High resolution emission vegard-kaplan bands of nitrogen technical report no. 8
Spectrograph, wavelength standards, light source, and resolution analysis for Vegard-Kaplan bands emitted by nitrogen
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High-resolution emission vegard-kaplan bands of nitrogen.
Laboratory light source emitting forbidden Vegard-Kaplan bands of nitrogen with sufficient intensity for high resolution spectrograph
NITROGEN↗
Rocket-borne spectroscopic measurements in the ultraviolet aurora - Nitrogen Vegard-Kaplan bands
Nitrogen Vegard-Kaplan and second positive band systems emission, using rocket-borne spectrometer in UV aurora
Sharp, W. E.↗
Ultraviolet spectrum of the Aurora /2000-2800 A/
Ultraviolet spectra between 2000 and 2800 delta-v of an IBC II(+) aurora were obtained by a rocket-borne Ebert-Fastie monochromator at 15-A resolution over Fort Churchill, Manitoba. The v-prime = 0-8 progressions of the N2 Vegard-Kaplan system, the delta-v = 8 sequence of the Lyman-Birge-Hopfield system, and a progression attributed to the Herman-Kaplan system were identified by a synthetic spectrum analysis. Relative populations of the first eight vibrational levels of the A3 Sigma u(+) state at high altitude were obtained from the theoretically generated spectra, and quenching rate coefficients were derived for these eight levels by using an atomic oxygen concentration derived from data from another experiment on board. For v = 0 the quenching rate coefficient was found to be 2.0 times 10 the minus 10th cu cm/sec and was not found to increase for higher vibrational levels. The intensity of the (0,2) band of the Herman-Kaplan system was found to be about 5 times the theoretically predicted value, but even so, the cascade from E3 Sigma g(+) provides less than 2% of the A3 Sigma u(+) state population.
Beiting, E. J., III↗
Influence of systematic radiation differences on the dynamics of a model atmosphere
Numerical experiments were run on the Goddard Laboratory for Atmospheric Sciences (GLAS) nine-level GCM using two different long-wave radiation routines - the Hogan routine and the Wu-Kaplan routine - to determine whether systematic radiation difference is important in the modeling of the general circulation of the atmosphere. The climatologies produced from GCM runs using the different radiation routines were compared for both winter and summer. Systematic differences were found in the mean zonal temperatures, in the location and shape of the zonal west wind maximum, in the strength of the Hadley and Ferrel cells, in the cloud and precipitation distributions, and in the mass distributions. On the basis of comparisons with observations, it was found that the Wu-Kaplan routine had a positive impact or at least made improvements in the right direction in most respects.
Wu, M.-L. C.↗
Corrections regarding the Lellouch et al. (1989) analysis of Mars atmospheric C-12O and C-13O spectra
Lellouch et al. (1989) obtained atmospheric CO mixing ratios from Martian C-12O and C-13O microwave spectra that were 3-5 times greater than the Kaplan et al. (1969) IR measurememts; they also inferred a factor-of-2 increase in atmospheric CO abundance between September, 1986 and January, 1987. A reanalysis has been conducted of the Lellouch material, and more detailed treatment of the radiative transfer analysis indicates that its observations are consistent with the Kaplan CO volume mixing ratio determination. It is also ascertained that the Lellouch atmospheric temperature profiles are in error, with no evidence being found for the extreme temperature inversions inferred for the lowest 5 km of the Martian atmosphere.
Clancy, R. Todd↗
A nested-grid limited-area model for short term weather forecasting
The present investigation is concerned with a mesoscale atmospheric simulation system (MASS), incorporating the sigma-coordinate primitive equations. The present version of this model (MASS 3.0) has 14 vertical layers, with the upper boundary at 100 mb. There are 128 x 96 grid points in each layer. The earlier version of this model (MASS 2.0) has been described by Kaplan et al. (1982). The current investigation provides a summary of major revisions to that version and a description of the parameterization schemes which are presently included in the model. The planetary boundary layer (PBL) is considered, taking into account aspects of generalized similarity theory and free convection, the surface energy budget, the surface moisture budget, and prognostic equations for the depth h of the PBL. A cloud model is discussed, giving attention to stable precipitation, and cumulus convection.
