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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

A Model-Based Thruster Leakage Monitor for the Cassini Spacecraft

The Cassini spacecraft was launched on October 15, 1997. It uses thrusters to perform many spacecraft control functions: to detumble the spacecraft, to maintain three-axis attitude control, to perform small trajectory correction burns, to desaturate the reaction wheels, and others.

Cassini↗

Feasibility of using distribute chemical sensing for CO2 leakage monitoring

The feasibility study focused on the development of new fiber for distributed chemical sensing (DCS) that will allow direct detection of CO 2 leakages in the environment. This is particularly important for monitoring well integrity for carbon capture and storage (CSS), to provide early warning for an incoming well failure and potential CO 2 leaking through it. We proposed Raman or IR interrogation within gas-filled Holey Fibers (HoFs) interleaved with standard solid core fibers and Fiber Bragg Grating (FBG) sections, so that the location and concentration of the gases would be provided simultaneously by means of reflectometry. The methodology would overcome current roadblocks to using fiber optics for CO 2 (and other gases) detection in wells with direct in-situ measurements of concentration along with other important parameters such as temperature and pressure as the baseline of environment background.

54 ENVIRONMENTAL SCIENCES↗

Feasibility of using distributed chemical sensing for CO2 leakage monitoring

The feasibility study focused on the development of new fiber for distributed chemical sensing (DCS) that will allow direct detection of CO 2 leakages in the environment. This is particularly important for monitoring well integrity for carbon capture and storage (CCS), to provide early warning for an incoming well failure and potential CO 2 leaking through it. We proposed using optical spectroscopy in optical fiber for direct detection of CO 2 . The main approach is based on Raman interrogation within gas-filled Holey Fibers (HoFs), so that the location and concentration of the gases would be provided simultaneously via backscattering. Additionally, Infrared (IR) Absorption Spectroscopy could also be used, and the architecture would be more discrete since interleaving with standard solid core fibers and Fiber Bragg Grating (FBG) sections is required to enable reflection to the I/O controls. The possible Raman length or the IR numbers of sections would be defined based on signal to noise ratio. The optical spectroscopy methodology would overcome current roadblocks to CCS, as fiber optics will allow for CO 2 (and other gases) detection in wells with direct in-situ measurements of concentration along with other important parameters such as temperature and pressure as the baseline of environment background.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Pressure Gauges Monitor Leakage Past Seals

Method devised to measure leakage of gas past each of two sets of primary and secondary seals into common volume from which aggregate flow measured. Although method applicable only to specific combination of flow configuration and thermal conditions, it serves as example of more general approach involving use of statistical analysis to extract additional information from measurements.

Smith, Steven A.↗

Seismic H2: Version 1.0

Seismic-H2 is an integrated software package for geological hydrogen reservoir simulation, optimization, and leakage monitoring. The package includes multiple components: (1) code used for modeling seismic wave propagation in 3D heterogeneous elastic media based on finite-difference method to support detection of geological hydrogen storage reservoir leakage; (2) 3D reservoir simulations of leaks from an underground reservoir and 3D simulations of saline aquifers and depleted gas reservoirs; (3) seismic monitoring costs of passive and active seismic monitoring required for UHS; (4) rock physics calculations and interpolations for converting the reservoir simulations from part (2) into the elastic media models in part (1); (5) pre-processing seismic data; and lastly (6), a GUI interface that combines these different components.

