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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1989

Silicon chemistry in interstellar clouds

Interstellar SiO was discovered shortly after CO but it has been detected mainly in high density and high temperature regions associated with outflow sources. A new model of interstellar silicon chemistry that explains the lack of SiO detections in cold clouds is presented which contains an exponential temperature dependence for the SiO abundance. A key aspect of the model is the sensitivity of SiO production by neutral silicon reactions to density and temperature, which arises from the dependence of the rate coefficients on the population of the excited fine structure levels of the silicon atom. This effect was originally pointed out in the context of neutral reactions of carbon and oxygen by Graff, who noted that the leading term in neutral atom-molecule interactions involves the quadrupole moment of the atom. Similar to the case of carbon, the requirement that Si has a quadrupole moment requires population of the J = 1 level, which lies 111K above the J = 0 ground state and has a critical density n(cr) equal to or greater than 10(6)/cu cm. The SiO abundance then has a temperature dependence proportional to exp(-111/T) and a quadratic density dependence for n less than n(cr). As part of the explanation of the lack of SiO detections at low temperatures and densities, this model also emphasizes the small efficiencies of the production routes and the correspondingly long times needed to reach equilibrium. Measurements of the abundance of SiO, in conjunction with theory, can provide information on the physical properties of interstellar clouds such as the abundances of oxygen bearing molecules and the depletion of interstellar silicon.

Langer, William D.↗
NASA NTRS1976

High-velocity interstellar clouds

Interstellar absorption line studies have revealed that rapidly moving clouds within one kiloparsec of the sun have considerably less depletion of heavy elements than in the low-velocity diffuse clouds, and their density is somewhat greater and their thickness smaller. Evaporation of interstellar grains, resulting from grain-grain collisions in interstellar shocks, may provide a possible explanation for the observations. Some problems involved in this mechanism are discussed, particularly the likely dominant importance of the interstellar magnetic field in confining the grains within the shocked layer and in accelerating them through the associated electric field, thus offsetting the frictional force of the gas.

Spitzer, L.↗
NASA NTRS1995

Hubble Space Telescope observations of C2 molecules in diffuse interstellar clouds

Interstellar C2 F-X (1342 A) and D-X (2313 A) bands in the spectrum of zeta Oph were detected using the Goddard High-Resolution Spectrograph (GHRS) on the Hubble Space Telescope (HST). The total C2 column density is (1.79 +/- 0.06) 10(exp 13)/sq cm for an adopted f-value of 0.0545 for the 2313 A band of the Mulliken (D-X) system. Relative f-values for the 0-0 F-X, 0-0 D-X, and 2-0 A-X (Phillips) bands are derived by combining ultraviolet and near-infrared spectra: f(sub 00 sup FX)/f(sub 00 sup DX) = 1.83 +/- 0.18 and f(sub 20 sup AX)/f(sub 00 sup DX) = 0.0226 +/- 0.0029. For the Mulliken system, lines are detected up to a rotational level J double prime = 24. The relative populations along the rotational ladder are shown to be consistent with the physical and environmental conditions suggested by other diagnostics. Interstellar C2 molecules were detected towards zeta Per (N(C2) = (0.80 +/- 0.23) 10(exp 13)) but not towards Beta(sup 1), pi, and omega(sup 1) Sco(N(C2) less than or equal to 0.17 x 10(exp 13)/sq cm.

Lambert, David L.↗
NASA NTRS1990

Studies of the local interstellar medium. VIII - Morphology and kinematics of the diffuse interstellar clouds toward Orion

Interstellar clouds in the direction of the Orion association show only positive velocities for target stars within 190 pc of the sun, and both positive and negative velocities for more distant target stars, confirming an earlier prediction by Cowie, Songaila, and York (1979). The nearby positive velocity cloud, designated here as Orion-Lepus 70 (OL 70), is a standard diffuse interstellar cloud: it is subject to the ambient galactic radiation field, with properties consistent with T about equal to 100 K and n about equal to 3/cu cm. Combined with a column density log N(H) = 19.8-20.0/sq cm, these values imply a cloud thickness of about 7 pc. The kinematics of OL 70 are consistent with either an origin as part of the expanding Loop I superbubble shell, or as part of Lindbald's expanding ring, or a synthesis of the two models. The negative velocity interstellar components seen in stars at d not less than 200 pc are caused by interstellar matter accelerated by the expanding Ori-Eri superbubble. Relatively dense interstellar gas at positive LSR velocities is also found within the Orion association, so that it is difficult to pick out OL 70 components in the spectra of the distant stars.

