Extremely High-Energy Density Batteries Using Fluoride-Ion Insertion
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Melot, Brent↗
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Development of a large insert gas ion thruster
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Steiner, G.↗
Theoretical study of the bonding of Sc, Y, and La singly charged and dipositive ions to C2H2, C2H4, and C3H6
The interaction of the Sc and Y singly-charged and dipositive ions with C2H2, C2H4, and C3H6 is studied using electronic structure calculations that include high levels of electron correlation. These results are compared with comparable calculations performed previously for La(+) and La(2+). For C2H2 and C2H4, all three metal ions insert into the C-C pi bond, making a three-membered ring. The optimal structures for the MC3H6(+) ions all involve rearrangement to make a four-membered ring. The strength of the metal-ligand bond for the singly charged ions follows the order La greater than Sc equal to about Y. In contrast, the bonds involving the dipositive ions are electrostatic, so that the binding energy increases as the size of the ion decreases, leading to the trend Sc greater than Y greater than La.
Bauschlicher, Charles W., Jr.↗
Fundamental Investigation of Si Anode in Li-Ion Cells
Silicon is a promising and attractive anode material to replace graphite for high capacity lithium ion cells since its theoretical capacity is approximately 10 times of graphite and it is an abundant element on earth. However, there are challenges associated with using silicon as Li-ion anode due to the significant first cycle irreversible capacity loss and subsequent rapid capacity fade during cycling. In this paper, cyclic voltammetry and electrochemical impedance spectroscopy are used to build a fundamental understanding of silicon anodes. The results show that it is difficult to form the SEI film on the surface of Si anode during the first cycle, the lithium ion insertion and de-insertion kinetics for Si are sluggish, and the cell internal resistance changes with the state of lithiation after electrochemical cycling. These results are compared with those for extensively studied graphite anodes. The understanding gained from this study will help to design better Si anodes.
Wu, James J.↗
Fundamental Investigation of Silicon Anode in Lithium-Ion Cells
Silicon is a promising and attractive anode material to replace graphite for high capacity lithium ion cells since its theoretical capacity is ~10 times of graphite and it is an abundant element on Earth. However, there are challenges associated with using silicon as Li-ion anode due to the significant first cycle irreversible capacity loss and subsequent rapid capacity fade during cycling. Understanding solid electrolyte interphase (SEI) formation along with the lithium ion insertion/de-insertion kinetics in silicon anodes will provide greater insight into overcoming these issues, thereby lead to better cycle performance. In this paper, cyclic voltammetry and electrochemical impedance spectroscopy are used to build a fundamental understanding of silicon anodes. The results show that it is difficult to form the SEI film on the surface of a Si anode during the first cycle; the lithium ion insertion and de-insertion kinetics for Si are sluggish, and the cell internal resistance changes with the state of lithiation after electrochemical cycling. These results are compared with those for extensively studied graphite anodes. The understanding gained from this study will help to design better Si anodes, and the combination of cyclic voltammetry with impedance spectroscopy provides a useful tool to evaluate the effectiveness of the design modifications on the Si anode performance.
