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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Combining TOPEX and SeaWinds Data to Refine Models for Ocean Surface Emissivity: Wind Vector Signatures at 18, 21 and 37 GHz

TOPEX Microwave Radiometer (TMR) brightness temperature observations at 18, 21, and 37 GHz have been collocated with near-simultaneous SeaWinds wind vector data as well as with a monthly SST climatological product. The combined data set allows us to study the dependence of ocean surface emissivity (at each frequency) upon both wind speed. Results show clear two-branch wind speed dependence; weak and linear below 6 m/s with an abrupt increase in sensitivity above that point. The analysis also shows that the zenith-directed ocean surface emissivity is polarization dependent above wind speeds of 5-6 m/s with an azimuthal variation related to the wind direction. This last result accords with recent polarimetric radiometer observations collected from aircraft. Implications of these observations to water vapor retrieval algorithms, nadir-viewing polarimetry, and ocean emission modeling will be discussed.

Vandemark, D.↗
NASA NTRSDate not supplied

A Reference Ocean Surface Emission and Backscatter Model from Microwaves to Infrared

Satellite observations are vital for the initialization of Numerical Weather Prediction models, and very important for climate monitoring and prediction, as well as other applications such as hydrology and flood awareness prediction. Knowledge of radiative contributions from the Earth's surface is needed to sound the lower troposphere from space. The lack of a reference quality ocean emission and backscatter model is a major gap in our ability to provide absolute calibration of the satellite based observing system. Uncertainty in emissivity models is not well characterized and different models are used for different spectral bands, for active and passive instruments. An International Space Science Institute (ISSI) team was put together [4] to address these issues. The objectives of the team are to provide a reference model as a community software (i.e., documented and freely available code), that is maintained and supported, has traceable uncertainty estimations, and that enables new science from microwaves to infrared with bidirectional reflectance distribution function (BRDF) capability. We will present the model and its various components, discussing the choices between various parameterizations, building on the LOCEAN model of [2]. The model predictions will be evaluated at various frequencies, including comparisons to radiometric observations by SMAP, AMSR2 and GMI (e.g., [5]). We will discuss early model evaluation in the infrared and for active microwave sensors. Areas of ongoing research include improving the foam parametrization (coverage and emissivity) to provide consistent performances across frequencies, building on [1], and the azimuthal dependence of the active and passive signals. The model will be used to generate training data for fast models e.g., Fastem, [3], that are used in operational data assimilation and climate re-analysis.

Emmanuel Dinnat↗
NASA NTRS2000

The Dependence of Ocean Surface Emissivity on Wind Vector as Measured with TMR

Global TMR brightness temperature observations at 18, 21, and 37 GHz have been colocated with near-simultaneous SeaWinds wind vector data as well as with a monthly SST climatological product. The combined data allow us to study the dependence of ocean surface emissivity, at each frequency, upon both wind speed and direction. Results show a clear two-branch wind speed dependence; weak and linear below 6 m/s with an abrupt increase in sensitivity above that point. Our analysis also shows that the nadir-view ocean surface emissivity depends on the angle between the wind direction and TMR's antenna polarization orientation.

Tran, N.↗
NASA NTRS2012

Ocean Surface Emissivity at L-band (1.4 GHz): The Dependence on Salinity and Roughness

A characterization of the emissivity of sea water at L-band is important for the remote sensing of sea surface salinity. Measurements of salinity are currently being made in the radio astronomy band at 1.413 GHz by ESA's Soil Moisture and Ocean Salinity (SMOS) mission and NASA's Aquarius instrument aboard the Aquarius/SAC-D observatory. The goal of both missions is accuracy on the order of 0.1 psu. This requires accurate knowledge of the dielectric constant of sea water as a function of salinity and temperature and also the effect of waves (roughness). The former determines the emissivity of an ideal (i.e. flat) surface and the later is the major source of error from predictions based on a flat surface. These two aspects of the problem of characterizing the emissivity are being addressed in the context of the Aquarius mission. First, laboratory measurements are being made of the dielectric constant of sea water. This is being done at the George Washington University using a resonant cavity. In this technique, sea water of known salinity and temperature is fed into the cavity along its axis through a narrow tube. The sea water changes the resonant frequency and Q of the cavity which, if the sample is small enough, can be related to the dielectric constant of the sample. An extensive set of measurements have been conducted at 1.413 GHz to develop a model for the real and imaginary part of the dielectric constant as a function of salinity and temperature. The results are compared to the predictions of models based on parameterization of the Debye resonance of the water molecule. The models and measurements are close; however, the differences are significant for remote sensing of salinity. This is especially true at low temperatures where the sensitivity to salinity is lowest.

