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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Characterization of metal oxide absorbents for regenerative carbon dioxide and water vapor removal for advanced portable life support systems

Characterization of the performance of a silver-oxide-based absorbent in terms of its ability to remove both gaseous CO2 and water vapor in an astronaut portable life support systems (PLSS) is discussed. Attention is focused on regeneration of the absorbent from the carbonite state of the oxide state, preconditioning of the absorbent using a humidified gas stream, and absorption breakthrough testing. Based on the results of bench-scale experiments, a test plan is carried out to further characterize the silver-oxide-based absorbent on a larger scale; it calls for examination of the absorbent in both an adiabatic packed bed and a near-isothermal cooled bed configuration. It is demonstrated that the tested absorbent can be utilized in a way that removes substantial amounts of CO2 and water vapor during an 8-hour extravehicular activity mission, and that applying the absorbent to PLSS applications can simplify the ventilation loop.

Kast, Timothy P.↗

Gold-on-Polymer-Based Sensing Films for Detection of Organic and Inorganic Analytes in the Air

A document discusses gold-on-polymer as one of the novel sensor types developed for part of the sensor development task. Standard polymer-carbon composite sensors used in the JPL Electronic Nose (ENose) have been modified by evaporating 15 nm of metallic gold on the surface. These sensors have been shown to respond to alcohols, aromatics, ammonia, sulfur dioxide, and elemental mercury in the parts-per-million and parts-per-billion concentration ranges in humidified air. The results have shown good sensitivity of these films operating under mild conditions (operating temperatures 23-28 C and regeneration temperature up to 40 C). This unique sensor combines the diversity of polymer sensors for chemical sensing with their response to a wide variety of analytes with the specificity of a gold sensor that shows strong reaction/binding with selected analyte types, such as mercury or sulfur.

Manatt, Kenneth↗

Regenerable Liquid Desiccants for High Efficiency Humidity Control in Microgravity

The NASA X-Hab project aims to design, manufacture, test, and prove functionality of an air humidity control subsystem to dehumidify and re-humidify air from a space cabin. The method of regulating cabin air humidity utilizes vortex phase separation, which uses an ionic liquid (IL) desiccant for air-water phase separation. This subsystem is intended to be integrated with a CO 2 removal system requiring de-humidified air to operate efficiently. The air humidity control subsystem is composed of a cold-desiccant or cold-side Vortex Phase Separator (VPS) that dehumidifies the cabin air. The dehumidified air exits the cold-side (CS) VPS chamber to flow into the CO 2 removal module, and the cold, water-laden liquid desiccant flows to a regenerative heat exchanger. From the heat exchanger the liquid desiccant continues to the heater. After heating, the desiccant flows into a hot-desiccant or hot-side (HS) VPS as the dehumidified air from CO 2 removal module enters through the HS VPS air inlet. The rehumidified air exits the HS VPS into the space cabin. One pump installed at the liquid exit of the CS VPS and one pump installed at the liquid exit of the HS VPS transport the fluid through the system. To evaluate the system’s efficiency and effectiveness, the temperature, pressure, flow rate and relative humidity are read, recorded, and analyzed at critical points along the module.

Gerardo Castro↗

Detecting Airborne Mercury by Use of Palladium Chloride

Palladium chloride films have been found to be useful as alternatives to the gold films heretofore used to detect airborne elemental mercury at concentrations of the order of parts per billion (ppb). Somewhat more specifically, when suitably prepared palladium chloride films are exposed to parts-per-billion or larger concentrations of airborne mercury, their electrical resistances change by amounts large enough to be easily measurable. Because airborne mercury adversely affects health, it is desirable to be able to detect it with high sensitivity, especially in enclosed environments in which there is a risk of leakage of mercury from lamps or other equipment. The detection of mercury by use of gold films involves the formation of gold/mercury amalgam. Gold films offer adequate sensitivity for detection of airborne mercury and could easily be integrated into an electronic-nose system designed to operate in the temperature range of 23 to 28 C. Unfortunately, in order to regenerate a gold-film mercury sensor, one must heat it to a temperature of 200 C for several minutes in clean flowing air. In preparation for an experiment to demonstrate the present sensor concept, palladium chloride was deposited from an aqueous solution onto sets of gold electrodes and sintered in air to form a film. Then while using the gold electrodes to measure the electrical resistance of the films, the films were exposed, at a temperature of 25 C, to humidified air containing mercury at various concentrations from 0 to 35 ppb (see figure). The results of this and other experiments have been interpreted as signifying that sensors of this type can detect mercury in room-temperature air at concentrations of at least 2.5 ppb and can readily be regenerated at temperatures <40 C.

Ryan, Margaret↗

Sorbent Structural Testing on Carbon Dioxide Removal Sorbents for Advanced Exploration Systems

Long term space missions require carbon dioxide removal systems that can function with minimal downtime required for maintenance, low power consumption and maximum efficiency for CO2 removal. A major component of such a system are the sorbents used for the CO2 and desiccant beds. Sorbents must not only have adequate CO2 and H2O removal properties, but they must have the mechanical strength to prevent structural breakdown due to pressure and temperature changes during operation and regeneration, as well as resistance to breakdown due to moisture in the system from cabin air. As part of the studies used to select future CO2 sorbent materials, mechanical tests are performed on various zeolite sorbents to determine mechanical performance while dry and at various humidified states. Tests include single pellet crush, bulk crush and attrition tests. We have established a protocol for testing sorbents under dry and humid conditions, and previously tested the sorbents used on the International Space Station carbon dioxide removal assembly. This paper reports on the testing of a series of commercial sorbents considered as candidates for use on future exploration missions.

Watson, David↗