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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Predicting Cislunar Orbit Lifetimes from Initial Orbital Elements

The volume of space between Earth’s geosynchronous orbit out to the Moon’s sphere of influence, including the lunar Lagrange points, is crucial for the successful planning and execution of space missions, but not fully understood dynamically. This region is a part of cislunar space. Trajectories through cislunar space are influenced by the gravitational forces of the Sun, Earth, Moon, and other Solar System planets leading to typically unpredictable and chaotic trajectory behavior. It is therefore difficult to predict the stability of an trajectory through cislunar space from a set of initial conditions or orbital elements. We simulate one million cislunar orbits to train a self-organizing map (SOM) to cluster the trajectories and orbits into families based on how long they remain stable within the cislunar space. Using the trained SOM, we are able to predict the stable lifetime of a trajectory through cislunar space from a set of initial orbital elements to within an accuracy of 10% for 8% of simulated trajectories and within 50% for 43% of the simulated trajectories. Clustering in the SOM suggests that a variety of trajectory morphologies have similar lifetimes. Once trained, the SOM can predict the stable lifetime of a given cislunar trajectory within milliseconds. The methods developed in this work enable the rapid identification of stable cislunar orbits and trajectories that could be used for future space exploration. Moreover, the developed SOM method can generate orbital and trajectory lifetime estimates from minimal observational data, such as a single two line element, making it useful for early warning systems and large-scale sensor network operations.

79 ASTRONOMY AND ASTROPHYSICS↗

Simulations of Interacting Binary Systems—Pathways to Radio-bright Gamma-Ray Burst Progenitors

Although the association of gamma-ray bursts (GRBs) with massive stellar death is on firm footing, the nature of the progenitor system and the key ingredients required for a massive star to produce a GRB remain open questions. Here, we investigate the evolution of a 15–25M ⊙ massive star with a 10–15M ⊙ black hole (BH) using Modules for Experiments in Stellar Astrophysics. We quantify companion-influenced angular-momentum evolution over a stellar lifetime for orbital periods where tides are significant, varying stellar and BH masses, initial stellar spin, and accretion and dynamo prescriptions while tracking mass loss and angular momentum. The final spin is set by tidal torques versus stellar winds. For binaries that initially avoid Roche-lobe overflow, tides can spin up the star, but a late-stage expansion can drive tidal stripping; associated mass and angular-momentum loss can suppress spin-up. We find that massive-star BH binaries at comparable mass ratios may be potential GRB progenitors for short orbital periods (∼20–5 × 10 2 days) and long orbital periods (∼2 × 10 3 –4 × 10 3 days), where our suite of lifetime simulations reveals a favored parameter space with negligible mass loss and enough spin angular momentum to power a GRB jet. For initially nonrotating stars, this provides a lower limit on the final spin above a threshold estimate consistent with forming a postcollapse BH mass of 5–10M ⊙ with a spin parameter ≥ 0.5. For initially rapidly rotating stars, tidal interactions may sustain high spin when mass loss is negligible because the binary is not tidally synchronized.

Hernandez, Angel [Univ. of Colorado, Boulder, CO (↗

Spin switchable optical phenomena in Rashba band structures through intersystem crossing in momentum space in solution-processing 2D-superlattice perovskite film

Spin-switchable phenomena are a critical element for the development of spintronic and chiroptic devices. Herein we combine a 2D-superlattice perovskite (4,4-DFPD2PbI4) film with a ferromagnetic cobalt (Co) layer to form a multiferroic perovskite/Co interface, and demonstrate spin-switchable circularly polarized luminescence (CPL) between right-handed σ+ and left-handed σ− polarizations. When the ferromagnetic spins of Co at the Co/perovskite interface are altered between positive and negative magnetic field directions, the CPL from the 2D-superlattice perovskite switches from σ+ to σ− polarization. The magnetic field effects present a unique method to confirm that CPL is generated by the circular-orbital momentum of light-emitting excitons within Rashba band structures, eliminating artifacts involving structural birefringence. Our polarized neutron reflectometry measurements confirm a super long-range spin-orbit interaction occurring in the 2D-superlattice perovskite films. The temperature dependence of spin-switchable phenomenon indicates an extraordinarily long orbital polarization lifetime, reaching microseconds at room temperature and milliseconds at 5 K.