LeVine, D. M.↗
NASA NTRS2024

Atmospheric CO 2 Emissions and Ocean Acidification From Bottom-Trawling

Trawling the seafloor can disturb carbon that took millennia to accumulate, but the fate of that carbon and its impact on climate and ecosystems remains unknown. Using satellite-inferred fishing events and carbon cycle models, we find that 55-60% of trawling-induced aqueous CO 2 is released to the atmosphere over 7-9 years. Using recent estimates of bottom trawling’s impact on sedimentary carbon, we found that between 1996-2020 trawling could have released, at the global scale, up to 0.34-0.37 Pg CO 2 yr -1 to the atmosphere, and locally altered water pH in some semi-enclosed and heavy trawled seas. Our results suggest that the management of bottom-trawling efforts could be an important climate solution.

climate mitigation↗
NASA NTRS2010

Finding the Missing Stratospheric Br(sub y): A Global Modeling Study of CHBr3 and CH2Br2

Recent in situ and satellite measurements suggest a contribution of ~5 pptv to stratospheric inorganic bromine from short-lived bromocarbons. We conduct a modeling study of the two most important short-lived bromocarbons, bromoform (CHBr3) and dibromomethane (CH2Br2), with the Goddard Earth Observing System Chemistry Climate Model (GEOS CCM) to account for this missing stratospheric bromine. We derive a "top-down" emission estimate of CHBr3 and CH2Br2 using airborne measurements in the Pacific and North American troposphere and lower stratosphere obtained during previous NASA aircraft campaigns. Our emission estimate suggests that to reproduce the observed concentrations in the free troposphere, a global oceanic emission of 425 Gg Br yr(exp -1) for CHBr3 and 57 Gg Br yr(exp -l) for CH2Br2 is needed, with 60% of emissions from open ocean and 40% from coastal regions. Although our simple emission scheme assumes no seasonal variations, the model reproduces the observed seasonal variations of the short-lived bromocarbons with high concentrations in winter and low concentrations in summer. This indicates that the seasonality of short-lived bromocarbons is largely due to seasonality in their chemical loss and transport. The inclusion of CHBr3 and CH2Br2 contributes ~5 pptv bromine throughout the stratosphere. Both the source gases and inorganic bromine produced from source gas degradation (Br~SLS) in the troposphere are transported into the stratosphere, and are equally important. Inorganic bromine accounts for half (2.5 pptv) of the bromine from the inclusion of CHBr3 and CHzBr2 near the tropical tropopause and its contribution rapidly increases to ~ 100% as altitude increases. More than 85% of the wet scavenging of Br(sub y)(sup VSLS) occurs in large-scale precipitation below 500 hPa. Our sensitivity study with wet scavenging in convective updrafts switched off suggests that Br(sub y)(sup SLS) in the stratosphere is not sensitive to convection. Convective scavenging only accounts for ~0.2 pptv (4%) difference in inorganic bromine delivered to the stratosphere.

