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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Computational Nanotechnology of Molecular Materials, Electronics, and Actuators with Carbon Nanotubes and Fullerenes

The role of computational nanotechnology in developing next generation of multifunctional materials, molecular scale electronic and computing devices, sensors, actuators, and machines is described through a brief review of enabling computational techniques and few recent examples derived from computer simulations of carbon nanotube based molecular nanotechnology.

Srivastava, Deepak↗
NASA NTRS2002

Computational Nanotechnology of Molecular Materials, Electronics and Machines

This viewgraph presentation covers carbon nanotubes, their characteristics, and their potential future applications. The presentation include predictions on the development of nanostructures and their applications, the thermal characteristics of carbon nanotubes, mechano-chemical effects upon carbon nanotubes, molecular electronics, and models for possible future nanostructure devices. The presentation also proposes a neural model for signal processing.

Srivastava, D.↗
NASA NTRS2002

Computational Nanotechnology Molecular Electronics, Materials and Machines

This presentation covers research being performed on computational nanotechnology, carbon nanotubes and fullerenes at the NASA Ames Research Center. Topics cover include: nanomechanics of nanomaterials, nanotubes and composite materials, molecular electronics with nanotube junctions, kinky chemistry, and nanotechnology for solid-state quantum computers using fullerenes.

Srivastava, Deepak↗
NASA NTRS2005

Association of Presolar Grains with Molecular Cloud Material in IDPs

Anhydrous interplanetary dust particles (IDPs) collected in the stratosphere appear chemically, mineralogically, and texturally primitive in comparison to meteorites. Particles that escape significant atmospheric entry heating have highly unequilibrated mineralogy, are volatile element rich, and, overall, appear to have escaped significant parent body hydrothermal alteration. These IDPs are comprised of the building blocks of the solar system. The strongest evidence that anhydrous IDPs are primitive is that they contain abundant stardust and molecular cloud material. In particular, presolar silicates were first identified in IDPs and are present in abundances (450-5,500 ppm) that are well above that observed in primitive meteorites (less than 170 ppm). The most fragile (cluster) IDPs also commonly exhibit large H and N isotopic anomalies that likely originated by isotopic fractionation during extremely low temperature chemical reactions in a presolar cold molecular cloud. The D/H ratios exceed that of most primitive meteorites, and in rare cases reach values directly observed from simple gas phase molecules in cold molecular clouds. The most extreme D- and N-15-enrichments are usually observed at the finest spatial scales (0.5-2 microns) that can be measured. These observations suggest that D and N-15 hotspots are in fact preserved nuggets of molecular cloud material, and that the materials within them also have presolar origins. The advanced capabilities of the NanoSIMS ion microprobe now enable us to test this hypothesis. Here, we report two recent examples of presolar silicates found to be directly associated with molecular cloud material.

Messenger, S.↗
NASA NTRS2002

Synthesis and Characterization of the First Liquid Single Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS2) Thin Film Materials

Molecular engineering of ternary single source precursors based on the [{PBu3}2Cu(SR')2In(SR')2] architecture have afforded the first liquid CIS ternary single source precursors (when R = Et, n-Pr), which are suitable for low temperature deposition (< 350 C). Thermogravimetric analyses (TGA) and modulated-differential scanning calorimetry (DSC) confirm their liquid phase and reduced stability. X-ray diffraction studies, energy dispersive analyzer (EDS), and scanning electron microscopy (SEM) support the formation of the single-phase chalcopyrite CuInS2 at low temperatures.

Banger, Kulbinder K.↗
NASA NTRS2019

CO2 Removal for the International Space Station – 4-Bed Molecular Sieve Material Selection and System Design

Efforts over the past three years have focused on the study of candidate sorbent materials for use in a 4BMS molecular sieve system. The accumulation of knowledge has been invaluable for further decisions and for reflecting on the conclusions of past decisions. The goal of the next generation CO2 removal system is continuous, failure-free operation for nearly 20,000 hours, but no complex life support system has yet reached this lofty goal. In addition to reliability, CO2 removal performance improvements have been intensively studied. The achievements toward this end include highly detailed isotherm measurements which drive system simulations as well as testing physical design improvements. Looking back on the successes and failures of past systems, correlating data from long-duration tests, and carefully projecting future results are all needed for the success of the next system. This work intends to reveal the path we have taken and illuminate the steps to come for CO2 removal life support with the 4BCO2 flight demonstration.

