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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Molecules and chains in a strong magnetic field - Statistical treatment

A Thomas-Fermi-Dirac-Weizsaecker statistical model is developed and employed to investigate diatomic molecules and infinite molecular chains in strong magnetic fields. The standard magnetic Thomas-Fermi-Dirac kinetic, potential, and exchange energy functionals are supplemented by a gradient correction to the kinetic energy. The numerical method used for solving this system in two spatial dimensions is detailed. Numerical solutions for a wide range of magnetic strengths and elements are presented to demonstrate the robustness, as well as the limitations, of the statistical approach. These calculations qualitatively reproduce many of the results of detailed quantum mechanical treatments. For example, the fractional binding energy is greatest for low atomic numbers and for strong magnetic fields.

Abrahams, Andrew M.↗
NASA NTRS1992

Hydrogen molecules and chains in a superstrong magnetic field

The electronic structures of hydrogen polymolecules H(n) (n = 2,3,4,...) is studied in a superstrong magnetic field (B greater than about 10 exp 12 G) typically found on the surface of a neutron star. Simple analytical scaling relations for several limiting cases (e.g., large n, high B field) are derived. The binding energies of H(n) molecules are numerically calculated for various magnetic-field strengths. For a given magnetic-field strength, the binding energy per atom in the H(n) molecules is found to approach a constant value as n increases. For typical field strengths of interest, energy saturation is essentially achieved once n exceeds 3 to 4. Also considered is the structure of negative H ions in a high magnetic field. For B about 10 exp 12 G, the dissociation energy of an atom in a hydrogen chain and the ionization potential of H(-) are smaller than the ionization potential of neutral atomic hydrogen.

Lai, Dong↗
NASA NTRS1990

Linearly polarized radiation from astrophysical masers due to magnetic fields of intermediate strength

Previous solutions for polarization of astrophysical maser radiation due to closed-shell molecules in a magnetic field have potentially serious limitations. These solutions are mostly based on the approximation that the Zeeman frequency g-Omega is much greater than the rate for stimulated emission R and the rate for decay Gamma of the molecular state. Others are asymptotic solutions obtained for an angular momentum J = 1-0 transition. It has been unclear whether the polarizations due to plausible Zeeman splittings are adequately represented by the solutions obtained for g-Omega/Gamma much greater than 1 and g-Omega/R much greater than 1. Actual masing transitions tend to involve molecular states with angular momenta that are higher than J = 1 and 0. Numerical solutions for the linear polarization are presented here which do not have the foregoing restrictions on the g-Omega and which are not limited to a J = 1-0 transition.

Nedoluha, Gerald E.↗
NASA NTRS1982

Compact Ion Source for Mass Spectrometers

Cyclotron-resonance device uses miniature components and permanent magnet for small size, low weight, and low cost. Gas molecules are ionized by electrons from hot filament. Magnetic field, acting with electrostatic drift field, causes ions to move in circles with a superimposed drift perpendicular to both fields, toward the exit. Compact source can be used for studying ion-molecule reactions by ion cyclotron-resonance methods in conventional mass spectrometer with either magnetic sector or quadrupole sector.

Anicich, V. G.↗
NASA NTRS2008

Magnetic Separator Enhances Treatment Possibilities

Since the earliest missions in space, NASA specialists have performed experiments in low gravity. Protein crystal growth, cell and tissue cultures, and separation technologies such as electrophoresis and magnetophoresis have been studied on Apollo 14, Apollo 16, STS-107, and many other missions. Electrophoresis and magnetophoresis, respectively, are processes that separate substances based on the electrical charge and magnetic field of a molecule or particle. Electrophoresis has been studied on over a dozen space shuttle flights, leading to developments in electrokinetics, which analyzes the effects of electric fields on mass transport (atoms, molecules, and particles) in fluids. Further studies in microgravity will continue to improve these techniques, which researchers use to extract cells for various medical treatments and research.

Source record↗
NASA NTRS1973

Computer checking of rotational line intensity factors for diatomic transitions.

Previously published analytical formulae for the rotational line intensity factors of diatomic molecules have been compared with results from a comprehensive computer program, which determines numerical intensity factors for both spin-allowed and spin-forbidden electric and magnetic dipole transitions in diatomic molecules. The comparison uncovered several typographical errors and a few algebraic errors in the published formulae. The changes required in the formulae to give agreement with the results from the computer program are tabulated.

Whiting, E. E.↗
NASA NTRSDate not supplied

Active Solar-Like Stars and the Production of Prebiotically Relevant Molecules in Young Earth Like Exoplanet

The magnetic activity of young G type stars produces elevated ionizing radiation fluxes for its planetary system. X-ray, Extreme UV, flare radiation and the associated precipitating energetic particles accelerated in coronal mass ejection driven shocks can drive complex chemistry in the exoplanetary atmosphere, and ignite the production of complex molecules (Airapetian et al., 2016; Hayworth et al. 2021). To address the efficiency of the production of prebiotic molecules in young Earth-like environments, we developed and coupled a set of atmospheric models that account for the determination of the flux of precipitating particle, its ionization/dissociation effects in the planetary atmosphere, and the subsequent chemistry that leads to the creation of prebiotic molecules and greenhouse gases. We show that the productions rates are high enough to provide critical input for the origin of prebiotic molecules on the early Earth. Overall, the impact of the space weather on the atmospheric photochemistry should not be neglected when assessing the factors of habitability of the environments of young rocky (exo)planets.

