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At least 19 records

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NASA NTRS2019

Continued Development of a Highly Reflective Solar Coating for Cryogenic Liquid Storage in Space

State-of-the-art solar reflectors absorb 6-8 % of the sun's irradiant power, which is adequate for spacecraft thermal control; but not for storage of cryogens in tanks exposed to the Sun. A solar reflector must absorb less than 0.4% of the Sun's power, while radiating effectively in the far IR, to allow LOX storage. Hibbard realized this in 1960's, at about the same time that nearly perfect optical reflectors were developed based on particle scattering. In 2015, under funding from the NASA Innovative Advanced Concepts Program (NIAC), these breakthroughs were rediscovered. Theoretical analysis showed that a tank coated with a thick (1 cm) layer of 150 nm particles, composed of a broadband material, could allow the tank to chill to cryogenic temperatures, even in the presence of 1 AU solar irradiance. Subsequent work lead to the demonstration and testing of BaF2 based rigid coupons. Placing one of these in a cryocooler-based simulated deep space environment and irradiating with simulated sunlight has shown about 1% absorption. This is better than the state-of-the-art but not yet sufficient for LOX storage.This paper will review the background material presented above but will concentrate on work performed over the last year, including the design and build-up of the testing apparatus. Since our last publication, we have changed materials from BaF2 to Y2O3. Y2O3 has slightly higher solar absorptance, but is hydrophobic and higher index.

Swanger, Adam↗

NASA NTRS2026

Assessing the Adhesion of Nanofibrous PVDF-HFP as Passive Thermal Control Coatings for the Extraterrestrial Storage of Cryogenic Propellants

Cryogenic propellant passive thermal management techniques in space are essential complements to active thermal management methods, helping reduce absolute dependence on the latter. Particularly, materials with superior optical properties (high solar reflectance and infrared emittance) would be beneficial for passive thermal control to reject most of the incident solar radiation and enhance thermal emission from the storage tank, leading to self-cooling. We developed a nanofibrous, porous passive thermal control material by electrospinning polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer onto an aluminum foil substrate. The material exhibits a very high solar reflectance (>99%) and infrared emittance (~86%) when characterized in the ultraviolet-visible-near infrared and mid-infrared wavelengths. This study focuses on the adhesion of the nanofibrous PVDF-HFP to the substrate. We incorporated in-lab fabricated and commercial adhesives, under normal room conditions, between the nanofibers and the aluminum foil substrate to improve their adhesion. Some samples were also exposed to space-like conditions – vacuum and thermal cycling, to investigate their effects on the strengths of adhesives. Subsequently, adhesion peel tests were conducted on all the samples to assess the peel strengths of the bonds. Peel test strengths after space environment conditioning of the adhesives were generally higher than those observed in the pristine, unaged samples. The results are discussed in this study.

Chieloka Ibekwe↗

NASA NTRS2026

Investigating Dual Electrospinning as a Means of Enhancing Passive Thermal Control Coatings for Cryogenic Propellant Storage in Extraterrestrial Environments

Passive thermal control is necessary as space exploration becomes increasingly widespread. Materials with superior optical properties (high solar reflectance and infrared emittance) are critical for passive thermal control because they can reject most of the incident solar radiation and promote thermal emission from cryogenic propellant storage tanks, enabling the extraterrestrial storage of cryogens. We have demonstrated in previous studies that electrospun nanofibers exhibit exceptional optical properties, offering significant benefits for passive radiative cooling in space. Particularly, electrospun polyvinylidene fluoride-co-hexafluoropropylene PVDF-HFP nanofibers demonstrate exceptionally high solar reflectance (>99%) and strong thermal emittance (measured at ~300 K). However, they exhibit nanostructural changes in the presence of atomic oxygen, which is prevalent in Low Earth Orbit. This study focuses on creating a unique blend of polymeric (PVDF-HFP) and ceramic-based (silica) nanofibers by leveraging the chemical stability and atomic oxygen resistance of silica, using the dual electrospinning manufacturing method. This approach aims to preserve the structural properties of the polymeric counterpart without compromising its optical performance, thereby providing an innovative method for manufacturing environmentally resilient passive thermal control nanofibers with desirable optical and thermal control functionalities for extraterrestrial storage of cryogenic propellants.

