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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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13 records

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NASA NTRS2002

A New Acceptor (N-type) Polyphenylenevinylene Building Block: SF-PPV-I

A new sulfone derivatized acceptor (n-type) polyphenylenevinylene "SF-PPV" with nano meter sizes and functional terminals has been synthesized and characterized. The SF-PPV-I that contains hydrocarbon alkyl-sulfone moieties has a strong photoluminescence in both solution and in solid thin film states. In dichloromethane, the 5-10 nm sized SF-PPV has a maximum emission at about 530 nm with excitation maximum at about 490 nm. UV-VIS shows a absorption peak onsite at about 500 nm. Optical spectroscopy and electrochemical studies revealed that the SF-PPV-I has an LUMO level at about -3.6 eV (relative to vacuum), and an HOMO level at about -6.1 eV. The average size (length) of SF-PPV-I can be controlled on the nano meter scale via synthetic means. The SF-PPV has the potential in developing polymer based supramolecular opto-electronic semiconductor devices.

Wang, Yiqing↗

NASA NTRS2000

A semiempirical study for the ground and excited states of free-base and zinc porphyrin-fullerene dyads

The ground and excited states of a covalently linked porphyrin-fullerene dyad in both its free-base and zinc forms (D. Kuciauskas et al., J. Phys. Chem. 100 (1996) 15926) have been investigated by semiempirical methods. The excited-state properties are discussed by investigation of the character of the molecular orbitals. All frontier MOs are mainly localized on either the donor or the acceptor subunit. Thus, the absorption spectra of both systems are best described as the sum of the spectra of the single components. The experimentally observed spectra are well reproduced by the theoretical computations. Both molecules undergo efficient electron transfer in polar but not in apolar solvents. This experimental finding is explained theoretically by explicitly considering solvent effects. The tenth excited state in the gas phase is of charge-separated character where an electron is transferred from the porphyrin donor to the fullerene acceptor subunit. This state is stabilized in energy in polar solvents due to its large formal dipole moment. The stabilization energy for an apolar environment such as benzene is not sufficient to lower this state to become the first excited singlet state. Thus, no electron transfer is observed, in agreement with experiment. In a polar environment such as acetonitrile, the charge-separated state becomes the S, state and electron transfer takes place, as observed experimentally. The flexible single bond connecting both the donor and acceptor subunits allows free rotation by ca. +/- 30 degrees about the optimized ground-state conformation. For the charge-separated state this optimized geometry has a maximum dipole moment. The geometry of the charge-separated state thus does not change relatively to the ground-state conformation. The electron-donating properties of porphyrin are enhanced in the zinc derivative due to a reduced porphyrin HOMO-LUMO energy gap. This yields a lower energy for the charge-separated state compared to the free-base dyad.

Bridged Compounds/chemistry↗

NASA NTRS2004

Arylethynyl Substituted 9,lO-Anthraquinones: Tunable Stokes Shifts by Substitution and Solvent Polarity

2-Arylethynyl- and 2,6- and 2,7-diarylethynyl-substituted 9,lO-anthraquinones were synthesized via Sonogashira coupling reactions of 2-bromo-, 2,6-dibromo-, and 2,7-dibromo-9,10- anthraquinone with para-substituted phenylacetylenes. While the redox properties of those compounds are almost insensitive to substitution, their absorption maxima are linearly related to the Hammett constants with different slopes for electron donors and electron acceptors. ABI compounds are photoluminescent both in solution (quantum yields of emission <= 6 %), and as solids. The emission spectra have the characteristics of charge-transfer bands with large Stokes shifts (100-250 nm). The charge-transfer character of the emitting state is supported by large dipole moment differences between the ground and the excited state as concluded on the basis of molecular modeling and Lippert-Mataga correlations of the Stokes shifts with solvent polarity. Maximum Stokes shifts are attained by both electron-donating and -withdrawing groups. This is explained by a destabilization of the HOMO by electron donors and a stabilization of the LUMO by electron acceptors. X-ray crystallographic analysis of, for example, 2,7-bisphenylethynfl- 9,lO-anthraquinone reveals a monoclinic P21In space group and no indication for pi-overlap that would promote quenching, thus explaining emission from the solid state. Representative reduced forms of the title compounds were isolated as stable acetates of the corresponding dihydrs-9,10- anthraquinones. The emission of these compounds is blue-shifted relative to the parent oxidized forms and is attributed to internal transitions in the dihydro-9,lO-anthraquinone core.

Yang, Jinhua↗

NASA NTRS2017

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Concept Design Update

In preparation for the 2020 Astrophysics Decadal Survey, NASA has commissioned the study of four large mission concepts, including the Large Ultraviolet / Optical / Infrared (LUVOIR) Surveyor. The LUVOIR Science and Technology Definition Team (STDT) has identified a broad range of science objectives including the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the epoch of reionization, star and planet formation, and the remote sensing of Solar System bodies. NASA’s Goddard Space Flight Center (GSFC) is providing the design and engineering support to develop executable and feasible mission concepts that are capable of the identified science objectives. We present an update on the first of two architectures being studied: a 15-meter-diameter segmented-aperture telescope with a suite of serviceable instruments operating over a range of wavelengths between 100 nm to 2.5 microns. Four instruments are being developed for this architecture: an optical / near-infrared coronagraph capable of 10(exp -10) contrast at inner working angles as small as 2 lambda/D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100 – 400 nm) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-IR imager; and a UV spectro-polarimeter being contributed by Centre National d’Etudes Spatiales (CNES). A fifth instrument, a multi-resolution optical-NIR spectrograph, is planned as part of a second architecture to be studied in late 2017.

