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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Commissioning the H i Observing Mode of the Beam Former for the Cryogenically Cooled Focal L-band Array for the GBT (FLAG)

We present the results of commissioning observations for a new digital beam-forming back end for the Focal plane L-band Array for the Robert C. Byrd Green Bank Telescope (FLAG), a cryogenically cooled Phased Array Feed (PAF) with the lowest measured T {sub sys}/η of any PAF outfitted on a radio telescope to date. We describe the custom software used to apply beam-forming weights to the raw element covariances to create research-quality spectral-line images for the new fine-channel mode, study the stability of the beam weights over time, characterize FLAG’s sensitivity over a frequency range of 150 MHz, and compare the measured noise properties and observed distribution of neutral hydrogen emission from several extragalactic and Galactic sources with data obtained with the current single-pixel L-band receiver. These commissioning runs establish FLAG as the preeminent PAF receiver currently available for spectral-line observations on the world’s major radio telescopes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The impact of neglecting ice phase on cloud optical depth retrievals from AERONET cloud mode observations

Clouds present many challenges to climate modelling. To develop and verify the parameterisations needed to allow climate models to represent cloud structure and processes, there is a need for high-quality observations of cloud optical depth from locations around the world.Retrievals of cloud optical depth are obtainable from radiances measured by Aerosol Robotic Network (AERONET) radiometers in “cloud mode” using a two-wavelength retrieval method. However, the method is unable to detect cloud phase, and hence assumes that all of the cloud in a profile is liquid.This assumption has the potential to introduce errors into long-term statistics of retrieved optical depth for clouds that also contain ice.Using a set of idealised cloud profiles we find that, for optical depths above 20, the fractional error in retrieved optical depth is a linear function of the fraction of the optical depth that is due to the presence ofice cloud (“ice fraction”). Clouds that are entirely ice have positive errors with magnitudes of the order of 55 % to 70 %. We derive a simple linear equation that can be used as a correction at AERONET sites where ice fraction can be independently estimated. Using this linear equation, we estimate the magnitude of the error for a set of cloud profiles from five sites of the Atmospheric Radiation Measurement programme. The dataset contains separate retrievals of ice and liquid retrievals; hence ice fraction can be estimated. The magnitude of the error at each location was related to the relative frequencies of occurrence in thick frontal cloud at the mid-latitude sites and of deep convection at the tropical sites – that is, of deep cloud containing both ice and liquid particles. The long-term mean optical depth error at the five locations spans the range 2–4, which we show to be small enough to allow calculation of top-of-atmosphere flux to within 10 % and surface flux to about 15 %.

54 ENVIRONMENTAL SCIENCES↗

Lightning Characteristics Associated With Storm Modes Observed During RELAMPAGO

Global satellite studies show a maximum in deep convection and lightning downstream of the Andes in subtropical South America. The Remote sensing of Electrification, Lightning, And Mesoscale/microscale Processes with Adaptive Ground Observations (RELAMPAGO) field campaign was designed to investigate the physical processes that contribute to the rapid development of deep convection and mesoscale convective systems (MCSs) in Argentina. A lightning mapping array (LMA) was deployed to Argentina as part of RELAMPAGO to collect lightning observations from extreme storms in the region. This study combines lightning data from the LMA and the Geostationary Lightning Mapper onboard GOES-16 with 1-km gridded radar data to examine the electrical characteristics of a variety of convective storms throughout their life cycle observed during RELAMPAGO. Results from the full campaign show 48% of flashes are associated with deep convection that occurs along the eastern edge of the Sierras de Córdoba (SDC) overnight. These flashes are 65 km 2 smaller on average compared to stratiform flashes, which occur most frequently 50–100 km east of the SDC in the early morning hours, consistent with the upscale growth of MCSs off the terrain. Analysis of the 13–14 December MCS shows that sharp increases in flash rates correspond to deep and wide convective cores that have high graupel and hail mass, 35-dBZ volume, and ice water path. This work validates previous satellite studies of lightning in the region, but also provides higher spatial and temporal resolution information across the convective life cycle that has not been available in previous studies.

