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At least 19 records

Deposition of Nanostructured Thin Film from Size-Classified Nanoparticles

Materials comprising nanometer-sized grains (approximately 1_50 nm) exhibit properties dramatically different from those of their homogeneous and uniform counterparts. These properties vary with size, shape, and composition of nanoscale grains. Thus, nanoparticles may be used as building blocks to engineer tailor-made artificial materials with desired properties, such as non-linear optical absorption, tunable light emission, charge-storage behavior, selective catalytic activity, and countless other characteristics. This bottom-up engineering approach requires exquisite control over nanoparticle size, shape, and composition. We describe the design and characterization of an aerosol system conceived for the deposition of size classified nanoparticles whose performance is consistent with these strict demands. A nanoparticle aerosol is generated by laser ablation and sorted according to size using a differential mobility analyzer. Nanoparticles within a chosen window of sizes (e.g., (8.0 plus or minus 0.6) nm) are deposited electrostatically on a surface forming a film of the desired material. The system allows the assembly and engineering of thin films using size-classified nanoparticles as building blocks.

Camata, Renato P.↗

Absorption Of Crushing Energy In Square Composite Tubes

Report describes investigation of crash-energy-absorbing capabilities of square-cross-section tubes of two matrix/fiber composite materials. Both graphite/epoxy and Kevlar/epoxy tubes crushed in progressive and stable manner. Ratio between width of cross section and thickness of wall determined to affect energy-absorption significantly. As ratio decreases, energy-absorption capability increases non-linearly. Useful in building energy-absorbing composite structures.

Farley, Gary L.↗

L(alpha)-induced two-photon absorption of visible light emitted from an O-type star by H2(+) ions located near the surface of the Stromgren sphere surrounding the star: A possible explanation for the diffuse interstellar absorption bands (DIDs)

In this paper, a new model is proposed to account for the DIB's (Diffuse Interstellar Bands). In this model, the DIB's result from a non-linear effect: resonantly-enhanced two-photon absorption of H(2+) ions located near the surface of the Stromgren sphere that surrounds an O- or B- type star. The strong light that is required to 'drive' the two-photon transition is provided by L(alpha) light emerging from the Stromgren sphere that bounds the H II region surrounding the star. A value of approximately 100 micro W/sq cm is estimated for the L(alpha) flux at the Stromgren radius, R(s), of a strong (O5) star. It is shown that a c.w. L(alpha) flux of this intensity should be sufficient to induce a few percent absorption for visible light radiated by the same star at a frequency (omega2) that completes an allowed two-photon transition, provided (1) the L(alpha) radiation happens to be nearly resonant with the frequency of a fully-allowed absorber transition that effectively represents the first step in the two-photon transition, and (2) an effective column density approximately 10(sup18)/sq cm of the absorber is present near the Stromgren sphere radius, R(sub s).

Glownia, James H.↗

Surface and Atmospheric Parameter Retrieval From AVIRIS Data: The Importance of Non-Linear Effects

AVIRIS data represent a new and important approach for the retrieval of atmospheric and surface parameters from optical remote sensing data. Not only as a test for future space systems, but also as an operational airborne remote sensing system, the development of algorithms to retrieve information from AVIRIS data is an important step to these new approaches and capabilities. Many things have been learned since AVIRIS became operational, and the successive technical improvements in the hardware and the more sophisticated calibration techniques employed have increased the quality of the data to the point of almost meeting optimum user requirements. However, the potential capabilities of imaging spectrometry over the standard multispectral techniques have still not been fully demonstrated. Reasons for this are the technical difficulties in handling the data, the critical aspect of calibration for advanced retrieval methods, and the lack of proper models with which to invert the measured AVIRIS radiances in all the spectral channels. To achieve the potential of imaging spectrometry, these issues must be addressed. In this paper, an algorithm to retrieve information about both atmospheric and surface parameters from AVIRIS data, by using model inversion techniques, is described. Emphasis is put on the derivation of the model itself as well as proper inversion techniques, robust to noise in the data and an inadequate ability of the model to describe natural variability in the data. The problem of non-linear effects is addressed, as it has been demonstrated to be a major source of error in the numerical values retrieved by more simple, linear-based approaches. Non-linear effects are especially critical for the retrieval of surface parameters where both scattering and absorption effects are coupled, as well as in the cases of significant multiple-scattering contributions. However, sophisticated modeling approaches can handle such non-linear effects, which are especially important over vegetated surfaces. All the data used in this study were acquired during the 1991 Multisensor Airborne Campaign (MAC-Europe), as part of the European Field Experiment on a Desertification-threatened Area (EFEDA), carried out in Spain in June-July 1991.

