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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Imaging spectrometry: Past, present, future

Imaging spectrometry for the remote sensing of the Earth from aircraft and satellites is discussed. Results with an aircraft instrument show that remote, direct identification of surface materials is possible. The airborne and spaceborne sensors can acquire images in 100 to 200 spectral bands. The next generation aircraft scanner (AVIRIS) is expected to be operational in 1987. Plans are underway for a Shuttle instrument (SISEX) to fly in 1991.

Abrams, M. J.↗
NASA NTRS1993

Terrestrial imaging spectrometry - Current status, future trends

A review of recent progress in the field of imaging spectrometry is presented based on the 14 articles comprising the special issue of this journal. The results presented were achieved through research done with data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), the first imaging spectrometer to cover the full solar reflected portion of the spectrum. The majority of the early work in imaging spectrometry prior to AVIRIS focused largely on geological applications and specifically surface mineral identification. In the past 5 years, the range of applications has expanded into the scientific disciplines of ecology, hydrology, oceanography, and atmospheric science. Significant progress has also been made in sensor design and calibration, and information extraction. NASA plans to place high spectral resolution sensors in earth orbit within the next few years; two have been flown already on recent planetary missions and have proven to be of great value to the study of planetary surfaces and atmospheres. The work presented in this issue will lead directly to more effective utilization of imaging spectrometry in the study of the earth. We present a discussion of future trends in imaging spectrometry at the conclusion of this article.

Vane, Gregg↗
NASA NTRS1986

Imaging spectrometry: Aircraft and space program

Imaging spectrometry for the remote sensing of the Earth is introduced. Reflected solar energy from the surface is dispersed in a spectrometer and used to form up to 200 registered spectral images. Each pixel has associated with it sufficient information for the reconstruction of a complete reflectance spectrum. The technique allows the diagnostic narrow band spectral features that are characteristic of many surface materials to be used to identify those materials. These spectral features are typically 20 to 40 nm wide; spectral imaging systems which acquire data in contiguous 10 nm bands therefore have sufficient resolution for direct identification of those materials with diagnostic spectral bands.

Abrams, M. J.↗
NASA NTRS1993

Imaging spectrometry of the Earth and other solar system bodies

Imaging spectrometry is a relatively new tool for remote sensing of the Earth and other bodies of the solar system. The technique dates back to the late 1970's and early 1980's. It is a natural extension of the earlier multi-spectral imagers developed for remote sensing that acquire images in a few, usually broad spectral bands. Imaging spectrometers combine aspects of classical spectrometers and imaging systems, making it possible to acquire literally hundreds of images of an object, each image in a separate, narrow spectral band. It is thus possible to perform spectroscopy on a pixel-by-pixel basis with the data acquired with an imaging spectrometer. Two imaging spectrometers have flown in space and several others are planned for future Earth and planetary missions. The French-built Phobos Infrared Spectrometer (ISM) was part of the payload of the Soviet Mars mission in 1988, and the JPL-built Near Infrared Mapping Spectrometer (NIMS) is currently en route to Jupiter aboard the Galileo spacecraft. Several airborne imaging spectrometers have been built in the past decade including the JPL-built Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) which is the only such sensor that covers the full solar reflected portion of the spectrum in narrow, contiguous spectral bands. NASA plans two imaging spectrometers for its Earth Observing System, the Moderate and the High Resolution Imaging Spectrometers (MODIS and HIRIS). A brief overview of the applications of imaging spectrometry to Earth science will be presented to illustrate the value of the tool to remote sensing and indicate the types of measurements that are required. The system design for AVIRS and a planetary imaging spectrometer will be presented to illustrate the engineering considerations and challenges that must be met in building such instruments. Several key sensor technology areas will be discussed in which miniaturization and/or enhanced performance through micromachining and nanofabrication may allow smaller, more robust, and more capable imaging spectrometers to be built in the future.

