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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Boosting alkaline hydrogen evolution: the dominating role of interior modification in surface electrocatalysis

The alkaline hydrogen evolution reaction (A-HER) holds great promise for clean hydrogen fuel generation but its practical utilization is severely hindered by the sluggish kinetics for water dissociation in alkaline solutions. Traditional ways to improve the electrochemical kinetics for A-HER catalysts have been focusing on surface modification, which still can not meet the demanding requirements for practical water electrolysis because of catalyst surface deactivation. In this work, we report an interior modification strategy to significantly boost the A-HER performance. Specifically, a trace amount of Pt was doped in the interior Co 2 P (Pt–Co 2 P) to introduce a stronger dopant–host interaction than that of the surface-modified catalyst. Consequently, the local chemical state and electronic structure of the catalysts were adjusted to improve the electron mobility and reduce the energy barriers for hydrogen adsorption and H–H bond formation. As a proof-of-concept, the interior-modified Pt–Co 2 P shows a reduced onset potential at near-zero volts for the A-HER, low overpotentials of 2 mV and 58 mV to achieve 10 and 100 mA cm –2 , and excellent durability for long-term utilization. The interior-modified Pt–Co 2 P delivers superior A-HER performance to Pt/C and other state-of-the-art electrocatalysts. This work will open a new avenue for A-HER catalyst design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Space station group activities habitability module study: A synopsis

Space station habitability was studied by investigating crew activity routines, proximities, ergonomic envelopes, and group volumes. Ten alternative schematic interior designs were proposed. Preliminary conclusions include: (1) in-service interior modifications may be necessary and should be planned for; (2) design complexity will be increased if the module cluster is reduced from five to three; (3) the increased crew circulation attendant upon enhancement of space station activity may produce human traffic bottlenecks and should be planned for; (4) a single- or two-person quiet area may be desirable to provide crew members with needed solitude during waking hours; and (5) the decision to choose a two-shift or three-shift daily cycle will have a significant impact on the design configuration and operational efficiency of the human habitat.

Nixon, David↗

New fireworthy composites for use in transportation vehicles

This paper presents an overview of certain aspects of the evaluation of the fireworthiness of air transport interiors. It examines some technical opportunities that are available today through the modification of aircraft interior subsystem components, modifications that may reasonably be expected to provide improvements in aircraft fire safety. These modifications have the potential of reducing the rate of fire growth, with a consequent reduction of heat, toxic gas, and smoke emission throughout the habitable interior of an aircraft, whatever the initial source of the fire. It is shown that these new materials modifications reduce the fire hazard not only because of their unique ablative properties, which help to contain or isolate the fire source, but also because there is a significant reduction in their characteristic flame spread, heat release, and smoke and toxic gas emissions.

Parker, J. A.↗

Stellar evolution at high mass with semiconvective mixing according to the Schwarzschild criterion

Evolutionary sequences for stellar models with 10, 15, 30, and 60 solar masses, as well as four different initial chemical compositions, are calculated to the end of core helium burning using the Schwarzschild criterion for convection. The results are analyzed in terms of the modifications of interior structure and surface parameters induced by semiconvective mixing as a result of adopting the Schwarzschild criterion. It is found that the main differences from results based on the Ledoux criterion are the great extent of the convectively unstable layers in the intermediate zone and the eventual development of a fully convective zone at the base of the semiconvective one. It is shown that semiconvection develops outside the convective core just after the ZAMS stage for masses greater than 12 solar masses and just before the stage of central hydrogen exhaustion for masses greater than 6 solar masses. The present models are found to be insufficiently hot in comparison with the bulk of observed stable blue supergiants and to predict far too many red supergiants fro the range above 20 solar masses. It is concluded that something is fundamentally wrong with the models, the most likely suspects being the stellar opacities adopted and the neglect of mass loss.

Stothers, R.↗

Fireworthiness of transport aircraft interior systems

The key materials question is addressed concerning the effect of interior systems on the survival of passengers and crew in the case of an uncontrolled transport aircraft fire. Technical opportunities are examined which are available through the modification of aircraft interior subsystem components, modifications that may reasonably be expected to provide improvements in aircraft fire safety. Subsystem components discussed are interior panels, seats, and windows. By virtue of their role in real fire situations and as indicated by the results of large scale simulation tests, these components appear to offer the most immediate and highest payoff possible by modifying interior materials of existing aircraft. These modifications have the potential of reducing the rate of fire growth, with a consequent reduction of heat, toxic gas, and smoke emission throughout the habitable interior of an aircraft, whatever the initial source of the fire.