Wu, James J.↗
Variable Depth Bragg Peak Method for Single Event Effects Testing
Traditionally, accelerator SEE testing is accomplished by removing the tops of packages so that the IC chips are accessible to heavy ions. However, ICs in some advanced packages cannot be de-lidded so a different approach is used that involves grinding and/or chemically etching away part of the package and the chip from the back side. The parts are then tested from the back side with ions having sufficient range to reach the sensitive volume. More recently, the entire silicon substrate in an SOI/SRAM was removed, making it possible to use low-energy ions with shorter ranges. Where removal of part of the package is not possible, facilities at Michigan State, NASA Space Radiation Laboratory, GANIL (France) and GSI (Germany) offer high-energy heavy ions with long ranges so that the ions can reach the devices' sensitive volumes without much change in the LET. Unfortunately, a run will typically involve only one ion species having a single energy and LET due to the long time it takes to tune a new energy. The Variable Depth Bragg Peak (VDBP) method is similar to the above method in that it involves the use of high-energy heavy ions that are able to pass through the packaging material and reach the device, obviating the need to remove the package. However, the method provides a broad range of LETs from a single ion by inserting degraders in the beam that modify the ion energy and, therefore, the LET. The crux of the method involves establishing a fiduciary point for degrader thickness, i.e., where the Bragg peak is located precisely at the sensitive volume in the device, for which the measured SEU cross-section and the ion LET are both also maxima and can be calculated using a Monte-Carlo program, TRIM. Once the fiduciary point has been established, calibrated high density polyethylene (HDPE) degraders are inserted into or removed from the beam to vary the ion LET at the device in a known manner. After each change of degrader thickness, the SEU cross-section is measured and the corresponding LET calculated from the change in degrader thickness. That information is used to generate a plot of cross-section as a function of ion LET. The advantages of this approach are that the part does not have to be de-lidded and a broad range of LETs is available from a single heavy ion without having to go to non-normal angles of incidence to change the "effective" LET. As we will show, it is possible to obtain an entire curve of cross-section versus LET using just two or three ions. Fig. 1 shows curves of cross-section vs LET for a Freescale 4 Mbit SOI/SRAM measured at the 88" Cyclotron at Berkeley and at NSRL. The open symbols are the data obtained from Berkeley for top-side and back-side irradiation. The solid data points are for the data obtained at NSRL using a device for which the package was intact. The data are for Iron and Gold and cover a range of LETs from 4 MeV.cm2/mg to 84 MeV.cm2/mg. The agreement between the data obtained from Berkeley and from NSRL is excellent, demonstrating that the VDBP method is capable of providing accurate values of cross-section versus LET, at least for the 4 Mbit SRAM. Details of the technique will be included in the final presentation.
Buchner, S.↗
Lithium-ion Battery Strain Gauge Monitoring and Depth of Discharge Estimation
Lithium-ion battery diagnostics and prognostics rely on measurements of electrical impedance, capacity, and voltage to infer the internal state of the battery. Mechanical changes to the cell structure represent an additional measure of the battery’s state because these changes are related to the overall battery health. As lithium-ion batteries are charged and discharged, lithium ions are inserted or removed from the anode and cathode, a process called intercalation and de-intercalation. As lithium ions intercalate and de-intercalate, they can cause changes to the lattice of the electrode particles, resulting in volumetric changes. These volumetric changes cause mechanical stresses and strains on the lithium-ion battery electrodes, and subsequently, the whole cell’s thickness varies as it is charged and discharged. This paper presents a study on the use of surface-mounted strain gauges for in-situ measurement of structural changes to lithium-ion batteries, along with a characterization of the unit-to-unit differences in strain response. A neural network modeling structure is then used to predict the battery’s depth of discharge under dynamic discharge conditions.
Lithium-ion batteries, depth of discharge, strain ↗
Experimental studies of the interaction between collisionless plasmas and electromagnetic fields.
Steady state interaction between collisionless plasma flow and immersed stationary magnetized or unmagnetized objects by inserting Cs ion accelerator into plasma wind tunnel
Cohen, L. G.↗
The Effect of Anode Configuration on the Plasma Plume of a 25-A class Hollow Cathode
The effect of anode configuration on the plasma plume properties of a 25-A class hollow cathode are experimentally characterized. At a nominal operating condition of 20.8 A and 14.7 sccm of xenon, the cathode was operated with two axially-segmented anodes of different diameters at varying distance from the cathode. A fast, reciprocating motion stage was used to rapidly insert an ion saturation probe and an emissive probe on cathode centerline, and from those measurements, spatial profiles of plasma density, plasma potential, and electron temperature were calculated. For both anode diameters, maximum plasma potential and electron temperature increased with increasing anode distance. However, the 64-mm diameter anode was found to be significantly more sensitive to position, with measurements indicating that parameters changed continuously with position instead of an instantaneous mode change at a certain critical distance. The 254-mm diameter, in contrast, showed much more similar plasma property profiles across the range of anode positions tested and much smaller changes per unit increase in distance. These results are discussed in the context of assessing anode design for component-level cathode tests.