36 MATERIALS SCIENCE↗

Orbital stability analysis of hypothetical Earth-mass and Luna-mass moons in the Sagarmatha (HD 100777) star system

Abstract Six of the solar system planets have 150 confirmed moons (Earth—1, Mars—2, Jupiter—53, Saturn—53, Uranus—27, Neptune—14) and seven of them (Ganymede, Titan, Callisto, Io, the Moon, Europa, Triton) have masses >0.001 $M_\oplus$. However, no exomoons have yet been discovered despite the successful detection of ∼5000 exoplanets. We can infer, based on the solar system planets, that these exoplanets are capable of hosting one or more exomoons. In this paper, we study the possible existence of hypothetical Earth-mass and Luna-mass moons orbiting the Jupiter-mass planet, Laligurans (HD 100777b) in the Sagarmatha (HD 100777) star system by means of orbital stability. We apply long-term orbital integrations and the MEGNO (mean exponential growth of nearby orbits) chaos indicator to study the orbital stability of the moons and predict a phase-space region comprising periodic, chaotic, and unstable orbits. The phase spaces primarily constitute the moon's semimajor axis, which extends from the host planet's Roche radius to the Hill radius, and full range of eccentricity. Specific points are picked from three different regions of the MEGNO map and run as single-orbit integration for up to 10 billion periods of the innermost orbit. Furthermore, the lifetime and maximum eccentricity maps are generated from the direct integration to inspect the stable and unstable orbital configurations. The analyses of these maps, with the aid of time-series plots, show that both moons maintain stable orbits in the low-eccentricity regime and semimajor axis between the Roche limit and 28.4% of the Hill radius of the planet.

Gautam, Aayush (ORCID:0000000247257589)↗

DMFT Reveals the Non-Hermitian Topology and Fermi Arcs in Heavy-Fermion Systems

When a strongly correlated system supports well-defined quasiparticles, it allows for an elegant one-body effective description within the non-Hermitian topological theory. While the microscopic many-body Hamiltonian of a closed system remains Hermitian, the one-body quasiparticle Hamiltonian is non-Hermitian due to the finite quasiparticle lifetime. We use such a non-Hermitian description in the heavy-fermion two-dimensional systems with the momentum-dependent hybridization to reveal a fascinating phenomenon which can be directly probed by the spectroscopic measurements, the bulk “Fermi arcs.” Starting from a simple two-band model, we first combine the phenomenological approach with the perturbation theory to show the existence of the Fermi arcs and reveal their connection to the topological exceptional points, special points in the Brillouin zone where the Hamiltonian is nondiagonalizable. The appearance of such points necessarily requires that the electrons belonging to different orbitals have different lifetimes. This requirement is naturally satisfied in the heavy-fermion systems, where the itinerant c electrons experience much weaker interaction than the localized f electrons. We then utilize the dynamical mean field theory to numerically calculate the spectral function and confirm our findings. We show here that the concept of the exceptional points in the non-Hermitian quasiparticle Hamiltonians is a powerful tool for predicting new phenomena in strongly correlated electron systems.

36 MATERIALS SCIENCE↗

Three-body capture, ejection, and the demographics of bound objects in binary systems

ABSTRACT We study the capture of light objects of arbitrary velocity by binary systems. Extending results for the capture of comets in the Solar system, we develop a simple geometric characterization of the capture cross-section, leading directly to the distribution of orbital parameters of captured objects. We use the same framework to study the lifetimes of these bound orbits prior to ejection, and find that a simplified version of the Öpik–Arnold approach readily yields a closed-form estimate for the ejection rate that agrees well with numerical experiments. Without any detailed-balance assumptions, our results make manifest the characteristics of close encounters leading to capture and ejection. As an application of our results, we demonstrate the estimation of the equilibrium population of captured dark matter particles in a binary system.