Decadal Study; Astrophysics; LUVOIR↗

NASA NTRS2018

The LUVOIR Surveyor: Decadal Mission Concept Update

The Large Ultraviolet/Optical/Infrared (LUVOIR) Science and Technology Definition Team (STDT) identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets and an array of general astrophysics and Solar System observations. To meet these objectives, the LUVOIR Study Office completed the first design iteration of a 15-m segmented-aperture observatory that includes four serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS); the LUVOIR UV Multi-object Spectrograph (LUMOS); the High Definition Imager (HDI); and Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d'Etudes Spatiales (CNES). The study team is now executing a second design iteration to further improve upon the 15-m concept, while simultaneously studying a 9-m concept. In these proceedings, we provide an update on these architectures.

LUVOIR↗

NASA NTRS2018

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Study Update

NASA commissioned the study of four large mission concepts, including the Large Ultraviolet / Optical / Infrared (LUVOIR) Surveyor, to be evaluated by the 2020 Decadal Survey in Astrophysics. In response, the Science and Technology Definition Team (STDT) identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. To meet these objectives, the LUVOIR Study Office, located at NASA's Goddard Space Flight Center (GSFC), completed the first design iteration of a 15-m segmented-aperture observatory that would be launched by the Space Launch System (SLS) Block 2 configuration. The observatory includes four serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical / near-infrared coronagraph capable of delivering 10(exp -10) contrast at inner working angles as small as 2 lambda/D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100 - 400 nm) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager; and Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d'Etudes Spatiales (CNES). The study team has executed a second design iteration to further improve upon the 15-m concept, while simultaneously studying an 8-m concept. In these proceedings, we provide an update on these two architectures.

cosmic origins↗

NASA NTRS2019

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Concept Study Update

In preparation for the 2020 Decadal Survey in Astronomy and Astrophysics, NASA commissioned the study of four large mission concepts: the Large UV/Optical/Infrared Surveyor (LUVOIR), the Habitable Exoplanet Imager (HabEx), the far-infrared surveyor Origins Space Telescope (OST), and the X-ray surveyor Lynx. The LUVOIR Science and Technology Definition Team (STDT) has identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. The LUVOIR Study Office, located at NASA's Goddard Space Flight Center (GSFC), is developing two mission concepts to achieve the science objectives. LUVOIR-A is a 15-meter segmented-aperture observatory that would be launched in an 8.4-m extended fairing on the Space Launch System (SLS) Block 2 configuration. LUVOIR-B is an 8-meter unobscured segmented aperture telescope that fits in a smaller, conventional 5-meter fairing, but still requires the lift capacity of the SLS Block 1B Cargo vehicle. Both concepts include a suite of serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical/near-infrared coronagraph capable of delivering 10 (sup minus10) contrast at inner working angles as small as 2 lambda divided by D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100-400 nanometer) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager. LUVOIR-A also has a fourth instrument, Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d'Etudes Spatiales (CNES). This paper provides an overview of the LUVIOR science objectives, design drivers, and mission concepts.

Decadal Study↗

NASA NTRS2019

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Concept Study Update

In preparation for the 2020 Decadal Survey in Astronomy and Astrophysics, NASA commissioned the study of four large mission concepts: the Large UV/Optical/Infrared Surveyor (LUVOIR), the Habitable Exoplanet Imager (HabEx), the far-infrared surveyor Origins Space Telescope (OST), and the X-ray surveyor Lynx. The LUVOIR Science and Technology Definition Team (STDT) has identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. The LUVOIR Study Office, located at NASA's Goddard Space Flight Center (GSFC), is developing two mission concepts to achieve the science objectives. LUVOIR-A is a 15-meter segmented-aperture observatory that would be launched in an 8.4-meter extended fairing on the Space Launch System (SLS) Block 2 configuration. LUVOIR-B is an 8-meter unobscured segmented aperture telescope that fits in a smaller, conventional 5-meter fairing, but still requires the lift capacity of the SLS Block 1B Cargo vehicle. Both concepts include a suite of serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical/near-infrared coronagraph capable of delivering 10 (sup minus 10) contrast at inner working angles as small as 2 lambda divided by D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100-400 nanometer) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager. LUVOIR-A also has a fourth instrument, Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d'Etudes Spatiales (CNES). This paper provides an overview of the LUVIOR science objectives, design drivers, and mission concepts.