54 ENVIRONMENTAL SCIENCES↗

Asynchronous quadratic control for constrained hidden markov jump linear systems with incomplete MTPM and MOCPM

Abstract This paper investigates the quadratic optimal control problem for constrained Markov jump linear systems with incomplete mode transition probability matrix (MTPM). Considering original system mode is not accessible, observed mode is utilized for asynchronous controller design where mode observation conditional probability matrix (MOCPM), which characterizes the emission between original modes and observed modes is assumed to be partially known. An LMI optimization problem is formulated for such constrained hidden Markov jump linear systems with incomplete MTPM and MOCPM. Based on this, a feasible state-feedback controller can be designed with the application of free-connection weighting matrix method. The desired controller, dependent on observed mode, is an asynchronous one which can minimize the upper bound of quadratic cost and satisfy restrictions on system states and control variables. Furthermore, clustering observation where observed modes recast into several clusters, is explored for simplifying the computational complexity. Numerical examples are provided to illustrate the validity.

Zhu, Jin↗

Lattice dynamics and phase transition in CrI 3 single crystals

Here, the vibrational properties of CrI 3 single crystals were investigated using Raman spectroscopy and were analyzed with respect to the changes of the crystal structure. All but one mode are observed for both the low-temperature R¯3 and the high-temperature C2/m phase. For all observed modes the energies and symmetries are in good agreement with DFT calculations. The symmetry of a single layer was identified as p¯31/m . In contrast to previous studies we observe the transition from the R¯3 to the C2/m phase at 180 K and find no evidence for coexistence of both phases over a wide temperature range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

High-pressure behavior of a linear chain alkane, tricosane

Exploring the behavior of hydrocarbon under pressure is important for understanding its role in planetary sciences and also for exploring novel organic chemistry. In this study, we explored the high-pressure behavior of a linear-chain hydrocarbon, tricosane (C 23 H 48 ), using Raman spectroscopy. We compressed tricosane up to 23 GPa and did not find any evidence for pressure-induced amorphization within the conditions explored in this study. Upon compression, we observe new modes in the low energy region 100–300 cm -1 . In order to understand the appearance of these new modes at high pressures, we used complementary ab initio calculations and explored the effect of chain configurations (linear and bent) on the predicted Raman spectra. We find that these new modes observed at higher pressures are better explained by bent configuration of tricosane chains. Thus, based on high-pressure Raman spectra, it is very likely that a linear chain of tricosane is bent under pressure, i.e., it undergoes a pressure-induced trans-gauche transformation. Furthermore, it is likely that such bent regions (i.e., kinks) will act as sites along which large chain hydrocarbons could dissociate into smaller chain lengths at extreme conditions relevant to the interiors of Jovian planets.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lattice dynamics and phase transitions in Fe 3 - x GeTe 2

We present Raman spectroscopy measurements of the van der Waals bonded ferromagnet Fe 3-x GeTe 2 , together with lattice dynamics. Four out of eight Raman active modes are observed and assigned, in agreement with numerical calculations. The energies and linewidths of the observed modes display an unconventional temperature dependence at about 150 and 220 K, followed by the nonmonotonic evolution of the Raman continuum. Whereas the former can be related to the magnetic phase transition, the origin of the latter anomaly remains an open question.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Wave and Particle Analysis of Z-Mode and O-Mode Emission in the Jovian Inner Magnetosphere

We report some of the most intense Z-mode and O-mode observations obtained by the Juno spacecraft while in orbit about Jupiter in a low to mid-latitude region near the inner edge of the Io torus. We have been able to estimate the density of the plasma in this region based on the lower frequency cutoff of the observed Z-mode emission. The results are compatible with the electron density measurements of the Jovian Auroral Distributions Experiment (JADE), on board the Juno spacecraft, if we account for unmeasured cold plasma. Direction-finding measurements indicate that the Z- and O-mode emission have distinct source regions. We have also used the measured phase space density of the JADE and the Jupiter energetic particle detector instruments to calculate estimated local growth rates of the observed O-mode and Z-mode emission assuming a loss cone instability and quasilinear analysis. The results suggest the emissions were observed near, but not within, a source region, and the free energy source is consistent with a loss cone. We have thus carried out the quasilinear wave analysis of the assumed remote Z- and O-mode wave growths. It is shown that the remotely generated waves, propagated through an inhomogeneous medium to the satellite location, may account for the observed wave characteristics. The importance of Z-mode in accelerating electrons in the inner Jovian magnetosphere makes these new wave mode confirmations at Jupiter of particular interest.