Green Robert O.↗

High Accuracy In-Flight Wavelength Calibration of Imaging Spectrometry Data

Accurate wavelength calibration of imaging spectrometer data is essential if proper atmospheric transmission corrections are to be made to obtain apparent surface reflectance. Accuracies of 0.1 nm are necessary for a 10 nm-sampling instrument in order to match the slopes of the deep atmospheric water vapor features that dominate the 0.7-2.3 micrometer regions. The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is calibrated in the laboratory to determine the wavelength position and full-width-half-maximum (FWHM) response for each of the 224 channels. The accuracies are limited by the quality of the monochromator used as a source. The accuracies vary from plus or minus to plus or minus 1.5 nm depending on the wavelength region, in general decreasing with increasing wavelength. Green et al. make corrections to the wavelength calibrations by using the known positions of 14 atmospheric absorption features throughout the 0.4-2.5 micrometer wavelength region. These features, having varying width and intensity, were matched to the MODTRAN model with a non-linear least squares fitting algorithm. A complete calibration was developed for all 224 channels by interpolation. Instrument calibration cannot be assumed to be stable to 0.1 nm over a flight season given the rigors of thermal cycling and launch and landing loads. The upcoming sensor HYDICE will require a means for in-flight spectral calibration of each scene because the calibration is both temperature and pressure sensitive. In addition, any sensor using a two-dimensional array has the potential for systematic wavelength shifts as a function of cross-track position, commonly called 'smile'. Therefore, a rapid means for calibrating complete images will be required. The following describes a method for determining instrument wavelength calibration using atmospheric absorption features that is efficient enough to be used for entire images on workstations. This study shows the effect of the surface reflectance on the calibration accuracy and the calibration history for the AVIRIS B spectrometer over the 1992 flight season.

Goetz, Alexander F. H.↗

Discussion of band selection and methodologies for the estimation of precipitable water vapour from AVIRIS data

An Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data set acquired over Canal Flats, B.C., on 14 Aug. 1990, was used for the purpose of developing methodologies for surface reflectance retrieval using the 5S atmospheric code. A scene of Rogers Dry Lake, California (23 Jul. 1990), acquired within three weeks of the Canal Flats scene, was used as a potential reference for radiometric calibration purposes and for comparison with other studies using primarily LOWTRAN7. Previous attempts at surface reflectance retrieval indicated that reflectance values in the gaseous absorption bands had the poorest accuracy. Modifications to 5S to use 1 nm step size, in order to make fuller use of the 20 cm(sup -1) resolution of the gaseous absorption data, resulted in some improvement in the accuracy of the retrieved surface reflectance. Estimates of precipitable water vapor using non-linear least squares regression and simple ratioing techniques such as the CIBR (Continuum Interpolated Band Ratio) technique or the narrow/wide technique, which relate ratios of combinations of bands to precipitable water vapor through calibration curves, were found to vary widely. The estimates depended on the bands used for the estimation; none provided entirely satisfactory surface reflectance curves.

Schanzer, Dena↗

Atmospheric Pre-Corrected Differential Absorption Techniques to Retrieve Columnar Water Vapor: Theory and Simulations

