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NASA NTRS1992

Tunable Electro-optic modulators for lidar systems and atmospheric applications

In global sensing applications using different types of lidars, the spectral range and fine frequency coverages are often limited because of the finite tunabilities of molecular lasers and the number of molecular species that are available. To overcome the above obstacle, we have proposed new broadband frequency tunable electro-optic (EO) modulators that can cover a wide range from the mid-infrared to the visible as lidar sources in atmospheric sensing applications such as high resolution atmospheric molecular spectroscopy, Differential Absorption Lidar (DIAL), and laser radar imaging. The configuration of the proposed new tunable EO modulators includes an electro-optic active crystal element surrounded by a ferrite tuning element which is placed inside a microwave waveguide. The tuning is provided by an external magnetic field, which is either longitudinal or transverse, and the modulator can be either single sideband type or a double sideband type depending on the application required for the spectral purity of the modulator output.

Eng, R. S.↗

NASA NTRS1991

Tunable far infrared studies of molecular parameters in support of stratospheric measurements

Lab studies were made in support of far infrared spectroscopy of the stratosphere using the Tunable Far InfraRed (TuFIR) method of ultrahigh resolution spectroscopy and, more recently, spectroscopic and retrieval calculations performed in support of satellite-based atmospheric measurement programs: the Global Ozone Monitoring Experiment (GOME), and the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY).

Chance, Kelly V.↗

NASA NTRS1990

Tunable far infrared studies of molecular parameters in support of stratospheric measurements

The purpose of this research is to make precise, fully line-resolved measurements of molecular parameters that are necessary for the analysis of spectra obtained in far infrared field measurement programs. These measurements make it possible to accurately analyze the data from field measurements to obtain atmospheric concentration profiles of key trace gases involved in the ozone chemistry. The research objectives include: measurements of pressure broadening of molecular lines of OH, O2, O3, HCl, and H2O, their temperature dependence, and, when possible, the pressure-induced frequency shifts of the lines; measurements of line positions of radical species, such as HO2.

Chance, K. V.↗

NASA NTRS1987

Tunable ultraviolet laser studies of photon-molecular interactions of cometary interest

Most of the cometary radicals are thought to be formed in the coma by photodissociation processes. Successful modeling of the coma requires a detailed knowledge of the products that are formed from the various parent molecules and the energy partitioning among these products. This information has to be obtained as a function of wavelength, because the sun is not a monochromatic source. In this review, the status of the experimental knowledge of some key molecules is discussed, along with the prospects of some new laboratory techniques that can fill in the gaps in the present knowledge.

Jackson, William M.↗

NASA NTRS1982

Optically pumped submillimeter-waves and applications

Rapid development of optically pumped lasers has shown the potential to be used as a source for a high resolution spectrometer. In this connection, a compact, stable FIR laser was designed, fabricated, and assembled, integrating both the pump laser and the FIR cavity in the same mechanical structure for its improved (both thermal and mechanical) stability and mobility. Performance of the mixer structure which was designed and constructed for the evaluation of the Schottky diodes was found to be satisfactory. The feasibility of generating tunable sideband for molecular spectroscopy studies was demonstrated.

Dutta, J. M.↗

NASA NTRS1991

The Berkeley tunable far infrared laser spectrometers

A detailed description is presented for a tunable far infrared laser spectrometer based on frequency mixing of an optically pumped molecular gas laser with tunable microwave radiation in a Schottky point contact diode. The system has been operated on over 30 laser lines in the range 10-100/cm and exhibits a maximum absorption sensitivity near one part in a million. Each laser line can be tuned by + or - 110 GHz with first-order sidebands.

Blake, G. A.↗

NASA NTRS1975

Waveguide CO2 laser gain: Dependence on gas kinetic and discharge properties

Using a simple rate equation approach the gas kinetic and discharge properties of waveguide CO2 lasers were examined. The dependence was calculated of the population inversion and laser small signal gain on gas pressure, gas mixture, pumping rate (discharge current), tube bore diameter, and wall temperature. At higher pressures the gain is optimized by using more helium rich mixtures and smaller bore diameters. The dependence of laser tunability on the gas kinetic properties and cavity losses was determined, it was found that for loss cavities the laser tunability may substantially exceed the molecular fullwidth at half maximum. The more helium rich gas mixtures give greater tunability when cavity losses are small and less tunability when cavity losses are large. The role of the various gases in the waveguide CO2 laser is the same as that in conventional devices, by contrast with conventional lasers, the waveguide laser transition is homogeneously broadened. The dependence of gain on gas pressure and other kinetic and discharge properties differs substantially from that predicted by scaling results from conventional low pressure lasers.