Chieloka Ibekwe↗

DOE OSTI2023

Eco-friendly passive radiative cooling using recycled packaging plastics

Passive daytime radiative cooling, requiring zero external energy consumption, is a promising cooling strategy achieved by simultaneously reflecting solar irradiance and thermally radiating heat into the cold outer space (~3 K) through the atmospheric transparency window. However, current materials for passive radiative cooling face huge challenges, such as complicated fabrication approaches, expensive raw materials, and environmental requirements for practical applications. In line with the urgent need for plastic recycling to curb global environmental pollution, the recycled plastics are used to fabricate a passive radiative cooling material. Herein, the foam-paper composite (FPC) with excellent self-cooling capability is fabricated by a simple crushing-and-mixing procedure using recycled polystyrene (PS) foam and printer paper. The superhydrophobic PS foam particles not only protect the FPC from water damage for field applications but also reinforce its solar reflectivity via their porous structure. The cellulose fibers in printer paper can efficiently emit infrared thermal radiation into the cold outer space and bond dispersed PS foam particles together, further increasing its mechanical strength. The combination of highly diffusely reflective PS foam particles and fiber-based printer paper results in a reflectivity of 96% in the solar spectrum, a sub-ambient cooling performance of 8.4 degrees C, and a maximum radiative cooling power of 90 W/m2 during a 24-h cycle. Meanwhile, the FPC with high humidity can maintain its high solar reflectivity, which promotes its application in humid subtropical areas. Further, the low material cost and ease of fabrication will provide a path for effective daytime radiative cooling, especially in less developed areas.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRSDate not supplied

Passive Cooling for Mercury Surface Lander Electronics

A significant barrier to operation of a mission on the surface of Mercury is the temperature. At Mercury’s perihelion distance of 0.313 AU, the solar intensity is 10.6 times the solar flux at Earth orbit, and at the subsolar point, the maximum surface temperature reaches 427°C. For a mission landing on the surface of Mercury at latitude of 40°S, we analyzed using passive thermal control to reduce the temperature of the critical electronics to within the operation temperature limits of silicon devices. The thermal control requires reducing the thermal conductance and infrared flux from the high temperature surface and surrounding spacecraft, and moderating the solar heat input using a surface coating with high solar reflectivity, and maximizing thermal cooling with high infrared emissivity. Using this approach, we find that we can passively cool an electronics box to a temperature of 393K (120°C) using a radiator-white surface with solar absorptivity 0.11 and infrared emissivity 0.91. This temperature is well under 175C target we use for the limits of high-temperature silicon integrated circuits, including RAM and microcontrollers. We could further reduce this operating temperature to as low as 321K (48°C) with an advanced thermal coating, a temperature well within the operational limits of conventional electronics.

Mercury↗

NASA NTRSDate not supplied

Passive Cooling for Mercury Surface Lander Electronics

Mercury↗

NASA NTRSDate not supplied

Fabrication and Performance Characterization of Electrospun Nanofibers for Terrestrial and Space Applications