Space propulsion↗
The Effect of Anode Configuration on the Plasma Plume of a 25-A class Hollow Cathode
The effect of anode configuration on the plasma plume properties of a 25-A class hollow cathode are experimentally characterized. At a nominal operating condition of 20.8 A and 14.7 sccm of xenon, the cathode was operated with two axially-segmented anodes of different diameters at varying distance from the cathode. A fast, reciprocating motion stage was used to rapidly insert an ion saturation probe and an emissive probe on cathode centerline, and from those measurements, spatial profiles of plasma density, plasma potential, and electron temperature were calculated. For both anode diameters, maximum plasma potential and electron temperature increased with increasing anode distance. However, the 64-mm diameter anode was found to be significantly more sensitive to position, with measurements indicating that parameters changed continuously with position instead of an instantaneous mode change at a certain critical distance. The 254-mm diameter, in contrast, showed much more similar plasma property profiles across the range of anode positions tested and much smaller changes per unit increase in distance. These results are discussed in the context of assessing anode design for component-level cathode tests.
space propulsion↗
The Plasma Proton Environment within Saturn’s F-G Ring Gap as Observed by the Cassini Plasma Spectrometer Ion Mass Spectrometer during Saturn Orbit Insertion
We report on the detection of protons and the potential detection of H 2 + between Saturn's F and G rings based on Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) time-of-flight (TOF) composition measurements acquired during Saturn Orbit Insertion (SOI) outbound pass. The range in dipole L shell is 2.3 < L < 2.8. Initial results based on TOF data were presented in E. C. Sittler et al., 2017. Here we present the latest results of our analysis. During the SOI outbound pass between the F and G rings the CAPS IMS was in a mode of reduced post-acceleration voltage at -6 kV instead of the usual -14.6 kV. This reduced voltage still allows the analysis of protons since 6 keV protons are minimally scattered by the instrument’s ultrathin carbon foils when compared to heavier ions O + and O 2 + , scattering. Background noise from penetrating radiation and ghost peaks produced by foil-scattered O + ions within the instrument were considered in our analysis. The analysis allowed determination of the proton density, temperature and flow velocity, accounting for spacecraft potential by assuming a convected Maxwellian for the proton velocity distribution function. We find average proton density n P = 3.2 ± 1.1 #/cm 3 , proton temperature T P = 1.74 ± 0.12 eV, proton rotational flow speed V P = 24 ± 1.5 km/s and spacecraft potential SC = -0.8 ±1.5 V. These results are compared with previous theoretical estimates of H + and H 2 + ions within Saturn’s inner magnetosphere.
E C Sittler↗
Mechanism of unassisted ion transport across membrane bilayers
To establish how charged species move from water to the nonpolar membrane interior and to determine the energetic and structural effects accompanying this process, we performed molecular dynamics simulations of the transport of Na+ and Cl- across a lipid bilayer located between two water lamellae. The total length of molecular dynamics trajectories generated for each ion was 10 ns. Our simulations demonstrate that permeation of ions into the membrane is accompanied by the formation of deep, asymmetric thinning defects in the bilayer, whereby polar lipid head groups and water penetrate the nonpolar membrane interior. Once the ion crosses the midplane of the bilayer the deformation "switches sides"; the initial defect slowly relaxes, and a defect forms in the outgoing side of the bilayer. As a result, the ion remains well solvated during the process; the total number of oxygen atoms from water and lipid head groups in the first solvation shell remains constant. A similar membrane deformation is formed when the ion is instantaneously inserted into the interior of the bilayer. The formation of defects considerably lowers the free energy barrier to transfer of the ion across the bilayer and, consequently, increases the permeabilities of the membrane to ions, compared to the rigid, planar structure, by approximately 14 orders of magnitude. Our results have implications for drug delivery using liposomes and peptide insertion into membranes.
NASA Discipline Exobiology↗
Impulsively Reflected Ions: A Plausible Mechanism for Ion Acoustic Wave Growth in Collisionless Shocks
We present recent high time resolution observations from an oblique (43 deg) shock crossing from the Magnetospheric Multiscale mission. Short-duration bursts between 10 and 100 ms of ion acoustic waves are observed in this event alongside a persistent reflected ion population. High time resolution (150 ms) particle measurements show strongly varying ion distributions between successive measurements, implying that they are bursty and impulsive by nature. Such signatures are consistent with ion bursts that are impulsively reflected at various points within the shock. We find that, after instability analysis using a Fried-Conte dispersion solver, the insertion of dispersive ion bursts into an already stable ion distribution can lead to wave growth in the ion acoustic mode for short durations of time. We find that impulsively reflected ions are a plausible mechanism for ion acoustic wave growth in the terrestrial bow shock and, furthermore, suggest that wave growth can lead to a small but measurable momentum exchange between the solar wind ions and the reflected population.
