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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

The millimeter-wave spectrum of CaH (X 2Sigma(+))

The millimeter-wave spectrum of the CaH and CaD radicals (X 2Sigma(+)) has been observed in the laboratory via direct absorption spectroscopy. The species were generated by the reaction of calcium vapor, produced in a Broida-type oven, with hydrogen atoms created in a microwave discharge. The six hyperfine components of the N = 0 yields 1 rotational transition of CaH near 254 GHz were resolved and their frequencies determined to an accuracy of +/- 100 kHz. The main hyperfine lines originating in the N = 0 yields 1, 1 yields 2, and 2 yields 3 rotational transitions of CaD were also detected. Spectroscopic constants were determined for both radicals from a nonlinear least squares fit to the data, using a 2Sigma Hamiltonian. These measurements constitute the first laboratory observation of CaH at high spectral resolution, and are essential to the detection of this radical in interstellar space.

Barclay, W. L., Jr.↗
NASA NTRS1986

A survey of the millimeter-wave spectrum of Sagittarius B2

More than 60 percent of the millimeter wave spectrum between 70 and 150 GHz of the giant Sgr B2 molecular cloud was surveyed with the Bell Laboratories 7 m telescope at a spectral resolution of 1 MHz. The observations and instrumentation are described, including beam efficiency and beamwidth as functions of frequency, frequency coverage, and rms noise. The catalog used to identify the 457 lines found is summarized, and the analysis of the data to determine column densities and rotational temperatures is discussed. The range of rotational temperatures obtained and their relation to the kinetic temperature, and their implications for the hydrogen density, are considered. More than 300 lines are transitions of 21 molecules, and the results for these are analyzed, giving excitation diagrams for most of them. A partly successful attempt is made to use ratios of the calculated abundances to predict abundances of as yet undetected species. Finally, the spectra for the entire survey are presented.

Cummins, S. E.↗
NASA NTRS1992

Study and interpretation of the millimeter-wave spectrum of Venus

The effects of the Venus atmospheric constituents on its millimeter wavelength emission are investigated. Specifically, this research describes the methodology and the results of laboratory measurements which are used to calculate the opacity of some of the major absorbers in the Venus atmosphere. The pressure broadened absorption of gaseous SO2/CO2 and gaseous H2SO4/CO2 has been measured at millimeter wavelengths. We have also developed new formalisms for computing the absorptivities of these gases based on our laboratory work. The complex dielectric constant of liquid sulfuric acid has been measured and the expected opacity from the liquid sulfuric acid cloud layer found in the atmosphere of Venus has been evaluated. The partial pressure of gaseous H2SO4 has been measured which results in a more accurate estimate of the dissociation factor of H2SO4. A radiative transfer model has been developed in order to understand how each atmospheric constituent affects the millimeter wave emissions from Venus. Our results from the radiative transfer model are compared with recent observations of the micro-wave and millimeter wave emissions from Venus. Our main conclusion from this work is that gaseous H2SO4 is the most likely cause of the variation in the observed emission from Venus at 112 GHz.

Fahd, Antoine K.↗
NASA NTRS1986

The laboratory millimeter-wave spectrum of methyl formate in its ground torsional E state

Over 250 rotational transitions of the internal rotor methyl formate (HCOOCH3) in its ground v(t) = 0 degenerate (E) torsional substate have been measured in the millimeter-wave spectral region. These data and a number of E-state lines identified by several other workers have been analyzed using an extension of the classical principal-axis method in the high barrier limit. The resulting rotational constants allow accurate prediction of the v(t) = 0 E substate methyl formate spectrum below 300 GHz between states with angular momentum J not greater than 30 and rotational energy of not more than 350/cm. The calculated transition frequencies for the E state, when combined with the results of the previous analysis of the ground-symmetric, nondegenerate state, account for over 200 of the emission lines observed toward Orion in a recent survey of the 215-265 GHz band.

