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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Absolute absorption of ozone in the midinfrared

The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1 percent using a Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared.

Pickett, H. M.↗
NASA NTRS1991

Derivation of Midinfrared (5-25 micrometers) Optical Constants of Some Silicates and Palagonite

The midinfrared 2000-400/ cm (5-25 microns) optical constants (real (n) and imaginary (k) indices of refraction) are presented for: (1) pyrophyllite; (2) kaolinite; (3) serpentine; (4) montmorillonite; (5) saponite; (6) palagonite; and (7) orthopyroxene. Comparison of the values derived here with those previously presented for serpentine, montmorillonite, and palagonite is generally quite good and discrepancies between values are probably due to either chemical differences between the actual samples or different techniques used to derive the values. For montmorillonite, saponite, and palagonite we were able to derive optical constants in the region of the H2O-bending fundamental near 6 microns. We find that if a pellet of pure material can be produced with a mirror-like surface then the optical constants of clays and other noncohesive materials can be readily derived.

Roush, T.↗
NASA NTRS1999

Spectral Behavior of Hematite at Visible/Near Infrared and Midinfrared Wavelengths

The oxide mineral hematite alpha-Fe2O3) is present on Mars as evidenced by spectroscopy using visible/near infrared (VNIR) and midinfrared (MIR) wavelengths. The physical nature of this surficial hematite varies from fine-grained, crystalline red hematite (red-Hm) in certain martian bright regions, to coarser-grained, crystalline gray hematite (gray-Hm) in the Sinus Meridiani equatorial site discovered in the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) data. The VNIR spectra require that the red hematite is present in amounts subordinate to a second ferric pigment, which accounts for the general shape and position of the martian ferric absorption edge. By analogy with palagonitic tephra and synthetic samples, the pigment is a nanophase ferric oxide, possibly nanophase hematite (np-Hm). The purpose of this abstract is to document the physicospectral properties of hematite in the VNIR (0.35 to 2.2 microns) and MIR (5 to 25 microns) with respect to the terms "nanophase" and "crystalline", "red" and "gray", and "fine-grained" and "coarse-grained". We will show that different "types" of hematite (no-, red-, and gray-Hm) have different spectral responses in the VNIR and MIR regions and that these differences are important for inferring the types of hematite and their relative proportions from remotely sensed spectra of Mars. Because hematite is an alteration product that forms through many different geologic processes, determination of the type of hematite provides important clues about the style and diversity of martian weathering processes.

Lane, Melissa D.↗
NASA NTRS1999

Spectral Behavior of Hematite at Visible/Near Infrared and Midinfrared Wavelengths

The oxide mineral hematite alpha-Fe2O3) is present on Mars as evidenced by spectroscopy using visible/near infrared (VNIR) and midinfrared (MIR) wavelengths. The physical nature of this surficial hematite varies from fine-grained, crystalline red hematite (red-Hm) in certain martian bright regions, to coarser-grained, crystalline gray hematite (gray-Hm) in the Sinus Meridiani equatorial site discovered in the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) data. The VNIR spectra require that the red hematite is present in amounts subordinate to a second ferric pigment, which accounts for the general shape and position of the martian ferric absorption edge. By analogy with palagonitic tephra and synthetic samples, the pigment is a nanophase ferric oxide, possibly nanophase hematite (np-Hm). The purpose of this abstract is to document the physicospectral properties of hematite in the VNIR (0.35 to 2.2 mm) and MIR (5 to 25 mm) with respect to the terms "nanophase" and "crystalline", "red" and "gray", and "fine-grained" and "coarse-grained". We will show that different "types" of hematite (np-, red-, and gray-Hm) have different spectral responses in the VNIR and MIR regions and that these differences are important for inferring the types of hematite and their relative proportions from remotely sensed spectra of Mars. Because hematite is an alteration product that forms through many different geologic processes, determination of the type of hematite provides important clues about the style and diversity of martian weathering processes. Additional information is contained in the original extended abstract.

Lane, M. D.↗
NASA NTRS2003

Midinfrared Temperature Measurement Technique Developed

Infrared thermography is the measuring of the temperature of an object by examining the spectral quantities of light emission. The microgravity combustion experiment Solid Inflammability Boundary at Low-Speeds (SIBAL) calls for full-field temperature measurements of a thin sheet of cellulosic fuel as a flame front moves across the fuel, and infrared thermography is the only technique that can accomplish this task. The thermography is accomplished by imaging the fuel with a midinfrared camera that is sensitive in the 3.0- to 5.0-microns wavelength region in conjunction with a 3.7 - to 4.1-microns bandpass filter to eliminate unwanted infrared radiation from components other than the fuel.

