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At least 19 records

Visual hydrogen detector with variable reversibility

Methods, processes and compositions are provided for a visual or chemochromic hydrogen-detector with variable or tunable reversible color change. The working temperature range for the hydrogen detector is from minus 100.degree. C. to plus 500.degree. C. A hydrogen-sensitive pigment, including, but not limited to, oxides, hydroxides and polyoxo-compounds of tungsten, molybdenum, vanadium, chromium and combinations thereof, is combined with nano-sized metal activator particles and preferably, coated on a porous or woven substrate. In the presence of hydrogen, the composition rapidly changes its color from white or light-gray or light-tan to dark gray, navy-blue or black depending on the exposure time and hydrogen concentration in the medium. After hydrogen exposure ceases, the original color of the hydrogen-sensitive pigment is restored, and the visual hydrogen detector can be used repeatedly. By changing the composition of the hydrogen-sensitive pigment, the time required for its complete regeneration is varied from a few seconds to several days.

Muradov, Nazim↗

Visual hydrogen detector with variable reversibilty

Methods, processes and compositions are provided for a visual or chemochromic hydrogen-detector with variable or tunable reversible color change. The working temperature range for the hydrogen detector is from minus 100.degree. C. to plus 500.degree. C. A hydrogen-sensitive pigment, including, but not limited to, oxides, hydroxides and polyoxo-compounds of tungsten, molybdenum, vanadium, chromium and combinations thereof, is combined with nano-sized metal activator particles and preferably, coated on a porous or woven substrate. In the presence of hydrogen, the composition rapidly changes its color from white or light-gray or light-tan to dark gray, navy-blue or black depending on the exposure time and hydrogen concentration in the medium. After hydrogen exposure ceases, the original color of the hydrogen-sensitive pigment is restored, and the visual hydrogen detector can be used repeatedly. By changing the composition of the hydrogen-sensitive pigment, the time required for its complete regeneration is varied from a few seconds to several days.

Muradov, Nazim Z.↗

Methods of Forming Visual Hydrogen Detector with Variable Reversibility

Methods, processes and compositions are provided for a visual or chemochromic hydrogen-detector with variable or tunable reversible color change. The working temperature range for the hydrogen detector is from minus 100 C to plus 500 C. A hydrogen-sensitive pigment, including, but not limited to, oxides, hydroxides and polyoxo-compounds of tungsten, molybdenum, vanadium, chromium and combinations thereof, is combined with nano-sized metal activator particles and preferably, coated on a porous or woven substrate. In the presence of hydrogen, the composition rapidly changes its color from white or light-gray or light-tan to dark gray, navy-blue or black depending on the exposure time and hydrogen concentration in the medium. After hydrogen exposure ceases, the original color of the hydrogen-sensitive pigment is restored, and the visual hydrogen detector can be used repeatedly. By changing the composition of the hydrogen-sensitive pigment, the time required for its complete regeneration is varied from a few seconds to several days.

Muradov, Nazim Z.↗

Visualization of hydrogen fires.

Hydrogen fire visualization detection techniques including application of photography, TV and image converter in IR and UV regions

ULTRAVIOLET RADIATION↗

Visualization of hydrogen injection in a scramjet engine by simultaneous PLIF imaging and laser holographic imaging

Flowfield characterization has been accomplished for several fuel injector configurations using simultaneous planar laser induced fluorescence (PLIF) and laser holographic imaging (LHI). The experiments were carried out in the GASL-NASA HYPULSE real gas expansion tube facility, a pulsed facility with steady test times of about 350 microsec. The tests were done at simulated Mach numbers 13.5 and 17. The focus of this paper is on the measurement technologies used and their application in a research facility. The HYPULSE facility, the models used for the experiments, and the setup for the LHI and PLIF measurements are described. Measurement challenges and solutions are discussed. Results are presented for experiments with several fuel injector configurations and several equivalence ratios.