Frisch, P. C.↗
NASA NTRS1994

On the hydrodynamic interaction of shock waves with interstellar clouds. 1: Nonradiative shocks in small clouds

The interstellar medium (ISM) is inhomogeneous, with clouds of various temperatures and densities embedded in a tenuous intercloud medium. Shocks propagating through the ISM can ablate or destroy the clouds, at the same time significantly altering the properties of the intercloud medium. This paper presents a comprehensive numerical study of the simplest case of the interaction between a shock wave and a spherical cloud, in which the shock far from the cloud is steady and planar, and in which radiative losses, thermal conduction, magnetic fields, and gravitational forces are all neglected. As a result, the problem is completely specified by two numbers: the Mach number of the shock, M, and the ratio of the density of the cloud to that of the intercloud medium, Chi. For strong shocks we show that the dependence on M scales out, so the primary independent parameter is Chi. Variations from this simple case are also considered: the potential effect of radiative losses is assessed by calculations in which the ratio of specific heats in the cloud is 1.1 instead of 5/3; the effect of the initial shape of the cloud is studied by using a cylindrical cloud instead of a spherical one; and the role of the initial shock is determined by considering the case of a cloud embedded in a wind. Local adaptive mesh refinement techniques with a second-order, two-fluid, two-dimensional Godunov hydrodynamic scheme are used to address these problems, allowing heretofore unobtainable numerical resolution. Convergence studies to be described in a subsequent paper demonstrate that about 100 zones per cloud radius are needed for accurate results; previous calculations have generally used about a third of this number. The results of the calculations are analyzed in terms of global quantities which provide an overall description of te shocked cloud: the size and shape of the cloud, the mean density, the mean pressure, the mean velocity, the velocity dispersion, and the total circulation.

Klein, Richard I.↗
NASA NTRS1974

Statistical properties of interstellar clouds

Scans of the interstellar 7699-A line of K I in the spectra of 26 stars show that the K I lines are highly appropriate for a study of the local statistical distributions of several observable properties of interstellar clouds and, in principle, of the intercloud medium. A description is presented of the distribution functions obtained from the currently available sample of 37 interstellar clouds, measured toward 17 stars. It is pointed out that a very considerable expansion of this sample should be possible in the immediate future.

Hobbs, L. M.↗
NASA NTRS1975

Interstellar clouds containing optically thick H2

Interstellar clouds containing optically thick H2 are investigated on the basis of the hypothesis that the population of the H2 rotational levels can be understood in terms of optical pumping in the Lyman and Werner bands. The observed populations are used to infer the densities and radiation fields within the clouds. The theoretical model adopted for an interstellar cloud and the analytical procedure are described. It is found that, of the 10 clouds studied, five are illuminated by a UV field appropriate to within a factor of two to that in the solar neighborhood, four appear to be near the stars against which they are observed, and one is irradiated by a very low intensity field. The results suggest that there are substantial pressure variations in the interstellar gas, even among those clouds not located near H II regions.

Jura, M.↗
NASA NTRS1977

Isotopic abundances in interstellar clouds

Results of microwave measurements in dense interstellar clouds are discussed which pertain to determinations of relative isotopic abundances. Difficulties in deriving relative abundances from observations of the relative intensities of isotopic lines are examined, and measures available for coping with these complications are outlined. Results are presented concerning the relative abundances of C-13, O-17, O-18, N-15, Si-30, S-33, S-34, and D in a variety of interstellar clouds; the consistency of these results is evaluated. It is concluded that: (1) the relative abundances of C-13 and O-17 in interstellar clouds are generally higher than those in the solar system; (2) the abundances of N-15 and D are lower than the solar-system values; (3) the O-18 abundance is possibly higher than in the solar system; and (4) there are substantial variations in the isotopic abundances between different large interstellar clouds, with some of these variations not dependent on distance from the galactic center alone.

Townes, C. H.↗
NASA NTRS1981

Molecules in interstellar clouds

The physical conditions and chemical compositions of the gas in interstellar clouds are reviewed in light of the importance of interstellar clouds for star formation and the origin of life. The Orion A region is discussed as an example of a giant molecular cloud where massive stars are being formed, and it is pointed out that conditions in the core of the cloud, with a kinetic temperature of about 75 K and a density of 100,000-1,000,000 molecules/cu cm, may support gas phase ion-molecule chemistry. The Taurus Molecular Clouds are then considered as examples of cold, dark, relatively dense interstellar clouds which may be the birthplaces of solar-type stars and which have been found to contain the heaviest interstellar molecules yet discovered. The molecular species identified in each of these regions are tabulated, including such building blocks of biological monomers as H2O, NH3, H2CO, CO, H2S, CH3CN and H2, and more complex species such as HCOOCH3 and CH3CH2CN.