Plummer, G. M.↗
NASA NTRS1983

Laboratory and astronomical measurement of the millimeter wave spectrum of the ethynyl radical CCH

The N = 0 yields 1 and 1 yields 2 rotational transitions of CCH at 87 and 174 GHz, respectively, have been detected in a laboratory glow discharge in a mixture of He and C2H2. The spectroscopic constants of CCH derived from measurements of the hfs of the transitions agree well with those derived from astronomical observations, confirming the astronomical detection of CCH. As the CCH lines in the Orion Nebula are narrower than the laboratory lines but less certain in rest frequency owing to uncertainty in the radial velocity, the most accurate values for the spectroscopic constants of CCH are obtained from a simultaneous fit of both the laboratory and astronomical data. For the rotation, centrifugal distortion, spin-rotation, and hyperfine constants, respectively, the values found are within 0.006 of 43674.534 MHz, within 0.0008 of 0.1071 MHz, within 0.004 of -62.606 MHz, b = within 0.019 MHz of 40.426, and c is within 0.026 of 12.254 MHz.

Gottlieb, C. A.↗
NASA NTRS1993

The millimeter-wave spectrum of the MgH and MgD radicals

The pure rotational spectrum of MgH radical (X 2 Sigma (+)) in its ground state v = 0 and v = 1 vibrational modes has been observed in the laboratory using millimeter/submillimeter direct absorption spectroscopy. The rotational spectra of two isotopically substituted species, MgD and (Mg-26)H, have been detected as well. All six hyperfine components of the N = 0 -1 transition of MgH in its v = 0 and v = 1 states have been directly measured to an accuracy of +/-50 kHz, and the five components have been observed for (Mg-26)H. The N = 0 +/-1 and N = 1 -2 transitions of MgD have also been detected. Rotational, fine structure, and hyperfine constants were determined for all species from a nonlinear least-squared fit to the data using a 2 Sigma Hamiltonian.

Ziurys, L. M.↗
NASA NTRS1993

The millimeter-wave spectrum of AlOH

The pure rotational spectrum of the AlOH and AlOD molecules in their X 1Sigma(+) (v = 0) ground electric states has been measured in the laboratory using direct absorption millimeter/submillimeter spectroscopy. The species were produced by the reaction of aluminum vapor, created in a Broida-type oven, with hydrogen peroxide or D2O2. Eight rotational transitions of AlOH and five transitions for AlOD were measured in the frequency range of 157-378 GHz to an accuracy better than +/- 75 kHz. Electric quadrupole interactions, arising from the aluminum nuclear spin of 5/2, were observed in the J = 4 - 5 and the J = 5 - 6 transitions of AlOH. The rotational constants of these molecules have been determined from a nonlinear least-squares fit to the data. The electric quadrupole coupling constant, eqQ, has been measured as well, and was found to have a value of -42.4 +/- 4.3 MHz. The spectra are consistent with quasi-linear ground states for AlOH and AlOD, as predicted by theory. AlOH is of astrophysical interest because of the relatively high cosmic abundance of aluminum.

Apponi, A. J.↗
NASA NTRS1994

The millimeter-wave spectrum of the CaF radical (X(sup 2)Sigma(+))

The pure rotational spectrum of the CaF radical has been measured in the laboratory using millimeter/sub-mm direct absorption spectroscopy. Fourteen rotational transitions have been detected originating in the v = 0 mode of the species. Rotational lines of the vibrationally excited v = 1, 2, and 3 states have also been observed. Spin-rotation splittings, as well as hyperfine interactions arising from the nuclear spin of the fluorine atom, were resolved in the CaF spectra. Rotational, fine-structure, and in some cases, hyperfine parameters were determined for the various vibrational modes of the molecule from a nonlinear least-squares fit to the data, using a (sup 2)Sigma Hamiltonian, and are in agreement with past measurements. The newly measured rest frequencies for CaF, which are accurate to at least + or - 100 kHz, will enable astronomical searches to be conducted for the molecule in interstellar and circumstellar gas. Given the recent detection of AlF in IRC + 10216, metal fluoride species may be more abundant than previously thought.

