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At least 19 records

Enhanced Groundwater Flow on and Below Vera Rubin Ridge, the Murray Formation, Gale Crater: Evidence from Thermochemical Modeling.

NASA’s Mars Science Laboratory Curiosity rover has been exploring Vera Rubin ridge (VRR), part of the Murray formation in Gale crater, Mars, between sol 1809 and 2302. Evidence for Fe-oxides and phyllosilicates in mineralogical and geochemical data for this region was returned by Curiosity [1-5]. We applied thermochemical modeling to con-strain the formation conditions of the phyllosilicate-hematite assemblage identified on and below VRR. Average alteration compositions for the Murray formation on and below VRR were derived using CheMin and APXS data. These compositions were reacted with Gale Portage Water (GPW) between 25–100 °C and for 10% and 50% Fe3+/Fetot of the host rock [6]. Here we summarize models run at 50 °C and 10% Fe3+/Fetot for alteration compositions derived from Murray host rock compositions.

Turner, S. M. R.↗

Fire Station #2, Former Sewage Treatment Plant #17, and Towway Area-SWMU 114 PFAS Site Assessment Progress Report Kennedy Space Center, Florida

This PFAS Site Assessment Progress Report (SAPR) presents the findings of the 2022 PFAS investigation conducted from November 2021 through August 2022 at Solid Waste Management Unit (SWMU) 114 located within Kennedy Space Center (KSC), Florida. SWMU 114 includes area around Fire Station #2, Former Sewage Treatment Plant #17, the southern portion of the Shuttle Landing Facility Runway, Remote Launch Vehicle Hangar, and the Towway area. Fire Station #2 was constructed in 2008 and is currently active, housing fire station personnel and equipment, including aqueous film forming foam (AFFF). Releases of AFFF has occurred at SWMU 114. Previous environmental assessments have been performed at SWMU 114, including soil, groundwater, and surface water sampling for volatile organic compounds, polycyclic aromatic hydrocarbons, total petroleum hydrocarbons, and metals. No active remediation has been performed at the SWMU 114. PFAS site assessment field activities were conducted at SWMU 114 from November 2021 through August 2022. During the 2021-2022 Site Assessment, 124 direct-push samples were collected from 27 locations, 17 surface water samples were collected from 15 locations, 41 groundwater samples were collected from 37 newly installed monitoring wells, five concrete samples were collected from four locations, and one asphalt sample was collected. Additionally, two soil borings were advanced to 60 feet for lithologic descriptions, ten staff gauges were installed, and one round of water level measurements were collected from monitoring wells and staff gauges for groundwater flow determination. All groundwater and surface water samples were analyzed for 25 PFAS analytes by USEPA Method 537M. Concrete, and asphalt samples were analyzed by synthetic precipitation leaching procedure (SPLP) PFAS analysis by USEPA Modified Method 537M. Groundwater results were compared to the most recent Regional Screening Levels (RSLs) published by USEPA for residential tap water (USEPA, 2022a) to determine the extent of PFAS contamination at SWMU 114 for six PFAS analytes (PFOA, PFNA, PFBS, PFHxS, PFOS, and GenX). Surface water results were compared to the FDEP surface water screening levels (SW SLs) (FDEP, 2020) for PFOA and PFOS. The PFAS investigation concluded that groundwater exceeding RSLs extends east and south to Banana Creek and west to approximately the center of the SLF runway. The extent of PFAS is approximated to the north, to an area between Sharkey Road and Astronaut Road, where samples below the RSLs do not fully bound SWMU 114. At least two distinct PFAS source areas are located near Fire Station #2 and along Towway, at S114-MW0007S, within SWMU 114. Groundwater head measurements indicate that flow at SWMU 114 is generally similar across the shallow and intermediate water tables. A northeast to southwest trending groundwater divide is located near the middle of Towway where groundwater southeast of the divide flows to the south and groundwater northwest of the divide flows to the west. The groundwater divide generally separates the two areas of higher PFAS concentrations. Surface water samples indicated concentrations of PFOS above the SW SLs in surface water bodies across the site. Further assessment and sampling are required to better understand the interaction between groundwater and surface water at SWMU 114. Concrete and asphalt samples collected confirm that a significant release of AFFF occurred near the stormwater pond northwest of Fire Station #2. Additional concrete samples surrounding Fire Station #2 and at the northwest and southeast edges of the SLF tarmac indicate elevated PFOS concentrations. These results indicate that discharges of AFFF in these locations have infiltrated into asphalt and concrete and may act as a continuing source of PFAS to groundwater and surface water after rain events. Additional direct-push samples are required to delineate PFAS at SWMU 114. Samples may need to extend beyond the Former SLF Rescue Building and Morpheous Test Site to delineate PFAS in groundwater. Monitoring wells should be sampled and gauged quarterly to determine if seasonal impacts are observable, especially in shallow wells near surface water features. Furthermore, surface water samples should be collected from additional ditches to further define the extent of surface water impacts at SWMU 114 and extending along the SLF runway. Staff gauges should be gauged quarterly with groundwater gauging to determine surface water flow and interaction with groundwater. The PFAS sampling results and path forward for SWMU 114 were presented to the KSC Remediation Team in October 2022. Once the PFAS SAPR is approved, it will be submitted to the Florida Department of Environmental Protection.