Liang, Q.↗
NASA NTRS2021

On the effects of the ocean on atmospheric CFC-11 lifetimes and emissions

The ocean is a reservoir for CFC-11, a major ozone-depleting chemical. Anthropogenic production of CFC-11 dramatically decreased in the 1990s under the Montreal Protocol, which stipulated a global phase out of production by 2010. However, studies raise questions about current overall emission levels and indicate unexpected increases of CFC-11 emissions of about 10 Gg/yr after 2013 (based upon measured atmospheric concentrations and an assumed atmospheric lifetime). These findings heighten the need to understand processes that could affect the CFC-11 lifetime, including ocean fluxes. We evaluate how ocean uptake and release through 2300 affects CFC-11 lifetimes, emission estimates, and the long-term return of CFC-11 from the ocean reservoir. We show that ocean uptake yields a shorter total lifetime and larger inferred emission of atmospheric CFC-11 from 1930 to 2075 compared to estimates using only atmospheric processes. Ocean flux changes over time result in small but not completely negligible effects on the calculated unexpected emissions change (decreasing it by 0.4 ± 0.3 Gg/yr). Moreover, it is expected that the ocean will eventually become a source of CFC-11, increasing its total lifetime thereafter. Ocean outgassing should produce detectable increases in global atmospheric CFC-11 abundances by the mid-2100s, with emission of around 0.5 Gg/yr; this should not be confused with illicit production at that time. An illustrative model projection suggests that climate change is expected to make the ocean a weaker reservoir for CFC-11, advancing the detectable change in the global atmospheric mixing ratio by about 5 yr.

Anthropogenic production of CFC-11↗
NASA NTRS2021

Ozone Production and Precursor Emission from Wildfires in Africa

Tropospheric ozone (O3) negatively impacts human health and is also a greenhouse gas. It is formed photochemically by reactions of nitrogen oxides (NOx) and volatile organic compounds (VOCs), of which wildfires are an important source. This study presents data from research flights sampling wildfires in West and Central African savannah regions, both close to the fires and after the emissions had been transported several days over the tropical North Atlantic Ocean. Emission factors (EFs) in g kg-1 for NOx (as NO), six VOCs and formaldehyde were calculated from enhancement to mole fractions in data taken close to the fires. For NOx, the emission factor was calculated as 2.05±0.43 g kg-1 for Senegal and 1.20±0.28 g kg-1 for Uganda, both higher than the average value of 1.13±0.6 g kg-1 for previous studies of African savannah regions. For most VOCs (except acetylene), EFs in Uganda were lower by factors of 20-50% compared to Senegal, with almost all the values below those in the literature. O3 enhancement in the fire plumes was investigated by examining the ΔO3/ΔCO enhancement ratio, with values ranging from 0.07 - 0.14 close to the fires up to 0.25 for measurements taken over the Atlantic Ocean up to 200 hours downwind. In addition, measurements of O3 and its precursors were compared to the output of a global chemistry transport model (GEOS-CF) for the flights over the Atlantic Ocean. Normalised mean bias (NMB) comparison between the measured and modelled data was good outside of the fire plumes, with CO showing a model under-prediction of 4.6% and O3 a slight over-prediction of 0.7% (both within the standard deviation of the data). For NOx the agreement was poorer, with an under-prediction of 9.9% across all flights. Inside the fire plumes the agreement between modelled and measured values is worse, with the model being biased significantly lower for all three species. In total across all flights, there was an under-prediction of 29.4%, 16.5% and 37.5% for CO, O3 and NOx respectively. Finally, the measured ΔO3/ΔCO enhancement ratios were compared those in the model for the equivalent flight data, with the model showing a lower value of 0.17±0.03 compared to an observed value of 0.29±0.05. The results detailed here show that the O3 burden to the North Atlantic Ocean from African wildfires may be underestimated and that further study is required to better study the O3 precursor emissions and chemistry.

James D Lee↗
NASA NTRS2011

Methane and Environmental Change during the Paleocene-Eocene Thermal Maximum (PETM): Modeling the PETM Onset as a Two-stage Event

An atmospheric CH4 box model coupled to a global carbon cycle box model is used to constrain the carbon emission associated with the PETM and assess the role of CH4 during this event. A range of atmospheric and oceanic emission scenarios representing different amounts, rates, and isotopic signatures of emitted carbon are used to model the PETM onset. The first 3 kyr of the onset, a pre-isotope excursion stage, is simulated by the atmospheric release of 900 to 1100 Pg C CH4 with a delta C-13 of -22 to - 30 %. For a global average warming of 3 deg C, a release of CO2 to the ocean and CH4 to the atmosphere totalling 900 to 1400 Pg C, with a delta C-13 of -50 to -60%, simulates the subsequent 1 -kyr isotope excursion stage. To explain the observations, the carbon must have been released over at most 500 years. The first stage results cannot be associated with any known PETM hypothesis. However, the second stage results are consistent with a methane hydrate source. More than a single source of carbon is required to explain the PETM onset.

