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At least 19 records

Distillation Column Flooding Predictor

The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

02 PETROLEUM↗

Multiscale drivers of extreme southern California flooding: ENSO, MJO, North Pacific jet, and atmospheric rivers

Extreme rainfall and flooding, driven by a powerful atmospheric river (AR) and a persistent Madden-Julian Oscillation (MJO), hit Southern California in February 2024 during the 2023–2024 El Niño, affecting over 10 million people. ARs are key contributors to extreme rainfall and flooding along the U.S. West Coast. Although the AR-MJO link has been documented, its spatio-temporal variability remains a major forecasting and risk-management challenge. Combining precipitation, stream gauge and demographic data, we quantify the physical drivers and population exposure to this extreme event. Leveraging a Lagrangian MJO precipitation tracking algorithm, we unravel the multiscale interactions responsible for the AR’s development. El Niño favored a large, long-lived MJO that interacted with the North Pacific Jet (NPJ) over more than three weeks. The MJO convective outflow modulated the NPJ by inducing negative potential vorticity advection along the tropopause. The ensuing NPJ extension and acceleration induced explosive cyclogenesis, whose AR-driven moisture transport resulted in extreme rainfall.

Atmospheric dynamics↗

Traction of Pneumatic Tires on Wet Runways

Recent work on the traction of pneumatic tires on wet runways is discussed, and it is shown that a loss of tire traction adversely affects cross-wind landings. The effect of runway surface texture is discussed,, and a simple method for measuring surface texture is described. A preliminary correlation of tire traction with surface texture is shown. Results of work at Langley Research Center on the use of air jets to improve tire traction on wet or flooded runways indicate that this is a promising approach for alleviating the large losses in tire braking and sideways traction that occur when tire hydroplaning occurs on a flooded runway.

Horne, Walter B.↗

Regional Climate Simulation with a Variable Resolution Stretched Grid GCM: The Regional Down-Scaling Effects

The results obtained with the variable resolution stretched grid (SG) GEOS GCM (Goddard Earth Observing System General Circulation Models) are discussed, with the emphasis on the regional down-scaling effects and their dependence on the stretched grid design and parameters. A variable resolution SG-GCM and SG-DAS using a global stretched grid with fine resolution over an area of interest, is a viable new approach to REGIONAL and subregional CLIMATE studies and applications. The stretched grid approach is an ideal tool for representing regional to global scale interactions. It is an alternative to the widely used nested grid approach introduced a decade ago as a pioneering step in regional climate modeling. The GEOS SG-GCM is used for simulations of the anomalous U.S. climate events of 1988 drought and 1993 flood, with enhanced regional resolution. The height low level jet, precipitation and other diagnostic patterns are successfully simulated and show the efficient down-scaling over the area of interest the U.S. An imitation of the nested grid approach is performed using the developed SG-DAS (Data Assimilation System) that incorporates the SG-GCM. The SG-DAS is run with withholding data over the area of interest. The design immitates the nested grid framework with boundary conditions provided from analyses. No boundary condition buffer is needed for the case due to the global domain of integration used for the SG-GCM and SG-DAS. The experiments based on the newly developed versions of the GEOS SG-GCM and SG-DAS, with finer 0.5 degree (and higher) regional resolution, are briefly discussed. The major aspects of parallelization of the SG-GCM code are outlined. The KEY OBJECTIVES of the study are: 1) obtaining an efficient DOWN-SCALING over the area of interest with fine and very fine resolution; 2) providing CONSISTENT interactions between regional and global scales including the consistent representation of regional ENERGY and WATER BALANCES; 3) providing a high computational efficiency for future SG-GCM and SG-DAS versions using PARALLEL codes.

Fox-Rabinovitz, Michael S.↗

Atmosphere-Land-Surface Interaction over the Southern Great Plains: Diagnosis of Mechanisms from SGP ARM Data

Work reported included analysis of pentad (5 day) averaged data, proposal of a hypothesis concerning the key role of the Atlantic Multi-decadal Oscillation in 20th century drought and wet periods over the Great Plains, analysis of recurrent super-synoptic evolution of the Great Plains low-level jet, and study of pentad evolution of the 1988 drought and 1993 flood over the Great Plains from a NARR perspective on the atmospheric and terrestrial water balance.