Anderson, Robert C.↗

Flow Visualization of Liquid Hydrogen Line Chilldown Tests

We present experimental measurements of wall and fluid temperature during chill-down tests of a warm cryogenic line with liquid hydrogen. Synchronized video and fluid temperature measurements are used to interpret stream temperature profiles versus time. When cold liquid hydrogen starts to flow into the warm line, a sequence of flow regimes, spanning from all-vapor at the outset to bubbly with continuum liquid at the end can be observed at a location far downstream of the cold inlet. In this paper we propose interpretations to the observed flow regimes and fluid temperature histories for two chilldown methods, viz. trickle (i.e. continuous) flow and pulse flow. Calculations of heat flux from the wall to the fluid versus wall temperature indicate the presence of the transition/nucleate boiling regimes only. The present tests, run at typical Reynolds numbers of approx O(10 (exp 5)), are in sharp contrast to similar tests conducted at lower Reynolds numbers where a well-defined film boiling region is observed.

Line chill down↗

3-D supersonic combustion experiments with hydrogen in V-trough

Both supersonic blowdown and free jet wind tunnels were used in oil flow visualization and hydrogen gas burning tests of 60- and 90-deg V-shaped trough combustion characteristics. Oil dots showed that mass outflow from the reattachment region at the bottom of the V-trough dominated flow behavior, and occupied the trough's entire length and 10% of its cross-section. Intermingled vortex pairs were also found to superimpose themselves upon the outflow, and hydrogen burning within troughs reduced missile base drag by 25%. The troughs were aligned so that their long dimensions were parallel to the airflow, and the two top edges of the V section were mounted flush with respect to the upstream flat surfaces. Step heights tested ranged from 3.4 mm to 6.25 cm.

Friedberg, R. A.↗

Experimental study of the laminar-turbulent transition of a concave wall in a parallel flow

The instability of the laminar boundary layer flow along a concave wall was studied. Observations of these three-dimensional boundary layer phenomena were made using the hydrogen-bubble visualization technique. With the application of stereo-photogrammetric methods in the air-water system it was possible to investigate the flow processes qualitatively and quantitatively. In the case of a concave wall of sufficient curvature, a primary instability occurs first in the form of Goertler vortices with wave lengths depending upon the boundary layer thickness and the wall curvature. At the onset the amplification rate is in agreement with the linear theory. Later, during the non-linear amplification stage, periodic spanwise vorticity concentrations develop in the low velocity region between the longitudinal vortices. Then a meandering motion of the longitudinal vortex streets subsequently ensues, leading to turbulence.

Bippes, H.↗

Species and velocity visualization of unseeded heated air and combusting hydrogen jets using laser and flashlamp sources

Three techniques for the visualization of species and/or velocity in unseeded H2/air flames and heated air jets are described and preliminary image data are presented. The techniques described are: (1) simultaneous ArF laser imaging of H2, O2, and Rayleigh cross-section weighted density in an H2, O2, and Rayleigh cross-section weighted density in an H2/air flame; (2) ultraviolet flashlamp imaging of O2, OH, and Rayleigh cross-section weighted density in an H2/air flame; and (3) Raman Excitation plus Laser Induced Electronic Fluorescence velocimetry in heater air flows, up to static temperatures of 700 K. Application of these techniques, individually or in combination, should provide useful insight into mixing and reacting flows containing H2, O2, N2 and reaction intermediates such as OH.

Diskin, Glenn S.↗

Experimental Investigation of the Near Wall Flow Structure of a Low Reynolds Number 3-D Turbulent Boundary Layer

Laser Doppler velocimetry (LDV) measurements and hydrogen bubble flow visualization techniques were used to examine the near-wall flow structure of 2D and 3D turbulent boundary layers (TBLs) over a range of low Reynolds numbers. The goals of this research were (1) an increased understanding of the flow physics in the near wall region of turbulent boundary layers,(2) to observe and quantify differences between 2D and 3D TBL flow structures, and (3) to document Reynolds number effects for 3D TBLs. The LDV data have provided results detailing the turbulence structure of the 2D and 3D TBLs. These results include mean Reynolds stress distributions, flow skewing results, and U and V spectra. Effects of Reynolds number for the 3D flow were also examined. Comparison to results with the same 3D flow geometry but at a significantly higher Reynolds number provided unique insight into the structure of 3D TBLs. While the 3D mean and fluctuating velocities were found to be highly dependent on Reynolds number, a previously defined shear stress parameter was discovered to be invariant with Reynolds number. The hydrogen bubble technique was used as a flow visualization tool to examine the near-wall flow structure of 2D and 3D TBLs. Both the quantitative and qualitative results displayed larger turbulent fluctuations with more highly concentrated vorticity regions for the 2D flow.