Cmarik, Gregory E.↗
NASA NTRS2005

Warm Molecular Gas Traced with CO J = 7 --> 6 in the Galaxy's Central 2 Parsecs: Dynamical Heating of the Circumnuclear Disks

We present an 11" resolution map of the central 2 pc of the Galaxy in the CO J = 7 --> 6 rotational transition. The CO emission shows rotation about Sgr A* but also evidence for noncircular turbulent motion and a clumpy morphology. We combine our data set with available CO measurements to model the physical conditions in the disk. We find that the molecular gas in the region is both warm and dense, with T approx. 200-300 K and n(sub H2) approx. (5-7) x 10(exp 4) cm(exp -3). The mass of warm molecular gas we measure in the central 2 pc is at least 2000 M(solar), about 20 times the UV-excited atomic gas mass, ruling out a UV heating scenario for the molecular material. We compare the available spectral tracers with theoretical models and conclude that molecular gas is heated with magnetohydrodynamic shocks with v approx. 10-20 km s(exp -1) and B approx. 0.3- 0.5 mG. Using the conditions derived with the CO analysis, we include the other important coolants, neutral oxygen and molecular hydrogen, to estimate the total cooling budget of the molecular material. We derive a mass-to-luminosity ratio of approx. 2-3 M(solar)(L(solar)exp -1), which is consistent with the total power dissipated via turbulent decay in 0.1 pc cells with v(sub rms) approx. 15 kilometers per second. These size and velocity scales are comparable to the observed clumping scale and the velocity dispersion. At this rate, the material near Sgr A* is dissipating its orbital energy on an orbital timescale and cannot last for more than a few orbits. Our conclusions support a scenario in which the features near Sgr A* such as the circumnuclear disk and northern arm are generated by infalling clouds with low specific angular momentum.

galatic nuclei↗
NASA NTRS1990

Warm dense gas in the reflection nebula NGC 2023

A photodissociation region (PDR) with a known UV excitation source was studied by examining emission from atomic and molecular material. In agreement with models of externally excited PDRs, the photodissociation region southwest of HD 37903 contains both atomic and excited molecular material and arises close to the exciting star than does the bulk of the molecular cloud. The C(+) emission arises closest to the star but is 1.5 x 10 to the 17th cm or less from the peaks in the excited CO and fluorescent H2 emission regions. The (C-18)O J = 2 - 1 line, which traces molecular column density, has its emission peak about 4 x 10 to the 17th cm beyond the C(+) peak. Even in a source with an incident UV flux as low as about 1000 times the mean interstellar radiation field, there is a significant amount of CO 7 - 6 emission arising from regions with T(gas) greater than 85 K which is substantially greater than T(dust).

Jaffe, D. T.↗
NASA NTRS1986

Clump 1 - An unusual molecular cloud complex near the Galactic center

The properties of the (C-12)O and (C-13)O emission from Clump I, a complex of molecular clouds which shows the largest noncircular velocities of any molecular material known in the Milky Way, are studied. Observations of the J = 1-0 rotational transitions of the above molecules are reported, and the large-scale distribution and kinematics of the molecular gas in the direction of Clump I are discussed. The small-scale structure is described based on one arcmin resolution of (C-13)O data. Physical properties of the molecular material are derived, and the dynamics of the Clump I clouds are discussed in the context of their stability against Galactic tidal forces. It is concluded that all the clouds in the complex are gravitationally bound, although their outer envelopes may be tidally disrupted by the Galactic potential. The relative motion of the clouds is qualitatively similar to giant molecular cloud complexes in spiral arms of the outer Galactic disk, but the velocities are higher.

Bania, T. M.↗
NASA NTRS1994

The giant molecular cloud Monoceros R2. 1: Shell structure

We have obtained a 45 sec resolution, Nyquist-sampled map in CO J = 1-0 covering approximately a 3 deg x 3 deg region of the giant molecular cloud Monoceros R2. The map consists of 167,000 spectra observed with the 15 element focal-plane array system on the FCRAO 14 m telescope. The data reveal that the large-scale structure of Mon R2 is dominated by a is approximately 30 pc diameter largely hemispherical shell containing approximately 4 x 10(exp 4) solar mass of molecular material and expanding at approximately 3-4 km s(exp -1) with symmetric axis roughly along the line of sight. The dynamical timescale of the shell is estimated to be approximately 4 x 10(exp 6) yr, which is consistent with the age of main-sequence stars powering the clusters of reflection nebulea in this region. There is no evidence for a redshifted shell on the far side of the interior 'bubble,' which is largely devoid of molecular material. Distortions of the shell are obvious, suggesting inhomogeneity of the cloud and possible presence of a magnetic field prior to its formation. Dense clumps in Mon R2, including the main core and the GGD 12-15 core, appear to be condensations located on the large shell. The reflection nebulea with their illuminating stars as well as embedded IRAS sources suggest that triggered star formation has taken place over a large part of the Mon R2 shell.