Santosuosso, George R.↗
NASA NTRS1991

Midinfrared (2.5-13.5 microns) reflectance spectra of powdered stony meteorites

Asteroid spectral measurements are presently approached via comparisons with reflectance spectra from 60 powdered meteorite samples representing 50 different meteorites. While the powdered meteorites have undergone alteration by exposure to water vapor and by hydrocarbon contamination characterized by absorption bands near 3.45 microns, they retain various other spectral features which render them useful for identification. While these features can be used independently to ascertain mineralogy and meteorite type, the use of the entire spectrum in a digital search library is preferred for successful identification.

Salisbury, John W.↗
NASA NTRS1991

Midinfrared spectral investigations of carbonates: Analysis of remotely sensed data

Recent airborne thermal infrared observations of Mars from the Kuiper Airborne Observatory (KAO) have provided evidence for the presence of carbonates, sulfates, and hydrates. Using the optical properties of calcite and anhydrite, it was estimated that CO3's and SO4's constituted about 1 to 3 and 10 to 15 wt. percent, repectively of the materials composing the atmospheric dust. Using the derived value as an estimate of total CO3 abundance, and making an assumption that the CO3's were uniformly distributed within the Martian regolith, it was estimated that such a CO3 reservoir could contain roughly 2 to 5 bars of CO2. While the results indicate that several volatile-bearing materials are present on Mars, the observations from the KAO are inherently limited in their ability to determine the spatial distributions of these materials. However, previous spacecraft observations of Mars provide both the spectral coverage necessary to identify these materials, as well as the potential for investigating their spatial variability. This has prompted us to pursue a reinvestigation of the Mariner 6 and 7 infrared spectrometer and Mariner 9 infrared interferometer spectrometer observations. The former data have been recently made available in digital format and calibration of wavelengths and intensities are almost complete. Additionally, we are pursuing the derivation of optical constants of more appropriate carbonates and sulfates.

Roush, T.↗
NASA NTRS1991

Derivation of midinfrared (5-25 microns) optical constants of some silicates and palagonite

The 5-25 micron real and imaginary refraction indices are presented for palagonite and the silicates pyrophyllite, kaolinite, serpentine, montmorillonite, saponite, and orthopyroxene. Optical constants in the region of the H2O-bending fundamental near 6 microns are obtained for saponite, montmorillonite, and palagonite. It is established that, if a pellet of pure material can be polished to a mirror finish, the optical constants of such noncohesive materials as clays are easily derivable.

Roush, T.↗
NASA NTRS1993

Derivation of the midinfrared (5.0-25.0 micron) optical constants of hydrous carbonate and sulfate

There is ample theoretical and observational evidence suggesting liquid water was once stable at the surface of Mars. Because water is essential to the evolution of life, it is important to understand the types of environments in which the liquid water was present. For example, if water were present early in Mars' history, then this raises the possibility that biological activity may have evolved only to eventually become extinct as liquid water became scarce. Alternatively, if liquid water were stable only later in Mars' history, then it becomes problematic to envision mechanisms by which biological activity evolved and remained viable without water until more favorable conditions existed. Even without biological activity, atmospheric carbon dioxide dissolved in water can assist the chemical weathering of primary igneous minerals producing common secondary phases such as hydartes, carbonates, and sulfates. While the identification of hydrates, carbonates, and sulfates on Mars cannot provide direct evidence of biological activity, it can provide significant information regarding the presence and duration of an environment that would support the presence of liquid water at the surface. The specific mineralogy of these secondary phases can provide insight into the environments of their formation. For example, the slow precipitation that occurs in large standing bodies of water, e.g. oceans or lakes, commonly results in the formation of calcite, magnesite, dolomite, siderite, and rhodochrosite. Rapid precipitation that occurs in ephemeral bodies of water, e.g. hypersaline lakes or playas, can result in the formation of all of the above phases as well as aragonite, vaterite, hydrated carbonates, alkali carbonates, bicarbonates, and other poorly ordered phases. Absorption features identified in recent near-infrared spectra of Mars have been interpreted as being due to bicarbonate and bisulfate located in the mineral scaplite. Spectral data returned by the Mariner 6 and 7 spacecraft have been inerpreted as remaining consistent with the presence of hydrated carbonates. Additional, airborne thermal infrared spectra of Mars have been interpreted as implying the presence of carbonates, sulfates, and hydrates. Modeling of the thermal infrared data relied upon the optical constants of calcite anhydrite and a mixture of water in basalt because of their availability. The derived abundances of carbonate and sulfate were 1-3 percent and 10-15 percent by volume. However, the observed complexity and positions of the bands suggested other carbonate-, and sulfate-bearing species. We have already derived optical constants for hydrous and anhydrous silicates, and we are now applying these techniques to the derivation of the optical constants of hydrous carbonate and sulfate.