79 ASTRONOMY AND ASTROPHYSICS↗

Observation of mode splitting in artificial spin ice: A comparative ferromagnetic resonance and Brillouin light scattering study

We report the dependence of the magnetization dynamics in a square artificial spin-ice lattice on the in-plane magnetic field angle. Using two complementary measurement techniques—broadband ferromagnetic resonance and micro-focused Brillouin light scattering spectroscopy—we systematically study the evolution of the lattice dynamics, for both a coherent radio frequency excitation and an incoherent thermal excitation of spin dynamics. We observe a splitting of modes facilitated by inter-element interactions that can be controlled by the external field angle and magnitude. Detailed time-dependent micromagnetic simulations reveal that the split modes are localized in different regions of the square network. Furthermore, this observation suggests that it is possible to disentangle modes with different spatial profiles by tuning the external field configuration.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Calibrated Radar Wind Profiler (RWP) Moments

The SGP Central Facility (C1) radar wind profiler (RWP) was calibrated using nearby surface disdrometer observations. Between 2011 and 2019, the SGP C1 RWP operated in two modes. The vertically pointing mode (named the precipitation mode) transmitted a short and long pulse length to have two different range resolutions and the beam-swinging mode (named the wind mode) transmitted one pulse length into three different beam directions. The precipitation-mode observations were available and calibrated from April 2011 through mid-August 2019. The wind-mode observations were available and calibrated between April 2014 and March 2019. The RWP spectra were processed to account for Nyquist velocity aliasing and coherent integration filtering effects before calculating the spectrum moments. During intense precipitation events, the calculated signal-to-noise ratio (SNR) is biased low due to signal power being distributed across the velocity spectrum such that some signal power is erroneously included in the noise level estimate, causing the noise level to be biased high. To correct for the low SNR bias, a new noise level is estimated using observations without precipitation and the SNR is increased accordingly. The adjusted SNR was converted to radar reflectivity factor and then calibrated against a nearby surface disdrometer. The calibration methodology is fully described in: Williams, CR, J Barrio, PE Johnston, P Muradyan, and S Giangrande. 2023. “Calibrating radar wind profiler reflectivity factor using surface disdrometer observations.” Atmospheric Measurement Techniques, https://egusphere.copernicus.org/preprints/2023/egusphere-2022-1405/

54 ENVIRONMENTAL SCIENCES↗

Explaining the extra crystal-field mode in 𝐴 ⁢Ce ⁢𝑋 2 (𝐴 = K, Rb, Na; 𝑋 = O, S, Se, Te)

A growing list of Ce-based magnets have shown an extra and heretofore unexplained crystal electric field (CEF) mode at high energies. We describe a process whereby an optical phonon can produce a split CEF mode well above the phonon energy. We use density functional theory and point-charge model calculations to estimate the phonon distortions and coupling to model this effect in KCeO 2 , showing that it accounts for the extra CEF mode observed. Furthermore, this mechanism is generic and may explain the extra modes observed on a variety of Ce 3+ compounds.

36 MATERIALS SCIENCE↗

Gasoline fuels properties for multi-mode operation – Observations in a GDI and the CFR engine

The combustion behavior of five full boiling range RON98 gasoline blends was evaluated for multi-mode operation in a GDI and the CFR octane rating engine. The GDI engine tests were conducted with stoichiometric air-fuel ratio in spark-ignition (SI), and with air-diluted homogeneous charge compression ignition (HCCI) mode. In the CFR engine, the knocking combustion was analyzed under standard RON testing conditions at both peak knocking lambda and stoichiometric air-fuel ratios, whereas compression ignited operation was characterized by utilizing the HCCI number test protocol. Disparate knock limited SI and HCCI combustion behavior was observed for the test fuels, despite four of the fuels having the same RON and octane sensitivity. It was found that knock-limited combustion phasing in the GDI engine did not align well with the RON. However, a detailed comparison of knock-limited SI operation in the GDI and CFR engine revealed that a more appropriate effective RON based on a common knock intensity metric (MAPO) and stoichiometric air-fuel ratio resulted in comparable knock characterization between the two engine platforms. Furthermore, the critical intake air temperature and the critical compression ratio were proposed to characterize knock-limited SI operation, while the minimum intake air heating and compression ratio were used to define a fuel's autoignition propensity for compression ignition operation in the GDI and CFR engine, respectively. Finally, each fuel's characteristic compression ratio needed to obtain knock-limited SI (KLSI) and HCCI operation was used to calculate an effective multi-mode octane number (MM-ON) based on the primary reference fuel blends.