Parker, J. A.↗

Fireworthiness of transport aircraft interior systems

This paper presents an overview of certain aspects of the evaluation of the fireworthiness of transport aircraft interiors. First, it addresses the key materials question concerning the effect of interior systems on the survival of passengers and crew in the case of an uncontrolled fire. Second, it examines some technical opportunities that are available today through the modification of aircraft interior subsystem components, modifications that may reasonably by expected to provide improvements in aircraft fire safety. Cost and risk benefits still remain to be determined.

Parker, J. A.↗

Fireworthiness of transport aircraft interior systems

The fire worthiness of air transport interiors was evaluated. The effect of interior systems on the survival of passengers and crew in an uncontrolled transport aircraft fire is addressed. Modification of aircraft interior subsystem components which provide improvements in aircraft fire safety are examined. Three specific subsystem components, interior panels, seats and windows, offer the most immediate and highest payoff by modifying interior materials of existing aircrafts. It is shown that the new materials modifications reduce the fire hazards because of significant reduction in their characteristic flame spread, heat release, and smoke and toxic gas emissions.

Parker, J. A.↗

XHAB 2012 Final Report Habitat Demonstration Unit Lite

The University of Maryland Space Systems Laboratory (SSL) was awarded a NASA X-Hab 2012 grant for the design and construction of a new Earth analogue habitat for habitability research. This work builds on the past ECLIPSE and X-Hab projects at the SSL, by combining these elements with a new habitat module in order to create a single research platform for habitability studies. The “Crew Habitat Evaluator for Long-duration Orbital, Near-earth, and Interplanetary Applications” (CHELONIA) will deliver a much more flexible architecture than the previously developed mock-ups, allowing facilitating faster modification of the interior layouts and available total volume. This will enable the investigators to evaluate crew assessments and task performance as a function of the interior layout, functional area allocation and total available volume. This paper documents the design of this new infrastructure, and includes the details of the manufacturing of a new habitat mock-up module and modifications to the existing elements. The paper also includes a brief discussion of possible future research goals. Initial layouts are implemented using foam-core volumetric mock-ups for internal equipment and outfitting. These low fidelity mock-ups constitute a “library” that will allow a very rapid evaluation of a multitude of layouts. CHELONIA is also suitable for higher fidelity functional mock-ups, as well as short to medium-duration mission simulations. This new facility will enable the examination of habitat layouts for both partial gravity and microgravity environments. While partial gravity systems will be easily evaluated with the habitat currently in development, microgravity subsystems will be studied by utilizing low fidelity volumetric neutral buoyancy mock-ups in order to determine if commonality in the design for these two environments is appropriate. Finally, this new facility is being integrated into the SSL Moonyard planetary surface simulation center. The Moonyard simulates a planetary surface by means of a large sandbox, and is used primarily for rover field trials and suit systems evaluation. This new facility will be a prime element in future Earth analog simulations at the University of Maryland in support of NASA exploration objectives.

Kevin Davis↗

The Transition from Complex Crater to Peak-Ring Basin on the Moon: New Observations from the Lunar Orbiter Laser Altimeter (LOLA) Instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.

Baker, David M. H.↗

Polymer Coatings on Virus-like Particle Nanoreactors at Low Ionic Strength—Charge Reversal and Substrate Access

Virus-like particles (VLPs) are a class of biomaterials which serve as platforms for achieving the desired functionality through interior and exterior modifications. Through ionic strength-mediated electrostatic interactions, VLPs have been assembled into hierarchically ordered materials. This work builds on predictive models to prepare polymer-coated VLP dusters at very low ionic strength. Zeta potential measurements showed that the clusters carried a strongly positive charge, a complete charge reversal from the VLP building block. SAXS analysis confirmed polymer adsorption onto the VLP exterior. Furthermore, we then studied the activity of an encapsulated enzyme toward small molecular and macromolecular substrates to determine the effect of each component of the hierarchically assembled material. We found that while encapsulation and polymer coating did not have a large effect on access to the enzyme by its native, small molecular substrate, substrate modification with a macromolecule caused the polymer coating and encapsulation to affect the access to the enzyme.