Cohen, S. C.↗

NASA NTRS1976

Waveguide CO2 laser gain - Dependence on gas kinetic and discharge properties

A simple rate-equation approach is used to examine the gas-kinetic and discharge properties of waveguide CO2 lasers. The dependence of the population inversion and laser small-signal gain on gas pressure, gas mixture, pumping rate (discharge current), tube bore diameter, and wall temperature is calculated along with the dependence of laser tunability on the gas-kinetic properties and cavity losses. It is found that for low-loss cavities, the laser tunability may substantially exceed the molecular full width at half-maximum. Furthermore, the more helium-rich gas mixtures give greater tunability when cavity losses are small, and less tunability when cavity losses are large. By contrast with conventional lasers, the waveguide-laser transition is homogeneously broadened. Thus, the dependence of gain on gas pressure and other kinetic properties differs substantially from that predicted by scaling results from conventional low-pressure lasers.

Cohen, S. C.↗

NASA NTRS1978

Saturated absorption in NH3 demonstrated using a tuneable diode laser

Saturation of molecular transitions using a tunable diode laser has been demonstrated for the first time using a standing-wave-cavity configuration with the laser beam focused at the sample. Observed saturation effects in NH3 transitions near 888 kaysers include sub-Doppler (Lamb-dip) resonances at the line center.

Jennings, D. E.↗

NASA NTRS1989

Stable isotope laser spectroscopy

Recent advances in semiconductor laser technology have produced a reliable lightweight device ideally suited for a spacecraft high resolution molecular spectrometer. Lead-salt tunable diode lasers (TDL) emit in several spectral modes, each with a very narrow linewidth of -0.0003/cm. This spectral resolution is much narrower than typical Doppler broadened molecular linewidths in the mid-IR range. Thus it is possible to detect individual rotational lines within the vibrational band and measure their intensity, which can be used to determine gas concentration. The narrow spectral lines of any impurity gas tend to lie between the narrow lines of the gas of interest. This represents a major advantage over the accepted gas chromatograph mass spectrometer (GCMS) technique for measuring gas concentrations and isotope ratios. The careful and extensive gas purification procedures required to remove impurities for reliable GCMS measurements will not be required for an IR laser gas analysis. The infrared laser gas analysis technique is being developed to measure stable isotopic ratios of gases such as CO2, CH4, N2O, and NH3. This will eventually lead to development of instruments capable of in situ istopic measurements on planets such as Mars. The carbon (C-12, C-13) isotope ratio is indicative of the type of carbon fixation mechanisms (e.g., photosynthesis, respiration) in operation on a planet, while the nitrogen (N-14, N-15) isotope ratio can probably be used to date nitrogen-bearing Martian samples. The absorbance ratio of two adjacent lines of CO2 in the 2300/cm (4.3 micron) region of the spectrum was measured. The precision of the measurement is presently better than 1 percent and significant improvement is anticipated as rapid sweep-integration techniques and computer controlled data acquistion capabilities are incorporated.

Becker, J. F.↗

NASA NTRS1985

Tunable diode laser Stark modulation spectroscopy for rotational assignment of the HNO3 7.5-micron band

The technique of Stark modulation spectroscopy for unraveling and assigning rotationally resolved dense molecular spectra has been employed using a tunable diode laser (TDL) source. Doppler-limited absorption and Stark modulation spectra of the HNO3 7.5-micron band near the 1326/cm band origin are presented with preliminary values of the excited-state rovibrational constants derived from both TDL and Bomem Fourier transform IR spectra.

Webster, C. R.↗

NASA NTRS1992

Polarization-stabilized 1.15- and 3.39-micron He-Ne lasers

Two methods for polarization stabilization of an internal-mirror 3.39-micron He-Ne laser are reported. The first relies on a concurrently lasing 1.15-micron transition by fixing the relative amplitude of two orthogonally polarized longitudinal modes that are split by a Rochon prism and detected with separate Si photodiodes. In the second method, two spatially separated orthogonally polarized adjacent 3.39-micron modes are optically balanced, differentially chopped, and recombined on a single InSb photodiode for phase-sensitive detection. The dual-wavelength scheme has been tested by beating against a methane-stabilized 3.39-micron He-Ne laser, which yields maximum excursions of less than 0.5 MHz over several hours and comparable reproducibility. The polarization-stabilized He-Ne laser has been used as a reference for a tunable color-center laser molecular-beam optothermal spectrometer and provides a precision of better than 2 MHz.

Junttila, M.-L.↗

NASA NTRS1987

Method and apparatus for enhancing laser absorption sensitivity

A simple optomechanical method and apparatus is described for substantially reducing the amplitude of unwanted multiple interference fringes which often limit the sensitivities of tunable laser absorption spectrometers. An exterior cavity is defined by partially transmissible surfaces such as a laser exit plate, a detector input, etc. That cavity is spoiled by placing an oscillating plate in the laser beam. For tunable diode laser spectroscopy in the mid-infrared region, a Brewster-plate spoiler allows the harmonic detection of absorptances of less than 10 to the -5 in a single laser scan. Improved operation is achieved without subtraction techniques, without complex laser frequency modulation, and without distortion of the molecular lineshape signal. The technique is applicable to tunable lasers operating from UV to IR wavelengths and in spectrometers which employ either short or long pathlengths, including the use of retroreflectors or multipass cells.

