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Results for “mesoscale temperature structure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Improved VAS regression soundings of mesoscale temperature structure observed during the 1982 atmospheric variability experiment

An Atmospheric Variability Experiment (AVE) was conducted over the central U.S. in the spring of 1982, collecting radiosonde date to verify mesoscale soundings from the VISSR Atmospheric Sounder (VAS) on the GOES satellite. Previously published VAS/AVE comparisons for the 6 March 1982 case found that the satellite retrievals scarcely detected a low level temperature inversion or a mid-tropospheric cold pool over a special mesoscale radiosonde verification network in north central Texas. The previously published regression and physical retrieval algorithms did not fully utilize VAS' sensitivity to important subsynoptic thermal features. Therefore, the 6 March 1982 case was reprocessed adding two enhancements to the VAS regression retrieval algorithm: (1) the regression matrix was determined using AVE profile data obtained in the region at asynoptic times, and (2) more optimistic signal-to-noise statistical conditioning factors were applied to the VAS temperature sounding channels. The new VAS soundings resolve more of the low level temperature inversion and mid-level cold pool. Most of the improvements stems from the utilization of asynoptic radiosonde observations at NWS sites. This case suggests that VAS regression soundings may require a ground-based asynoptic profiler network to bridge the gap between the synoptic radiosonde network and the high resolution geosynchronous satellite observations during the day.

Chesters, Dennis↗
NASA NTRS2001

Covariation of Mesoscale Ocean Color and Sea-Surface Temperature Patterns in the Sargasso Sea

During the lifetime of the Coastal Zone Color Scanner, there were 21 instances in which both satellite-derived ocean color and sea-surface temperature are simultaneously available over large areas of the Sargasso Sea. These images reveal close correspondence between mesoscale structures observed in temperature and pigment fields. In general, higher (lower) pigment biomass occurs in mesoscale features consisting of cold (warm) temperature anomalies. This relationship is consistent with the idea that upward displacement of isopycnals at the base of the euphotic zone by mesoscale eddies is an important mechanism of nutrient supply in the region.

McGillicuddy, Dennis J., Jr.↗
NASA NTRS2001

Covariation of Mesoscale Ocean Color and Sea-Surface Temperature Patterns in the Sargasso Sea

During the lifetime of the Coastal Zone Color Scanner, there were 21 instances in which both satellite-derived ocean color and sea-surface temperature are simultaneously available over large areas of the Sargasso Sea. These images reveal close correspondence between mesoscale structures observed in temperature and pigment fields. In general, higher (lower) pigment biomass occurs in mesoscale features consisting of cold (warm) temperature anomalies. This relationship is consistent with the idea that upward displacement of isopycnals at the base of the euphotic zone by mesoscale eddies is an important mechanism of nutrient supply in the region.

McGillicuddy, D. J.↗
NASA NTRS1984

Variational assimilation of VAS data into the mass model

Experiments are reported in which VAS data at 1200, 1500, and 1800 GMT 20 July 1981 were assimilated using both the adiabatic and full physics version of the Mesoscale Atmospheric Simulation System (MASS). A nonassimilation forecast is compared with forecasts assimilating temperature gradients only and forecasts assimilating both temperature and humidity gradients. The effects of successive vs single assimilations are also examined. It is noted that the greatest improvements to the forecast resulted when the VAS data resolved the mesoscale structure of the temperature and relative humidity fields. When this structure was assimilated into MASS, the ensuing simulations more clearly defined a mesoscale structure in the developing instabilities.

Cram, J. M.↗
NASA NTRS1983

Use of the VAS for analysis of a prethunderstorm environment

The information content of the VAS radiances can be converted to meteorological parameters useful for analyzing a severe weather environment. The method by which the VAS variances are converted to vertical profiles of temperature, dewpoints, and equivalent potential temperature involves a basic regression technique using the most local radiosonde data available for establishing a correlation matrix. The results indicate that mesoscale features apparent within images of the radiances can be converted to usable temperature and moisture fields using regression when surface temperature and dewpoint observations are included within the total data base. In addition, results indicate that surface data are very important for better defining lower tropospheric structure that the VAS radiances alone cannot properly resolve. Analyses of these retrievals distinctly show mesoscale structure in the temperature and moisture fields derived with VAS radiances collected every 3 hours, and 0000 GMT. The retrievals capture the moisture structure. More important, convective instability is clearly detected immediately before the onset of convection. The results indicate that the VAS is capable of providing valuable mesoscale information suitable for analyzing a preconvective environment that is generally clear.