Decadal Study↗

NASA NTRS2019

Optical Instrument Thermal Control on the Large Ultraviolet/Optical/Infrared Surveyor

The Large Ultraviolet/Optical/Infrared Surveyor (LUVOIR) is a multi-wavelength observatory commissioned by NASA as one of four large mission concept studies for the Astro2020 Decadal Survey. Two concepts are under study which bound a range of cost, risk, and scientific return: an 8-meter diameter unobscured segmented aperture primary mirror and a 15-meter segmented aperture primary mirror. Each concept carries with it an accompanying suite of instruments. The Extreme Coronagraph for Living Planetary Systems (ECLIPS) is a near-ultraviolet (NUV) / optical / near-infrared (NIR) coronagraph; the LUVOIR Ultraviolet Multi-object Spectrograph (LUMOS) provides multi-object imaging spectroscopy in the 100-400 nanometer ultraviolet (UV) range; and the High Definition Imager (HDI) is a wide field-of-view near-UV / optical / near-IR camera that can also perform astrometry. The 15-meter concept also contains an additional instrument, Pollux, which is a high-resolution UV spectro-polarimeter. While the observatory is nominally at a 270 Kelvin operational temperature, the requirements of imaging in both IR and UV require separate detectors operating at different temperature regimes, each with stringent thermal stability requirements. The change in observatory size requires two distinct thermal designs per instrument. In this current work, the thermal architecture is presented for each instrument suite. We describe here the efforts made to achieve the target operational temperatures and stabilities with passive thermal control methods. Additional discussion will focus on how these instrument thermal designs impact the overall system-level architecture of the observatory and indicate the thermal challenges for hardware implementation.

Decadal Study↗

NASA NTRS2019

Optical Instrument Thermal Control on the Large Ultraviolet/Optical/Infrared Surveyor

LUVOIR↗

NASA NTRS2019

LUVOIR: Engineering Design & Technology Overview

The Large Ultraviolet / Optical / Infrared Surveyor (LUVOIR) is one of four large mission concepts being study by NASA in preparation for the 2020 Decadal Survey in Astronomy and Astrophysics. Over the past three and a half years, the LUVOIR Science and Technology Definition Team (STDT) and Study Office at NASA's Goddard Space Flight Center have developed a broad, compelling science case for LUVOIR, and detailed engineering point designs to achieve it. In this paper, we provide an overview of the two LUVOIR concepts: LUVOIR-A, a 15-m segmented, obscured aperture observatory, and LUVOIR-B, an 8-m segmented, unobscured aperture observatory. Both versions of LUVOIR cover a broad spectral range between 100 nm and 2.5 Âµm with a suite of imagers and spectrographs, including the High Definition Imager (HDI), the LUVOIR Ultraviolet Multi-object Spectrograph (LUMOS), and the Extreme Coronagraph for Living Planetary Systems (ECLIPS). LUVOIR-A will carry an additional fourth instrument, Pollux, a high-resolution UV spectropolarimeter being studied by the Centre National d'Etudes Spatiales (CNES). Both versions of LUVOIR are also designed to be serviceable and upgradeable. We will also provide a summary of the LUVOIR technology development program, which identifies critical enabling technologies, enhancing technologies, and a development plan to mature those technologies to TRL 6.

technology↗

NASA NTRS2019

Overview of the Optomechanical Design of the LUVOIR Instruments

The Large Ultraviolet/Optical/Infrared Surveyor (LUVOIR) is a space telescope being submitted for review to the 2020 Decadal Survey in Astronomy and Astrophysics. Its science objectives include both direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of planet, star, and galaxy formation, the transfer of matter between different galaxies, and the remote sensing of objects within the Solar System. Two architectures have been designed: a 15 m diameter on-axis telescope (LUVOIR-A) and an 8 m off-axis telescope (LUVOIR-B). This paper discusses the opto-mechanical design of the three LUVOIR instruments: the High Definition Imager (HDI), the LUVOIR UV Multi-object Spectrograph (LUMOS), and the Extreme Coronagraph for Living Planetary Systems (ECLIPS). For both the LUVOIR-A and LUVOIR-B variants of each instrument, optical design specifications are presented including first-order constraints, packaging requirements, and optical performance metrics. These factors are used to illustrate the final design of each instrument and LUVOIR as a whole. In addition to the optical designs, mechanical models are presented for each instrument showing the optical mounts, mechanisms, support structure, etc.

Decadal Study↗

NASA NTRS2018

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Study Update

NASA commissioned the study of four large mission concepts, including the Large Ultraviolet / Optical / Infrared (LUVOIR) Surveyor, to be evaluated by the 2020 Decadal Survey in Astrophysics. In response, the Science and Technology Definition Team (STDT) identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. To meet these objectives, the LUVOIR Study Office, located at NASA’s Goddard Space Flight Center (GSFC), completed the first design iteration of a 15-m segmented-aperture observatory that would be launched by the Space Launch System (SLS) Block 2 configuration. The observatory includes four serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical / near-infrared coronagraph capable of delivering 10^-10contrast at inner working angles as small as 2 O/D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100 – 400 nm) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager; and Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d’Etudes Spatiales (CNES).The study team has executed a second design iteration to further improve upon the 15-m concept, while simultaneously studying an 8-m concept. In these proceedings, we provide an update on these two architectures.

space telescopes↗