Restructuring of Benzimidazole-Based Copper Complexes during Electrochemical CO 2 Reduction
Copper-based molecular catalysts have been widely used for the electrochemical reduction of carbon dioxide (ERCO 2 ). However, establishing a correlation between structure and catalytic performance has been challenging due to the dynamic nature of these materials under ERCO 2 working conditions. Here, we report on the restructuring of the copper complexes [Cu(bzimpy)Cl 2 ] and [Cu(pyrben) 2 (NO 3 )]NO 3 during ERCO 2 in an acidic medium, evidencing its effects on the observed activity, selectivity, and stability. In situ X-ray absorption spectroscopy (XAS) suggested that, at sufficiently negative potentials, the Cu 2+ centers of both complexes are reduced to undercoordinated Cu 0 species. Pb underpotential deposition of post-ERCO 2 samples indicated that such Cu 0 species also present a dominant contribution of the (100) domain, which is in line with the high Faradaic efficiency toward C 2 products (∼45%) shown by both complexes at −1.24 V vs RHE. By combining online electrochemical mass spectrometry, in situ XAS, electron paramagnetic resonance (EPR), and quantitative product analysis, we found that [Cu(bzimpy)Cl 2 ] exhibits a partially reversible restructuring, regenerating the main complex moiety, [Cu(bzimpy)] 2+ , and its geometry.