Howard Franklin Fowler↗

A groundwater convection model for Rio Grande rift geothermal resources

It has been proposed that forced convection, driven by normal groundwater flow through the interconnected basins of the Rio Grande rift is the primary source mechanism for the numerous geothermal anomalies along the rift. A test of this concept using an analytical model indicates that significant forced convection must occur in the basins even if permeabilities are as low as 50-200 millidarcies at a depth of 2 km. Where groundwater flow is constricted at the discharge areas of the basins forced convection can locally increase the gradient to a level where free convection also occurs, generating surface heat flow anomalies 5-15 times background. A compilation of groundwater data for the rift basins shows a strong correlation between constrictions in groundwater flow and hot springs and geothermal anomalies, giving strong circumstantial support to the convection model.

Morgan, P.↗

Representation of Stormflow and a More Responsive Water Table in a TOPMODEL-Based Hydrology Model

This study presents two new modeling strategies. First, a methodology for representing the physical process of stormflow within a TOPMODEL framework is developed. In using this approach, discharge at quickflow time scales is simulated and a fuller depiction of hydrologic activity is brought about. Discharge of water from the vadose zone is permitted in a physically realistic manner without a priori assumption of the level within the soil column at which stormflow saturation can take place. Determination of the stormflow contribution to discharge is made using the equation for groundwater flow. No new parameters are needed. Instead, regions of near saturation that develop during storm events, producing vertical recharge, are allowed to contribute to soil column discharge. These stormflow contributions to river runoff, as for groundwater flow contributions, are a function of catchment topography and local hydraulic conductivity at the depth of these regions of near saturation. The second approach improves groundwater flow response through a reduction of porosity and field capacity with depth in the soil column. Large storm events are better captured and a more dynamic water table develops with application of this modified soil column profile (MSCP). The MSCP predominantly reflects soil depth differences in upland and lowland regions of a watershed. Combined, these two approaches - stormflow and the MSCP - provide a more accurate representation of the time scales at which soil column discharge responds and a more complete depiction of hydrologic activity. Storm events large and small are better simulated, and some of the biases previously evident in TOPMODEL simulations are reduced.

Shaman, Jeffrey↗

Role of groundwater in formation of Martian channels

A global 3-D model of groundwater flow has been used to study possible behavior of groundwater on Mars and its role in creating fluvial features. Conclusions drawn from an earlier 2-D groundwater model are supplemented and expanded. Topical headings are discussed as follows: timescales of groundwater flow; wet areas on Mars and location of outflow channels; implications for valley networks; the enigma of Hellas; absence of fluvial or periglacial features on Syrtis Major; development of chaotic terrain and associated outflow channels; and structurally controlled valley networks.

Howard, Alan D.↗

A Martian global groundwater model

A global groundwater flow model was constructed for Mars to study hydrologic response under a variety of scenarios, improving and extending earlier simple cross sectional models. The model is capable of treating both steady state and transient flow as well as permeability that is anisotropic in the horizontal dimensions. A single near surface confining layer may be included (representing in these simulations a coherent permafrost layer). Furthermore, in unconfined flow, locations of complete saturation and seepage are determined. The flow model assumes that groundwater gradients are sufficiently low that DuPuit conditions are satisfied and the flow component perpendicular to the ground surface is negligible. The flow equations were solved using a finite difference method employing 10 deg spacing of latitude and longitude.