Vane, Gregg↗
DOE OSTI2025

Predicting High‐Resolution Spatial and Spectral Features in Mass Spectrometry Imaging with Machine Learning and Multimodal Data Fusion

Recent advancements in molecular Mass Spectrometry Imaging have sparked interest in integrating high spatial resolution methods with molecular mass-spectrometry-based chemical imaging. Fusion-based algorithms have proven effective in generating high spatial-resolution molecular mass spectra. However, a significant challenge stems from the differing physical mechanisms underlying image generation and data upsampling techniques, potentially leading to discrepancies in integrated information channels. Integrating physical constraints into data processing workflows is essential to tackle this issue. In this study, we propose an innovative approach that merges data from Fourier transform ion cyclotron resonance (FTICR), time-of-flight matrix-assisted laser desorption/ionization, and time-of-flight secondary ion mass spectrometry imaging techniques. By leveraging FT-ICR's unparalleled spectral resolution and ToF-SIMS's exceptional spatial resolution, we achieve submicron spatial resolution, enabling the observation of intact molecular species with remarkable spectral precision. Canonical correlation analysis is employed to incorporate physical constraints. Through sophisticated image processing and machine learning techniques, the results of this fusion hold significant promise for advancing our comprehension of complex systems and unveiling concealed molecular intricacies.

canonical correlation analysis↗
NASA NTRS1986

Detection of hydrothermal alteration at Virginia City, Nevada using Airborne Imaging Spectrometry (AIS)

Airborne Imaging Spectrometer (AIS) data were collected over Virginia City, Nevada; an area of gold and silver mineralization with extensive surface exposures of altered volcanic rocks. The data were corrected for atmospheric effects by a flat-field method, and compared to library spectra of various alteration minerals using a spectral analysis program SPAM. Areas of strong clay alteration were identified on the AIS images that were mapped as kaolinitic, illitic, and sericitic alterations zones. Kaolinitic alteration is distinguishable in the 2.1 to 2.4 and 1.2 to 1.5 micrometer wavelength regions. Montmorillonite, illite, and sericite have absorption features similar to each other at 2.2 micrometer wavelength. Montnorillonite and illite also may be present in varying proportions within one Ground Instantaneous Field of View (GIFOV). In general AIS data is useful in identifying alteration zones that are associated with or lie above precious metal mineralization at Virginia City.

Hutsinpiller, A.↗
NASA NTRS1988

Image processing software for imaging spectrometry data analysis

Imaging spectrometers simultaneously collect image data in hundreds of spectral channels, from the near-UV to the IR, and can thereby provide direct surface materials identification by means resembling laboratory reflectance spectroscopy. Attention is presently given to a software system, the Spectral Analysis Manager (SPAM) for the analysis of imaging spectrometer data. SPAM requires only modest computational resources and is composed of one main routine and a set of subroutine libraries. Additions and modifications are relatively easy, and special-purpose algorithms have been incorporated that are tailored to geological applications.

Mazer, Alan↗
NASA NTRS1996

Evolution of Imaging Spectrometry: Past, Present and Future

An overview of the physical principals of imaging spectrometry for detailed characterization of remote objects and of gas vapors is given. The terms Multi-spectral, Hyperspectral, and Ultra-spectral are defined within the framework of applications and instrument system design approaches.

imaging↗
DOE OSTI2026

Desorption Electrospray Ionization–Mass Spectrometry Imaging Provides Spatiochemical Information on Potential Biocontrol Agents against Phytophthora capsici Infection in Tomato Plants

Biological control agents can offer an eco-friendly and more sustainable alternative to conventional chemical pesticides, providing protection against destructive pathogens, such as Phytophthora capsici, while reducing potential environmental harm associated with synthetic pesticide use in agricultural systems. This work evaluates the biocontrol effectiveness of Bacillus vallismortis, Bacillus amyloliquefaciens, Bacillus thuringiensis, and Bacillus subtilis, against the widespread plant pathogen Phytophthora capsici. Our studies showed that Bacillus thuringiensis and Bacillus subtilis promote plant growth and provide protection against Phytophthora capsici in both in vitro and in vivo greenhouse studies, while Bacillus vallismortis and Bacillus amyloliquefaciens were effective in vitro but not in vivo. Specifically, Bacillus thuringiensis was observed to both hinder the growth of Phytophthora capsici and enhance plant resilience to this pathogen, with B. thuringiensis-treated, pathogen-exposed plants displaying a 94.4% increase in root length and a 74.0% increase in shoot height compared to plants with only oomycete exposure. To probe the molecular interactions between the biocontrol agent and pathogen, a dual culture of Bacillus thuringiensis and Phytophthora capsici was analyzed in situ using a desorption electrospray ionization–mass spectrometry imaging (DESI-MSI) workflow. This approach interrogated the spatially oriented biochemical interactions that may serve as the molecular foundation for the effectiveness of these biological control agents in crop protection, identifying seven unique phenotypic regions within the dual culture. Herein, we demonstrate the benefits of biological control agent application in tomato cultivation and showcase the strengths of desorption electrospray ionization–mass spectrometry imaging when applied to the spatially resolved molecular characterization of agriculturally relevant microorganisms.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

