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At least 19 records

Extending 3D Near-Cloud Corrections from Shorter to Longer Wavelengths

Satellite observations have shown a positive correlation between cloud amount and aerosol optical thickness (AOT) that can be explained by the humidification of aerosols near clouds, and/or by cloud contamination by sub-pixel size clouds and the cloud adjacency effect. The last effect may substantially increase reflected radiation in cloud-free columns, leading to overestimates in the retrieved AOT. For clear-sky areas near boundary layer clouds the main contribution to the enhancement of clear sky reflectance at shorter wavelengths comes from the radiation scattered into clear areas by clouds and then scattered to the sensor by air molecules. Because of the wavelength dependence of air molecule scattering, this process leads to a larger reflectance increase at shorter wavelengths, and can be corrected using a simple two-layer model. However, correcting only for molecular scattering skews spectral properties of the retrieved AOT. Kassianov and Ovtchinnikov proposed a technique that uses spectral reflectance ratios to retrieve AOT in the vicinity of clouds; they assumed that the cloud adjacency effect influences the spectral ratio between reflectances at two wavelengths less than it influences the reflectances themselves. This paper combines the two approaches: It assumes that the 3D correction for the shortest wavelength is known with some uncertainties, and then it estimates the 3D correction for longer wavelengths using a modified ratio method. The new approach is tested with 3D radiances simulated for 26 cumulus fields from Large-Eddy Simulations, supplemented with 40 aerosol profiles. The results showed that (i) for a variety of cumulus cloud scenes and aerosol profiles over ocean the 3D correction due to cloud adjacency effect can be extended from shorter to longer wavelengths and (ii) the 3D corrections for longer wavelengths are not very sensitive to unbiased random uncertainties in the 3D corrections at shorter wavelengths.

aerosol optical depth

Risk of longer-term endocrine and metabolic conditions in the Deepwater Horizon Oil Spill Coast Guard cohort study – five years of follow-up

Abstract Introduction Long-term endocrine and metabolic health risks associated with oil spill cleanup exposures are largely unknown, despite the endocrine-disrupting potential of crude oil and oil dispersant constituents. We aimed to investigate risks of longer-term endocrine and metabolic conditions among U.S. Coast Guard (USCG) responders to the Deepwater Horizon (DWH) oil spill. Methods Our study population included all active duty DWH Oil Spill Coast Guard Cohort members ( N = 45,224). Self-reported spill exposures were ascertained from post-deployment surveys. Incident endocrine and metabolic outcomes were defined using International Classification of Diseases (9th Revision) diagnostic codes from military health encounter records up to 5.5 years post-DWH. Using Cox proportional hazards regression, we estimated adjusted hazard ratios (aHR) and 95% confidence intervals (CIs) for various incident endocrine and metabolic diagnoses (2010–2015, and separately during 2010–2012 and 2013–2015). Results The mean baseline age was 30 years (~ 77% white, ~ 86% male). Compared to non-responders ( n = 39,260), spill responders ( n = 5,964) had elevated risks for simple and unspecified goiter (aHR = 2.09, 95% CI: 1.29–3.38) and disorders of lipid metabolism (aHR = 1.09, 95% CI: 1.00–1.18), including its subcategory other and unspecified hyperlipidemia (aHR = 1.10, 95% CI: 1.01–1.21). The dysmetabolic syndrome X risk was elevated only during 2010–2012 (aHR = 2.07, 95% CI: 1.22–3.51). Responders reporting ever ( n = 1,068) vs. never ( n = 2,424) crude oil inhalation exposure had elevated risks for disorders of lipid metabolism (aHR = 1.24, 95% CI: 1.00–1.53), including its subcategory pure hypercholesterolemia (aHR = 1.71, 95% CI: 1.08–2.72), the overweight, obesity and other hyperalimentation subcategory of unspecified obesity (aHR = 1.52, 95% CI: 1.09–2.13), and abnormal weight gain (aHR = 2.60, 95% CI: 1.04–6.55). Risk estimates for endocrine/metabolic conditions were generally stronger among responders reporting exposure to both crude oil and dispersants (vs. neither) than among responders reporting only oil exposure (vs. neither). Conclusion In this large cohort of active duty USCG responders to the DWH disaster, oil spill cleanup exposures were associated with elevated risks for longer-term endocrine and metabolic conditions.

Denic-Roberts, Hristina

Declining Reservoir Reliability and Increasing Reservoir Vulnerability: Long-Term Observations Reveal Longer and More Severe Periods of Low Reservoir Storage for Major United States Reservoirs

Hydrological drought is a pervasive and reoccurring challenge in managing water resources. Reservoirs are critical for lessening the impacts of drought on water available for many uses. We use a novel and generalized approach to identify periods of unusually low reservoir storage—via comparisons to operational rule curves and historical patterns—to investigate how droughts affect storage in 250 reservoirs across the conterminous U.S. (CONUS). We find that the maximum amount of water stored in reservoirs is decreasing, and that periods of unusually low storage are becoming longer, more severe, and more variable in (a) western and central CONUS reservoirs, and (b) reservoirs with primarily over-year storage. Results suggest that reservoir storage has become less reliable and more vulnerable to larger deviations from desired storage patterns. These changes have coincided with ongoing shifts to the hydroclimate of CONUS, and with sedimentation further reducing available reservoir storage.