Xie, Taoling↗
NASA NTRS1990

CS J = 2 yields 1 emission toward the central region of M82

M82 is an irregular (Type II) galaxy located at a distance of approximately 3.5 Mpc. Its unusual appearance and high luminosity, particularly in the infrared, has led many astronomers to classify it as a starburst galaxy. This interpretation is supported by the observation of a large number of radio continuum sources within the central arcminute of the galaxy. These sources are thought to be associated with supernova remnants. The starburst in the central region of the galaxy is believed to have been triggered by tidal interaction with either M81 or the HI cloud surrounding the M81 group. High angular resolution CO-12 J=1 to 0 maps by Nakai (1984) and Lo et al. (1987) indicate the existence of a 400 to 450 pc rotating ring of molecular material about the central region of M82. Red- and blue-shifted absorption components of the HI and OH lines measured by Weliachew et al. (1984) provided the first evidence for the presence of the ring. Many astronomers, each using a different angular resolution, have compared CO-12 J=1 to 0, J=2 to 1, and J=3 to 2 emission and concluded that a large fraction of the CO emission is optically thin. Additional observations suggest that the molecular material toward the center of M82 is clumpy and dense. Unlike the lower rotational transitions of CO, CS is excited only at relatively high densities, n sub H sub 2 greater than or equal to 10(exp 4) cm(-3). It is in clouds with these densities that stars are expected to form. This makes CS an excellent probe of star formation regions. Researchers observed the CS J=2 to 1 transition (97.981 GHz) toward 52 positions in M82 using the National Radio Astronomy Observatory (NRAO) 12 m telescope.

Walker, C. E.↗
NASA NTRS1991

Neutral matter in planetary nebulae

A review of current studies of neutral envelopes is presented with particular attention given to the use of the envelopes as test cases for understanding the ionization and thermal structure of photodissociation regions. The study of near-IR H2 emission is discussed with detailed spectra given for a few planetary nebulae, and airborne observations of far-IR atomic lines are discussed. These two methods can discern photodissociation regions with warm gas and UV flux is fairly prominent. The use of resonance-absorption-line spectroscopy is also reviewed with respect to the analysis of the Na D lines, and thereby allows the measurement of integrated columns of material through the shell. The methods provide evidence for the notion that planetary nebulae consist of more than just ionized material; large amounts of neutral and molecular material are being confirmed, which has important implications for the mass-loss episode of the nebulae.

Dinerstein, Harriet L.↗
NASA NTRS1980

Molecular clouds in Orion and Monoceros

A 1.2-m millimeter-wave telescope has been used to survey CO in the constellations of Orion and Monoceros. Many new molecular clouds have been found. The distribution of molecular material shows two striking characteristics: (1) Most of the molecular clouds in this region appear to be connected by continuous extensions and filaments. To judge from continuity in radial velocity, most of these connections appear to be real, and are not merely the result of projection along the line of sight; (2) There are at least two slender filamentary features longer than 10 deg in angular extent. These filaments may connect the molecular clouds lying well out of the Galactic plane to clouds lying in the plane. Their shape and orientation suggest that magnetic fields may play a role in their evolution. The observed velocity gradients may be explained by accelerated gas flow along the filament.

Morris, M.↗
NASA NTRS1994

Hydrogen and related materials at high density: Physics, chemistry and planetary implications

