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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Proposed Lunar Measurements of r-Process Radioisotopes to Distinguish the Origin of Deep-sea 244 Pu

Abstract 244 Pu has recently been discovered in deep-sea deposits spanning the past 10 Myr, a period that includes two 60 Fe pulses from nearby supernovae. 244 Pu is among the heaviest r -process products, and we consider whether it was created in supernovae, which is disfavored by nucleosynthesis simulations, or in an earlier kilonova event that seeded the nearby interstellar medium with 244 Pu that was subsequently swept up by the supernova debris. We discuss how these possibilities can be probed by measuring 244 Pu and other r -process radioisotopes such as 129 I and 182 Hf, both in lunar regolith samples returned to Earth by missions such as Chang’e and Artemis, and in deep-sea deposits.

79 ASTRONOMY AND ASTROPHYSICS↗

Apollo Next Generation Sample Analysis (ANGSA): an Apollo Participating Scientist Program to Prepare the Lunar Sample Community for Artemis

As a first step in preparing for the return of samples from the Moon by the Artemis Program, NASA initiated the Apollo Next Generation Sample Analysis Program (ANGSA). ANGSA was designed to function as a low-cost sample return mission and involved the curation and analysis of samples previously returned by the Apollo 17 mission that remained unopened or stored under unique conditions for 50 years. These samples include the lower portion of a double drive tube previously sealed on the lunar surface, the upper portion of that drive tube that had remained unopened, and a variety of Apollo 17 samples that had remained stored at -27 °C for approximately 50 years. ANGSA constitutes the first preliminary examination phase of a lunar “sample return mission” in over 50 years. It also mimics that same phase of an Artemis surface exploration mission, its design included placing samples within the context of local and regional geology through new orbital observations collected since Apollo and additional new “boots-on-the-ground” observations, data synthesis, and interpretations provided by Apollo 17 astronaut Harrison Schmitt. ANGSA used new curation techniques to prepare, document, and allocate these new lunar samples, developed new tools to open and extract gases from their containers, and applied new analytical instrumentation previously unavailable during the Apollo Program to reveal new information about these samples. Most of the 90 scientists, engineers, and curators involved in this mission were not alive during the Apollo Program, and it had been 30 years since the last Apollo core sample was processed in the Apollo curation facility at NASA JSC. There are many firsts associated with ANGSA that have direct relevance to Artemis. ANGSA is the first to open a core sample previously sealed on the surface of the Moon, the first to extract and analyze lunar gases collected in situ, the first to examine a core that penetrated a lunar landslide deposit, and the first to process pristine Apollo samples in a glovebox at -20 °C. All the ANGSA activities have helped to prepare the Artemis generation for what is to come. The timing of this program, the composition of the team, and the preservation of unopened Apollo samples facilitated this generational handoff from Apollo to Artemis that sets up Artemis and the lunar sample science community for additional successes.

79 ASTRONOMY AND ASTROPHYSICS↗

Development towards stable chlorine isotope measurements of astromaterials using the modified Middleton source of an accelerator mass spectrometer

The volatile element Cl can be lost during the formation and evolution of planetary bodies, leading to fractionation of its two stable isotopes 35 Cl and 37 Cl. Chlorine isotope variations (reported as δ 37 Cl in parts per thousand (‰) relative to Standard Mean Ocean Chloride, SMOC) are documented to exceed 80‰ between different lunar rock samples and have been variably interpreted as the fingerprint of degassing during accretion, magma ocean, or volcanic portions of lunar history. The large intersample and intrasample variations observed by both bulk isotope ratio mass spectrometry (IRMS) and in-situ secondary ion mass spectrometry (SIMS) methods are difficult to interpret in part because of a paucity of bulk Cl isotope measurements. This lack of high-precision bulk data is due to the relative rarity of IRMS laboratories capable of making these high precision measurements on small samples of precious planetary materials such as those returned by human or robotic exploration. Here we present a new method for performing high precision δ 37 Cl measurements using the modified Middleton ion source of an existing accelerator mass spectrometer. For samples with as little as 1 μg Cl–the equivalent of 2–4 mm 3 of a typical lunar rock sample–the average cathode accuracy is ~1‰. Finally, cathode reproducibility is typically ~1‰ (2σ) for samples with at least 10 μg of Cl, increasing to ~3–6‰ for aliquots with ~1–2 μg Cl, similar to published SIMS results and sufficient to study astromaterials from the Moon, Mars, or 4 Vesta, which have tens of ‰ observed variations.

07 ISOTOPE AND RADIATION SOURCES↗

Revealing the Moon's Taurus‐Littrow Landslide via Integrated Analysis of Pristine Apollo 17 Soil Core 73001/2

The “light mantle” deposit at the base of South Massif in the Moon's Taurus‐Littrow Valley was a primary science target for the Apollo 17 exploration. The possibility that it was a landslide triggered by ejecta from Tycho Crater is critical for establishing the age of Tycho and constraining recent lunar impact chronology; however, the mechanism of emplacement of the deposit has recently been questioned. The newly opened 73001/73002 double drive tube from Station 3 sampled 70.6 cm deep into the regolith and represents the first stratigraphic section of an extraterrestrial landslide deposit returned to Earth. Here we provide an overview of the stratigraphy of the 73001/73002 core based on top to bottom variations revealed by coordinated laboratory analyses and explore constraints on the emplacement of the light mantle deposit. Briefly, the upper ∼10 cm of 73002 contains a disturbed zone from space weathering and emplacement of ejecta from a nearby crater that excavated and ejected basaltic material. Below 10 cm is a nearly uniform unit of immature regolith. These data support a single event for the emplacement of the deposit at this location, followed by weathering and mixing of materials from nearby crater ejecta in the upper 10 cm. Slight variations in chemistry and clast components may reflect the relative stratigraphy of the South Massif slope, with material toward the bottom of 73001 originating from lower slopes and material from higher up in the core representing regolith from higher up the South Massif slopes.

58 GEOSCIENCES↗

A New Martian Crater Chronology: Implications for Jezero Crater

Crater chronologies are a fundamental tool to assess the relative and absolute ages of planetary surfaces when direct radiometric dating is not available. Martian crater chronologies are derived from lunar crater spatial densities on terrains with known radiometric ages, and thus they critically depend on the Moon-to-Mars extrapolation. This extrapolation requires knowledge of the time evolution of the impact flux, including contributions from various impactor populations, factors that are not trivially connected to the dynamical evolution of the early Solar System. In this paper, we will present a new Martian crater chronology based on current dynamical models, and consider the main sources of uncertainties (e.g., impactor size–frequency distribution; dynamical models with late and early instabilities, etc.). The resulting “envelope” of Martian crater chronologies significantly differs from previous chronologies. The new Martian crater chronology is discussed using two interesting applications: Jezero crater’s dark terrain (relevant to the NASA Mars 2020 mission) and the southern heavily cratered highlands. Our results indicate that Jezero’s dark terrain may have formed ∼3.1 Ga, i.e., up to 0.5 Gyr older than previously thought. In addition, available crater chronologies (including our own) overestimate the number of craters larger than 150 km on the southern highlands, suggesting either that large craters have been efficiently erased over Martian history or that dynamical models need further refinement. Further, our chronology constrains the age of Isidis basin to be 4.05–4.2 Ga and that of the Borealis basin to be 4.35–4.40 Ga; these are predictions that can be tested with future sample and return missions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