Howard, Alan D.↗

Wilson Corners SWMU 001 2019-2020 Annual Long-Term Monitoring Report Kennedy Space Center, Florida

This report presents a summary of the long-term monitoring (LTM) activities that occurred in 2019 and 2020 at Wilson Corners, Solid Waste Management Unit 001, at the John F. Kennedy Space Center (KSC), Florida. The site is monitored under KSC’s Resource Conservation and Recovery Act Corrective Action Program. Adaptive site management is being utilized through ongoing assessment, design, and interim measures. This approach also meets the requirements of Chapter 62-780, Florida Administrative Code. The goal of LTM at this site is threefold: to determine groundwater flow characteristics, monitor the downgradient concentration trends, and monitor select locations internal to the groundwater plume. Every 5 years, upgradient and side-gradient monitoring wells are sampled to verify delineation. The last time this was performed was in 2015. Sampling of these wells in 2020 was replaced with the direct push technology investigations in October 2020 and April 2021. The activities presented in this report include three field events: (1) December 2019 -groundwater gauging of 38 monitoring wells and sampling of 36 monitoring wells; (2) May 2020 - groundwater sampling of 7 monitoring wells; and (3) December 2020 - groundwater gauging of 49 monitoring wells and sampling of 43 monitoring wells. During the December 2019 and May 2020 events, monitoring wells were sampled using passive diffusion bags and were analyzed for a “full list” of volatile organic compounds (VOCs), including Freon 113. During the December 2020 event, the low flow sampling method was used, and samples were analyzed for a “select list” of VOCs, including Freon 113. The following conclusions can be made based on the 2019 and 2020 LTM results: •In December 2019 and December 2020, groundwater flow for the site was generally to the west with the individual zones only varying by occasional northerly and southerly components. This is generally consistent with historical observations at the site. •The GCTL plume continues to extend both horizontally and vertically beyond our current monitoring well network. •The vertical extent of VOCs was historically generally delineated by monitoring wells screened greater than 48 feet bls. The results from the two vertical extent monitoring wells WILC-MW0078 and WILC-MW0130 that were sampled during the 2019 and 2020 LTM indicate that groundwater VOC concentrations in both wells were greater than the GCTL. •Freon 113 was not detected above GCTLs during the 2019 and 2020 LTM events. Based on groundwater sampling activities performed during this reporting period, including recent DPT groundwater sampling conducted for the implementation of an air sparge system, the following recommendations are provided: •Install 10 new monitoring wells, which will be sampled along with 49 existing monitoring wells, to assist with delineation of the low concentration plume. The wells are listed inTable 4-1, and the proposed locations are presented on Figures4 -1 through 4-5. (Figures 4-1, 4-2, 4-3, and 4-5 also show updated plumes and proposed performance monitoring well locations. This information will be discussed and presented under a separate cover.) •Modify the annual LTM sampling plan as presented inTable 4-1. •Sampling for future events at the site will be conducted using low flow pumping methods. The next annual LTM sampling event is currently planned for December 2021. Please note the 10 new monitoring wells will not be installed before this event but will be installed as part of the upcoming IM construction and will be sampled during baseline sampling, along with the 49 existing monitoring wells. Following this sampling event, it is recommended that the Annual LTM be combined with the performance monitoring under the IM implementation, and LTM be temporarily discontinued. Objectives of the 2021 LTM are to: (i) evaluate groundwater gradient and flow direction by collecting depth to water measurements from LTM wells; (ii) continue monitoring the peripheral VOC trends in the northern, southern, and western portions of the site by monitoring existing wells and installing and monitoring new wells as recommended; and (iii) monitor select internal plume wells.