An evaluation of imaging spectrometry for estimating forest canopy chemistry

High spectral resolution Airborne Imaging Spectrometer (AIS) data were acquired over 20 well-studied Wisconsin forest sites to evaluate the potential of remote sensing for estimating forest canopy chemistry. Intensive nutrient cycling research in these forests demonstrates that canopy lignin content is strongly related to measured annual nitrogen mineralization at the undisturbed sites and may serve as an accurate index for nitrogen cycling rates. Ground measurements were made of foliar biomass and canopy nitrogen and lignin content, the latter within two weeks of the AIS overflight. The spectral data were transformed using derivative techniques modified from laboratroy spectroscopy. Stepwise regression assisted in determining combinations of wavelengths most highly correlated with canopy chemistry and biomass. Strong correlations between AIS data and total canopy lignin content in deciduous forests and canopy lignin concentration (total lignin/biomass) in both deciduous and coniferous stands indicate that imaging spectrometry can be used to estimate canopy lignin content and, from that, the spatial distribution of annual nitrogen mineralization rates.

Wessman, Carol A.↗
NASA NTRS1992

Utility of imaging spectrometry for lithologic mapping in Greenland

Landsat Thematic Mapper (TM) multispectral image data and field-based spectral reflectance measurements for a portion of the island of Storo, southwestern Greenland, were used to evaluate the potential of imaging spectrometry for lithologic mapping in arctic terrains. TM data allow mapping of tundra vegetation that typically covers moraines at lower elevations, and lichen-covered bedrock exposed at higher elevations. However, the ubiquitous lichen cover, combined with the limited spectral and radiometric capabilities of TM, severely hamper mapping of the amphibolite, anorthosite, gneiss, and granite outcrops on the island. Diagnostic mineral signatures can be discerned from high spectral and radiometric resolution observations, because lichen cover is patchy at mineral and outcrop scales. Results imply that high resolution imaging spectrometer data (e.g., from the HIRIS sensor to fly on the Earth Observing System), detailed field work, and application of subpixel mixing models will dramatically improve the ability to identify and map bedrock in similar terrains.

Rivard, Benoit↗
NASA NTRS1989

Imaging spectrometry in the post-EOS era

It is argued that the next generation of imaging spectrometers will need greater capabilities and more flexibility than the High Resolution Imaging Spectrometer (HIRIS) and the Moderate Resolution Imaging Spectrometer (MODIS), which were designed for the first Earth Observation System platform. The emerging technology that represents a major advance in the scientific utility of imaging spectrometry is the acoustooptic tunable filters, (AOTFs). AOTFs are compact robust solid-state crystals which provide rapid (millisecond) electronically-controlled spectral tunability. This paper discusses the evolving requirements of imaging spectrometers and examines the basic system parameters of the HIRIS and the MODIS concepts involving the use of AOTFs, which will satisfy these requirements.

Duval, Valerie G.↗
NASA NTRS1985

Imaging spectrometry for earth remote sensing

Initial results of the novel remote earth sensing technique of imaging spectrometry, which is technically feasible from both spacecraft and aircraft platforms, indicate that the direct identification of surface materials on a picture-element basis is possible through proper sampling of absorption features in the reflectance spectrum. Sensors of this type are able to acquire images simultaneously in 100-200 contiguous spectral bands. Computerized data reduction and storage techniques are available for the large data sets thus generated, and novel analytic techniques are under development to maximize information content extraction.

Goetz, A. F. H.↗
DOE OSTI2024

Single-colony MALDI mass spectrometry imaging reveals spatial differences in metabolite abundance between natural and cultured Trichodesmium morphotypes

Trichodesmium, a globally significant N 2 -fixing marine cyanobacterium, forms extensive surface blooms in nutrient-poor ocean regions. These blooms consist of a dynamic assemblage of Trichodesmium species that form distinct colony morphotypes and are inhabited by diverse microorganisms. Trichodesmium colony morphotypes vary in ecological niche, nutrient uptake, and organic molecule release, differentially impacting ocean carbon and nitrogen biogeochemical cycles. Here, we assessed the poorly studied spatial abundance of metabolites within and between three morphologically distinct Trichodesmium colonies collected from the Red Sea. We also compared these results with two morphotypes of the cultivable Trichodesmium strain IMS101. Using matrix-assisted laser desorption/ionization (MALDI) mass spectrometry imaging (MSI) coupled with liquid extraction surface analysis (LESA) tandem mass spectrometry (MS2), we identified and localized a wide range of small metabolites associated with single-colony Trichodesmium morphotypes. Our untargeted MALDI-MSI approach revealed 80 unique features (metabolites) shared between Trichodesmium morphotypes. Discrimination analysis showed spatial variations in 57 shared metabolites, accounting for 62% of the observed variation between morphotypes. The greatest variations in metabolite abundance were observed between the cultured morphotypes compared to the natural colony morphotypes, suggesting substantial differences in metabolite production between the cultivable strain IMS101 and the naturally occurring colony morphotypes that the cultivable strain is meant to represent. This study highlights the variations in metabolite abundance between natural and cultured Trichodesmium morphotypes and provides valuable insights into metabolites common to morphologically distinct Trichodesmium colonies, offering a foundation for future targeted metabolomic investigations.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1991