FLOW VISUALIZATION↗

Development of an unsteady water tunnel.

A detailed description is given of an unsteady hydrodynamic flow facility located at the University of Alabama in Huntsville, Alabama. This facility is used to measure unsteady pressures and forces and to acquire hydrogen bubble flow visualization data pertaining to bodies submerged in different types of accelerating flow. Various data acquisition systems are delineated along with typical experimental results acquired using cylindrical models. The method of facility operation and theoretical design considerations are shown along with a comparison between calculations and experimental results. This comparison indicates that the theoretical design procedures sufficiently represented the physical phenomenon for facility design.

Schutzenhofer, L.↗

Application of the hydrogen-bubble technique for velocity measurements in thin liquid films.

A unique adaptation of the hydrogen-bubble flow visualization method was applied to measure velocity profiles and film thicknesses of very thin films on an inclined plane wall. Data were obtained in the three flow regions for a developing falling film with an initially uniform velocity profile and thickness less than or equal to 0.1 in. The measured profiles compared more favorably with parabolic profiles in the intermediate fully developed region than in the initial developing region. However, measured film thicknesses compared favorably with a simplified solution of the integral momentum equation based on parabolic velocity profiles. The results confirm the theoretical prediction that a relatively long distance may be required even for a thin film before nonaccelerating flow with a constant film thickness is obtained and Nusselt's classical analysis applies. The experimental technique was shown to be a practical experimental method for obtaining data for the two-dimensional laminar flow of thin liquid films.

Thomas, W. C.↗

Experimental studies on the stability and transition of 3-dimensional boundary layers

Three-dimensional unstable boundary layers were investigated as to their characteristic instabilities, leading to turbulence. Standing cross-flow instabilities and traveling waves preceding the transition were visualized with the hydrogen bubble technique in the boundary layer above the wall of a swept cylinder. With the sublimation method and hot film technique, a model consisting of a swept flat plate with a pressure-inducing displacement body in the 1 m wind tunnel was studied. Standing waves and traveling waves in a broad frequency are observed. The boundary layer of this model is close to the assumptions of the theory.

Nitschke-Kowsky, P.↗

Hazard Assessment of Personal Protective Clothing for Hydrogen Peroxide Service

Selection of personal protective equipment (PPE) for hydrogen peroxide service is an important part of the hazard assessment process. But because drip testing of chemical protective clothing for hydrogen peroxide service has not been reported for about 40 years, it is of great interest to test new protective clothing materials with new, high-concentration hydrogen peroxide following similar procedures. The suitability of PPE for hydrogen peroxide service is in part determined by observations made when hydrogen peroxide is dripped onto swatches of protective clothing material. Protective clothing material was tested as received, in soiled condition, and in grossly soiled condition. Materials were soiled by pretreating the material with potassium permanganate (KMnO4) solution then drying to promote a reaction. Materials were grossly soiled with solid KMnO4 to greatly promote reaction. Observations of results including visual changes to the hydrogen peroxide and materials, times to ignition, and self-extinguishing characteristics of the materials are reported.

Greene, Ben↗

The effects of stabilizing and destabilizing longitudinal curvature on the structure of turbulent, two-stream mixing layers

The construction and development of the multi-component traversing system and associated control hardware and software are presented. A hydrogen bubble/laser sheet flow visualization technique was developed to visually study the characteristics of the mixing layers. With this technique large-scale rollers arising from the Taylor-Gortler instability and its interaction with the primary Kelvin-Helmholtz structures can be studied.