Jennifer Lynn Joyal↗

Wilson Corners Solid Waste Management Unit (SWMU) 001: 2021 Annual Long-Term Monitoring Report, Kennedy Space Center, Florida

This report presents a summary of the long-term monitoring (LTM) activities that occurred in 2021 at Wilson Corners, Solid Waste Management Unit (SWMU) 001, at Kennedy Space Center (KSC), Florida. The site is monitored under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action Program. Adaptive site management is being utilized through ongoing assessment, design, and interim measures (IM). Annual LTM of the groundwater is also being conducted at the site. This approach also meets the requirements of Chapter 62-780, Florida Administrative Code (F.A.C.). The goal of LTM at this site is threefold: to determine groundwater flow characteristics, monitor the downgradient concentration trends, and monitor select locations internal to the groundwater plume. Every 5 years, upgradient and side-gradient monitoring wells are sampled to verify delineation. The last time this was performed was in 2015. The sampling of these wells in 2020 was replaced with the direct push technology (DPT) investigations completed in October 2020 and April 2021. This DPT groundwater data was presented in an Advance Data Package (ADP) in September 2021 and discussed in the Implementation Work Plan (IWP) dated November 2021 for installation of an air sparge (AS) system. Based on results from groundwater sampling activities performed during the previous reporting period, including the 2020 and 2021 DPT groundwater sampling, it was determined that the LTM sampling plan was no longer meeting the goal of LTM because delineation was not verified. The 2021 LTM sampling plan was modified to include the sampling of monitoring wells located around the perimeter of the low concentration plume (LCP); the area with concentrations of contaminants of concern [COCs] greater than Groundwater Cleanup Target Levels [GCTLs]), and sampling of 10 monitoring wells proposed for installation (April 2021 KSC Remediation Team (KSCRT) Meeting, Decision 2104-D32). The modified LTM plan received team consensus at the September 2021 KSCRT Meeting (Decision Number 2109-D03), and sampling of the existing monitoring wells was completed in December 2021. The proposed monitoring wells are planned for installation in late 2022, concurrent with ongoing IM construction activities. December 2021 LTM data was presented at the May 2022 KSCRT Meeting, and activities are summarized in this report. The activities presented in this report include the December 2021 groundwater gauging of 42 monitoring wells and sampling of 44 monitoring wells. During the December 2021 event, the low flow sampling method was used, and samples were analyzed for a select list of volatile organic compounds (VOCs), including 1,1,2-trichloro-1,2,2-trifluoroethane (Freon 113). The following conclusions can be made based on the 2021 LTM results: - In December 2021, groundwater flow for the site was generally to the west at all intervals. This is generally consistent with historical observations at the site, with the exception of a southwest and southeast flow component observed at 34 to 48 feet below land surface (bls). - The vertical extent of VOCs was historically delineated by monitoring wells screened greater than 48 feet bls. The results from the two vertical extent monitoring wells, WILC-MW0078 (screened 65 to 70 feet bls) and WILC-MW0130 (screened 56 to 66 feet bls) that were sampled during the 2021 LTM indicate that groundwater vinyl chloride (VC) concentrations in both wells were greater than the GCTL. The Remediation Team has previously agreed to delay deeper DPT investigations in this area to prevent the creation of additional pathways for vertical migration. - The LCP continues to extend both horizontally, predominantly to the west, and vertically beyond the current monitoring well network, with some retraction observed to the southeast. Evaluation of this data combined with data from the 2020 and 2021 DPT sampling event indicate that the LCP encompasses an estimated 20.7 acres based on an expanded sampling area, as compared to the 2020 LCP footprint of 17.0 acres. - Freon 113 was not detected above GCTLs during the 2021 LTM event. Based on groundwater sampling activities performed in 2021, including April 2021 DPT groundwater sampling, the following recommendations are provided: - Perform the next LTM sampling event, targeted to occur in 2023, concurrently with the IM baseline sampling prior to AS system installation; - Include sampling from nine monitoring wells that are planned to be installed in late 2022, concurrent with upcoming IM construction activities. Installation of one deep vertical well, screened 70 to 80 feet bls, will be delayed to prevent the creation of an additional pathway for vertical migration; - Continue to sample under the modified annual LTM plan as presented in Table 4-1 concurrently with IM baseline sampling; and - Once the AS system install and start-up is complete, select monitoring wells from the LTM program will transition into the performance monitoring plan, and LTM will be temporarily discontinued. Performance monitoring will be performed quarterly, and the monitoring well network will be evaluated following the first performance monitoring sampling event.

long-term monitoring (LTM)↗

Wilson Corners SWMU 001 2015 Annual Long Term Monitoring Report Kennedy Space Center, Florida