54 ENVIRONMENTAL SCIENCES↗

Rare Atmospheric River Caused Record Floods Across the Middle East

Atmospheric rivers (ARs) are responsible for some of the hydroclimatic extremes around the world. Their mechanisms and contribution to flooding in the Middle East are relatively poorly understood. This study shows that the record floods during March 2019 across the Middle East were caused by a powerful AR, originated from the North Atlantic Ocean. Iran, in particular, was substantially affected by the floods. The nearly 9000 km long AR propagated across North Africa and the Middle-East, and was fed by additional moisture from several other sources on its pathway. Simultaneous presence of a mid-latitude system and a subtropical jet facilitated the moisture supply. The AR, as passing over the Zagros Mountains, produced record rainfall induced by the orographic forcing. The resulting floods caused widespread damage to infrastructures and left a death toll of at least 76 in Iran.

Amin Dezfuli↗

The Climate Signal in Regional Moisture Fluxes: A Comparison of Three Global Data Assimilation Products

This study assesses the quality of estimates of climate variability in moisture flux and convergence from three assimilated data sets: two are reanalysis products generated at the Goddard Data Assimilation Office (DAO) and the National Centers for Environmental Prediction/National Centers for Atmospheric Research (NCEPJNCAR), and the third consists of the operational analyses generated at the European Center for Medium Range Forecasts (ECMWF). The regions under study (the United States Great Plains, the Indian monsoon region, and Argentina east of the Andes) are characterized by frequent low level jets (LLJs) and other interannual low level wind variations tied to the large-scale flow. While the emphasis is on the reanalysis products, the comparison with the operational product is provided to help assess the improvements gained from a fixed analysis system. All three analyses capture the main moisture flux anomalies associated with selected extreme climate (drought and flood) events during the period 1985-93. The correspondence is strongest over the Great Plains and weakest over the Indian monsoon region reflecting differences in the observational coverage. For the reanalysis products, the uncertainties in the lower tropospheric winds is by far the dominant source of the discrepancies in the moisture flux anomalies in the middle latitude regions. Only in the Indian Monsoon region, where interannual variability in the low level winds is comparatively small, does the moisture bias play a substantial role. In contrast, the comparisons with the operational product show differences in moisture which are comparable torhe differences in the wind in all three regions. Compared with the fluxes, the anomalous moisture convergences show substantially larger differences among the three products. The best agreement occurs over the Great Plains region where all three products show vertically-integrated moisture convergence during the floods and divergence during the drought with differences in magnitude of about 25%. The reanalysis products, in particular, show good agreement in depicting the different roles of the mean flow and transients during the flood and drought periods. Differences between the three products in the other two regions exceed 100% reflecting differences in the low level jets and the large scale circulation patterns. The operational product tends to have locally larger amplitude convergence fields which average out in area-mean budgets: this appears to be at least in part due to errors in the surface pressure fields and aliasing from the higher resolution of the original ECMWF fields. On average, the reanalysis products show higher coherence with each other than with the operational product in the estimates of interannual variability. This result is less clear in the Indian monsoon region where differences in the input observations appears to be an important factor. The agreement in the anomalous convergence patterns is, however, still rather poor even over relatively data dense regions such as the United States Great Plains. These differences are attributed to deficiencies in the assimilating GCM's representations of the planetary boundary layer and orography, and a global observing system incapable of resolving the highly confined low level winds associated with the climate anomalies.

Min, Wei↗

Multiscale Aspects of the Storm Producing the June 2013 Flooding in Uttarakhand, India

Conditions producing disastrous flooding in Uttarakhand, India, in June 2013 differed from conditions that produced other notorious floods in the Himalayan region in recent years. During the week preceding the Uttarakhand flood, deep convection moistened the mountainsides, making them vulnerable to flooding. However, the precipitation producing the flood was not associated with a deep convective event. Rather, an eastward-propagating upper-level trough in the westerlies extended abnormally far southward, with the jet reaching the Himalayas. The south end of the trough merged with a monsoon low moving westward across India. The merged system produced persistent moist low-level flow oriented normal to the Himalayas that advected large amounts of water vapor into the Uttarakhand region. The flow was moist neutral when it passed over the Himalayan barrier, and orographic lifting produced heavy continuous rain over the region for 2–3 days. The precipitation was largely stratiform in nature although embedded convection of moderate depth occurred along the foothills, where some mild instability was being released. The Uttarakhand flood had characteristics in common with major 2013 floods in the Rocky Mountains in Colorado and Alberta, Canada.