Wong, V. C.↗
some comments on the use of infrared radiometry for remote atmospheric probing
A critique is presented of the lead paper by L.D. Kaplan on infrared radiometry. The following topics are analyzed: the extent to which the desirable thermal resolution of the lower troposphere can be achieved, the effects of complex cloud structure on infrared data, the effective weighting function if linearization is possible, remote sounding from below the atmosphere, first-guess fields and operational techniques to blend satellite infrared data into a mix of data from various meteorological systems, a simple inversion procedure for thermal structure, and problems arising from cloud and haze layers of variable amount and emissivity.
Godson, W. L.↗
Vibrational population of the A super 3 sigma sub u/+/ and B super 3 pi sub g states of N2 in normal auroras.
Use of new electron impact excitation cross sections for the six lowest triplet states (A, B, W, C, E, D) of N2, and solution of the coupled equations of statistical equilibrium to obtain the vibrational population of each electronic state. The results show that cascade from high levels of the A super 3 sigma sub u(+) state and from the W super 3 delta sub u state is significant in populating the lower vibrational levels of the B state and hence the character of its ?apparent' excitation cross sections. For the B state excited under auroral conditions, the fraction of the total population due to cascade processes exceeds 25% for all levels lower than 7 and is greater than 80% for B(v' = 0). For the A state under similar conditions, cascade from the B state contributes 50% or more of the total vibrational population for levels lower than 7, and 80% or more for levels below 4. For levels of the A state greater than 7, the A yields B transitions depopulate the levels rapidly and indicate that the Vegard-Kaplan emissions from these higher levels will be weak or totally absent in normal auroras.
Cartwright, D. C.↗
Vacuum ultraviolet spectra of the late twilight airglow.
Evaluation of sounding rocket spectra of the late twilight (solar-zenith angle of 120 deg) ultraviolet airglow between 1260 and 1900 A. The only observed features are O I 1304 and 1356. When the instrument looked at an elevation of 17 deg above the western horizon, the brightnesses were 70 and 33 rayleighs, respectively. The upper limits on the total intensity of the Lyman-Birge-Hopfield and Vegard-Kaplan systems of N2 were 26 plus or minus 26 and 55 plus or minus 55 rayleighs, respectively. An estimate shows that a large part of the O I emissions may be due to excitation by conjugate-point electrons.
Buckley, J. L.↗
High dispersion spectroscopic studies of Mars. V - A search for oxygen in the atmosphere of Mars.
In order to set a new upper limit on the amount of diatomic oxygen in the atmosphere of Mars, we have reduced a number of high-dispersion spectra of the 7620 A band of oxygen obtained during the 1969 apparition of Mars. Our new upper limit is 15 atm cm(stp) for the Martian abundance in a single vertical path. This result confirms and lowers the 1963 upper limit of 70 cm atm(stp) by Kaplan, Muench, and Spinrad (1964). The features reported by Hunten and Belton (1966) do not appear on our spectra. Further, we have measured the pressure shift of the A band in the laboratory, and found that the shift required by their tentative identification of diatomic oxygen in the Martian atmosphere does not exist. We conclude that their tentative identification was spurious, and their upper limit dubious.
Margolis, J. S.↗
Deactivation of N2 A/super 3/Sigma/sub u/+ molecules in the aurora.
Recent rocket observations of the molecular nitrogen Vegard-Kaplan system in the aurora have been reinterpreted using an atmospheric model based on mass spectrometer measurements in an aurora of similar intensity at the same time of year. It is found that the population rates of the considered levels in the aurora are accurately determined by radiative cascade from two other states excited by direct electron impact. In some bright auroras the role of NO in quenching the lower vibrational levels of the A state is significant. The conclusions are based on a number of relevant auroral observations in combination with calculations using electron cross section and transition probability measurements by Shemansky and Broadfoot (1971).