59 BASIC BIOLOGICAL SCIENCES↗

A low cost igniter utilizing an SCB and titanium sub-hydride potassium perchlorate pyrotechnic

A conventional NSI (NASA Standard Initiator) normally employs a hot-wire ignition element to ignite ZPP (zirconium potassium perchlorate). With minor modifications to the interior of a header similar to an NSI device to accommodate an SCB (semiconductor bridge), a low cost initiator was obtained. In addition, the ZPP was replaced with THKP (titanium sub-hydride potassium perchlorate) to obtain increased overall gas production and reduced static-charge sensitivity. This paper reports on the all-fire and no-fire levels obtained and on a dual mix device that uses THKP as the igniter mix and a thermite as the output mix.

R. W. Bickes, Jr.↗

Effects of an internal floor on low frequency sound transmission into aircraft cabins - An experimental investigation

A simplified cylindrical model of an aircraft fuselage is used to experimentally study the effects of an internal floor on low frequency sound transmission into aircraft cabins. A scaled-down lattice floor support and floor skin are designed based upon selected characteristics of a business aircraft. Thus, the model provides a simplified procedure for studying the effects of various structural modifications as well as other important effects. Modal decomposition of the shell response and the corresponding pressure response at various interior locations are presented. Results indicate that the main effect of the floor on interior pressure levels is due to modification of the interior acoustic mode shape and not due to the structural modification of the fuselage caused by the lattice floor support.

Jones, J. D.↗

Volatile-rich Crater Interior Deposits on Mars: An Energy Balance Model of Modification

Several craters on Mars are partially filled by material emplaced by post-impact processes. Populations of such craters include those in the circumsouth polar cap region, in Arabia Terra, associated with the Medusae Fossae Formation, and in the northern lowlands proximal to the north polar cap. In this study, crater fill material refers to an interior mound, generally separated from the interior walls of the crater by a trough that may be continuous along the crater s circumference (i.e. a ring-shaped trough), or may only partially contact the crater walls (i.e. a crescent-shaped trough). The fill deposit is frequently off-center from the crater center and may be asymmetric, (i.e. not circular) in plan view shape. Here we test the hypothesis that asymmetries in volatile fill shape, profile, and center-location within a crater result from asymmetries in local energy balance within the crater due mainly to variation of solar insolation and radiative effects of the crater walls over the crater interior. We first focus on Korolev crater in the northern lowlands. We can then apply this model to other craters in different regions. If asymmetry in morphology and location of crater fill are consistent with radiative-dominated asymmetries in energy budget within the crater, then 1) the volatile-rich composition of the fill is supported (this process should not be effective at shaping volcanic or sedimentary deposits), and 2) the dominant factor determining the observed shape of volatile-rich crater fill is the local radiative energy budget within the crater (and erosive processes such as eolian deflation are not necessary).

Russell, Patrick S.↗

The role of rim slumping in the modification of lunar impact craters

The role of rim slumping in the formation of terraces on interior crater walls and consequent modifications of the shapes of large lunar impact craters is evaluated. Impact excavation cavities were reconstructed by means of a terrace restoration model for twelve lunar craters ranging in diameter from 19 to 137 km. For craters up to 30 km, reconstructed cavity depths are comparable to or greater than cavity depths extrapolated from nonterraced smaller craters, and in the 30 to 70 km diameter range, the reconstructed cavity depths are significantly greater. For craters larger than 70 km, however, the reconstructed cavity depths are consistently less than those predicted from small crater morphometry, indicating a significant additional contribution from ejecta fallback and basement rebound to the modification of the shape of impact craters greater than 70 km.

Settle, M.↗

A discontinuous piecewise polynomial generalized moving least squares scheme for robust finite element analysis on arbitrary grids