Houze, R. A.↗

Large-scale Meteorological Organization of Extreme Weather Events: Final Technical Report

Although the occurrence of regional extreme weather events (EWEs) such as cold air outbreaks, heat waves, droughts and floods are known to be related to planetary climate modes (PCMs) such as the El-Nino Southern Oscillation or North Atlantic Oscillation, intermediate meteorological patterns (IMPs) such as jet stream blocking, cyclones, and high pressure systems are required to connect PCMs to EWEs. Our project has revealed a physical pathway for the interplay among EWEs, IMPs and PCMs. Under support of this award, we have characterized the behavior of IMPs that cause winter cold air outbreaks, extreme floods and warm season dry spells in the US. This includes formulating meteorological “fingerprints” for easily identifying IMPs. The research performed includes a parallel analysis of how well modern climate models are able to simulate IMP behavior. We have also developed a novel approach for characterizing PCM structures and identifying EWE-LMP-PCM linkages. We discovered that dry spells occurring during spring and summer over the US are affected by changes in the North Pacific Ocean temperature. We further revealed the physical origin of a critical jet stream pattern occurring over the North Pacific Ocean that provides a “bridge” between the water cycles of East Asia and North America, respectively. We developed an advanced diagnostic technique (called piecewise tendency diagnosis or PTD) to understand the physical causes for the IMP formation and EWE-LMP-PCM linkages.

54 ENVIRONMENTAL SCIENCES↗

The MELTSPREAD Code for Modeling of Ex-Vessel Core Debris Spreading Behavior, Code Manual – Version3-beta

MELTSPREAD3 is a transient one-dimensional computer code that has been developed to predict the gravity-driven flow and freezing behavior of molten reactor core materials (corium) in containment geometries. Predictions can be made for corium flowing across surfaces under either dry or wet cavity conditions. The spreading surfaces that can be selected are steel, concrete, a user-specified material (e.g., a ceramic), or an arbitrary combination thereof. The corium can have a wide range of compositions of reactor core materials that includes distinct oxide phases (predominantly Zr, and steel oxides) plus metallic phases (predominantly Zr and steel). The code requires input that describes the containment geometry, melt “pour” conditions, and cavity atmospheric conditions (i.e., pressure, temperature, and cavity flooding information). For cases in which the cavity contains a preexisting water layer at the time of RPV failure, melt jet breakup and particle bed formation can be calculated mechanistically given the time-dependent melt pour conditions (input data) as well as the heatup and boiloff of water in the melt impingement zone (calculated). For core debris impacting either the containment floor or previously spread material, the code calculates the transient hydrodynamics and heat transfer which determine the spreading and freezing behavior of the melt. The code predicts conditions at the end of the spreading stage, including melt relocation distance, depth and material composition profiles, substrate ablation profile, and wall heatup. Code output can be used as input to other models such as CORQUENCH that evaluate long term core-concrete interaction behavior following the transient spreading stage. MELTSPREAD3 was originally developed to investigate BWR Mark I liner vulnerability, but has been substantially upgraded and applied to other reactor designs (e.g., the EPR), and more recently to the plant accidents at Fukushima Daiichi. The most recent round of improvements that are documented in this report have been specifically implemented to support industry in developing Severe Accident Water Management (SAWM) strategies for Boiling Water Reactors.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Recreating the California New Year's Flood Event of 1997 in a Regionally Refined Earth System Model

Abstract The 1997 New Year's flood event was the most costly in California's history. This compound extreme event was driven by a category 5 atmospheric river that led to widespread snowmelt. Extreme precipitation, snowmelt, and saturated soils produced heavy runoff causing widespread inundation in the Sacramento Valley. This study recreates the 1997 flood using the Regionally Refined Mesh capabilities of the Energy Exascale Earth System Model (RRM‐E3SM) under prescribed ocean conditions. Understanding the processes causing extreme events informs practical efforts to anticipate and prepare for such events in the future, and also provides a rich context to evaluate model skill in representing extremes. Three California‐focused RRM grids, with horizontal resolution refinement of 14 km down to 3.5 km, and six forecast lead times, 28 December 1996 at 00Z through 30 December 1996 at 12Z, are assessed for their ability to recreate the 1997 flood. Planetary to synoptic scale atmospheric circulations and integrated vapor transport are weakly influenced by horizontal resolution refinement over California. Topography and mesoscale circulations, such as the Sierra barrier jet, are better represented at finer horizontal resolutions resulting in better estimates of storm total precipitation and storm duration snowpack changes. Traditional time‐series and causal analysis frameworks are used to examine runoff sensitivities state‐wide and above major reservoirs. These frameworks show that horizontal resolution plays a more prominent role in shaping reservoir inflows, namely the magnitude and time‐series shape, than forecast lead time, 2‐to‐4 days prior to the 1997 flood onset.