Passive thermal control is vital in space, especially for extended missions involving cryogen storage needing protection from sunlight. This presentation covers the development of a thermal coating with wavelength-selective characteristics using polymeric materials that scatter sunlight with minimal absorption, resulting in high solar reflectance. Furthermore, these coatings allow emission in infrared wavelengths, making them suitable for deep-space missions requiring extended storage. The study chose polymer and surface morphology suitable as solar reflectors that are lightweight, compact, and easily manufacturable, focusing on different multilayered nanofibers made using polytetrafluoroethylene and polyethylene-oxide (PTFE-PEO), polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP), and silica (SiO2). To understand how these materials interact with sunlight, we analyze light propagation through several layers of electrospun nanofibers to determine spectral reflectance, absorptance, and transmittance by solving the Maxwell equations. The model is also compared with measurements of spectral reflectance and transmittance of the various electrospun nanofibers using spectrophotometers interfaced with integrating spheres in the ultraviolet, visible, near-infrared, and mid-infrared wavelengths. The presentation will also describe the design and analysis, fabrication of the nanofibers using electrospinning, and several experimental characterization techniques to determine suitability for space applications. The nanofibers are tested using various tools to determine their suitability for cryogenic applications in space. Lastly, the samples were tested under low vacuum conditions and exposing them to sunlight inside a vacuum chamber maintained at 300 K. Relative to the incoming solar flux (1000 W/m2), only 1% of the energy was absorbed under these operating conditions. With further optimization and testing under high vacuum cryogenic environments, the samples could demonstrate much lower absorption or higher reflection of incoming solar radiation, which can translate to low temperatures suitable for cryogen storage.

Chieloka Ibekwe↗

NASA NTRS2019

SOFI Coating Study

Results are presented for the reflectivity of spray on foam insulation (SOFI) samples coated with a new high solar reflectivity coating. Reflectance spectra are presented comparing bare SOFI to samples with one, two, or three layers of the new coating as well as one sample with white paint. Samples were coated on the front side of the SOFI, where the surface height varies significantly, as well as on the flatter back surface. Predicted solar absorbance values are provided for a few select cases.

Youngquist, R.↗

NASA NTRSDate not supplied

Thermal Radiation Control in Space using Hollow Microsphere-based Coatings

Thermal radiation control is a crucial method of thermal regulation in space, where the dominant means of heat transfer is radiation. To maintain optimal temperature in space, the surface needs to reflect sun light and release thermal radiation. For such reason, hollow microspheres are suitable for thermal radiation control, since they exhibit high solar reflectivity and IR emissivity. Herein, we experimentally present sprayable hollow microsphere coating, including their optical and thermal properties. These coatings have potentials to offer thermal management in space via thermal radiation control.

Hoyeon Park↗

NASA NTRSDate not supplied

Impact of Thermochromic Coatings on Thermal Management for Human Spacecraft Applications

Thermochromic variable emittance coatings (VECs) allow for passive, dynamic thermal management of space vehicles due to their temperature dependent optical properties. Ideally, a thermochromic material should exhibit low mid-IR emissivity for lower temperatures and switch to high mid-IR emissivity for higher temperatures; one promising material that demonstrates these characteristics is Lanthanum Strontium Manganite (LSM). The transition temperatures of LSM are dependent on the Lanthanum-to-Strontium ratio x, La1-xSrxMnO3. La0.8Sr0.2MnO3, which has an emittance of 0.5 for < 270 K, then a linear increase in emittance to 0.8 over an increase of 70 K where it will saturate at ~340K, is commonly utilized but this is tunable by changing the Sr concentration. The tunability of the transition temperature range of LSM motivates a need to understand the optimal thermal transition range for human spacecraft. Additionally, LSM has high solar absorptance and to combat this issue the VEC will be micropatterned on top of a highly solar reflective layer of Barium Sulfate (BaSO4). Consequently, this work will elucidate the tradeoffs between solar absorptance and variable emittance for this technology since the micropattern adversely couples the solar absorptance to the mid-IR emittance. This work develops a computational model using Thermal Desktop to study the utility of VECs on human spacecraft, such as Orion, subjected to mission phases such as lunar transit and Gateway docking. The model considers both external heat loads, from solar irradiation and planetary IR, as well as vehicle heat loads, from avionics and crew, as an input into the body mounted thermochromic radiators. There are several design targets for VECs, i.e. achieving the largest change in emittance, finding the optimal temperature range for the transition, and achieving the highest emittance in the high temperature phase. This work prioritizes these design targets for LSM to achieve the optimal heat rejection for a human spacecraft. The VECs are compared with static emittance coatings and the efficiency gains are quantified. Thermochromic VECs will ultimately lead to simplifications of active cooling systems which synergistically correlates to mass reduction and less energy consumption for space vehicles.