Uccellini, L. W.↗
NASA NTRS1984

VAS data assimilation into a mesoscale model

In numerical weather prediction, one of the arising problems has always been related to insufficient data, especially in cases involving scales smaller than the synoptic rawinsonde network. The Visible Infrared Spin-Scan Radiometer (VISSR) Atmospheric Sounder (VAS) instrument on the Geostationary Operational Environmental Satellite (GOES) can provide mesoscale vertical profiles of temperature and moisture several times over a twelve hour period. However, as this data is only available over a relatively small area at any one time, the VAS data is more suited to data assimilation. A variational method has been developed to assimilate VAS data into a mesoscale model. In the present paper, the assimilation method and VAS data from one case are discussed. It is found that the greatest improvements to the forecast resulted when the VAS data resolved the mesoscale structure of the temperature and relative humidity fields.

Cram, J. M.↗
DOE OSTI2019

Lattice disorder effect on magnetic ordering of iron arsenides

This study investigates magnetic ordering temperature in nano- and mesoscale structural features in an iron arsenide. Although magnetic ground states in quantum materials can be theoretically predicted from known crystal structures and chemical compositions, the ordering temperature is harder to pinpoint due to potential local lattice variations that calculations may not account for. In this work we find surprisingly that a locally disordered material can exhibit a significantly larger Néel temperature (T N ) than an ordered material of precisely the same chemical stoichiometry. Here, a EuFe 2 As 2 crystal, which is a ‘122’ parent of iron arsenide superconductors, is found through synthesis to have ordering below T N = 195 K (for the locally disordered crystal) or T N = 175 K (for the ordered crystal). In the higher T N crystals, there are shorter planar Fe-Fe bonds [2.7692(2) Å vs. 2.7745(3) Å], a randomized in-plane defect structure, and diffuse scattering along the [00 L] crystallographic direction that manifests as a rather broad specific heat peak. For the lower T N crystals, the a-lattice parameter is larger and the in-plane microscopic structure shows defect ordering along the antiphase boundaries, giving a larger T N and a higher superconducting temperature (T c ) upon the application of pressure. First-principles calculations find a strong interaction between c-axis strain and interlayer magnetic coupling, but little impact of planar strain on the magnetic order. Neutron single-crystal diffraction shows that the low-temperature magnetic phase transition due to localized Eu moments is not lattice or disorder sensitive, unlike the higher-temperature Fe sublattice ordering. This study demonstrates a higher magnetic ordering point arising from local disorder in 122.

36 MATERIALS SCIENCE↗
NASA NTRS1986

Temperature-plant pigment-optical relations in a recurrent offshore mesoscale eddy near Point Conception, California

The temperature-plant pigment-optical structure of a mesoscale anticyclonic eddy consistently found in shipboard surveys and satellite-sensed data several hundred kilometers southwest of Point Conception, CA, is described on three different time scales (100-day mesoscale, annual, and several-year). The satellite coastal zone color scanner (CZCS) ocean color imagery detected the near-surface chlorophyll structure of the eddy, but in situ optical and plant pigment data suggest that such imagery does not provide a good estimate of the integrated chlorophyll field of the eddy. The temperature and plant pigment boundaries of the eddy, as determined from two-dimensional gradients of advanced very high resolution radiometer (AVHRR) and CZCS imagery, do not coincide spatially. This and in situ temperature, plant pigment, and optical structure provide additional evidence that some eddy systems in the California Current are not isolated vortex systems but rather continuously entrain waters of nonlocal origin laterally into their upper layers. Within the California Current a ratio of AVHRR/CZCS data is useful for separating inshore from oceanic water masses and following their surface entrainment by offshore vortices. The historical 28-year California Cooperative Oceanic Fisheries Investigations data for the Point Conception region of the California Current and remotely sensed data over this region show that the Point Conception eddy is a recurrent feature in the offshore California Current. Moreover, the available data provide evidence that a large number of warm-core mesoscale eddies occur simultaneously in a transition zone between coastal and oceanic regimes, that these features recur at preferred locations within the transition zone, and that this family of eddies should impose a significant offshore boundary condition on the flow of the California Current.

Simpson, James J.↗
NASA NTRS1985

A cool anomaly off northern California - An investigation using IR imagery and in situ data

The OPTOMA (Ocean Prediction Through Observation, Modeling and Analysis) program is developing an ocean descriptive-predictive system for four-dimensional data assimilation. It is presently concerned with the mesoscale variability in the California Current System (CCS). The present paper has the objective to assess the relationship of surface temperature structure to subsurface temperature structure and flow fields. Surface temperature anomalies are related to the mesoscale horizontal advective and subsurface mass fields. The cool anomaly off northern California in summer 1982 is discussed, taking into account the temperature structure along transects, T-S variations and inferred water masses, variation of horizontal temperature patterns with depth, and synoptic information from IR data.