Goodrich, Katherine A.↗
NASA Electronic Parts and Packaging (NEPP) Field Programmable Gate Array (FPGA) Single Event Effects (SEE) Test Guideline Update
The following are updated or new subjects added to the FPGA SEE Test Guidelines manual: academic versus mission specific device evaluation, single event latch-up (SEL) test and analysis, SEE response visibility enhancement during radiation testing, mitigation evaluation (embedded and user-implemented), unreliable design and its affects to SEE Data, testing flushable architectures versus non-flushable architectures, intellectual property core (IP Core) test and evaluation (addresses embedded and user-inserted), heavy-ion energy and linear energy transfer (LET) selection, proton versus heavy-ion testing, fault injection, mean fluence to failure analysis, and mission specific system-level single event upset (SEU) response prediction. Most sections within the guidelines manual provide information regarding best practices for test structure and test system development. The scope of this manual addresses academic versus mission specific device evaluation and visibility enhancement in IP Core testing.
Test guidelines↗
NASA Electronic Parts and Packaging Field Programmable Gate Array Single Event Effects Test Guideline Update
The following are updated or new subjects added to the FPGA SEE Test Guidelines manual: academic versus mission specific device evaluation, single event latch-up (SEL) test and analysis, SEE response visibility enhancement during radiation testing, mitigation evaluation (embedded and user-implemented), unreliable design and its affects to SEE Data, testing flushable architectures versus non-flushable architectures, intellectual property core (IP Core) test and evaluation (addresses embedded and user-inserted), heavy-ion energy and linear energy transfer (LET) selection, proton versus heavy-ion testing, fault injection, mean fluence to failure analysis, and mission specific system-level single event upset (SEU) response prediction. Most sections within the guidelines manual provide information regarding best practices for test structure and test system development. The scope of this manual addresses academic versus mission specific device evaluation and visibility enhancement in IP Core testing.
Field Programmable Gate Array (FPGA)↗
Barium Depletion in the NSTAR Discharge Cathode After 30,000 Hours of Operation
Dispenser hollow cathodes rely on a consumable supply of barium released by impregnant materials in the pores of a tungsten matrix to maintain a low work function surface. Examinations of cathode inserts from long duration ion engine tests show deposits of tungsten at the downstream end that appear to block the flow of barium from the interior. In addition, a numerical model of barium transport in the insert plasma indicates that the barium partial pressure in the insert may exceed the equilibrium vapor pressure of the dominant barium-producing reaction, and it was postulated previously that this would suppress barium loss in the upstream part of the insert. New measurements of the depth of barium depletion from a cathode insert operated for 30,352 hours reveal that barium loss is confined to a narrow region near the downstream end, confirming this hypothesis.
plasma transport↗
Flexible Hybrid Battery/Pseudocapacitor
Batteries keep devices working by utilizing high energy density, however, they can run down and take tens of minutes to hours to recharge. For rapid power delivery and recharging, high-power density devices, i.e., supercapacitors, are used. The electrochemical processes which occur in batteries and supercapacitors give rise to different charge-storage properties. In lithium ion (Li+) batteries, the insertion of Li+, which enables redox reactions in bulk electrode materials, is diffusion controlled and can be slow. Supercapacitor devices, also known as electrical double-layer capacitors (EDLCs) store charge by adsorption of electrolyte ions onto the surface of electrode materials. No redox reactions are necessary, so the response to changes in potential without diffusion limitations is rapid and leads to high power. However, the charge in EDLCs is confined to the surface, so the energy density is lower than that of batteries.
Tucker, Dennis S.↗
A phenomenological model describing orificed, hollow cathode operation
A phenomenological model is presented which describes the emission processes occurring within the orificed, hollow cathode. The model defines a region of ion production inside the cathode and assumes that the cathode emission current can be accounted for by considering the ion and electron currents which cross the boundary of this region. Most of the current (approximately 72%) comes from electrons produced by field-enhanced, thermionic emission from a well-defined emission surface at the downstream end of the insert which circumscribes the ion product region. The electrons produced at the emission surface feed the ionization process in the region of ion production; the rest of the current (approximately 28%) is carried by the ions produced in the process. Moving at the Bohm velocity, these ions leave the production volume; they then complete the current path by being collected at various cathode potential surfaces, including the emission surface. The model establishes the ratio of ion to electron currents at the emission surface on the basis of the energy balance at that surface. Experimental results corroborating the principal assumptions of the model are presented and discussed.
Siegfried, D. E.↗