This document presents the findings of the 2015 Long Term Monitoring (LTM) that was completed at the Wilson Corners site, located at the National Aeronautics and Space Administration John F. Kennedy Space Center, Florida. The objectives of the 2015 LTM event were to evaluate the groundwater flow direction and gradient, to monitor the vertical and horizontal extent of the volatile organic compounds (VOCs; including the upgradient and sidegradient extents, which are monitored every five years), and to monitor select locations internal to the dissolved groundwater plume. The 2015 LTM event included several upgradient and sidegradient monitoring wells that are not sampled annually to verify the extent of VOCs in this portion of the site. The December 2015 LTM groundwater sampling event included, depth to groundwater measurements, 40 VOC samples collected using passive diffusion bags, and one VOC sample collected using low-flow techniques. Additionally, monitoring well MW0052DD was overdrilled and abandoned using rotasonic drilling techniques. The following conclusions can be made based on the 2015 LTM results: groundwater flow is generally to the west with northwest and southwest flow components from the water table to approximately 55 feet below land surface (ft BLS); peripheral monitoring wells generally delineate VOCs to groundwater cleanup target levels (GCTLs) except for monitoring wells MW0088, MW0090, MW0095, and NPSHMW0039, which had vinyl chloride (VC) concentrations near the GCTL and MW0062, which had trichloroethene (TCE), cis-1,2-dichloroethenen (cDCE), and VC concentrations above natural attenuation default concentrations (NADCs); VOCs in interior downgradient wells generally fluctuate within historic ranges except for monitoring wells in the north-northwest portion of the site, which have increasing VC concentrations indicating potential plume migration and expansion; Historically, the vertical extents of the VOCs were delineated by monitoring wells screened greater than 60 ft BLS (MW0083 through MW0086, and MW0078). The 2015 LTM results indicate that concentrations of daughter product cDCE is greater than the NADC in MW0078 and that cDCE and VC are greater than NADCs in MW0130. TCE was greater than the GCTL in monitoring well MW130 and not detected above method detection limits (9 micrograms per Liter) in monitoring well MW0078. No GCTL exceedances were identified in monitoring wells MW0083 or MW0086; the dissolved plume footprint appears generally stable, though not fully delineated by monitoring well data in the northeast portion of the site; and 2015 LTM results generally support the existing Conceptual Site Model. Geosyntec recommends modifying the LTM program, collecting a verification sample from monitoring well MW0062, and performing a direct push technology instigation in the northnortheastern portion of the site. A cluster of monitoring wells (MW0132 [2 to 12 ft BLS], MW0133 [15 to 25 ft BLS], and MW0134 [29 to 34 ft BLS]) is proposed to delineate impacts in the northnortheast portion of the site. Geosyntec recommends installation of a vertical extent well in the center of the site (Hot Spot 2 area) post-remediation implementation.

groundwater↗

Hypogenic Karst of the Great Basin

Discoveries in the 1980s greatly expanded speleologists’ understanding of therole that hypogenic groundwater flow can play developingcaves at depth. Ascending groundwater charged with carbon dioxide and,especially,hydrogen sulfide,can readily dissolve carbonate bedrock just below and above the water table. Sulfuric acid speleogenesis, in which anoxic, rising, sulfidic groundwater mixes with oxygenated cave atmosphere to form aggressive sulfuric acid (H2SO4), formed spectacular caves in CarlsbadCaverns National Park. Cueva de Villa Luz in Mexico provides an aggressively active example of sulfuric acid speleogenesisprocesses, and the Frasassi Caves in Italy preserve the results of sulfuric acid speleogenesis in its upper levels while sulfidic groundwater currently enlarges cave passages in the lower levels. Manycaves in east-central Nevada and western Utah are products of hypogenic speleogenesis and formed before the current topography fully developed. Wet climate during the late Neogeneand Pleistocene brought extensive meteoric infiltration into the caves and calcite speleothems (e.g., stalactites, stalagmites, shields) coat the walls and floors of the caves, concealing evidence of the earlier hypogenic stage. However, by studying the speleogenetic features in well-established sulfuric acid speleogenesis caves, evidence ofhypogenic, probably sulfidic, speleogenesis inmany Great Basin caves can be teased out.Compelling evidence of hypogenicspeleogenesis in these cavesinclude folia, mammillaries, bubble trails, cupolas, and metatyuyamunite. Sulfuric acid speleogenesis signsinclude hollowcoralloidstalagmites,trays, gypsum crust, pseudoscallops, rills, and acid pool notches. Lehman Caves is particularly informative as a low-permeability capstone protected about half of the cave from significant meteoric infiltration, preserving early speleogeneticfeatures.