54 ENVIRONMENTAL SCIENCES↗

Interactions Between Vestige Atlantic Tropical Cyclones and Mid-Latitude Storms Over Mediterranean Basin

One of the more interesting tropical-mid-latitude interactions is one that has important effects on precipitation within the Mediterranean basin. This interaction consists of an Atlantic tropical cyclone vestige whose original disturbance travels eastward and northward across Atlantic basin, eventually intermingling with a mid-latitude cyclone entering southern Europe and/or the \bestern Mediterranean Sea. The period for these interactions is from mid-September through November. If the tropical cyclone and its vestige is able to make the eastward Atlantic transit within the low to mid-levels, or if an upper level potential vorticity perturbation Cjet streak) emitted by a Hurricane in its latter stages within the central Atlantic is able to propagate into and along the longwave pattern affecting the western Mediterranean Sea (MED), then there is the prospect for the tropical cyclone remnant to produce a major modification of the mid-latitude storm system preparing to affect the MED region. For such an occurrence to take place, it is necessary for an amplifying baroclinic perturbation to be already situated to the rear of a longwave trough, or to be excited by the emitted jet streak to the rear of a longwave trough -- in either case, preparing to affect the western MED. The Algiers City flood of 9-10 November 2001, which killed some 700 people, was produced by a Mediterranean cyclone that had been influenced by two vestige Atlantic tropical cyclones, 1,orenzo and Noel. A published modeling study involving various of this study's authors has already described the dynamical development of the Algiers storm as it amplified from a developing baroclinic disturbance in the Rossby wave train, into a northern Africa hazardous flood system, then lingered in the western MED as a semi-intense warm core cyclone. In our new modeling experiments, we investigate the impact of what might have happened in the eventual precipitation field. had the main features of the tropical cyclones NOT interacted with thc developing baroclinic disturbance as it penetrated the western MED. To do so, we first remove the moisture and dynamical features of the two vestigial tropical cyclones from the large scale meteorological fields used to initialize the Mediterranean cyclone simulation. This is done through depletion of the moisture front associated with the two tropical cyclones, accomplished by relaxation to the suppressed east Atlantic conditions. The dynamical effects are removed through energetic destruction of the latter stages of the eastward traveling tropical cyclones, accomplished by lowering the underlying sea surface temperatures. A precipitation-distribution impact experiment is then run by initializing with the customized large-scale fields. The final precipitation-impact field is described by differencing the "impact" run from the "control" run -- the latter defined as the original simulation which intrinsically includes the effects of the two vestigial tropical cyclones.

Smith, Eric A.↗

Record-Breaking Atmospheric River Drives April 2024 Extreme Precipitation in the United Arab Emirates and the Surrounding Gulf Region

In mid-April 2024, the United Arab Emirates (UAE) and the surrounding Gulf region experienced unprecedented rainfall and catastrophic flooding, causing widespread damage, loss of life, and significant economic costs. During the 3-day period from 15 to 17 April, rainfall in the UAE exceeded 100 mm in the hardest-hit areas, with more than 170% of the typical annual precipitation recorded in just 72 h. The event was associated with exceptionally strong integrated water vapor transport (IVT), driven by a persistent low pressure system and a focused corridor of moisture transport. This environment, combined with favorable dynamical and convective conditions, triggered intense thunderstorms and widespread flooding. This article examines the role of an atmospheric river (AR) in the April 2024 extreme precipitation event, emphasizing the contribution of extreme IVT to preconditioning and amplifying the heavy rainfall. While this event has previously been described primarily in terms of a mesoscale convective system (MCS) and potential vorticity (PV) streamers, here we document and illustrate its close relationship to a record-breaking moisture transport corridor. This AR-based perspective highlights how large-scale moisture-transport frameworks can complement synoptic and mesoscale analyses in understanding extreme rainfall in arid and semiarid regions such as the UAE and the Gulf. The event serves as a stark example of the vulnerabilities faced by arid regions, where atmospheric conditions conducive to extreme flooding may become more frequent in the future.