Two different approaches exist to retrieve columnar water vapor from imaging spectrometer data: (1) Differential absorption techniques based on: (a) Narrow-Wide (N/W) ratio between overlapping spectrally wide and narrow channels; (b) Continuum Interpolated Band Ratio (CIBR) between a measurement channel and the weighted sum of two reference channels. (2) Non-linear fitting techniques which are based on spectral radiative transfer calculations. The advantage of the first approach is computational speed and of the second, improved retrieval accuracy. Our goal was to improve the accuracy of the first technique using physics based on radiative transfer. Using a modified version of the Duntley equation, we derived an "Atmospheric Pre-corrected Differential Absorption" (APDA) technique and described an iterative scheme to retrieve water vapor on a pixel-by-pixel basis. Next we compared both, the CIBR and the APDA using the Duntley equation for MODTRAN3 computed irradiances, transmissions and path radiance (using the DISORT option). This simulation showed that the CIBR is very sensitive to reflectance effects and that the APDA performs much better. An extensive data set was created with the radiative transfer code 6S over 379 different ground reflectance spectra. The calculated relative water vapor error was reduced significantly for the APDA. The APDA technique had about 8% (vs. over 35% for the CIBR) of the 379 spectra with a relative water vapor error of greater than +5%. The APDA has been applied to 1991 and 1995 AVIRIS scenes which visually demonstrate the improvement over the CIBR technique.

Borel, Christoph C.↗

Near Simultaneous Spectroscopic and Polarimetric Observations of Be Stars

Near simultaneous optical spectroscopic (on four nights) and linear continuum (B, V, R and I bands) polarimetric (on seven nights) observations of 29 Be stars were carried out during November - December 1993. The program Be stars displayed wavelength dependence of intrinsic polarizations with no frequency dependence of position angles. Measured values of linear intrinsic polarizations of these Be stars were all less than 1.6%. The Be and Be-shell stars displayed no clear distinction in their polarization values. Observed polarizations at B, V, R and I bands were compared with the theoretically computed linear polarization values of the program stars. It has been suggested that these observed polarizations indicate that the envelopes of the Be stars may have a range of oblateness. Early-type Be stars displayed relatively higher polarizations than the late-type ones. Full widths at half intensity maximum of H(sub alpha) profiles and the intrinsic linear continuum polarizations are closely correlated with the projected rotational velocities of the program stars. Photospheric-absorption-corrected equivalent widths of H(sub alpha), profiles [W((alpha)] and the radii of H(sub alpha) emitting envelopes (R(sub e)) are non-linearly correlated with the intrinsic continuum polarizations of these stars. However, W((alpha) and R(sub e) are linearly correlated. Detail discussion of these results are presented in this paper.

Ghosh, K. K.↗

The Sun's Impact on Climate

We provide an overview of the impact of the Sun on the Earth atmosphere and climate system, focused on heating of Earth's atmosphere and oceans. We emphasize the importance of the spectral measurements of SIM and SOLSTICE- that we must know how solar variations are distributed over ultraviolet, visible, and infrared wavelengths, since these have separate characteristic influences on Earth's ozone layer, clouds, and upper layers of the oceans. Emphasis is also given to understanding both direct and indirect influences of the Sun on the Earth, which involve feedbacks between Earth's stratosphere, troposphere, and oceans, each with unique time scales, dynamics, chemistry, and biology, interacting non-linearly. Especially crucial is the role of all three phases of water on Earth, water vapor being the primary greenhouse gas in the atmosphere, the importance of trace gases such as CO2 arising from their absorption in the "water vapor window" at 800 - 1250/cm (12.5 to 8 microns). Melting of polar ice is one major response to the post-industrial global warming, enhanced due to "ice-albedo" feedback. Finally, water in liquid form has a major influence due to cloud albedo feedback, and also due to the oceans' absorption of solar radiation, particularly at visible wavelengths, through the visible "liquid water window" that allows penetration of visible light deep into the mixed layer, while nearby ultraviolet and infrared wavelengths do not penetrate past the upper centimeter ocean surface skin layer. A large fraction of solar energy absorbed by the oceans goes into the latent heat of evaporation. Thus the solar heating of the atmosphere-ocean system is strongly coupled through the water cycle of evaporation, cloud formation, precipitation, surface runoff and ice formation, to Earth's energy budget and climate, each different climate component responding to variations in different solar spectral bands, at ultraviolet, visible and infrared wavelengths.

Cahalan, Robert↗

Calculation of Nonequilibrium Radiation in the Flight Regimes of Aeroassisted Orbital Transfer Vehicles

A computer code has been developed that calculates radiative properties of nonequilibrium air in the low-density regimes expected during the flight of aeroassisted, orbital transfer vehicles. From the given nonequilibrium thermodynamic state variables, the code calculates number densities of internal states and the accompanying emission and absorption characteristics. In addition, the code calculates the number density of the hypothetical gas in radiative equilibrium that produces the same radiation emission as the given nonequilibrium gas. Sample results are shown to demonstrate how the code predicts the non-linear variation of radiation with density at low densities.