Carozza, David A.↗
NASA NTRS2013

Modeling and Evaluation of the Global Sea-Salt Aerosol Distribution: Sensitivity to Emission Schemes and Resolution Effects at Coastal/Orographic Sites

One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multi-scale chemical transport model NMMB/BSC-CTM. We compare 5 year global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD) from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1). Model results are highly sensitive to the introduction of sea-surface-temperature (SST)-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 teragrams per year to 8114 teragrams per year, lifetime varies between 7.3 hours and 11.3 hours, and the average column mass load is between 5.0 teragrams and 7.2 teragrams. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8 percent to +38.8 percent. Surface concentration is simulated with normalized biases ranging from minus 9.5 percent to plus 28 percent and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

Bias↗
NASA NTRS1991

Aircraft multifrequency passive microwave observations of light precipitation over the ocean

Aircraft passive microwave observations at 18, 37, 92, and 183 GHz of light oceanic precipitation are studied in conjunction with visible and infrared observations and ground-based radar data. Microwave signatures for clear, cloudy, and precipitating conditions are defined, with results in general agreement with previous theoretical results. Emission signatures are evident at 18, 37, and 92 GHz with clouds and precipitation producing an increase in brightness temperature over that observed over the low-emissivity ocean background. Polarization differences at 18 and 37 GHz also decrease in precipitation areas to minima of 30 K at 18 GHz and 15 K at 37 GHz. The 92-GHz brightness temperature shows a double-valued relationship, with an increase in cloudy and very lightly raining areas and a subsequent decrease for higher rain rates and deeper clouds where the ice scattering process becomes important. The 183-GHz observations display a distinct sensitivity to small amounts of ice. Simple channel differences are shown to compare favorably to the rain field, including polarization differences at 18 and 37 GHz and frequency differences between 92 and 37 GHz and between 183 and 92 GHz.

Adler, Robert F.↗
NASA NTRS1993

Carbon disulfide measurements in the atmosphere of the western North Atlantic and the northwestern South Atlantic Oceans

Carbon disulfide (CS2) measurements were made over the western and equatorial North Atlantic Ocean and the northwestern and equatorial South Atlantic Ocean. Carbon disulfide was in the range 0.4-50 pptrv in the atmosphere of the western North Atlantic Ocean. Emissions from anthropogenic sources and wet lands were found to be important although anthropogenic sources were 4-6 times larger than biogenic sources. The flux of CS2 from eastern North America between 30 and 39 deg latitude was estimated to be 2 x 10(exp 8)g/yr or sulfur. The anthropogenic contribution was 1.8 x 10(exp 8)g/yr of sulfur whereas the contribution of marshes was 0.2 x 10(exp 8)g/yr of sulfur. Sources of CS2 at high latitudes in the northern hemisphere were comparatively weak. Carbon disulfide levels in the western South Atlantic Ocean between -5 and 1 deg latitude were in the range 0.2-6 pptrv. Most of the CS2 appeared to come from biomass burning in Africa. Carbon disulfide was much higher close to shore suggesting that the South American continent was a significant source although too few data were available to quantify it. On ferry lights from Wallops, Virginia to Natal, Brazil, CS2 levels at the ferry altitude of about 6 km averaged 1.2 pptrv. This background CS2 was adequate to account for all the carbonyl sulfide (OCS) in the atmosphere.