33 ADVANCED PROPULSION SYSTEMS↗

Comparisons of the v11.1 Orbiting Carbon Observatory‐2 (OCO‐2) X CO2 Measurements With GGG2020 TCCON

The Orbiting Carbon Observatory 2 (OCO-2) is NASA's first Earth observation satellite mission dedicated to studying the sources and sinks of carbon dioxide (CO 2 ) on a global scale. The observations of reflected sunlight are inverted in a retrieval algorithm to produce estimates of the dry air mole-fractions of CO 2 (X CO2 ). The OCO-2 Level 2 data release, version 11.1 (v11.1) retrievals from the Atmospheric Carbon Observations from Space (ACOS) algorithm, includes significant improvements in the X CO2 data product compared to older OCO-2 data versions. This work compares the v11.1 X CO2 from OCO-2 against X CO2 estimates collected from a global ground-based network known as the Total Carbon Column Observing Network (TCCON), OCO-2's primary validation source. The OCO-2 project provides a version of the Level 2 data product, called “lite” files that include calibrated and bias-corrected XCO2 values, accessible together with all OCO-2 data products through the NASA Goddard Earth Sciences Data and Information Services Center (GES DISC). This work shows that OCO-2 X CO2 observations made between September 2014 and December 2023, after quality filtering and the application of an averaging kernel correction, agree well with coincident TCCON data for all OCO-2 observational modes of land (nadir, glint, target) and ocean (glint). The aggregated, bias-corrected, and quality-filtered absolute average bias values are less than or equal to 0.20 parts per million (ppm) globally for all OCO-2 observation modes, where the biases do not indicate a statistically significant time dependence. The land nadir/glint mode has the lowest bias value of −0.03 ± 0.85 ppm.

54 ENVIRONMENTAL SCIENCES↗

Orbit-following simulations of fast-ion transport and losses due to the Alfvén eigenmode burst in the Large Helical Device

Orbit-following simulations of fast-ion transport and losses with time-dependent electromagnetic perturbations are performed to clarify the roles of Alfvén eigenmodes (AEs) and the low-frequency magnetohydrodynamic (MHD) mode observed in the kinetic-MHD hybrid simulation of AE bursts in the Large Helical Device. Fast-ion pressure profile flattening in the kinetic-MHD hybrid simulation can be reproduced by an orbit-following simulation with only the primary single AE of the time-dependent amplitude following the kinetic-MHD hybrid simulation result, while orbit-following simulations with constant AE amplitude of average level during AE burst cannot reproduce the fast-ion pressure profile flattening observed. The effects of other modes are negligible on the fast-ion pressure profile flattening. The fast-ion losses in kinetic-MHD hybrid simulation can be reproduced by an orbit-following simulation with time-dependent amplitude when the low-frequency MHD mode is considered in addition to multiple AEs. This indicates the synergetic effect of multiple AEs and the low-frequency MHD mode on fast-ion losses.

Seki, Ryohsuke↗

Experiments on excitation of Alfvén eigenmodes by alpha-particles with bump-on-tail distribution in JET DTE2 plasmas

Dedicated experiments were performed in JET DTE2 plasmas for obtaining an α-particle bump-on-tail (BOT) distribution aiming at exciting Alfvén eigenmodes (AEs). Neutral beam injection-only heating with modulated power was used so that fusion-born α-particles were the only ions present in the MeV energy range in these DT plasmas. The beam power modulation on a time scale shorter than the α-particle slowing down time was chosen for modulating the α-particle source and thus sustaining a BOT in the α-particle distribution. High-frequency modes in the toroidicity-induced Alfven eigenmode (TAE) frequency range and multiple short-lived modes in a wider frequency range have been detected in these DT discharges with interferometry, soft x-ray cameras, and reflectometry. The modes observed were localised close to the magnetic axis and were not seen in the Mirnov coils. Analysis with the TRANSP and Fokker-Planck FIDIT codes confirms that α-particle distributions with BOT in energy were achieved during some time intervals in these discharges though no clear correlation was found between the times of the high-frequency mode excitation and the BOT time intervals. The combined magneto-hydrodynamic (MHD) and kinetic modelling studies show that the high-frequency mode in the TAE frequency range is best fitted with a TAE of toroidal mode number n= 9. This mode is driven mostly by the on-axis beam ions while the smaller drive due to the pressure gradient of α-particles allows overcoming the marginal stability and exciting the mode. The observed multiple short-lived modes in a wider frequency range are identified as the on-axis kinetic AEs predicted in Rosenbluth and Rutherford.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Emergent actin flows explain distinct modes of gliding motility