Shemansky, D. E.↗
Auroral spectrum between 1200 and 4000 angstroms.
Results of spectroscopic observations of an auroral event made simultaneously by airborne and satellite-borne scanning spectrometers in the wavelength region between 1200 and 4000 A. Photon emission rates of several vibrational bands of the N2, 2nd positive, Vegard-Kaplan, and Lyman-Birge-Hopfield systems, the N I lines at 1200 and 3466 A, and O I lines at 1304, 1356, and 2972 A were recorded. Model calculations of the emission rates of the observed features are found to be in reasonable agreement with the measurements. Electron impact excites the nitrogen band systems, as well as the O I 1356-A line. A spectral feature at 2150 A is tentatively identified as the (1, 0) gamma band of N O.
Sharp, W. E.↗
On the temperature distribution in a planetary atmosphere.
Criteria for the appearance of a double maximum in the absorption spectra are derived. A very oversimplified model atmosphere which consists of two isothermal layers of gas is considered. The model involves the presence of two absorption cells in series, in front of a light source that has a higher temperature than either of the cells. The possibility that the double maximum is due to a quantum-mechanical interaction is studied. It is concluded that the effect reported by Kaplan (1962) was due to noise, and that it is impossible to detect temperatures as high as 700 K in the atmosphere of Venus by means of ground-based observations of the 7820 A carbon dioxide band.
Young, L. D. G.↗
Studies of molecular nitrogen bands from airborne auroral spectroscopy
Absolute auroral emission rates of several bands of the 1 PG (first positive), 2 PG, and Vegard-Kaplan systems of N2 and of the 1 NG (first negative) system of N2(+) were obtained from simultaneous spectral scans of two Ebert spectrophotometers mounted on board the NASA CV 990 aircraft. Analysis of these bands emitted during a 2-min auroral event leads to some conclusions regarding the excitation mechanisms of the C(3)Pi, B(3)Pi, and A(3)Sigma levels: the v' = 0 to v' = 3 levels of the C(3)Pi electronic state are populated by electron impact; the cross sections predict absolute emission rates that are in good agreement with the observations. Cross sections for excitation of the v' = 4 to v' = 8 levels, derived from laboratory measurement of the optical excitation functions, predict well the 1 PG bands observed in the auroral event.
Rees, M. H.↗
A search for nitric oxide gamma band emission in an aurora
A strong emission feature at 2150 A has been observed by a rocket-borne spectrophotometer in an IBC II(+) aurora. This feature, commonly identified with the NO gamma (1,0) band, is comparable in intensity to the nearby N2 Vegard-Kaplan bands. Comparison of the observed spectra with a theoretically produced synthetic spectrum allows all but this feature to be assigned to N2 transitions. No bands of the v prime = 0 or 2 progressions or any other bands from v prime = 1 appear, casting serious doubt on the identification of this feature as the NO gamma (1,0) band.
Beiting, E. J., III↗
Airglow from the inner comas of comets
The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only 'airglow' emissions initiated by the absorption of EUV radiation have been considered. The photoionizations of H2O, CO, CO2, and N2 are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H2O(+), CO(+) (first negative), CO (fourth positive), CO (Cameron), CO2(+), N2 (Vegard-Kaplan), N2(+) (first negative), and O I (1304 A). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance-scattering and fluorescence-excitation mechanisms appropriate for the outer coma and tail.
Cravens, T. E.↗
The ultraviolet aurora - The spectrum between 2100 A and 2300 A
Rocket-borne spectroscopic observations of the ultraviolet aurora between 2100 A and 2300 A reveal bands from the N2 Lyman-Birge-Hopfield and Vegard-Kaplan systems. A strong feature at 2144 A is identified as the quintet doublet of N II. This emission feature is shown from altitude profiles to have little if any quenching.
Sharp, W. E.↗