Joseph Peoples↗

NASA NTRS1995

Thermal Switch for Satellite Temperature Control

An active radiator tile (ART) thermal valve has been fabricated using silicon micromachining. Intended for orbital satellite heat control applications, the operational principal of the ART is to control heat flow between two thermally isolated surfaces by bring the surfaces into intimate mechanical contact using electrostatic actuation. Prototype devices have been tested in a vacuum and demonstrate thermal actuation voltages as low as 40 volts, very good thermal insulation in the OFF state, and a large increase in radiative heat flow in the ON state. Thin, anodized aluminum was developed as a coating for high infrared emissivity and high solar reflectance.

Ziad, H.↗

DOE OSTI2023

A review of challenges, barriers, and opportunities for large-scale deployment of cool surfaces

Major urban centers are warming due to a combination of global and local phenomena. City governments are increasingly adopting strategies to mitigate the causes and impacts of extreme heat on their populations. Among these strategies are high solar-reflectance (cool) surfaces installed on building roofs and walls. Use of cool surfaces is a cost-effective and simple strategy that replaces conventional darker surfaces with surfaces that have a high reflectance to shortwave (solar) energy. This report reviews the recent history of cool-surface deployment efforts. This includes peer-reviewed literature, conference proceedings, and grey literature to identify challenges and barriers to wide-scale deployment of cool surfaces. We have also researched heat action plans and programs from cities and different codes and standards, as well as available incentive and rebate programs. The review identifies challenges, barriers, and opportunities associated with large-scale deployment of cool surfaces and categorize them broadly as being related to product development & performance or policies & mandates. It provides a foundation upon which we intend to build a roadmap for rapidly accelerating future deployments of cool surfaces. Finally, this roadmap will address identified challenges and incorporate lessons learned from historical efforts to generate a practical and actionable plan.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1979

Inorganic Zn2TiO4 thermal control coatings

Silicate-bonded zinc orthotitanate thermal control coatings for space applications have been developed. This paper discusses preparation of the pigment, paint formulation and application, and some properties of the coatings. Very high reflectance (low solar absorptance), high emittance, and good stability in an ultraviolet-vacuum environment are indicated for this paint.

Harada, Y.↗

NASA NTRS1997

Investigation of Teflon FEP Embrittlement on Spacecraft in Low-Earth Orbit

Teflon fluorinated ethylene propylene (FEP) (DuPont) is commonly used on exterior spacecraft surfaces for thermal control in the low-Earth orbit environment. Silverized or aluminized Teflon FEP is used for the outer layers of the thermal control blanket because of its high reflectance, low solar absorptance, and high thermal emittance. Teflon FEP is also desirable because, compared with other spacecraft polymers (such as Kapton), it has relatively high resistance to atomic oxygen erosion. Because of its comparably low atomic oxygen erosion yield, Teflon FEP has been used unprotected in the space environment. Samples of Teflon FEP from the Long Duration Exposure Facility (LDEF) and the Hubble Space Telescope (retrieved during its first servicing mission) were evaluated for solar-induced embrittlement and for synergistic effects of solar degradation and atomic oxygen.