Bandy, Alan R.↗
NASA NTRS2001

Background Maritime Aerosol: Their Optical Thickness and Scattering Properties

The effect of human induced change in the aerosol concentration and properties, or the aerosol response to climate change (e.g. droughts producing fires or dust) should be measured relative to a "background aerosol". How to define this background aerosol, so that it is both measurable and useful? Here we use 10 stations located in the Pacific, Atlantic and Indian Oceans to answer this question. Using a data set of the spectral optical thickness measured by the Aerosol Robotic network (AERONET), extending 1-3 years, we find the background conditions for these stations. The oceanic background aerosol is the result of ocean emission and spray, and some residual long lived continental aerosol. Its source is very broadly spread and is expected to vary little in time. Pollution or dust sources are from specific locations, emitted and transported to the measuring site in specific combination of meteorological conditions. Therefore they are expected to vary with time. It follows that the background aerosol can be identified as the median for conditions with small variations. To define the background we compute the median of N consequent measurements. We use N=50 that in average cloudy conditions corresponds to 2-3 days of measurements and N=100 (4-5 days). Most high polluted or dusty conditions correspond to data sequences with high standard deviation (greater than 0.02 in optical thickness) and are excluded. From the remaining N point running medians with low standard deviations we derive again the median. This excludes those rare cases of pollution or dust that is stable during the N measurements. The results show that the background aerosol over the Pacific Ocean is characterize by optical thickness of 0.055 at 500 nm and Angstrom exponent of 0.74. Over the Atlantic Ocean the values are 0.070 and 1.1 respectively, with little influence of the assumed value of N (50 or 100). The derivation of the background uses 20,000 and 5000 medians respectively that passed the criteria. The contribution of coarse and fine aerosol to the background aerosol is also calculated.

Kaufman, Yoram J.↗
NASA NTRS1980

Satellite remote sensing facility for oceanograhic applications

The project organization, design process, and construction of a Remote Sensing Facility at Scripps Institution of Oceanography at LaJolla, California are described. The facility is capable of receiving, processing, and displaying oceanographic data received from satellites. Data are primarily imaging data representing the multispectral ocean emissions and reflectances, and are accumulated during 8 to 10 minute satellite passes over the California coast. The most important feature of the facility is the reception and processing of satellite data in real time, allowing investigators to direct ships to areas of interest for on-site verifications and experiments.

Evans, R. H.↗
NASA NTRS2020

Missing OH Reactivity in the Global Marine Boundary Layer

The hydroxyl radical (OH) reacts with thousands of chemical species in the atmosphere, initiating their removal and the chemical reaction sequences that produce ozone, secondary aerosols, and gas-phase acids. OH reactivity, which is the inverse of OH lifetime,influences the OH abundance and the ability of OH to cleanse the atmosphere. The NASA Atmospheric Tomography (ATom) campaign used instruments on the NASA DC-8 aircraft to measure OH reactivity and more than 100 trace chemical species. ATom presented a unique opportunity to test the completeness of the OH reactivity calculated from the chemical species measurements by comparing it to the measured OH reactivity over two oceans across four seasons. Although, throughout much of the free troposphere, the calculated OH reactivity was below the limit-of-detection for the ATom instrument used to measure OH reactivity, the instrument was able to measure the OH reactivity in and just above the marine boundary layer. The mean measured value of OH reactivity in the marine boundary layer across all latitudes and all ATom deployments was 1.9 s-1, which is 0.5 s-1larger than the mean calculated OH reactivity. The missing OH reactivity, the difference between the measured and calculated OH reactivity, varied between 0 s-1to 3.5 s-1, with the highest values over the Northern Hemisphere Pacific Ocean. Correlations of missing OH reactivity with formaldehyde, dimethyl sulfide, butanal, and sea surface temperature suggest the presence of unmeasured or unknown volatile organic compounds or oxygenated volatile organic compounds associated with ocean emissions.

NASA Atmospheric Tomography (ATom)↗
NASA NTRS1978

The effect of wind on the microwave emission from the ocean's surface at 37 GHz

The microwave brightness temperature measurements from the Electrically Scanned Microwave Radiometer (frequency = 37 GHz) are compared with oceanic wind measurements from data buoys. It is shown that the brightness temperature can be manipulated to yield a measure of the surface roughening which can be very well accounted for by a simple geometric optics model. The data of 1.4, 8.36 and 19.34 GHz were similarly manipulated and shown to require a surface with less slope variance than predicted by optical measurements. It is also shown that the surface may be treated as isotropic to an accuracy equivalent to the roughening produced by a 2 m/s wind speed increment.

Wilheit, T. T.↗
NASA NTRS1979

A model for the microwave emissivity of the ocean's surface as a function of wind speed

A quanitative model is presented which describes the ocean surface as a ensemble of flat facets with a normal distribution of slopes. The variance of the slope distribution is linearly related to frequency up to 35 GHz and constant at higher frequencies. These facets are partially covered with an absorbing nonpolarized foam layer. Experimental evidence is presented for this model.

Wilheit, T. T.↗