During host infection, Toxoplasma gondii and related unicellular parasites move using gliding, which differs fundamentally from other known mechanisms of eukaryotic cell motility. Gliding is thought to be powered by a thin layer of flowing filamentous (F)-actin sandwiched between the plasma membrane and a myosin-covered inner membrane complex. How this surface actin layer drives the various gliding modes observed in experiments—helical, circular, twirling and patch, pendulum or rolling—is unclear. Here we suggest that F-actin flows arise through self-organization and develop a continuum model of emergent F-actin flow within the confines provided by Toxoplasma geometry. In the presence of F-actin turnover, our model predicts the emergence of a steady-state mode in which actin transport is largely directed rearward. Removing F-actin turnover leads to actin patches that recirculate up and down the cell, which we observe experimentally for drug-stabilized actin bundles in live Toxoplasma gondii parasites. These distinct self-organized actin states can account for observed gliding modes, illustrating how different forms of gliding motility can emerge as an intrinsic consequence of the self-organizing properties of F-actin flow in a confined geometry.

59 BASIC BIOLOGICAL SCIENCES↗

Structures of glasses created by multiple kinetic arrests

X-ray scattering has been used to characterize glassy itraconazole (ITZ) prepared by cooling at different rates. Faster cooling produces ITZ glasses with lower (or zero) smectic order with more sinusoidal density modulation, larger molecular spacing, and shorter lateral correlation between the rod-like molecules. We find that each glass is characterized by not one, but two fictive temperatures T f (the temperature at which a chosen order parameter is frozen in the equilibrium liquid). The higher T f is associated with the regularity of smectic layers and lateral packing, while the lower T f with the molecular spacings between and within smectic layers. This indicates that different structural features are frozen on different timescales. The two timescales for ITZ correspond to its two relaxation modes observed by dielectric spectroscopy: the slower δ mode (end-over-end rotation) is associated with the freezing of the regularity of molecular packing and the faster α mode (rotation about the long axis) with the freezing of the spacing between molecules. Finally, our finding suggests a way to selectively control the structural features of glasses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantifying the agreement between observed and simulated extratropical modes of interannual variability

Using historical simulations of the Coupled Model Intercomparison Project-5 (CMIP5) and multiple observationally-based datasets, we employ skill metrics to analyze the fidelity of the simulated Northern Annular Mode, the North Atlantic Oscillation, the Pacific North America pattern, the Southern Annular Mode, the Pacific Decadal Oscillation, the North Pacific Oscillation, and the North Pacific Gyre Oscillation. We assess the benefits of a unified approach to evaluate these modes of variability, which we call the common basis function (CBF) approach, based on projecting model anomalies onto observed empirical orthogonal functions (EOFs). The CBF approach circumvents issues with conventional EOF analysis, eliminating, for example, corrections of arbitrarily assigned, but inconsistent, signs of the EOF’s/PC’s being compared. It also avoids the problem that sometimes the first observed EOF is more similar to a higher order model EOF, particularly if the simulated EOFs are not well separated. Compared to conventional EOF analysis of models, the CBF approach indicates that models compare significantly better with observations in terms of pattern correlation and root-mean-squared-error (RMSE) than heretofore suggested. In many cases, models are doing a credible job at capturing the observationally-based estimates of patterns; however, errors in simulated amplitudes can be large and more egregious than pattern errors. In the context of the broad distribution of errors in the CMIP5 ensemble, sensitivity tests demonstrate that our results are relatively insensitive to methodological considerations (CBF vs. conventional approach), observational uncertainties in pattern (as determined by using multiple datasets), and internal variability (when multiple realizations from the same model are compared). The skill metrics proposed in this study can provide a useful summary of the ability of models to reproduce the observed EOF patterns and amplitudes. Additionally, the skill metrics can be used as a tool to objectively highlight where potential model improvements might be made. Finally, we advocate more systematic and objective testing of simulated extratropical variability, especially during the non-dominant seasons of each mode, when many models are performing relatively poorly.

58 GEOSCIENCES↗