Guillaume Gronoff↗
NASA NTRS1977

Stellar rotation and the thermomagnetic torque

It is noted that any reasonable assumption for the rotation rates of the interstellar clouds which must collapse to produce stars will result in stars which rotate much faster than suggested by observations if angular momentum is conserved throughout the collapse. The contribution of thermomagnetic torque, which can exist when a rarefied gas of polyatomic molecules is subjected to a magnetic field and a nonuniform temperature gradient, to the angular momentum of a collapsing protostellar object is examined in order to determine whether the magnitude of this torque is sufficient to slow down contracting protostellar clouds. Calculations are performed for two times during protostellar collapse when conditions may be favorable for thermomagnetic torque to play a role in angular-momentum considerations. The results indicate that this torque is apparently of no importance in determining or modifying stellar rotation during the early stages of stellar evolution.

Spear, G. G.↗
NASA NTRS1981

Broad-band polarization in molecular spectra

The rotational lines of the CN(0,0) red system have been observed to show a strongly asymmetric Zeeman profile. Certain molecules are very susceptible to magnetic perturbation because of the weakness of their spin-rotation coupling; a fairly weak magnetic field can cause a complete Paschen-Back effect. The calculation of transition probabilities incorporating this effect into the Hamiltonian is discussed, and the detailed calculation is then given. The resulting transition probabilities are transformed into synthetic line profiles by using the Unno (1956) model of polarized radiation transfer. The dependence of the net polarized flux on magnetic field and equivalent width is investigated. It is shown that entire band systems may be significantly polarized. Broad-band circular polarization of sunspots may be due, in part, to molecular bands. Analysis of the CH G band indicates a magnetic field of 0.25-0.50 x 10 to the 6th gauss in the white dwarf G99-37, an order of magnitude lower than previous estimates.

Illing, R. M. E.↗
NASA NTRS1986

The role of spinning electrons in paramagnetic phenomena

An attempt is made to explain paramagnetic phenomena without assuming the orientation of a molecule or ion in a magnetic field. Only the spin angular momentum is assumed to be responsible. A derivative of the Gurie-Langevin law and the magnetic moments of ions are given as a function of the number of electrons in an inner, incomplete shell. An explanation of Gerlach's experiments with iron and nickel vapors is attempted. An explanation of magnetomechanical experiments with ferromagne elements is given.

Bose, D. M.↗
NASA NTRSDate not supplied

Bessel Tube to Capture Lunar Volatiles

Current arts to create linear motion or acceleration of fine particles and molecules into devices such as mass spectrometers and vacuum pumps rely on the pressure difference created by a pinhole or mechanical processes. However, in an environment of vacuum, these approaches do not create such a pressure differential to drive and move fine particles and molecules. In some cases, electrostatic or magnetic processes may work to create the desired motion. A cylindrical harmonic of electric field, which is widely used in electron accelerators, offers a unique capability to capture and induce a linear motion of molecules and particles when electrically charged. Generally, lunar volatiles are electrostatically charged. The idea to capture and collect the lunar volatiles by creating a drift axis of motion using a cylindrical harmonic field has led to the development of a device concept, called a Bessel Tube. The Bessel Tube concept ingests fine particles, gaseous atoms, and gaseous molecules and guides them along an extraction tube for collection, separation, and analysis. The Bessel Tube concept for lunar volatile collection is discussed.

Bessel Tube↗
NASA NTRS1996

Method and system for measurement of mechanical properties of molecules and cells

Mechanical stresses and deformations are applied directly to cell surface receptors or molecules and measured using a system including a magnetic twisting device in combination with ferromagnetic microbeads coated with ligands for integrins or any other surface receptors. The system can be used diagnostically to characterize cells and molecules and to determine the effect of transformation and compounds, including drugs, on the cells and molecules. The system can also be used to induce cells to grow or alter production of molecules by the cells.

Butler, James P.↗
NASA NTRS2010

Maglev Facility for Simulating Variable Gravity

An improved magnetic levitation apparatus ("Maglev Facility") has been built for use in experiments in which there are requirements to impose variable gravity (including zero gravity) in order to assess the effects of gravity or the absence thereof on physical and physiological processes. The apparatus is expected to be especially useful for experiments on the effects of gravity on convection, boiling, and heat transfer in fluids and for experiments on mice to gain understanding of bone loss induced in human astronauts by prolonged exposure to reduced gravity in space flight. The maglev principle employed by the apparatus is well established. Diamagnetic cryogenic fluids such as liquid helium have been magnetically levitated for studying their phase transitions and critical behaviors. Biological entities consist mostly of diamagnetic molecules (e.g., water molecules) and thus can be levitated by use of sufficiently strong magnetic fields having sufficiently strong vertical gradients. The heart of the present maglev apparatus is a vertically oriented superconducting solenoid electromagnet (see figure) that generates a static magnetic field of about 16 T with a vertical gradient sufficient for levitation of water in normal Earth gravity. The electromagnet is enclosed in a Dewar flask having a volume of 100 L that contains liquid helium to maintain superconductivity. The Dewar flask features a 66-mm-diameter warm bore, lying within the bore of the magnet, wherein experiments can be performed at room temperature. The warm bore is accessible from its top and bottom ends. The superconducting electromagnet is run in the persistent mode, in which the supercurrent and the magnetic field can be maintained for weeks with little decay, making this apparatus extremely cost and energy efficient to operate. In addition to water, this apparatus can levitate several common fluids: liquid hydrogen, liquid oxygen, methane, ammonia, sodium, and lithium, all of which are useful, variously, as rocket fuels or as working fluids for heat transfer devices. A drop of water 45 mm in diameter and a small laboratory mouse have been levitated in this apparatus.

Liu, Yuanming↗