic graphite crystal will be oriented at 45 deg to the optic axis of the telescope, thereby preferentially reflecting those X-rays which satisfy the Bragg condition and have electric vectors that are perpendicular to the plane defined by the incident and reflected photons. The reflected X-rays will be detected by an imaging proportional counter with the image providing direct X-ray aspect information. The crystal will be about 50 microns thick to allow X-rays with energies of 4 keV or greater to be transmitted to a lithium block mounted below the graphite. The lithium is used to measure the polarization of these high energy X-rays by exploiting the polarization dependence of Thomson scattering. The development of thin mosaic graphite crystals is discussed and recent reflectivity, transmission, and uniformity measurements are presented.

Holley, J.↗
NASA NTRS1978

X-ray spectra of A0620-00 obtained with a Bragg crystal spectrometer

The OSO 8 graphite crystal spectrometer was used to obtain observations, in October 1975 and January 1976, of the transient X-ray source A0620-00, which yield upper limits of no more than about 10 eV to the equivalent widths of narrow emission lines of Si XIII, Si XIV, S XV, and S XVI. Photoionization is unlikely to alter the principal conclusion that the electron scattering in the source is substantial. High-resolution spectra obtained in October 1975 reveal a featureless continuum which is better characterized as blackbody (kT about 0.5 keV) than as thin bremsstrahlung emission.

Long, K. S.↗
NASA NTRS1985

A micrographic and gravimetric study of intercalation and deintercalation of graphite fibers

Intercalation and deintercalation of Union Carbide P-100 graphite fibers with liquid and vaporous bromine was studied gravimetrically and microscopically. The mass of the bromine intercalated fibers was found to be 17 to 20 percent greater than their pristine counterpart. This variation decreased to 17 to 18 percent after heating in air for 3 days at 200 C and to 14.5 to 18 percent after 6 days of 260 C heating. The fiber length did not change throughout the experiment. The fiber diameter increased during intercalation and decreased slightly upon deintercalation but was not affected by heating to 260 C for 3 days in air. Comparing the mass and volume data to those with highly oriented pyrolitic graphite or natural single crystal graphite suggested the possibility that the intercalated P-100 fibers could be mostly stage 4.

Hung, C. C.↗
NASA NTRS1976

Stellar crystal X-ray spectroscopy on OSO-8

The large-area graphite crystal X-ray spectrometer on the OSO-8 satellite is described, and its response to stellar line and continuum radiation is discussed. A high resolution X-ray spectrum of Sco X-1 obtained from a preliminary analysis of quick look data shows a strong, smooth continuum with an absence of emission or absorption features over the energy range 2.2 to 8 keV. Upper limits are set on narrow line emission from highly ionized states of S, Ca, and Fe.

Kestenbaum, H. L.↗
NASA NTRS1975

Focusing crystal polarimeter designed for X-ray polarimetry - Construction and performance

A method for the construction of a graphite crystal polarimeter designed for measuring linear polarization of X-ray continuum sources is described. The dependence of reflected intensity upon the polarization direction of the incident beam at Bragg angles of 45 deg is used to measure the polarization. The particular instrument described was designed for a satellite X-ray polarimeter. By using a focusing parabolic surface instead of a nonfocusing flat crystal, the signal-to-background ratio is improved by a factor of 30 as compared to a flat crystal polarimeter of the same effective area. The focusing properties of the reflector were tested both optically and with X-rays. The performance of the instrument as a polarimeter was tested with a continuum X-ray source of small polarization, which was independently measured by a single flat crystal polarimeter. The agreement between the two measurements is excellent, indicating that the instrument can measure polarizations as low as 0.3%.

Toraskar, J. R.↗
NASA NTRS1990

Carbon-rich aggregates in type 3 ordinary chondrites - Characterization, origins, and thermal history

Carbon-rich aggregates from three type 3.4-3.6 ordinary chondrites and two chondritic clasts have been characterized in detail, using TEM techniques. The aggregates in all the meteorites studied range in size from 5-1000 microns and consist of a fine scale intergrowth of poorly graphitized carbon, amorphous carbon, Fe,Ni metal, and minor chromite. Contrary to previous reports, well-crystallized graphite and magnetite are absent. The association of Fe,Ni metal and carbonaceous material suggests that the original carbonaceous material may have formed by Fischer-Tropsch (FT) type reactions at low temperatures (less than 400 K), possibly in the solar nebula. This carbonaceous material probably consisted of a complex mixture of hydrocarbons, kerogen-like material, and other complex organic molecules. The aggregates were subsequently accreted onto the ordinary chondrite parent bodies and underwent planetary thermal processing which resulted in the catalytic graphitization of hydrocarbons, in the presence of Fe,Ni metal, to produce poorly graphitized carbon. None of the meteorites studied experienced temperatures sufficiently high to produce crystalline, ordered graphite. Using the empirical geothermometer of Rietmeijer and Mackinnon (1985), the measured d(002) spacings of poorly graphitized carbon show that graphitization occurred at temperatures between 300 and 450 C. This range of temperatures is significantly lower than the generally quoted metamorphic temperatures for type 3.4-3.6 ordinary chondrites (about 450-500 C).

Brearley, Adrian J.↗
NASA NTRS1977

OSO-8 X-ray polarimeter and Bragg crystal spectrometer observations

Results are discussed for observations of the Crab Nebula, Cyg X-1, and Cyg X-2 with the focusing mosaic graphite crystal X-ray polarimeter aboard OSO-8 as well as for observations of A0620-00 with the Bragg crystal spectrometer aboard the same satellite. The observed X-ray polarization of the Crab Nebula is shown to be in agreement with a previous measurement of the optical polarization and to confirm with very high confidence the earlier conclusion that the X-ray emission occurs by the synchrotron process. No evidence is found for polarization of X-rays from Cyg X-1, but a preliminary result of 4.8% + or 1.0% polarization at an energy of 2.6 keV and a position angle of 141.7 + or - 6.6 deg is reported for Cyg X-2. It is noted that this value is within the range expected for accretion disks. The spectrometry of A0620-00 yielded a continuous spectrum that can be accurately fitted with a thermal bremsstrahlung spectrum at a temperature of 15 million K.

Novick, R.↗
NASA NTRS1990

On the performance of the scattering and crystal polarimeters for the Spectrum-X-Gamma mission

X-ray scattering from a lithium disk and Bragg reflection from a mosaic graphite crystal can be exploited to measure the linear polarization of radiation emitted from cosmic X-ray sources. The sensitivity is enhanced if the polarimeters are placed at the focus of an X-ray telescope. Such devices form two of the components of the Stellar X-ray Polarimeter experiment scheduled to fly on the Spectrum-X-Gamma mission. The expected on-axis performance of the two components is described based on detailed Monte Carlo simulations. The polarimetry experiment is expected to provide sensitive measurements of linear polarization for many cosmic X-ray sources. The nature and utility of such observations is described for pulsing X-ray sources such as the Crab pulsar and Her X-1.

Elsner, R. F.↗