Recent studies of low-Z molecular materials including hydrogen to multimegabar pressures (less than 300 GPa) have uncovered a range of phenomena relevant to understanding the nature of the interiors of the outer planets and their satellites. Synchrotron x ray diffraction measurements (to 42 GPa) have been used to determine the crystal structure of the solid (hexagonal-close packed) and equation of state. Sound velocities in fluid and solid hydrogen (to 24 GPa) have been inverted to obtain elastic constants and aggregate bulk and shear moduli. In addition, an improved intermolecular potential has been determined which fits both static and shock-wave data. Use of the new potential for the molecular envelope of Jupiter suggests the need for major revisions of existing Jovian models or a reanalysis of reported free oscillations for the planet. Studies at higher pressures (greater than 100 GPa) reveal a sequence of pressure-induced symmetry-breaking transitions in molecular hydrogen, giving rise to three high-pressure phases (1, 2, and 3). Phase 1 is the rotationally disordered hcp phase which persists from low pressure to well above 100 GPa at high temperature (e.g., 300 K). Phase 2 is a low-temperature, high-pressure phase (transition at 100 GPa and 77 K in H2) with spectral features indicative of partial rotational ordering and crystallographic distortion. The transition to Phase 3 at 150 GPa is accompanied by a weakening of the molecular bond, gradual changes in orientational ordering, strong enhancement of the infrared intramolecular vibrational absorption, and strong intermolecular interactions similar to those of ambient-pressure network solids. Studies of the phase diagram reveal a triple point near 130 K and 160 GPa. Higher pressure measurements of vibrational spectra place a lower bound of approximately 250 GPa on the predicted transition pressure for dissociation of molecular hydrogen to form a monatomic metal.

Hemley, R. J.↗
NASA NTRS1989

The physical state of the obscuring torus in Seyfert galaxies

Calculations are presented describing the ionization, chemical, and thermal state of molecular material in the obscuring tori close to the nuclei of many Seyfert galaxies. These are unusual molecular clouds: their electron fractions are about .001 and their temperatures are about 1000 K. Cooling is accomplished primarily by radiation of NIR H2 lines and FIR CO lines. High-J (C-12)(O-16) rotational lines should eventually be detectable from the nearer Seyfert galaxies. Medium-J lines due to (C-13)(O-16) and (C-12)(O-18) as well as (C-12)(O-16) should also be strong. Because ordinary molecular clouds are weak in these lines, the nuclear CO emissions can be distinguished from CO emission farther out in the host galaxy's disk.

Krolik, Julian H.↗
NASA NTRS1986

The molecular content of the nearby galaxy from IRAS and HI observations

Because infrared emission is a very good tracer of mass at high latitudes, by combining it with HI observations it provides a convenient though indirect way of observing the spatial distribution of molecular material. Moreover, these observations will premit placing limits on the fraction of total infrared luminosity emitted by dust associated with molecular and atomic hydrogen clouds. A preliminary result from the study of the correlation between HI column density and 100 micron infrared flux density as measured by the IRAS satellite is reported. The ratio F100/W(HI) = R has an average value of roughty 17 KJy/sr/(K km/s) over the whole sky. Bright regions in the FIR such as the Galactic plane and HII regions are excluded from the data. The histogram of the number of pixels vs R has a strong peak near 17 (same units as before) and is asymmetric about this mean value, having a tail at higher values of R. This basic shape is fairly independent of the region of the sky we observe. The peak confirms the general correlation between infrared emission and HI column density reported previously. One way to explain the shape of the distribution is to assume a constant dust to gas mass ratio and a constant interstellar radiation field and associate points in the tail with molecular clouds. In this case the ratio R is higher for points in the tail because it does not account for the column density of molecular hydrogen.

Bazell, D.↗
NASA NTRS1990

Observations of CO isotopic emission and the far-infrared continuum of Centaurus A

Researchers present maps of the CO-12(1=0) line and the 100 micron and 50 micron far-infrared emission of Centaurus A, as well as measurements of the CO-12(2-1), CO-13(1-0), and the C-18O(1-0) lines at selected positions. The observations were taken with the Swedish-ESO Submillimeter Telescope (SEST) and the CPC instrument on board the Infrared Astronomy Satellite (IRAS). The millimeter data show that the bulk molecular material is closely associated with the dust lane and contained in a disk of about 180 seconds diameter and a total molecular mass of about 2 x 10 to the 8th power solar mass. The total molecular mass of the disk and bulge is of the order of 3 x 10 to the 8th power solar mass. The molecular gas in the nucleus is warm with a kinetic temperature of the order of 15 K and a number density of 10 to the 3rd power to 3 x 10 to the 4th power cm(-3). Absorption features in the CO-12 and CO-13 lines against the nuclear continuum emission indicate that the properties of giant molecular clouds are comparable to those of the Galaxy. The far-infrared data show that to a good approximation the dust temperature is constant across the dust lane at a value of about 42 K. The ratio between the far-infrared luminosity and the total molecular mass is 18 solar luminosity/solar mass and close to the mean value obtained for isolated galaxies. A comparison of the CO-12(1-0) and the far-infrared data indicates that a considerable amount of the far-infrared emission is not intimately associated with massive star formation.

Eckart, A.↗