Vegetation Biochemistry: What Can Imaging Spectrometry Tell Us About Canopies?

Changes in ecosystem processes such as productivity and decomposition may be expressed in the canopy foliar chemistry resulting from altered carbon allocation patterns, metabolic processes and nutrient availability. Understanding carbon balance on land over large regions requires quantitative determination of leaf constituents such as lignin and total nitrogen from remote sensing imaging systems. Results from spectral reflectance measurements of stacked leaves in the laboratory show that spectrum matching techniques are applicable to the derivation of the equivalent liquid water thickness in plants as well as to the extraction of dry leaf matter reflectance spectra from spectra of green leaves. The residual spectra derived by subtracting water spectra from the spectra of green leaves shows a feature at 1.72 micrometers that can be related to the lignin content of the leaves. Oak leaves have a deeper residual absorption feature than do cotton leaves which is consistent with their relative lignin content. Similar results are achieved when deriving the residuals from images taken over areas of grass and pine trees. Imaging spectrometry provides promise in developing images of various foliar biochemical constituents.

Goetz, Alexander F. H.↗
NASA NTRS1995

Spectral identification of minerals using imaging spectrometry data: Evaluating the effects of signal to noise and spectral resolution using the tricorder algorithm

The rapid development of sophisticated imaging spectrometers and resulting flood of imaging spectrometry data has prompted a rapid parallel development of spectral-information extraction technology. Even though these extraction techniques have evolved along different lines (band-shape fitting, endmember unmixing, near-infrared analysis, neural-network fitting, and expert systems to name a few), all are limited by the spectrometer's signal to noise (S/N) and spectral resolution in producing useful information. This study grew from a need to quantitatively determine what effects these parameters have on our ability to differentiate between mineral absorption features using a band-shape fitting algorithm. We chose to evaluate the AVIRIS, HYDICE, MIVIS, GERIS, VIMS, NIMS, and ASTER instruments because they collect data over wide S/N and spectral-resolution ranges. The study evaluates the performance of the Tricorder algorithm, in differentiating between mineral spectra in the 0.4-2.5 micrometer spectral region. The strength of the Tricorder algorithm is in its ability to produce an easily understood comparison of band shape that can concentrate on small relevant portions of the spectra, giving it an advantage over most unmixing schemes, and in that it need not spend large amounts of time reoptimizing each time a new mineral component is added to its reference library, as is the case with neural-network schemes. We believe the flexibility of the Tricorder algorithm is unparalleled among spectral-extraction techniques and that the results from this study, although dealing with minerals, will have direct applications to spectral identification in other disciplines.

Swayze, Gregg A.↗
NASA NTRS1994

Galileo infrared imaging spectrometry measurements at the Moon

Imaging spectrometer observations were made of the surface of the Moon during the December 1990 flyby of the Earth-Moon system by the Galileo spacecraft. This article documents this data set and presents analyses of some of the data. The near infrared mapping spectrometer (NIMS) investigation obtained 17 separate mosaics of the Moon in 408 spectral channels between about 0.7 and 5.2 micrometers. The instrument was originally designed to operate in orbit about Jupiter and therefore saturates at many spectral channels for most measurement situations at 1 AU. However, sufficient measurements were made of the Moon to verify the proper operation of the instrument and to demonstrate its capabilities. Analysis of these data show that the NIMS worked as expected and produced measurements consistent with previous ground-based telescopic studies. These are the first imaging spectrometer measurements of this type from space for the Moon, and they illustrate several major points concerning this type of observation and about the NIMS capabilities specifically. Of major importance are the difference between framing and scanning instruments and the effects of the spacecraft and the scan platform on the performance of such and experiment. The science return of subsequent NIMS and other investigation measurements will be significantly enhanced by the experience and results gained.

Mccord, Thomas B.↗