Creasy, Neala↗

The future of subsurface monitoring: AEC’s breakthroughs in CCS technology

Carbon capture and storage (CCS) has emerged as a key solution in the fight against climate change. However, for CCS to succeed, it is crucial to ensure that the sequestered CO2 stays safely trapped underground. The U.S. Department of Energy (DOE) has emphasized the need for advancements in subsurface monitoring, measurement, reporting, and verification. Aside from caprock integrity failure, the other primary failure points usually involve defective cement in the casing annulus of wellbores or plugged and abandoned wells. In addition, many energy producers (e.g., oil and gas, geothermal) and storage and disposal operators (e.g., H2 and water) must deal with the same issue. Poorly placed or degraded cement can create pathways for gas or fluid to escape from casing annuli and in plugged and abandoned or orphan wells, posing environmental risks. Yet, a reliable and cost-effective way to monitor cement and well integrity over multiple decades is still unavailable. Traditional geophysical methods like 4D seismic imaging and surface-based electromagnetic monitoring lack the resolution and accuracy for detecting these types of failures (Vasco et al., 2022; Fawad and Mondol, 2021). Wireline logging is expensive to run continuously and is obtrusive to the operation. While fiber optics can potentially be a solution, its bulkiness can significantly compromise the cement's integrity. To address these challenges, the Advanced Energy Consortium (AEC) at The University of Texas at Austin’s Bureau of Economic Geology (the Bureau) has been pioneering research in subsurface monitoring using its portfolio of distributed autonomous microfabricated sensors for harsh subsurface environments since 2008. A class of these microsensors [System on a Chip (SoC)] can be mixed in cement and permanently placed without compromising the cement column; the sensors would then communicate with each other or a data acquisition (DAQ) master node. Another class of the AEC microsensors can be fully autonomous, with rechargeable micro-batteries capable of exceeding 100°C, flash memory, and, currently, a pressure and temperature sensor. They are designed to circulate in mud, geothermal fluids, U-loops, or pipelines. They can log data into memory and are unobtrusive to operations. Our team has been working on a multi-year DOE-funded project (DE-FE0031856)—supported by $2.95M in federal funding and $0.75M in cost-matching from the AEC—to demonstrate SoC sensor utility for CO2 leakage monitoring in CCS applications. This multi-institutional collaboration developed a novel sensing architecture utilizing radiofrequency (RF) microsensors embedded within the cement sheath. These sensors detect CO2 migration and are interrogated via a Smart Casing Collar (SCC).

58 GEOSCIENCES↗

Calibration and field deployment of low-cost sensor network to monitor underground pipeline leakage

Recent technological advances in methane detection have improved leak detection and repair. However, current methods to reliably measure methane concentrations rely on expensive instruments or demand significant labor input. There is interest in using affordable methane sensors that are responsive to ppmv level changes in methane concentrations in both urban and rural environments for monitoring underground natural gas pipeline leaks. This is especially relevant for situations where potentially significant leaks cannot be repaired immediately or smaller leaks that require long-term monitoring and further evaluation. In this work, a low-cost sensor unit, equipped with a metal oxide sensor, was designed, built, and calibrated over a wide range of methane concentrations and environmental conditions in preparation for field application. A network of these sensors was then installed at the test site and used to measure methane concentrations at ground level above known sub-surface natural gas emissions which emulated underground gas pipeline leaks. This low-cost sensor network measured over 4 days total for the two different known leakage rates. Results demonstrate that the sensors can continuously measure relative methane variability for extended periods but require calibration for a wide range of temperature and humidity conditions to properly determine absolute gas (i.e., methane) concentrations. Furthermore, when a regression analysis was conducted to evaluate the effects of meteorological parameters on methane concentration, air temperature and wind speed have strong impacts on the concentration. Overall, the network approach allows improved identification of leak location and monitoring of underground natural gas leaks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monitoring of helium gas leakage from canister storing spent nuclear fuel: Radiological consequences and management

Chloride-induced stress corrosion cracking (CISCC) of canisters has been identified as a potential degradation mechanism requiring ageing management — especially in a marine air environment. Methods for monitoring helium gas leakage from canisters have been developed on the basis of a phenomenon that the bottom temperature of the canister increases as the top temperature of the canister decreases when helium gas leaks during storage. In this paper, we consider the radiological consequences of CISCC based on two scenarios of helium gas leakage and propose effective management that includes a timeline for monitoring and mitigation. Monitoring helium gas leakage by measuring the difference in temperature between canister surfaces in the dry cask storage of spent fuel (SF) can detect leakage before SF undergoes oxidation as a result of air ingress and before country-specific regulatory limits of off-site doses are exceeded, thereby enabling mitigatory action.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Atmospheric leakage and condensate production in NASA's biomass production chamber. Effect of diurnal temperature cycles

A series of tests were conducted to monitor atmospheric leakage rate and condensate production in NASA's Biomass Production Chamber (BPC). Water was circulated through the 64 plant culture trays inside the chamber during the tests but no plants were present. Environmental conditions were set to a 12-hr photoperiod with either a matching 26 C (light)/20 C (dark) thermoperiod, or a constant 23 C temperature. Leakage, as determined by carbon dioxide decay rates, averaged about 9.8 percent for the 26 C/20 C regime and 7.3 percent for the constant 23 C regime. Increasing the temperature from 20 C to 26 C caused a temporary increase in pressure (up to 0.5 kPa) relative to ambient, while decreasing the temperature caused a temporary decrease in pressure of similar magnitude. Little pressure change was observed during transition between 23 C (light) and 23 C (dark). The lack of large pressure events under isothermal conditions may explain the lower leakage rate observed. When only the plant support inserts were placed in the culture trays, condensate production averaged about 37 liters per day. Placing acrylic germination covers over the tops of culture trays reduced condensate production to about 7 liters per day. During both tests, condensate production from the lower air handling system was 60 to 70 percent greater than from the upper system, suggesting imbalances exist in chilled and hot water flows for the two air handling systems. Results indicate that atmospheric leakage rates are sufficiently low to measure CO2 exchange rates by plants and the accumulation of certain volatile contaminants (e.g., ethylene). Control system changes are recommended in order to balance operational differences (e.g., humidity and temperature) between the two halves of the chamber.