Irvine, W. M.↗
NASA NTRS1978

Energetic secondary electrons and the nonthermal galactic radio background - A probe of the magnetic field in interstellar clouds

A previous analysis of the manifestations of charged-pion-decay secondary electrons in interstellar cloud material is extended to include those contributions to the Galactic radio and soft gamma-ray backgrounds that are directly attributable to energetic secondaries. The equilibrium distribution of secondary electrons in dense interstellar clouds is calculated, synchrotron emissivity from isolated interstellar clouds is examined, and it is shown how the value of the magnetic field in these clouds may be determined by observing the radio emission in their directions. The contribution that such clouds make to the integrated radio background is evaluated, and the Galactic distribution of bremsstrahlung gamma rays that arise from interactions of secondary electrons with thermal material in dense clouds is computed. The results indicate that a magnetic field of no more than 80 microgauss is characteristic of dense clouds and that the integrated synchrotron radiation from secondary electrons in interstellar clouds will contribute a significant fraction of the nonthermal brightness along the Galactic equator even if the mean cloud field is as low as 35 microgauss.

Marscher, A. P.↗
NASA NTRS1993

Theoretical studies in interstellar cloud chemistry

This final report represents the completion of the three tasks under the purchase order no. SCPDE5620,1,2F. Chemical composition of gravitationally contracting, but otherwise quiescent, interstellar clouds and of interstellar clouds traversed by high velocity shocks, were modeled in a comprehensive manner that represents a significant progress in modeling these objects. The evolutionary chemical modeling, done under this NASA contract, represents a notable advance over the 'classical' fixed condition equilibrium models because the evolutionary models consider not only the chemical processes but also the dynamical processes by which the dark interstellar clouds may have assumed their present state. The shock calculations, being reported here, are important because they extend the limited chemical composition derivable from dynamical calculations for the total density and temperature structures behind the shock front. In order to be tractable, the dynamical calculations must severely simplify the chemistry. The present shock calculations take the shock profiles from the dynamical calculations and derive chemical composition in a comprehensive manner. The results of the present modeling study are still to be analyzed with reference to astronomical observational data and other contemporary model predictions. As far as humanly possible, this analysis will be continued with CRE's (Creative Research Enterprises's) IR&D resources, until a sponsor is found.

Chiu, Y. T.↗
NASA NTRS1980

Modeling of diffuse interstellar clouds - The case of Gamma Arae

Observations of the interstellar cloud toward Gamma Arae (Morton and Hu, 1975) are analyzed with an improved version of the isobaric, steady-state model of Glassgold and Langer (1974). Good agreement is obtained using parameters which are close to those which represent the average properties of many diffuse interstellar clouds. The successful correlation of the data for H, H2, C II, C I, OI, CO, and OH supports current concepts on interstellar thermodynamics and chemistry.

Federman, S. R.↗
NASA NTRS1995

Organic molecules in the gas phase of dense interstellar clouds

Since a previous Committee on Space Research (COSPAR) review on this subject, the number of molecular species identified by astronomers in dense interstellar clouds or in the envelopes expelled by evolved stars has grown from about eighty to approximately one hundred. Recent detections in stellar envelopes include the radical CP, the second phosphorus-containing astronomical molecule; SiN, the first astronomical molecule with a Si-N bond; and the HCCN radical. In the dense interstellar clouds recent detections or verifications of previous possible identifications include the H3O(+) ion, which is a critical intermediary in the production of H2O and O2; the CCO radical, which is isoelectronic with HCCN; the SO(+) ion, which appears to be diagnostic of shock chemistry; two new isomers of cyanoacetylene, HCCNC and CCCNH; and the two cumulenes H2C3 and H2C4. Some recent work is also described on the mapping of interstellar clouds in multiple molecular transitions in order to separate variations in chemical abundance from gradients in physical parameters.

Irvine, W. M.↗
NASA NTRS1973

A search for H alpha emission from interstellar clouds.

Upper limits have been determined for the emission measures of five interstellar clouds. These limits are significantly smaller than the emission measures predicted by a recent model in which the variation in the column-density ratio Na/Ca(+) among interstellar clouds is attributed to differences in the temperature, density, and hydrogen ionization fraction of the clouds.

Reynolds, R. J.↗
NASA NTRS1972

The formation of diatomic molecules in interstellar clouds.

The formation of the classical interstellar molecules CH, CH(+), and CN is investigated, giving attention to the chemistry of moderate-density interstellar clouds. An H I region is considered in the model employed in the study. The major constituents in the region are atoms or ions because of the intensity of the UV radiation field. Aspects of radiative association are discussed together with chemical reactions, the electronic states and optical properties of CH and CH(+), and photodissociation rates.

Solomon, P. M.↗
NASA NTRS1981

Abundance of atomic carbon /C I/ in dense interstellar clouds

The abundance of interstellar neutral atomic carbon is investigated by means of its ground state fine-structure line emission at 492 GHz using the 91.5 cm telescope of NASAs Kuiper Airborne Observatory. Atomic carbon is found to be very abundant in dense interstellar molecular clouds with column densities of about 10 to the 19th per sq cm. Because the observations have considerably greater column densities than current theories of carbon chemistry, it is suggested that the physical conditions of these clouds are not as simple as assumed in the models. Various situations are discussed which would lead to large C I abundances, including the possibility that the chemical lifetimes of the clouds are relatively short.

Phillips, T. G.↗