Rienecker, M. M.↗
DOE OSTI2023

Thermodynamic and electron transport properties of Ca 3 Ru 2 O 7 from first-principles phonon calculations and Boltzmann transport theory

Here, this work demonstrates a first-principles-based approach to obtaining finite temperature thermal and electronic transport properties which can be employed to model and understand mesoscale structural evolution during electronic, magnetic, and structural phase transitions. A computationally tractable model was introduced to estimate electron relaxation time and its temperature dependence. The model is applied to Ca 3 Ru 2 O 7 with a focus on understanding its electrical resistivity across the electronic phase transition at 48 K. A quasiharmonic phonon approach to the lattice vibrations was employed to account for thermal expansion while the Boltzmann transport theory including spin-orbit coupling was used to calculate the electron-transport properties, including the temperature dependence of electrical conductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Mechanical Behavior of Additively Manufactured Molybdenum and Fabrication of Microtextured Composites

Refractory metals are a class of high-melting-temperature materials suitable for use in extreme environment applications. Interestingly, during additive manufacturing many pure refractory metals exhibit a switch from (001) to (111) build direction fiber preference with increasing surface energy density. Here we exploit this solidification physics to fabricate material with “mesoscale composite” engineered structures consisting of features with contrasting (001) and (111) build direction microtextures. Separately, elevated temperature tensile testing of EBM fabricated material with a randomized distribution of mixed (001)/(111)-fiber grains is shown to exhibit excellent properties. These results are utilized to build a crystal plasticity model for evaluating the local inelastic response of the composite mesoscale structures. Analysis of printed microstructures and microstructure-scale simulations indicate that both macro-scale and localized material behavior may be tailored. This strategy can be potentially used to synthesize materials with optimized performance for high-temperature applications.

36 MATERIALS SCIENCE↗
NASA NTRS1993

An evaluation of satellite-derived humidity and its relationship to convective development

An aircraft prototype of the High-Resolution Interferometer Sounder (HIS) was flown over Tennessee and northern Alabama during summer 1986. The HIS temperature and dewpoint soundings were examined on two flight days to determine their error characteristics and utility in mesoscale analyses. Random errors were calculated from structure functions while total errors were obtained by pairing the HIS soundings with radiosonde-derived profiles. Random temperature errors were found to be less than 1 C at most levels, but random dewpoint errors ranged from 1 to 5 C. Total errors of both parameters were considerably greater, with dewpoint errors especially large on the day having a pronounced subsidence inversion. Cumulus cloud cover on 15 June limited HIS mesoscale analyses on that day. Previously undetected clouds were found in many HIS fields of view, and these probably produced the low-level horizontal temperature and dewpoint variations observed in the retrievals. HIS dewpoints at 300 mb indicated a strong moisture gradient that was confirmed by GOES 6.7-micron imagery. HIS mesoscale analyses on 19 June revealed a tongue of humid air stretching across the study area. The moist region was confirmed by radiosonde data and imagery from the Multispectral Atmospheric Mapping Sensor (MAMS). Convective temperatures derived from HIS retrievals helped explain the cloud formation that occurred after the HIS overflights. Crude estimates of Bowen ratio were obtained from HIS data using a mixing-line approach. Values indicated that areas of large sensible heat flux were the areas of first cloud development. These locations were also suggested by GOES visible and infrared imagery. The HIS retrievals indicated that areas of thunderstorm formation were regions of greatest instability. Local landscape variability and atmospheric temperature and humidity fluctuations were found to be important factors in producing the cumulus clouds on 19 June. HIS soundings were capable of detecting some of this variability. The authors were impressed by HIS's performance on the two study days.

Fuelberg, Henry E.↗
DOE OSTI2021

A predictive modeling tool for damage analysis and design of hydrogen storage composite pressure vessels

In this study, a predictive modeling tool is developed for damage analysis and design of hydrogen (H 2 ) storage composite pressure vessels. It integrates micromechanics of matrix cracking into a continuum damage mechanics (CDM) description for damage evolution, and three-dimensional (3D) finite element (FE) modeling of the vessel structural response. At the scale of the composite layer (mesoscale), the temperature-dependent stiffness reduction law in terms of the damage variable for transverse matrix cracking is computed using an Eshelby-Mori-Tanaka approach for the initial composite thermoelastic properties and a self-consistent model for the stiffness reduction as a function of the damage variable. While transverse matrix cracking obeying a damage evolution relation can progressively evolve from an initiation to a saturation state, fiber failure is predicted by a micromechanical fiber rupture criterion that accounts for the fiber strength and matrix stress. The implementation of this integrated multiscale modeling model into a 3D FE formulation enables damage analysis and design of H 2 storage composite pressure vessels. The developed tool is illustrated through 3D damage analyses of a cryogenically compressed H 2 storage vessel model subjected to thermomechanical loadings to investigate effects of the helical layer fiber orientation and loading scenario on damage development, vessel integrity and burst pressure.