Roush, Ted L.↗
NASA NTRS1994

Powerful model for the point source sky: Far-ultraviolet and enhanced midinfrared performance

I report further developments of the Wainscoat et al. (1992) model originally created for the point source infrared sky. The already detailed and realistic representation of the Galaxy (disk, spiral arms and local spur, molecular ring, bulge, spheroid) has been improved, guided by CO surveys of local molecular clouds, and by the inclusion of a component to represent Gould's Belt. The newest version of the model is very well validated by Infrared Astronomy Satellite (IRAS) source counts. A major new aspect is the extension of the same model down to the far ultraviolet. I compare predicted and observed far-utraviolet source counts from the Apollo 16 'S201' experiment (1400 A) and the TD1 satellite (for the 1565 A band).

Cohen, Martin↗
NASA NTRS2000

Evidence for a Hematite Ore Body on Mars

The Mars Global Surveyor (MGS) spacecraft was launched from Cape Kennedy in November 1996. MGS was put into orbit around Mars in September of 1997 and has since been sending back data from a suite of instruments, including the Thermal Emission Spectrometer (TES). The TES instrument is an interferometric spectrometer designed to map the surface mineralogy of Mars by measuring the midinfrared emitted radiation over the spectral region of about 1600 to 200 cm(exp -1) (about 6 to 50 microns). This mineralogically sensitive technique utilizes the characteristic intra- and inter-molecular vibrations of minerals that are manifested in the midinfrared spectra. These spectral "fingerprints" are unique because they are dependent upon chemical composition, crystal structure, crystal orientation, and other factors. Midinfrared spectral data received from the MGS-TES instrument have indicated the presence of a large deposit of hematite (alpha-Fe2O3) in Sinus Meridiani, Mars. This hematite ore body, that is accompanied by basalt, is really extensive, encompassing an area about 350 by 500 km. To better understand the geologic context of this large deposit, a detailed laboratory spectroscopic investigation was conducted using more than 20 hematite samples so that their spectra could be compared to the martian spectra. The samples included red and gray polycrystaline hand samples, gray single-crystal hand samples, and red and gray fine- and coarse-grained particulates. The laboratory analyses provided thermal emissivity spectra that, when compared to the hematite emissivity spectra from Mars, suggest the Sinus Meridiani hematite is possibly an exposure of oriented hematite grains. These grains are likely coarser that 10 microns (and may be much larger) and gray in color. The characteristic of oriented grains is suggested by the apparent crystal axis-dependence of the energy emitted from the surface of Mars. The strong degree of crystal alignment exhibited in the emissivity spectra of Mars suggests that these oriented hematite crystals most likely occur as bedrock of aligned specular hematite grains (possibly schistose in texture) or as a secondary coating on bedrock, rather than as discrete particles. We are investigating the nature of this vast hematite deposit in order to understand better the geologic setting and infer past conditions and geological evolution on Mars.

Morris, Richard V.↗
NASA NTRS2000

Evidence for a Hematite Ore Body on Mars

The Mars Global Surveyor (MGS) spacecraft was launched from Cape Kennedy in November 1996. MGS was put into orbit around Mars in September of 1997 and has since been sending back data from a suite of instruments, including the Thermal Emission Spectrometer (TES). The TES instrument is an interferometric spectrometer designed to map the surface mineralogy of Mars by measuring the midinfrared emitted radiation over the spectral region of approximately 1600 to 200 per centimeter (appjroximately 6 to 50 microns). This mineralogically sensitive technique utilizes the characteristic intra- and inter-molecular vibrations of minerals that are manifested in the midinfrared spectra. These spectral "fingerprints" are unique because they are dependent upon chemical composition, crystal structure, crystal orientation, and other factors. Midinfrared spectral data received from the MGS-TES instrument have indicated the presence of a large deposit of hematite (alpha-Fe2O3) in Sinus Meridiani, Mars. This hematite ore body, that is accompanied by basalt, is areally extensive, encompassing and area approximately 350 by 500 km. To better understand the geologic context of this large deposit, a detailed laboratory spectroscopic investigation was conducted using more than 20 hematite samples so that their spectra could be compared to the martian spectra. The samples included red and gray polycrystaline hand samples, gray single-crystal hand samples, and red and gray fine- and coarse-grained particulates. The laboratory analyses provided thermal emissivity spectra that, when compared to the hematite emissivity spectra from Mars, suggest the Sinus Meridiani hematite is possibly an exposure of oriented hematite grains. These grains are likely coarser that 10 microns (and may be much larger) and gray in color The characteristic of oriented grains is suggested by the apparent crystal axis-dependence of the energy emitted from the surface of Mars. The strong degree of crystal alignment exhibited in the emissivity spectra of Mars suggests that these oriented hematite crystals most likely occur as bedrock of aligned specular hematite grains (possibly schistose in texture) or as a secondary coating on bedrock, rather than as discrete particles. We are investigating the nature of this vast hematite deposit in order to understand better the geologic setting and infer past conditions and geological evolution on Mars.