Wheeler, Raymond M.↗

Quantification of CO 2 Mineralization at the Wallula Basalt Pilot Project

In 2013, the Pacific Northwest National Laboratory led a geologic carbon sequestration field demonstration where ~1000 tonnes of CO 2 was injected into several deep Columbia River Basalt zones near Wallula, Washington. Rock core samples extracted from the injection zone two years after CO 2 injection revealed nascent carbonate mineralization that was qualitatively consistent with expectations from laboratory experiments and reactive transport modeling. In this study, we report on a new detailed analysis of the 2012 pre-injection and 2015 post-injection hydrologic tests that capitalizes on the difference in fluid properties between scCO 2 and water to assess changes in near-field, wellbore, and reservoir conditions that are apparent approximately two years following the end of injection. This comparative hydrologic test analysis method provides a new way to quantify the amount of injected CO 2 that was mineralized in the field test. Modeling results indicate that approximately 60% of the injected CO 2 was sequestered via mineralization within two years, with the resulting carbonates occupying ~4% of the available reservoir pore space. The method presented here provides a new monitoring tool to assess the fate of CO 2 injected into chemically reactive basalt formations but could also be adapted for long-term monitoring and verification within more traditional subsurface carbon storage reservoirs.

54 ENVIRONMENTAL SCIENCES↗

Induced microseismicity and tremor signatures illuminate different slip behaviours in a natural shale fault reactivated by a fluid pressure stimulation (Mont Terri)

SUMMARY Fault slip induced by fluid perturbation in shale formations may only lead to a sparse seismicity. However, fault slip may strongly impact the integrity of shale formations that serve as caprocks for geological reservoirs holding buoyant fluids such as CO2, natural gas or hydrogen. A better understanding of the fluid reactivation processes of fault and the seismic triggering process is therefore critical for reservoir monitoring and fault stability. Here we analyse the seismic responses of a shale fault exposed to fluid pressurization during an in situ field-scale injection experiment at ∼340 m depth in the Mont Terri underground research laboratory (Switzerland). Two main types of seismic signals are observed as the fault was activated and started to slowly slip. After an aseismic phase, we observed tremor signatures and an increase in noise amplitude, which were directly associated with the slowly propagating fault slip in response to fluid injection. These signatures were later followed by micro-earthquakes that seem to occur further away from the fluid-pressurized area. We interpret these micro-earthquakes to be triggered by stress perturbations from the main slip growth. These two classes of seismic responses therefore highlight two different processes. Tremors seem to be a more direct observation for the fluid-induced slip propagation than micro-earthquakes. Even hidden in the noise, they precede earthquake failures, thus providing a useful tool for monitoring fluid leakage activated by slow deformation on low permeable shale faults, with applications for sealing integrity of caprocks.

De Barros, Louis (ORCID:0000000255419162)↗

Leak Tester for Cryogenic Flowlines

Gas chromatography measures leakage into cavity surrounding joint under test. System surrounds joint being tested with sealed cavity. Presence of leakage gas in cavity monitored by gas chromatograph. Leakage rate found by multiplying relative leakage gas concentration by mass flow rate of purge as into cavity.

Mortensen, G. D.↗

Quick-Actuating Closure And Handling System

Quick-actuating closure and handling system developed for containers, particularly for high-pressure vessels or shells entered frequently. Features simplicity in design and operation, saving of time, monitoring of leakage, and safety. Another significant feature, use of conical surfaces to engage effectively shear blocks in locked position to provide necessary preload and to transmit internal-pressure load directly to pressure vessel. Designed to impart proper radial movement to shear blocks, based on space available for longitudinal travel of screwjacks. Adaptable to many applications; used for such containers as autoclaves, vacuum chambers, and wide variety of specialized vessels requiring frequent entry and closure.

White, Dorsey E.↗