Massoud, Elias [ORNL] (ORCID:0000000217725361)↗

Effect of Rocky Mountains and Tibetan Plateau 1998 Spring Land Temperature on N. American and East Asian Summer Precipitation Anomalies

This work follows up on the GEWEX/LS4P Phase I (LS4P-I) experiments, a community effort highlighting the spring land surface temperature anomalies in the Tibetan Plateau (TP) as a useful source for subseasonal to seasonal (S2S) prediction of summer precipitation in global hot spot regions, particularly in East Asia and North America. This paper extends the investigation to both the US Rocky Mountain (RM) region and the TP, considering the 1998 summer drought/flood event in North America/East Asia, respectively, as a case study. A previously developed initialization method for land surface temperature/subsurface temperature (LST/SUBT) is used in the NCEP Global Forecast System, coupled with a land model, SSiB2 (GFS/SSiB2), to produce observed RM cold May temperature anomaly. Forward simulation yields June precipitation anomalies at five remote locations. Likewise, the TP warm May temperature anomaly also produces June precipitation anomalies at these five locations. The effects of RM (cold) and TP (warm) temperature anomalies are consistent in the US South Coastal regions and the south Yangtze River Basin, yielding 49% (42%) of observed drought and 34% (44%) of observed flood, respectively. These LST/SUBT effects in RM and TP induce a global large-scale wave train linking North America with the TP, affecting the subtropical westerly jet and thereby modulating summer precipitation. Global SST effect is examined for comparison but does not yield statistically significant June precipitation anomalies in GFS/SSiB2. Furthermore, this study adds to evidence that high-mountain LST effects in the RM and TP are first-order sources of S2S precipitation predictability in summer months.

Nayak, Hara Prasad [University of California, Los ↗

Changes in the Regional Water Cycle and Their Impact on Societies

ABSTRACT Changes in “blue water”, which is the total supply of fresh water available for human extraction over land, are quite closely related to changes in runoff or equivalently precipitation minus evaporation, . This article examines how climate change‐driven recent past and future changes in the regional water cycle relate to blue water availability and changes in human blue water demand. Although at the largest scales theoretical and numerical model predictions are in broad agreement with observations, at continental scales and below models predict large ranges of possible future and runoff especially at the scale of individual river catchments and for shorter timescale subseasonal floods and droughts. Nevertheless, it is expected that the occurrence and severity of floods will increase and that of droughts may increase, possibly compounded by human‐driven non‐climatic changes such as changes in land use, dam water impoundment, irrigation and extraction of groundwater. Contemporary assessments predict that increases in 21st century human water extraction in many highly‐populated regions are unlikely to be sustainable given projections of future . To reduce uncertainty in future predictions, there is an urgent need to improve modeling of atmospheric, land surface and human processes and how these components are coupled. This should be supported by maintaining the observing network and expanding it to improve measurements of land surface, oceanic and atmospheric variables. This includes the development of satellite observations stable over multiple decades and suitable for building reanalysis datasets appropriate for model evaluation.

54 ENVIRONMENTAL SCIENCES↗

Seasonally Dependent Future Changes in the U.S. Midwest Hydroclimate and Extremes

This study investigates the responses of the hydroclimate and extremes in the U.S. Midwest to global warming, based on ensemble projections of phase 6 of the Coupled Model Intercomparison Project and the multimodel initial-condition large-ensemble simulations. The precipitation response features a seasonally dependent change with increased precipitation in April–May but reduced precipitation in July–August. In this work, the late-spring wetting is attributed to the enhanced low-level moisture-transporting southerlies, which are induced by regional sea level pressure anomalies linked to the poleward shift of the North American westerly jet (NAWJ). The late-summer drying is attributed to the weakened storm track, which is also linked to the poleward NAWJ shift. The seasonally dependent future changes of the Midwest precipitation are analogous to its climatological seasonal progression, which increases over late spring as the NAWJ approaches the Midwest and decreases over late summer as the NAWJ migrates away. In response to the mean precipitation changes, extremely wet late springs (April–May precipitation above the 99th percentile of the historical period) and extremely dry late summers (below the 1st percentile) will occur much more frequently, implying increased late-spring floods and late-summer droughts. Future warming in the Midwest is amplified in late summer due to the reduced precipitation. With amplified background warming and increased occurrence, future late-summer droughts will be more devastating. Our results highlight that, under a time-invariant poleward jet shift, opposite precipitation changes arise before and after the peak rainy month, leading to substantial increases in the subseasonal extremes. The severity of such climate impacts is obscured in projections of the rainy-season mean.