Louise D Hose↗

Interim Measures Pilot Study Completion Report, South Repeater Building, Solid Waste Management Unit 121, Hydraulic Containment and Groundwater Treatment System for Per- and Polyfluoroalkyl Substances

This Per- and Polyfluoroalkyl Substances (PFAS) Interim Measures Pilot Study Completion Report was prepared for the National Aeronautics and Space Administration by AECOM Technical Services, Inc. under Contract 80KSC019D0010, Task Order 80KSC021F0096. The purpose of this report is to document the pilot study activities at the South Repeater Building, Solid Waste Management Unit (SWMU) 121. This report details the additional assessment activities completed from June 2023 through November 2023 and the subsequent pilot study completed at the South Repeater Building conducted in December 2023 through February 2024. Initial activities were conducted in accordance with the Pilot Study Work Plan (NASA 2023), submitted to the KSC Remediation Team and accepted by the team on October 26, 2023. The objectives of the pilot study were to: • Provide information on aquifer characteristics and to aid in future modeling and remedial design activities to mitigate off-KSC migration of PFAS compounds. • Develop information on characteristics of the surficial aquifer system, specifically transmissivity, storage coefficient, hydraulic conductivity, and vertical hydraulic conductivity. • Obtain data to support construction and calibration of a groundwater flow model. • Acquire design parameters necessary for future remedial design activities, specifically radius of influence, drawdown, flow rates, and pump settings. The following activities were completed to meet the pilot study objectives: • Groundwater and surface water sampling • Geophysical investigation via Hydraulic Profiling Tool (HPT) and soil sampling • Installation of observation and extraction wells via rotosonic techniques • Slug, step, and pump testing activities • Initial modeling efforts for a groundwater hydraulic containment system. Results of the pilot study and modeling activities are being used in the development of a groundwater containment and treatment system for the site.

PFAS↗

Wilson Corners SWMU 001 2014 Annual Long Term Monitoring Report Kennedy Space Center, Florida

This document presents the findings of the 2014 Long Term Monitoring (LTM) that was completed at the Wilson Corners site, located at the National Aeronautics and Space Administration (NASA) John F. Kennedy Space Center (KSC), Florida. The goals of the 2014 annual LTM event were to evaluate the groundwater flow direction and gradient and to monitor the vertical and downgradient horizontal extent of the volatile organic compounds (VOCs) in groundwater at the site. The LTM activities consisted of an annual groundwater sampling event in December 2014, which included the collection of water levels from the LTM wells. During the annual groundwater sampling event, depth to groundwater was measured and VOC samples were collected using passive diffusion bags (PDBs) from 30 monitoring wells. In addition to the LTM sampling, additional assessment sampling was performed at the site using low-flow techniques based on previous LTM results and assessment activities. Assessment of monitoring well MW0052DD was performed by collecting VOC samples using low-flow techniques before and after purging 100 gallons from the well. Monitoring well MW0064 was sampled to supplement shallow VOC data north of Hot Spot 2 and east of Hot Spot 4. Monitoring well MW0089 was sampled due to its proximity to MW0090. MW0090 is screened in a deeper interval and had an unexpected detection of trichloroethene (TCE) during the 2013 LTM, which was corroborated during the March 2014 verification sampling. Monitoring well MW0130 was sampled to provide additional VOC data beneath the semi-confining clay layer in the Hot Spot 2 area.