54 ENVIRONMENTAL SCIENCES

Short-range order and longer-range disorder revealed in germanium–tin alloy thin films by extended x-ray absorption fine structure analysis

Short-range order (SRO) in semiconductor alloys, a relatively under-studied structural phenomenon in which local atomic arrangements differ from those of a random solid solution, is investigated in molecular beam epitaxy (MBE)-grown GeSn thin films. A novel preparation technique is used to pattern these films into microscale ribbons that are released from the substrate for extended x-ray absorption fine structure (EXAFS) analysis. The results indicate a strong SRO in which the first shell around Sn atoms is greatly denuded of Sn atoms relative to the nominal atomic composition of the alloy. This effect is more pronounced than that observed recently in GeSn nanowires grown by chemical vapor deposition. Additionally, the presence of a longer-range disorder detected by EXAFS analysis in the shells of atoms more distant from the absorbers is indicative of the defects and inhomogeneous strain present in the MBE-grown films. The evident existence of the SRO in GeSn alloys deposited by different growth methods and in different strain states suggests that SRO is a general phenomenon in the thin films of this metastable solid solution.

74 ATOMIC AND MOLECULAR PHYSICS

Very slow classical Cepheids - Theoretical models with periods longer than 50 days

Systematics of the light curves of classical Cepheids with the longest known periods have been investigated with the help of full-amplitude models of pulsating stellar envelopes. For periods exceeding about 60 days, flat-topped light curves of the S Vul type are found to replace the smooth, asymmetric light curves characteristic of the slightly faster Cepheids. Predicted light and velocity amplitudes (although not the predicted radius amplitudes) agree well with observations. Variables with fluctuating light minima are observed to lie well off the mean period-luminosity relation, as are a few other (more stable?) variables with similarly long periods. The explanation for the long periods is probably low effective temperature rather than a low stellar mass. Because of the abnormal slowness of the classical Cepheids with periods longer than about 100 days, it is recommended that these variables not be used to calibrate the mean period-luminosity relation. Analogies between the slow classical Cepheids and the slow Population II Cepheids are drawn.

Carson, T. R.

CO2 lidar observations of Mount Pinatubo debris: FIRE 2 and longer-term measurements

The volcanic debris in the stratosphere from the June 1991 eruption of Mt. Pinatubo first appeared over the NOAA Wave Propagation Laboratory (WPL) field site near Boulder, Colorado (40.15 N, 105.23 W), in July of 1991. The presence of the Pinatubo cloud has allowed us to characterize both the tropospheric and stratospheric aerosol backscatter using the NOAA/WPL CO2 Doppler lidar. The lidar has measured vertical backscatter profiles at lambda = 10.59 mu m for over a decade. Analysis of this dense set of profiles reveals the effects of atmospheric and microphysical processes during the buildup and decay of Mt. Pinatubo's clouds. Further information on the NOAA lidar, specifically calibrations using a hard target, can be found in Post and Cupp (1990). We present results of those measurements for June 15, 1991, through December 31, 1992. During that period of longer-term measurements, WPL took part in FIRE II (First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment II), from November 12 through December 8, 1991, measuring vertical backscatter profiles almost daily. One of the mechanisms for purging stratospheric aerosols is tropopause folding, which occurs in cold-core extratropical cyclones. Tropospheric mass loading occurs during folding events which can substantially increase the amount of ice nuclei in the upper troposphere, and may affect the formation of cirrus in that region. Spring and fall are prominent times for tropopause folding events because of the migration of the subtropical and polar jet streams during the transition seasons. Sassen has suggested that the volcanic aerosols from Pinatubo played a role in the formation of cirrus during FIRE II, particularly during a period of moist subtropical flow on December 5-6, 1991.

Levinson, David H.

A Reanalysis for the Seasonal and Longer-Period Cycles and the Trends in Middle Atmosphere Temperature from the HALOE

Previously published analyses for the seasonal and longer-period cycles in middle atmosphere temperature versus pressure (or T(p)) from the Halogen Occultation Experiment (HALOE) are extended to just over 14 years and updated to properly account for the effects of autocorrelation in its time series of zonally-averaged data. The updated seasonal terms and annual averages are provided, and they can be used to generate temperature distributions that are representative of the period 1991-2005. QBO-like terms have also been resolved and are provided, and they exhibit good consistency across the range of latitudes and pressure-altitudes. Further, exploratory analyses of the residuals from each of the 221 time series have yielded significant 11-yr solar cycle (or SC-like) and linear trend terms at a number of latitudes and levels. The amplitudes of the SC-like terms for the upper mesosphere agree reasonably with calculations of the direct solar radiative effects for T(p). Those SC amplitudes increase by about a factor of 2 from the lower to the upper mesosphere and are also larger at the middle than at the low latitudes. The diagnosed cooling trends for the subtropical latitudes are in the range, -0.5 to -1.0 K/decade, which is in good agreement with the findings from models of the radiative effects on pressure surfaces due to known increases in atmospheric CO2. The diagnosed trends are somewhat larger than predicted with models for the upper mesosphere of the northern hemisphere middle latitudes.