A variational approach is developed with a meshless discretization to enable accurate and robust numerical simulation of partial differential equations for meshes that are of poor quality. Traditional finite element methods use the mesh to both discretize the geometric domain and to define the finite element shape functions. The latter creates a dependence between the quality of the mesh and the properties of the finite element basis that may adversely affect the accuracy of the discretized problem. Here, we propose a new approach for defining finite element shape functions that breaks this dependence and separates mesh quality from the discretization quality, which we call discontinuous piecewise polynomial generalized moving least squares (DPP-GMLS). At the core of the approach is a meshless definition of the shape functions, which limits the purpose of the mesh to representing the geometric domain and integrating the basis functions without having any role in their approximation quality. The resulting non-conforming space can be utilized within a standard discontinuous Galerkin framework, providing a rigorous foundation for solving partial differential equations on low-quality meshes. We present a collection of numerical experiments demonstrating our approach in a wide range of settings: strongly coercive elliptic problems, linear elasticity in the compressible regime, and the stationary Stokes problem. We demonstrate convergence for all problems and stability for element pairs for problems which usually require inf-sup compatibility for conforming methods, also referring to a minor modification possible through the symmetric interior penalty Galerkin framework for stabilizing element pairs that would otherwise be traditionally unstable. Mesh robustness is particularly critical for elasticity, and we provide an example that our approach provides a greater than 5 x improvement in accuracy and allows for taking an 8 x larger stable timestep for a highly deformed mesh, compared to the continuous Galerkin finite element method.

97 MATHEMATICS AND COMPUTING↗

Regression Based Approach for Robust Finite Element Analysis on Arbitrary Grids. LDRD Final Report

This report summarizes the work performed under a one-year LDRD project aiming to enable accurate and robust numerical simulation of partial differential equations for meshes that are of poor quality. Traditional finite element methods use the mesh to both discretize the geometric domain and to define the finite element shape functions. The latter creates a dependence between the quality of the mesh and the properties of the finite element basis that may adversely affect the accuracy of the discretized problem. In this project, we propose a new approach for defining finite element shape functions that breaks this dependence and separates mesh quality from the discretization quality. At the core of the approach is a meshless definition of the shape functions, which limits the purpose of the mesh to representing the geometric domain and integrating the basis functions without having any role in their approximation quality. The resulting non-conforming space can be utilized within a standard discontinuous Galerkin framework providing a rigorous foundation for solving partial differential equations on low-quality meshes. We present a collection of numerical experiments demonstrating our approach in a wide range of settings: strongly coercive elliptic problems, linear elasticity in the compressible regime, and the stationary Stokes problem. We demonstrate convergence for all problems and stability for element pairs for problems which usually require inf-sup compatibility for conforming methods, also referring to a minor modification possible through the symmetric interior penalty Galerkin framework for stabilizing element pairs that would otherwise be traditionally unstable. Mesh robustness is particularly critical for elasticity, and we provide an example that our approach provides a greater than 5x improvement in accuracy and allows for taking an 8x larger stable timestep for a highly deformed mesh, compared to the continuous Galerkin finite element method. The report concludes with a brief summary of ongoing projects and collaborations that utilize or extend the products of this work.

97 MATHEMATICS AND COMPUTING↗

A strategy for the efficient simulation of viscous compressible flows using a multi-domain pseudospectral method

The viscous compressible flow in a quasi-1D nozzle is presently simulated by means of a novel multidomain pseudospectral method in which interface-point flow variables are advanced in time on the basis of the second-order time-marching scheme used for the interior points. A spectrally accurate modification of Van Leer's (1982) flux-vector flux-splitting method is used to evaluate the spatial derivatives of the inviscid flux vector; these derivatives are alternately evaluated from neighboring subdomains, and the scheme is found to be spectrally accurate and to resolve shock waves without oscillations.

Hanley, Patrick↗

Wind-Related Modification of Some Small Impact Craters on Mars

Inferred wind-related modifications of impact craters are observed in the vicinity of the Mare Pathfinder (MPF) site and in other regions of Mars. Mars Orbiter Camera (MOC) images show three types of inferred wind-modified morphologies for craters 0.3-1 km in diameter Such modifications could be related to seasonal variations of the strongest winds and a possible paleowind regime. Geomorphic mapping of Big Crater at the MPF shows evidence of former aeolian modification of the crater rim and interiors similar to smaller craters in the area. The morphologic patterns are in good agreement with the results from the Mars Regional Atmospheric Modeling Simulation (MRAMS) of topographically forced wind circulation and atmosphere surface interactions generated by flow over small craters. Simulations show that the maximum surface stress is on the downwind crater rim, consistent with inferred wind modification of the crater rim seen in MOC images. The trend of the Inferred paleowind regime at the MPF site cannot be explained by a change In the global atmospheric circulation resulting ~ from changes in Mars obliquity. We suggest that this wind regime could be associated with a regional meteorological pattern that is not modeled by global scale circulation, An alternative explanation is that Mars spin axis was in a different geographic position than it is at present.

Kuzmin, Ruslan O.↗