Anderson, M. A.↗
NASA NTRS1995

Measurements of the millimeter-wave spectrum of interstellar dust emission

We report measurements of the differential brightness of interstellar dust emission near the Galactic plane and at high Galactic latitudes. The data were obtained as part of a program to measure anisotropy in the cosmic microwave background (CMB). The measurements were made with a 0.5 deg beam size and a 1.3 deg sinusoidal chop, in broad bands (Delta nu/nu approximately 0.3) centered near frequencies of 6, 9, and 12 cm(exp -1). A measurement made toward the Galactic plane, at longitude 1 = 23.7 deg, is compared with the contrast observed in the 100 micrometers IRAS data. Assuming the dust emission has a brightness I(sub nu) proportional to nu(sup n)B(sub nu)(T(sub d)), where B(sub nu) is the Planck function, a best fit yields n = 1.6 +/- 0.4, T(sub d) = 24 +/- 5 K. In a region near the star mu Pegasi (mu PEG l = 91 deg, b = -31 deg), the comparison of our data with the 100 micrometers IRAS data yields n = 1.4 +/- 0.4, and T(sub d) = 18 +/- 3 K. In a second region near the star gamma Ursa Minoris (GUM l = 108 deg, b = 41 deg), an upper limit is placed on contrast in dust emission. This upper limit is consistent with spectrum measured at mu PEG and the IRAS 100 micrometer emission contrast at GUM, which is approximately 8 times lower than mu PEG.

Fischer, M. L.↗
DOE OSTI2020

Experimental demonstration of externally driven millimeter-wave particle accelerator structure

We report the experimental demonstration of a mm-wave electron accelerating structure powered by a high-power rf source. We demonstrate reliable coupling of an unprecedented rf power—up to 575kW into the mm-wave accelerator structure using a quasi-optical setup. This standing wave accelerating structure consists of a single-cell copper cavity and a Gaussian to TM 01 mode converter. The accelerator structure is powered by 110 GHz, 10-ns long rf pulses. These pulses are chopped from 3 microsecond pulses from a gyrotron oscillator using a laser-driven silicon switch. We show an unprecedented high gradient up to 230MV/m that corresponds to a peak surface electric field of more than 520 MV/m. We have achieved these results after conditioning the cavity with more than 100,000 pulses. We also report preliminary measurements of rf breakdown rates, which are important for understanding rf breakdown physics in the millimeter-wave regime. Furthermore, these results open up many frontiers for applications not only limited to the next generation particle accelerators but also x-ray generation, probing material dynamics, and nonlinear light-matter interactions at mm-wave frequency.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

Metastable argon dynamics in a pulsed microplasma at 43 GHz

Short pulses of millimeter wave (MMW) radiation at 43 GHz create microplasma within a photonic crystal for pressures from 40 to 600 Torr (1.3 × 10 3 –8.0 × 10 4 Pa). Gas breakdown occurs within a photonic crystal, which acts as an electromagnetic resonator to create a strong initial electric field. The time response of the argon metastable density is experimentally determined during the pulse and in the afterglow using laser absorption. The metastable density overshoots the steady-state condition at the beginning of the pulse and during the afterglow. Modeling is presented to understand these observations. The overproduction of argon 1s5 at the beginning of each pulse is due to a concurrent overshoot in the MMW electric field within the photonic crystal. This field overheats the plasma electrons and enhances the production of excited states. The burst of argon metastables observed in the afterglow is due to the pooled energy of the plasma stored in electrons, ions, and excited states of argon. As a result, understanding metastable production is an important intermediate step to ionization and is also critical in the study of diode-pumped rare gas lasers.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1988

The laboratory millimeter- and submillimeter-wave spectrum of CH3OD

The millimeter-wave and submillimeter-wave spectrum of CH3OD, a deuterated isotope of methanol known to be present in the interstellar medium, has been studied in the laboratory. Like all isotopes of methanol, CH3OD possesses a complex dense spectrum because of the phenomenon of internal rotation, sometimes referred to as torsional motion. Approximately 300 lines in the frequency range 130-700 GHz have been assigned. These lines involve transitions between rotational states with rotational quantum number J of not greater than 9 in both the A and the E substates of the lowest torsional state (v sub t = 0). The present data and previous data at lower frequencies (longer wavelengths) have been combined and analyzed by a procedure called the 'internal axis method'. The analysis yields spectral constants for CH3OD which, in turn, have been used to predict the frequencies of a number of other transitions of this species not measured in the laboratory.