Webster, Christopher R.↗

NASA NTRS1990

High resolution infrared spectroscopy of planetary molecules using diode lasers and Fourier transform spectrometers

Modern observations of infrared molecular lines in planets are performed at spectral resolutions which are as high as those available in the laboratory. Analysis of such data requires laboratory measurements at the highest possible resolution, which also yield accurate line positions and intensities. For planetary purposes the spectrometer must be coupled to sample cells which can be reduced in temperature and varied in pressure. An approach which produces the full range of required molecular line parameters uses a combination of tunable diode lasers and Fourier transform spectrometers (FTS). The FTS provides board spectral coverage and good calibration accuracy, while the diode laser can be used to study those regions which are not resolved by the FTS.

Jennings, Donald E.↗

NASA NTRS2001

Novel High Efficient Organic Photovoltaic Materials

In man's mission to the outer space or a remote site, the most abundant, renewable, nonpolluting, and unlimited external energy source is light. Photovoltaic (PV) materials can convert light into electrical power. In order to generate appreciable electrical power in space or on the Earth, it is necessary to collect sunlight from large areas due to the low density of sunlight, and this would be very costly using current commercially available inorganic solar cells. Future organic or polymer based solar cells seemed very attractive due to several reasons. These include lightweight, flexible shape, ultra-fast optoelectronic response time (this also makes organic PV materials attractive for developing ultra-fast photo detectors), tunability of energy band-gaps via molecular design, versatile materials synthesis and device fabrication schemes, and much lower cost on large-scale industrial production. It has been predicted that nano-phase separated block copolymer systems containing electron rich donor blocks and electron deficient acceptor blocks will facilitate the charge separation and migration due to improved electronic ultrastructure and morphology in comparison to current polymer composite photovoltaic system. This presentation will describe our recent progress in the design, synthesis and characterization of a novel donor-bridge-acceptor block copolymer system for potential high-efficient organic optoelectronic applications. Specifically, the donor block contains an electron donating alkyloxy derivatized polyphenylenevinylene, the acceptor block contains an electron withdrawing alkyl-sulfone derivatized polyphenylenevinylene, and the bridge block contains an electronically neutral non-conjugated aliphatic hydrocarbon chain. The key synthetic strategy includes the synthesis of each individual block first, then couple the blocks together. While the donor block stabilizes the holes, the acceptor block stabilizes the electrons. The bridge block is designed to hinder the electron-hole recombination. Thus, improved charge separation is expected. In addition, charge migration will also be facilitated due to the expected nano-phase separated and highly ordered block copolymer ultrastructural. The combination of all these factors will result in significant overall enhancement of photovoltaic power conversion efficiency.

Sun, Sam↗

NASA NTRS1991

Two-dimensional imaging of molecular hydrogen in H2-air diffusion flames using two-photon laser-induced fluorescence

The use of a tunable ArF laser at 193.26 nm to record simultaneous single-laser-shot, planar images of molecular hydrogen and hot oxygen in a turbulent H2-air diffusion flame. Excitation spectra of fuel and oxidant-rich flame zones confirm a partial overlap of the two-photon H2 and single-photon O2 Schumann-Runge absorption bands. UV Rayleigh scattering images of flame structure and estimated detection limits for the H2 two-photon imaging are also presented.

Lempert, W.↗

NASA NTRSDate not supplied

P-ACTIVE (PCM-Based Actively Tunable Filter) Project at NASA

Phase change material (PCM)-based actively tunable mid-wave IR filters have broad imaging and sensing applications—from probing molecular vibrations in chemical species to detecting radiant thermal signatures. We introduce the Phase-change actively tunable filter (P-ACTIVE) project lead by NASA Langley Research Center with collaborators MIT and the University of Cambridge. It covers background science, experimental and theoretical device performance, as well as recent results obtained from a MISSE-14 mission for space qualification of active metasurface optics and constituent PCM. We conclude with a prospective view of the technology and discuss the potential for these filters to serve multiple NASA missions.

phase change material↗

NASA NTRS1993

Molecular-beam spectrum of the 970/cm Fermi triad of CF3CH3

A tunable MW-sideband CO2 laser is used with an electric-resonance optothermal spectrometer to investigate the IR spectrum of CF3CH3 near 970/cm. A Fermi-coupled triad of states is observed, resulting from the interactions of 2nu6+nu11 and nu5+nu12 with the fundamental vibration, nu10, which is assumed to carry the oscillator strength in this region. The high resolution (about 3 MHz) of the spectrometer allows the observation of tunneling splittings associated with the nu6 torsional vibration. These splittings are used to identify the torsional character of the states observed. At the normal-mode level the nu10 and nu5+nu12 states are found to be nearly degenerate and interacting by an anharmonic matrix element of about 3/cm. The present investigation illustrates the utility of using resolved torsional splittings to unravel complex vibrational couplings in molecules.

Fraser, G. T.↗