54 ENVIRONMENTAL SCIENCES↗

Experience with 800 x 800 virtual phase and 500 x 500 three-phase CCD imagers

A description of the Galileo/Institute for Astronomy charge-coupled device (CCD) imaging system and its initial operation has been presented previously. Originally designed to operate a 500 x 500 backside illuminated three-phase CCD, the system has been modified to allow use of either the 500 x 500 sensor or the TI 800 x 800 virtual phase CCD. The modifications for the operation of the virtual phase CCD and current system performance with each type of sensor are discussed. A description is given of the implementation of various techniques discovered at the Jet Propulsion Laboratory that improve imager performance. These techniques include tri-level clocking of the virtual phase CCD to eliminate spurious charge generation in the serial register, the use of ultraviolet light flood with the backside thinned 500 x 500 three-phase device to dramatically improve the quantum efficiency in the blue, and the practical elimination of deferred charge in the three-phase device. Results of astronomical observations with each sensor are presented.

Hlivak, R. J.↗

Improved Mobility Control for Carbon Dioxide (CO{sub 2}) Enhanced Oil Recovery Using Silica-Polymer-Initiator (SPI) Gels

SPI gels are multi-component silicate based gels for improving (areal and vertical) conformance in oilfield enhanced recovery operations, including water-floods and carbon dioxide (CO{sub 2}) floods, as well as other applications. SPI mixtures are like-water when pumped, but form light up to very thick, paste-like gels in contact with CO{sub 2}. When formed they are 3 to 10 times stronger than any gelled polyacrylamide gel now available, however, they are not as strong as cement or epoxy, allowing them to be washed / jetted out of the wellbore without drilling. This DOE funded project allowed 8 SPI field treatments to be performed in 6 wells (5 injection wells and 1 production well) in 2 different fields with different operators, in 2 different basins (Gulf Coast and Permian) and in 2 different rock types (sandstone and dolomite). Field A was in a central Mississippi sandstone that injected CO{sub 2} as an immiscible process. Field B was in the west Texas San Andres dolomite formation with a mature water-alternating-gas miscible CO{sub 2} flood. Field A treatments are now over 1 year old while Field B treatments have only 4 months data available under variable WAG conditions. Both fields had other operational events and well work occurring before/ during / after the treatments making definitive evaluation difficult. Laboratory static beaker and dynamic sand pack tests were performed with Ottawa sand and both fields’ core material, brines and crude oils to improve SPI chemistry, optimize SPI formulations, ensure SPI mix compatibility with field rocks and fluids, optimize SPI treatment field treatment volumes and methods, and ensure that strong gels set in the reservoir. Field quality control procedures were designed and utilized. Pre-treatment well (surface) injectivities ranged from 0.39 to 7.9 MMCF/psi. The SPI treatment volumes ranged from 20.7 cubic meters (m{sup 3}, 5460 gallons/ 130 bbls) to 691 m{sup 3} (182,658 gallons/ 4349 bbls). Various size and types of chemical/ water buffers before and after the SPI mix ensured that pre-gelled SPI mix got out into the formation before setting into a gel. SPI gels were found to be 3 to 10 times stronger than any commercially available cross-linked polyacrylamide gels based on Penetrometer and Bulk Gel Shear Testing. Because of SPI’s unique chemistry with CO{sub 2}, both laboratory and later field tests demonstrated that multiple, smaller volume SPI treatments maybe more effective than one single large SPI treatment. CO{sub 2} injectivities in injection well in both fields were reduced by 33 to 70% indicating that injected CO{sub 2} is now going into new zones. This reduction has lasted 1+ year in Field A. Oil production increased and CO{sub 2} production decreased in 5 Field A production wells, offsets to Well #1 injector, for a total of about 2,250 m{sup 3} (600,000 gallons/ 14,250 bbls) of incremental oil production- a $140 / SPI bbl return. Treated marginal production well, Field A Well #2, immediately began showing increased oil production totaling 238 m{sup 3} (63,000 gallons/ 1500 BBLs) over 1 year and an immediate 81% reduced gas-oil ratio.

01 COAL, LIGNITE, AND PEAT↗