Anderson, Todd↗
NASA NTRS2017

Ultra-Wideband Array in PCB for Millimeter-Wave 5G and ISM

Next generation 5G mobile architectures will take advantage of the millimeter-wave spectrum to deliver unprecedented bandwidth. Concurrently, there is a need to consolidate numerous disparate allocations into a single, multi-functional array. Existing arrays are either narrow-band, prohibitively expensive or cannot be scaled to these frequencies. In this paper, we present the first ultra-wideband millimeter-wave array to operate across the six 5G and ISM bands spanning 24-71 GHz. Critically, the array is realized using low-cost PCB. The design concept and optimized layout are presented, and fabrication and measurement considerations are discussed.

Ultra-Wideband Array↗
DOE OSTI2022

Uncoordinated Spectrum Sharing in Millimeter Wave Networks Using Carrier Sensing

Here, we propose using Carrier Sensing (CS) for distributed interference management in millimeter-wave (mmWave) cellular networks where spectrum is shared by multiple operators that do not coordinate among themselves. In addition, even the base station sites can be shared by the operators. We describe important challenges in using traditional CS in this setting and propose enhanced CS protocols to address these challenges. Using stochastic geometry, we develop a general framework for downlink coverage probability analysis of our shared mmWave network in the presence of CS and derive the downlink coverage probability expressions for several CS protocols. Our work is the first to investigate and analyze (using stochastic geometry) CS for mmWave networks with spectrum and BS sites shared among non-coordinating operators. We evaluate the downlink coverage probability of our shared mmWave network using simulations as well as numerical examples based on our analysis. Our evaluations show that our proposed approach leads to an improvement in coverage probability, compared to the coverage probability with no CS, for higher values of signal-to-interference and noise ratio (SINR). Interestingly, our evaluations also reveal that for lower values of SINR, not using any CS is the best strategy in terms of the downlink coverage probability.

42 ENGINEERING↗
NASA NTRS1987

The laboratory millimeter- and submillimeter-wave spectrum of C-13 methanol

A comprehensive millimeter- and submillimeter-wave study of the rotational spectrum of (C-13)H3OH is presented. Approximately 300 new transitions of this species were measured at frequencies up to 650 GHz, and the transitions were analyzed along with previously measured spectra using the internal axis method of Herbst et al. (1984). The resulting spectral constants allow prediction of an additional large number of transitions which should allow astronomers to identify many strong rotational lines of C-13 methanol throughout much of the submillimeter region.

Anderson, Todd↗
NASA NTRS1977

Theoretical study of the butadiynyl and cyanoethynyl radicals - Support for the identification of C3N in IRC + 10216

Quantum-mechanical calculations, using the matrix Hartree-Fock model, have been performed for the butadiynyl and cyanoethynyl radicals. A rotation constant of 4753 MHz is calculated for C4H, while for C3N the value 4955 MHz is obtained. These may be compared with the rotation constant of 4947.5 MHz derived from the recently observed doublets in the millimeter-wave spectrum of IRC + 10216, suggesting the cyanoethynyl radical as the carrier species of these lines. The electric dipole moment and hyperfine coupling constants of both species are predicted.

Wilson, S.↗
NASA NTRS1978

Detection of the C4H radical toward IRC plus 10216

Four emission doublets in the millimeter-wave spectrum of IRC plus 10216 are identified as successive rotational transitions of the linear butadiynyl radical (C4H). The identifications are made on the basis of the agreement to within about 1 part in 1000 between the observed rotation constant of C4H and the value obtained from a Hartree-Fock calculation. A rough estimate of the amounts of C4H and C3N in the molecular envelope of IRC plus 10216 is given. The results indicate that C4H seems to be the more abundant species by about a factor of 4.

Guelin, M.↗
NASA NTRS1979

Interstellar methyl mercaptan

Methyl mercaptan (CH3SH) has been identified in Sgr B2 from observations of six lines in its millimeter-wave spectrum. The CH3SH rotational temperature and column density in Sgr B2 are T(rot) = 9 plus or minus 3 K and N = 1.5 plus or minus 0.2 x 10 to the 14th per sq cm, respectively. The CH3SH/CH3OH ratio is apparently not greatly different from the cosmic S/O ratio.

Linke, R. A.↗