Lane, M. D.↗
NASA NTRS2001

Real-time measurements of endogenous CO production from vascular cells using an ultrasensitive laser sensor

Carbon monoxide (CO) has been implicated as a biological messenger molecule analogous to nitric oxide. A compact gas sensor based on a midinfrared laser absorption spectroscopy was developed for direct and real-time measurement of trace levels (in approximate pmol) of CO release by vascular cells. The midinfrared light is generated by difference frequency mixing of two nearinfrared lasers in a nonlinear optical crystal. A strong infrared absorption line of CO (4.61 microm) is chosen for convenient CO detection without interference from other gas species. The generation of CO from cultured vascular smooth muscle cells was detected every 20 s without any chemical modification to the CO. The sensitivity of the sensor reached 6.9 pmol CO. CO synthesis was measured from untreated control cells (0.25 nmol per 10(7) cells/h), sodium nitroprusside-treated cells (0.29 nmol per 10(7) cells/h), and hemin-treated cells (0.49 nmol per 10(7) cells/h). The sensor also detected decreases in CO production after the addition of the heme oxygenase (HO) inhibitor tin protoporphyrin-IX (from 0.49 to 0.02 nmol per 10(7) cells/h) and increases after the administration of the HO substrate hemin (from 0.27 to 0.64 nmol per 10(7) cells/h). These results demonstrate that midinfrared laser absorption spectroscopy is a useful technique for the noninvasive and real-time detection of trace levels of CO from biological tissues.

Non-NASA Center↗
NASA NTRS1991

Diffraction limited infrared images of the binary star T Tauri

High-resolution images of T Tau and its infrared companion have been reconstructed from near- and midinfrared data collected at the Hale 5-m telescope. The near-infrared (1-5 microns) results were obtained by 2D speckle imaging and the midinfrared (10-20 microns) results were derived from shift-and-add procedures applied to slit scans. The spectral energy distributions of the separated components were constructed from 1- to 20-micron data collected in less than half a year (September 1990 to January 1991). The spectral energy distribution of the optical component (T Tau N) is interpreted as containing two distinct constituents, a photosphere and a surrounding disk of circumstellar material. Measurements at a number of infrared wavelengths over the period December 1985 to January 1991 show a 2-mag color-independent change in the brightness of the infrared component (T Tau S). It is proposed that this may have been caused by an increase in accretion onto T Tau S and model the spectral energy distribution of T Tau S as being dominated by an accretion disk.

Ghez, A. M.↗
NASA NTRS1992

Mid-infrared imaging of Orion BN/KL - Astrometry of IRc2 and the SiO maser

Array images of Orion BN/KL at nine midinfrared (5-20 microns) wavelengths have revealed a subarcsecond structure near IRc2 which provides new constraints on the relationship between IRc2 and the Orion SiO maser. The infrared source positions have been improved, and IRc2 is found to be displaced 0.8 +/- 0.2 arcsec (at least 400 AU) from the SiO maser, an order of magnitude greater than the separation assumed in the current maser model. The SiO maser and the IRc2 midinfrared source may be physically independent objects. There are indications that IRc2 is eroded on the south side adjacent to the SiO/H2O maser cluster, suggesting that another luminous object near IRc2, most likely a stellar object associated with radio continuum point source 'I', is the host for the Orion SiO maser.

Gezari, Daniel Y.↗
NASA NTRS1977

A high-resolution far-infrared survey of the W31 region

A 1-m balloon-borne telescope was used to conduct a far-infrared survey of the W31 region at an effective wavelength of 69 microns with a resolution of 1 arcmin. Within this region seven far-infrared sources were observed. Five of these sources were associated with thermal radio emission. For each of these sources the infrared luminosity is much greater than the Ly-alpha luminosity, a situation requiring either dust absorption of Lyman-continuum photons or a large nonionizing stellar luminosity. Two faint infrared sources had no radio counterparts. Far-infrared radiation was not detected from two known radio sources and from one midinfrared source in this region.

Wright, E. L.↗