Park, Chul↗

Non-linear phenomena in films of solar arrays

The paper assesses nonlinear effects in films which are associated with the instability of their shape as a result of contractions during longitudinal and transverse in-plane oscillations. The following problems are solved analytically: transverse in-plane oscillations, longitudinal oscillations in films of rotating solar sail, transverse in-plane oscillations in films of a rotating solar sail, and effect of damping in films of a rotating solar sail. The reason for damping lies in the loss of kinetic energy during absorption of the film particles by root wrinkles without reflection (absolutely inelastic shock).

Zak, M.↗

Growth and characterization of binary and pseudo-binary 3-5 compounds exhibiting non-linear optical behavior. Undergraduate research opportunities in microgravity science and technology

In line with the specified objectives, a Bridgman-type growth configuration in which unavoidable end effects - conventionally leading to growth interface relocation - are compensated by commensurate input-power changes is developed; the growth rate on a microscale is predictable and unaffected by changes in heat transfer conditions. To permit quantitative characterization of the growth furnace cavity (hot-zone), a 3-D thermal field mapping technique, based on the thermal image, is being tested for temperatures up to 1100 C. Computational NIR absorption analysis was modified to now permit characterization of semi-insulating single crystals. Work on growth and characterization of bismuth-silicate was initiated. Growth of BSO (B12SiO20) for seed material by the Czochralski technique is currently in progress. Undergraduate research currently in progress includes: ground based measurements of the wetting behavior (contact angles) of semiconductor melts on substrates consisting of potential confinement materials for solidification experiments in a reduced gravity environment. Hardware modifications required for execution of the wetting experiments in a KC-135 facility are developed.

Witt, August F.↗

Near UV atmospheric absorption measurements from the DC-8 aircraft during the 1987 airborne Antarctic ozone experiment

During the Airborne Antarctic Ozone Experiment from 28 August to 30 September 1987 near UV zenith scattered sky measurements were made over Antarctic from the NASA DC-8 aircraft using a one third m spectrograph equipped with a diode-array detector. Scattered sky light data in the wavelength range 348 nm to 388 nm was spectrally analyzed for O3, NO2, OClO, and BrO column abundances. Slant column abudances of O3, NO2, OClO and BrO were determined, using a computer algorithm of non-linear and linear least square correlation of Antarctic scattered sky spectra to laboratory absorption cross section data. Using measured vertical electrochemical sonde ozone profiles from Palmer, Halley Bay, and the South Pole Stations the slant columns of O3 were converted into vertical column abundances. The vertical column amounts of NO2, OClO, and BrO were derived using vertical profiles calculated by a chemical model appropriate for Antarctica. NO2 vertical column abundances show steep latitudinal decrease with increasing latitude for all 13 flights carried out during the mission. In the regions where NO2 abudances are low, OClO and BrO were observed. The spatial and temporal vertical column abundances of these species are discussed in the context of the chemistry and dynamics in the antarctic polar vortex during the austral spring.

Wahner, A.↗

Multiwavelength Observations of Mkn 501 During the 1997 High State

During the observation period 1977, the close Blazar Mkn 501 showed extremely strong emission and high variability. We examine multiwavelength aspects of this event using Radio optical, soft and hard X-ray and TeV data. We concentrate on the medium-timescale variability of the broadband spectra averaged over 1-week intervals. We confirm the previously found correlation between soft and hard X-ray emission and the at TeV energies while the source shows only minor variability at radio and optical wavelengths. The non-linear correlation between hard X-ray and TeV fluxes is consistent with a simple analytic estimate based on an SSC model in which Klein-Nishina effects are important for the highest-energy electrons in the jet and flux; variations are caused by variations of the electron density and/or the spectral index of the electron injection spectrum. The time-averaged spectra are fitted with an SSC dominated leptonic jet model using the full Klein-Nishina cross section and following the self-consistent evolution of relativistic particles along the jet accounting for gamma gamma absorption and pair production within the source as well as due to the intergalactic infrared red background radiation. The contribution from external inverse-Compton scattering is tightly constrained by the low maximum EGRET flux and found co be negligible.