Remsberg, Ellis E.

Condensed-Phase Photochemical Processes in Titan's Aerosols and Surface: The Role of Longer Wavelength Photochemistry

We will discuss photochemical properties of Titan's organic molecules in the condensed phase as solid aerosols or surface material, from small linear polyyenes (polyacetylenes and polycyanoacetylenes) such as C2H2, C4N2, HC5N, etc. In particular we will focus on photochemistry caused by longer wavelength UV-VIS photons (greater than 250 nm) photons that make it through Titan's atmosphere to the haze region (approximately 100 km) and on to the surface of Titan.

Surface area

Comparison of Equilibrium Climate Sensitivity Estimates From Slab Ocean, 150‐Year, and Longer Simulations

We compare equilibrium climate sensitivity (ECS) estimates from pairs of long (≥ 800‐year) control and abruptly quadrupled CO2 simulations with shorter (150, 300 year) coupled atmosphere‐ocean simulations and Slab Ocean Models (SOM). Consistent with previous work, ECS estimates from shorter coupled simulations based on annual averages for years 1‐150 underestimate those from SOM (‐8% ± 13%) and long (‐14% ± 8%) simulations. Analysis of only years 21‐150 improved agreement with SOM (‐2% ± 14%) and long (‐8% ± 10%) estimates. Use of pentadal averages for years 51‐150 results in improved agreement with long simulations (‐4% ± 11%). While ECS estimates from current generation US models based on SOM and coupled annual averages of years 1‐150 range from 2.6°C to 5.3°C, estimates based longer simulations of the same models range from 3.2°C to 7.0°C. Such variations between methods argues for caution in comparison and interpretation of ECS estimates across models.

Climate sensitivity

Toward an Integrated Product of Higher Accuracy and Longer Time Span: Improvement of the Upcoming NASA GEWEX SRB Data Release 4 over Release 3 Based on Validation Against Surface-Based Measurements

The NASA Global Energy and Water Exchanges (GEWEX) Surface Radiation Budget (SRB) is moving toward its next generation, the Release 4 Integrated Product (Rel. 4-IP), and its shortwave algorithm preliminary results as of this writing span 34 years continuously from July 1983 to June 2017 on a quasi-equal-area grid system with 44,016 gridboxes ranging from 1 longitude times 1 latitude around the Equator to 120 longitude times 1 latitude. The data are in the form of 3-hourly, 3-hourly-monthly, daily and monthly means. The Baseline Surface Radiation Network (BSRN) is a project of the Data and Assessments Panel from the GEWEX under the umbrella of the World Climate Research Programme (WCRP). Currently in the archive there are data from 67 sites located in all seven continents spanning from 1992 to the very present. The original BSRN records are at 1-, 2-, 3- or 5-minute intervals, and sophisticated quality-control procedures have been developed to eliminate erroneous records before hourly, daily and monthly means are computed. The Pacific Marine Environmental Laboratory (PMEL) arrays of buoys in the tropical oceans, TAO/TRITON (Pacific Ocean), RAMA (Indian Ocean) and PITARA (Atlantic Ocean), measure shortwave downward fluxes using pyranometers. These buoys transmit measured data to shore in real-time via the Argos satellite system. And these buoys are major components of the CLIVAR climate analysis project and the GOOS, GCOS, and GEOSS observing systems. So far there are data from 64 buoys and the earliest data start from 2000. We have extensively validated the Rel. 4-IP preliminary results against the BSRN and PMEL 3-hourly, daily and monthly means. In this paper, we will show that the new results not only temporally span 10 years longer than its predecessor, Release 3, but agree significantly better with the BSRN data over the land and PMEL data over the ocean.

Taiping Zhang

Plasma jet electrode has longer operating life

Water-cooled, silver-infiltrated tungsten electrode has twice the operating lifetime of the pure tungsten electrode used in plasma jet generators. This electrode reduces the erosion rate, ensures excellent heat transfer, and reduces thermal stresses.

Gracey, C. M.

Longer term consequences of the Short Take-Off and Landing (STOL) aircraft system

An assessment of the STOL aircraft and the various means of employing it are discussed in the light of a research study to evaluate the efficacy of such analyses. It was determined that current approaches to assessment are generally inadequate for investigating the full social consequences of implementing a new technology. It is stated that a meaningful methodology of technology assessment must reflect mechanisms underlying the relationship of technology to social change. Interrelated methods which are discussed are: (1) gaming and simulation as heurisitic approaches in analysis and inquiry, (2) long range planning and questions of the future, (3) planning theory as a background for critical analysis of policy planning, and (4) social theory, with particular emphasis on social change and systems theories.

Laporte, T. R.

Longer shelf life for ceramic slurries

Viscosity of ceramic-coating slurries containing organic acrylate viscosity-control agent is stabilized for over 2 months by addition of ammonium hydroxide without significant changes.

Izu, Y. D.