Plesniak, Michael W.↗

Development of Hairpin Vortices in Turbulent Spots and End-Wall Transition

The end-stage phase of boundary layer transition is characterized by the development of hairpin-like vortices which evolve rapidly into patches of turbulent behavior. In general, the characteristics of the evolution form this hairpin stage to the turbulent stage is poorly understood, which has prompted the present experimental examination of hairpin vortex development and growth processes. Two topics of particular relevance to the workshop focus will be covered: 1) the growth of turbulent spots through the generatio and amalgamation of hairpin-like vortices, and 2) the development of hairpin vortices during transition in an end-wall junction flow. Brief summaries of these studies are described below. Using controlled generation of hairpin vortices by surface injection in a critical laminar boundary layer, detailed flow visualization studies have been done of the phases of growth of single hairpin vortices, from the initial hairgin generation, through the systematic generation of secondary hairpin-like flow structures, culminating in the evolution to a turbulent spot. The key to the growth process is strong vortex-surface interactions, which give rise to strong eruptive events adjacent to the surface, which results in the generation of subsequent hairpin vortex structures due to inviscid-viscuous interactions between the eruptive events and the free steam fluid. The general process of vortex-surface fluid interaction, coupled with subsequent interactions and amalgamation of the generated multiple hairpin-type vortices, is demonstrated as a physical mechanism for the growth and development of turbulent spots. When a boundary layer flow along a surface encounters a bluff body obstruction extending from the surface (such as cylinder or wing), the strong adverse pressure gradients generated by these types of flows result in the concentration of the impinging vorticity into a system of discrete vortices near the end-wall juncture of the obstruction, with the extensions of the vortices engirdling the obstruction to form "necklace" or "horseshoe" vortices. Recent hydrogen bubble and particle image visualization have shown that as Reynolds number is increased for a laminar approach flow, the flow will become critical, and a destabilization of the necklace vortices results in the development of an azimuthal waviness, or "kinks", in the vortices. These vortex kinks are accentuated by Biot-Savart effects, causing portions of a distorted necklace vortex to make a rapid approach to the surface, precipitating processes of localized, three-dimensional surface interactions. These interactions result in the rapid generation, focussing, and ejection of thin tongues of surface fluid, which rapidly roll-over and appear as hairpin vortices in the junction region. Subsequent amalgamation of these hairpin vortices with the necklace vortices produces a complex transitional-type flow. A presentation of key results from both these studies will be done, emphasizing both the ubiquity of such hairpin-type flow structures in manifold transitional-type flows, and the importance of vortex-surface interactions n the development of hairpin vortices.

Smith, Charles R.↗

Dispersion of flammable vapor clouds resulting from large spills of liquid hydrogen

The purpose of this paper is to report the preliminary findings of hydrogen vapor cloud dispersion experiments conducted by NASA. The experiments were performed to obtain basic information regarding the physical phenomena governing the dispersion of flammable clouds formed as the result of spills of large quantities of liquid hydrogen. The experiments consisted of ground spills of up to 5.7 cubic meters (1500 gal) of liquid hydrogen, with spill durations of approximately 35 seconds. Instrumented towers, located downwind of the spill site, gather data on the temperature, hydrogen concentration, and turbulence levels as the hydrogen vapor cloud drifted downwind. Visual phenomena were recorded by motion picture and still cameras. Preliminary results of the experiments indicate that, for rapid spills, thermal and momentum induced turbulences cause the cloud to disperse to safe concentration levels and become positively buoyant long before mixing due to normal atmospheric turbulence becomes a major factor.

Witcofski, R. D.↗

Experiments on shear layer mixing at hypervelocity conditions

Utilization of an expansion tube to acquire turbulent, compressible free shear layer data with gases of direct relevance to hypersonic combustion systems (nitrogen, hydrogen, and oxygen) is demonstrated. Visualizations of the free shear layer by laser holographic interferometry and schlieren imaging show a distinctly asymmetric growth rate that is highly preferential toward the lower speed (secondary stream) side. For the nitrogen/nitrogen case, for which the convective velocity was lowest and convective Mach number highest, the growth rate on the primary side was virtually zero until the mixing layer reached the opposite (secondary) wall.

Erdos, John↗