Petry, D.↗

Cepheid Calibration of the Peak Brightness of SNe Ia.: SN 1989B in NGC 3627 - 9

Repeated imaging observations have been made of NGC 3627 with the Hubble Space Telescope in 1997/98, over an interval of 58 days. Images were obtained on 12 epochs in the F555W band and on five epochs in the F8141,V band. The galaxy hosted the prototypical, "Branch normal", type la supernova SN 1989B. A total of 83 variables have been found, of which 68 are definite Cepheid variables with periods ranging from 75 days to 3.85 days. The de-reddened distance modulus is determined to be (m - M)(sub 0) = 30.22 +/- 0.12 (internal uncertainty) using a subset of the Cepheid data whose reddening and error parameters are secure. The photometric data of Wells et al. (1994), combined with the Cepheid data for NGC 3627 give MB(max) = -19.36 +/- 0.18 and M(sub V)(max) = -19.34 +/- 0.16 for SN 1989B. Combined with the previous six calibrations in this program, plus two additional calibrations determined by others gives the mean absolute magnitudes at maximum of (M(sub B)) = -19.48 +/- 0.07 for "Brunch normal" SNe Ia at this interim stage in the calibration program. Using the argument by Wells et al. (1994) that SN 1989B here is virtually identical in decay rate and colors at maximum with SN 198ON in NGC 1316 in the Fornax cluster, and that such identity means nearly identical absolute magnitude, it follows that the difference in the distance modulus of NGC 3627 and NGC 1316 is 1.62 +/- 0.03 mag. Thus the NGC 3627 modulus implies that (m - M)(sub 0) = 31.84 for NGC 1316. The second parameter correlations of M(max) of blue SNe la with decay rate, color at maximum, and Hubble type are re-investigated. The dependence of (M(max)) on decay rate is non-linear, showing a minimum for decay rates between 1.0 less than ADelta(sub m)15 less than 1.6. Magnitudes corrected for decay rate show no dependence on Hubble type, but a dependence on color remains. Correcting both the fiducial sample of 34 SNe la with decay-rate data and the current eight calibrating SNe la for the correlation with decay rate as well as color gives H(sub 0) = 60 +/- 2 (internal) km/s Mpc, in both B and V. The same value to within 4% is obtained if only the SNe la in spirals (without second parameter corrections) are considered. The correlation of SNe la color at maximum with M(max) cannot be due to internal absorption because the slope coefficients in B, V, and I with the change in magnitude are far from or even opposite to the canonical reddening values. The color effect must be intrinsic to the supernova physics. "Absorption" corrections of distant blue SNe la will lead to incorrect values of H(sub 0). The Cepheid distances used in this series are insensitive to metallicity differences. The zeropoint of the P-L relation is based on an assumed LMC modulus of (m - M)(sub 0) = 18.50. As this may have to be increased by 0(sup m).06 to 0(sup m).08, all distances in this paper will follow and Ho will decrease by 3 - 4%.

Saha, A.↗

Temperature dependence of Lorentz air-broadening and pressure-shift coefficients of (12)CH4 lines in the 2.3-micron spectral region

High-resolution (0.01/cm) absorption spectra of lean mixtures of CH4 in dry air were recorded with the McMath-Pierce Fourier transform spectrometer (FTS) of the National Solar Observatory on Kitt Peak at various temperatures between 24 and -61 C. The spectra have been analyzed to determine the values at room temperature of pressure-broadened widths and pressure-induced shifts of more than 740 transitions. The temperature dependence of air-broadened widths and pressure-induced shifts was deduced for approx. 370 transitions in the nu(sub 1) + nu(sub 4), nu(sub 3) + nu(sub 4), and nu(sub 2) + nu(sub 3) bands of (12)CH4 located between 4118 and 4615/cm. These results were obtained by analyzing a total of 29 spectra simultaneously using a multi-spectral non-linear least-squares fitting technique. This new technique allowed the determination of correlated spectral line parameters (e.g. intensity and broadening coefficient) better than the procedure of averaging values obtained by fitting the spectra individually. This method also provided a direct determination of the uncertainties in the retrieved parameters due to random errors. For each band analysed in this study the dependence of the various spectral line parameters upon the tetrahedral symmetry species and the rotational quantum numbers of the transitions is also presented.