deGroh, Kim K.↗

NASA NTRS1994

Limits on coronal reflection using high-frequency solar oscillations

Acoustic waves in the Sun with frequencies above about 5.3 mHz can propagate in the chromosphere. We examine imaged solar intensity data for evidence of reflection of these waves in the upper chromosphere, where the temperature increases by a large factor over a short distance. Our method is to compare the observed and theoretically derived frequency spacings between peaks in the power spectrum. We find that our theoretical frequencies provide the best fit to the data when the reflection in the upper atmosphere is eliminated. In particular, the model of Kumar (1993b), which includes the source depth, and radiative damping, in the calculation of power spectra but ignores chromospheric reflection, gives peak frequencies that are in good agreement with the observations. For acoustic waves of frequency greater than 6 mHz we put an upper limit to the reflectivity of chromosphere and corona, using our method, of about 10%. At a given spherical harmonic degree, the frequency spacing between peaks in the data generally decreases with increasing frequency, because the lower turning point of the waves is moving inward. However, between 5 and 5.5 mHz the frequency spacing increases slightly. This feature is probably associated with the acoustic cutoff frequency in the solar atmosphere, i.e., it indicates a transition from trapped waves to propagating waves. We are able to reproduce the observed behavior by a crude modeling of the solar atmosphere. Further study of these peaks should provide an independent way of exploring the mean structure of the solar atmosphere, particularly around the temperature minimum region.

Kumar, P.↗

NASA NTRSDate not supplied

NASA's CLARREO Pathfinder Mission: The Reflected Solar’s First SITSat

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) Pathfinder mission will take reflected solar (RS) highly accurate measurements needed to monitor Earth’s climate and will be the first RS SI-traceable Satellite Sensor (SITSat). The mission includes a RS spectrometer that will be installed on the International Space Station (ISS) and take measurements for at least one year. CLARREO Pathfinder (CPF) will use on-orbit calibration to achieve an unprecedented high accuracy with SI-traceability and the inter-calibration of other on-orbit instruments. The spectrometer is based on the HyperSpectral Imager for Climate Science (HySICS) instrument developed by the University of Colorado/Laboratory for Atmospheric and Space Physics of Boulder, CO, USA. HySICS is being designed to have a radiometric uncertainty of 0.3% (1-sigma), a five to ten times improvement over existing spaceflight RS instruments. High accuracy SI-traceable measurements such as these are critical to develop long-term climate-quality data sets. Additionally, by measuring spectral reflectance with high accuracy the CPF instrument will serve as an on-orbit intercalibration radiometric reference for operational Earth-viewing sensors, such as the Clouds and Earth’s Radiant Energy System (CERES) broadband shortwave instrument and the Visible/Infrared Imaging Radiometer Suite (VIIRS). Two-axis pointing, a spectral range from 350 nm to 2300 nm, and a spectral resolution ≤6 nm enable CPF to provide nearly coincident temporal, spatial, angular, and spectral matching of intercalibration targets, with sampling sufficient to reduce random errors. The intercalibration method will refine knowledge of target sensors’ effective offsets, gain, non-linearity, spectral response, and polarization sensitivity (as is relevant). Calibrated reflectance and reflected radiance spectra will be distributed to the scientific community through a NASA Distributed Active Archive Center (DAAC). We will present an overview of the CLARREO Pathfinder mission, its anticipated impact on monitoring climate variability, and the novel CPF direct intercalibration approach.

climate↗

NASA NTRSDate not supplied

CLARREO Pathfinder: Mission Overview and Current Status

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) Pathfinder (CPF) mission consists of a high accuracy reflected solar spectrometer that will take measurements from the International Space Station for one year starting in 2023. CPF will demonstrate that its novel on-orbit absolute calibration approaches are capable of achieving 0.3% (1-sigma) radiometric uncertainty. Additionally, using its two-axis pointing gimbal which enables nearly-concurrent measurements matching look angles with other orbiting sensors, CPF will demonstrate a novel inter-calibration approach by inter-calibrating CERES and VIIRS. CPF is currently in its Final Design and Fabrication Stage and recently passed its Critical Design Review.

Yolanda Shea↗

NASA NTRSDate not supplied

CLARREO Pathfinder: Mission Status and Current Status

Yolanda Shea↗