Monitoring↗

Modeling the Effect of Wetlands, Flooding, and Irrigation on River Flow: Application to the Aral Sea

As the world's population continues to increase, additional stress is placed on water resources. This stress, coupled with future uncertainties regarding climate change, makes arid and semi-arid regions particularly vulnerable. One example is the Aral Sea where the freshwater inflow, which is dominated by snowmelt runoff, has decreased significantly since the expansion of intensive irrigation in the 1960s. The purpose of this paper is to use a river routing scheme from a global climate model to examine the flow of the Amu Dar'ya River into the Aral Sea. The river routing scheme is modified to include groundwater flow, flooding, and evaporative losses in the river's wetlands and floodplain, and anthropogenic withdrawals for irrigation. A set of scenarios is designed to test the sensitivity of river flow to the inclusion of these modifications into the river routing scheme. When riverine wetlands and floodplains are present, the river flow is reduced significantly and is similar to the observed flow. In addition the model results show that it is essential to incorporate human diversions to accurately represent the inflow to the Aral Sea, and they also indicate potential management strategies that might be appropriate to maintain a balance between inflow to the Sea and upstream diversions for irrigation.

Ferrari, Michael R.↗

An Unusual Inverted Saline Microbial Mat Community in an Interdune Sabkha in the Rub' Alkhali (the Empty Quarter), UAE: an Analog for Habitats on Present Mars

Salt flats (sabkha) are a recognized habitat for microbial life in desert environments and as analogs for habitats for life on Mars. Here we report on the physical setting and microbiology of interdune sabkhas among the large dunes in the Rub' al Khali (the Empty Quarter) in Liwa Oasis, United Arab Emirates. The salt flats, composed of gypsum and halite, between the dunes are moistened by relatively fresh ground water from below. The result is a salinity gradient that is inverted compared to most salt flat communities with the hypersaline layer at the top and freshwater layers below. We describe and characterize a rich photosynthetically-based microbial ecosystem that is protected from the arid outside environment below the translucent salt crust. Gases collected from sediments under shallow ponds in the sabkha contain methane in concentrations as high as 3400 ppm. The salt layer provides environmental protection to the habitat below and could preserve biomarkers and other evidence for life in the salt after it dries out. Chloride-filled depressions have been identified on Mars and although the surface flow of water is unlikely on Mars today, ground water is possible. Such a near surface system with modern groundwater flowing under ancient salt deposits could be present on Mars and could be accessed by surface rovers.

Hypersaline environments in deserts↗

South Repeater Building (Swmu 121) Pilot Study Work Plan, Kennedy Space Center, Florida

This document is a Pilot Study Work Plan for a groundwater remediation system at the South Repeater Building (N6-1118) located at the John F. Kennedy Space Center (KSC), Florida. Aqueous fire-fighting foam was applied near the building in the late 1990s during a wildfire. Per- and polyfluoroalkyl substances (PFAS) are components of the foam. Sampling completed at and near the South Repeater Building identified PFAS in groundwater, surface water and soil. KSC is planning to design and install a groundwater remediation system to address the potential for off-Center migration of PFAS compounds in groundwater. This Pilot Study Work Plan outlines subsurface hydrogeologic data that will be collected to use in the construction of a groundwater flow model that will guide the design of a full-scale remediation system. This document was prepared by AECOM Technical Services, Inc., for NASA under Indefinite Delivery Indefinite Quantity Contract 80KSC019D0010, Task Order 80KSC019F0096.

PFAS↗

Stability of streams and lakes on Mars

The freezing of small Martian streams is modelled for a variety of climatic conditions, on the supposition that the Martian atmosphere may have been considerably thicker in the past, at the time of the formation of the valley networks. This model examines the energy balance at the upper and lower surfaces of ice on streams, in order to determine the rate at which ice thickens with time. Results indicate that freezing rates are not strongly dependent on atmospheric pressure, and, under windy conditions, dependence on atmospheric pressure is even weaker. It is noted that the main problem in valley formation is in initiating the flow. Groundwater seepage alone is inadequate, due to the difficulty of groundwater system replenishment.

Carr, M. H.↗

Karst on Mars? The thumbprint terrain

The nature of the 'thumbprint' terrain noted by Guest et al. (1977) in high-resolution Viking Orbiter photographs of the northern plains of Mars is considered in light of plausible terrestrial analogs. At least some portion of such terrain may be due to differential solution of large carbonate deposits located in low-lying areas; comparative morphology may therefore indicate it to be an analog of the arid karst of Australia's Nullabor Plain, provided that groundwater flow was available during the terrain's formative period on Mars.

Schaefer, Martha W.↗