08 HYDROGEN↗
DOE OSTI2020

Adaptive Machine Learning for Bragg Coherent Diffraction Imaging (BCDI) of 3D Electron Density Maps with Application to La 2-x Ba x CuO 4 (LBCO) High Temperature Superconductor Studies [PowerPoint]

Understanding mesoscale heterogeneity is important for evaluating fatigue and failure of structural materials and for manufacturing processes. Data-driven tools can facilitate in guiding effort investment (measurements and computations) at various stages of the materials development. Our 3D reconstruction approach is to find a set of coefficients which define a bounding surface of the electron density. Data for training the 3D CNN was generated by sampling coefficients from uniform distributions. Test vs. prediction values are shown for the 28 even-valued coefficients for 1000 test structures, with the best and worst performers highlighted. The adaptive part of this work utilized a model independent extremum seeking (ES). The predictions of the CNN were used as the starting point for the ES algorithm. The convergence of the ES algorithm for 3 different structures is illustrated, and the robustness of the adaptive ML approach was demonstrated on experimentally measured 3D crystal from high energy diffraction microscopy. Reconstruction of a non-uniform density volume with different levels of Poisson noise is also shown. Preliminary attempts at reconstructing measured La 2-x Ba x CuO 4 diffraction patterns have so far failed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1990

HIS analyses of mesoscale phenomena

Results are presented from two sets of measurements made by the High-resolution Interferometer Sounder (HIS) during two aircraft flights over the Cooperative-Huntsville-Meteorological-Experiment region on June 15 and 19, 1986. It is shown that the temperature and the dew-point field retrieved from HIS spectra contain distinct mesoscale structures. The features in the HIS dew-point fields agreed well with the cloud and moisture structures observed in visible and 6.7 micron GOES imagery.

Bradshaw, John T.↗
NASA NTRS1984

Initialization of a mesoscale model for April 10, 1979, using alternative data sources

A 35 km grid limited area mesoscale model was initialized with high density SESAME radiosonde data and high density TIROS-N satellite temperature profiles for April 10, 1979. These data sources were used individually and with low level wind fields constructed from surface wind observations. The primary objective was to examine the use of satellite temperature data for initializing a mesoscale model by comparing the forecast results with similar experiments employing radiosonde data. The impact of observed low level winds on the model forecasts was also investigated with experiments varying the method of insertion. All forecasts were compared with each other and with mesoscale observations for precipitation, mass and wind structure. Several forecasts produced convective precipitation systems with characteristics satisfying criteria for a mesoscale convective complex. High density satellite temperature data and balanced winds can be used in a mesoscale model to produce forecasts which verify favorably with observations.

Kalb, M. W.↗
DOE OSTI2024

In Situ Insights into Cathode Calcination for Predictive Synthesis: Kinetic Crystallization of LiNiO 2 from Hydroxides

Abstract Calcination is a solid‐state synthesis process widely deployed in battery cathode manufacturing. However, its inherent complexity associated with elusive intermediates hinders the predictive synthesis of high‐performance cathode materials. Here, correlative in situ X‐ray absorption/scattering spectroscopy is used to investigate the calcination of nickel‐based cathodes, focusing specifically on the archetypal LiNiO 2 from Ni(OH) 2 . Combining in situ observation with data‐driven analysis reveals concurrent lithiation and dehydration of Ni(OH) 2 and consequently, the low‐temperature crystallization of layered LiNiO 2 alongside lithiated rocksalts. Following early nucleation, LiNiO 2 undergoes sluggish crystallization and structural ordering while depleting rocksalts; ultimately, it turns into a structurally‐ordered layered phase upon full lithiation but remains small in size. Subsequent high‐temperature sintering induces rapid crystal growth, accompanied by undesired delithiation and structural degradation. These observations are further corroborated by mesoscale modeling, emphasizing that, even though calcination is thermally driven and favors transformation towards thermodynamically equilibrium phases, the actual phase propagation and crystallization can be kinetically tuned via lithiation, providing freedom for structural and morphological control during cathode calcination.

36 MATERIALS SCIENCE↗