Devi, V. Malathy↗

Experimental Study of Nonane and Nonane/Hexanol Fuel Droplet Combustion in Microgravity

In this presentation we review experiments carried out on nonane droplets, and a nonane/hexanol droplet, burning in microgravity to promote spherical symmetry. The nonane/hexanol combination was selected for the following reasons: 1) the spherically symmetric burning history of nonane and nonane/hexanol mixtures has not been previously studied; 2) measurements of the burning history of pure nonane droplets in air extend the existing data base of spherical droplet flames of soot-producing fuels which are useful for testing detailed chemical kinetic models of the spherically symmetric droplet burning process; 3) nonane and hexanol have almost identical boiling points so heterogeneous nucleation on a support fiber is unlikely; 4) hexanol does not have a strong propensity for water vapor absorption; 5) hexanol produces less soot than nonane so that mixtures of nonane and hexanol should show an effect of composition on soot formation. The far-field gas was atmospheric pressure air at room temperature. The evolution of droplet diameter was measured using high speed cine photography of spark-ignited droplets within a confined volume in a drop tower. The importance of soot formation during droplet combustion is derived from the fact that soot is the basic component of the particulate emission process that occurs in spray combustion. The complexity of soot formation motivates a one-dimensional transport condition which is advantageous for modeling. Recent numerical studies of droplet combustion have assumed spherical symmetry when incorporating such aspects as detailed chemistry and radiation, though soot formation itself has not yet been included in any droplet combustion modeling effort. If radiation is not important as would be the case for'small' droplets (i.e., droplets with initial diameters less than about ]mm), soot formation can lead to a nonlinear burning process and a time-varying burning rate, (non-linear burning of a non-sooting fuel like methanol is due to water vapor absorption on the droplet. The classical quasi-steady droplet burning theory predicts a linear evolution of droplet diameter in scaled coordinates for any fuel type.

Avedisian, C. T.↗

Linear operating region in the ozone dial photon counting system

Ozone is a relatively unstable molecule found in Earth's atmosphere. An ozone molecule is made up of three atoms of oxygen. Depending on where ozone resides, it can protect or harm life on Earth. High in the atmosphere, about 15 miles up, ozone acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. Without this shield, we would be more susceptible to skin cancer, cataracts, and impaired immune systems. Closer to Earth, in the air we breathe, ozone is a harmful pollutant that causes damage to lung tissue and plants. Since the early 1980's, airborne lidar systems have been used for making measurements of ozone. The differential absorption lidar (DIAL) technique is used in the remote measurement of O3. This system allows the O3 to be measured as function of the range in the atmosphere. Two frequency-doubled Nd:YAG lasers are used to pump tunable dye lasers. The lasers are operating at 289 nm for the DIAL on-line wavelength of O3, and the other one is operated at 300 nm for the off-line wavelength. The DIAL wavelengths are produced in sequential laser pulses with a time separation of 300 micro s. The backscattered laser energy is collected by telescopes and measured using photon counting systems. The photon counting system measures the light signal by making use of the photon nature of light. The output pulse from the Photo-Multiplier Tube (PE), caused by a photon striking the PMT photo-cathode, is amplified and passed to a pulse height discriminator. The peak value of the pulse is compared to a reference voltage (discrimination level). If the pulse amplitude exceeds the discrimination level, the discriminator generates a standard pulse which is counted by the digital counter. Non-linearity in the system is caused by the overlapping of pulses and the finite response time of the electronics. At low count rates one expects the system to register one event for each output pulse from the PMT corresponding to a photon incident upon the photocathode, however, at higher rates the limitations of the discrimination/counting system will cause the observed count rate to be non-linear with respect to the true count rate. Depending on the pulse height distribution and the discriminator level, the overlapping of pulses (pulse pile-up) can cause count loss or even an additional apparent count gain as the signal levels increase. Characterization of the system, including the pulse height distribution, the signal to noise ratio, and the effect of the discriminator threshold level, is critical in maximizing the linear operating region of the system, thus greatly increasing the useful dynamic range of the system.

Andrawis, Madeleine↗