79 ASTRONOMY AND ASTROPHYSICS↗

Planet-induced Vortices with Dust Coagulation in Protoplanetary Disks

In this work, we study how the dust coagulation/fragmentation will influence the evolution and observational appearances of vortices induced by a massive planet embedded in a low-viscosity disk by performing global 2D high-resolution hydrodynamical simulations. Within the vortex, due to its higher gas surface density and steeper pressure gradients, dust coagulation, fragmentation, and drift (to the vortex center) are all quite efficient, producing dust particles ranging from 1 μm to ~1.0 cm, as well as an overall high dust-to-gas ratio (above unity). In addition, the dust size distribution is quite nonuniform inside the vortex, with the mass-weighted average dust size at the vortex center (~4.0 mm) being a factor of ~10 larger than other vortex regions. Both large (~millimeter) and small (tens of microns) particles contribute strongly to affect the gas motion within the vortex. As such, we find that the inclusion of dust coagulation has a significant impact on the vortex lifetime and the typical vortex lifetime is about 1000 orbits. Furthermore, after the initial gaseous vortex is destroyed, the dust spreads into a ring with a few remaining smaller gaseous vortices with a high dust concentration and a large maximum size (~millimeter). At late time, the synthetic dust continuum images for the coagulation case show as a ring inlaid with several hot spots at the 1.33 mm band, while only distinct hot spots remain at 7.0 mm.

79 ASTRONOMY AND ASTROPHYSICS↗

Observation of large Rashba spin–orbit coupling at room temperature in compositionally engineered perovskite single crystals and application in high performance photodetectors

Indirect absorption extended below the direct transition edge and increase in carrier lifetime derived from Rashba spin–orbit coupling may advance the optoelectronic applications of metal halide perovskites. Spin-orbit coupling in halide perovskites is due to the presence of heavy elements in their structure. However, when these materials lack an inversion symmetry, for example by the application of strain, spin–orbit coupling becomes odd in the electron’s momentum giving rise to a splitting in the electronic energy bands. Here we report on the observation of a large Rashba splitting of 117 meV at room temperature, as predicted by relativistic first-principles calculations, in halide perovskite single crystals through a facile compositional engineering approach. Partial substitution of organic cations by rubidium in single crystals induces significant indirect absorption and dual peak photoluminescence as a result of a large Rashba splitting. We measured circularly polarized photoluminescence and magneto-photoluminescence in perovskite films printed by single crystals as well as magneto-electroluminescence and magneto-photocurrent in spin-LEDs based on perovskite single crystals. They indicated significant spin-momentum locking due to the large Rashba effect. A hybrid perovskite single crystal photodetector achieved record figures of merit, including detectivity of more than 1.3 × 10 18 Jones which represents a three orders of magnitude improvement compared to the to date record. Furthermore, these findings show that facile compositional engineering of perovskite single crystals holds great promise for further advancing the optoelectronic properties of existing materials.

36 MATERIALS SCIENCE↗

Accidental persistent spin textures in the proustite mineral family

Persistent spin textures (PSTs) in momentum space have the potential to enable spintronic devices which are currently limited by spin lifetimes in nonmagnetic spin-orbit coupled materials. We perform a first-principles study on the proustite mineral family, Ag 3 ⁢B⁢Q 3 (B = As, Sb; Q = S, Se), and show these chalcogenides exhibit nonsymmetry-protected PSTs, which we refer to as symmetry-assisted PSTs. Chemical substitution can be used to tune the PST quality and properties, e.g., spin lifetime, and we find that a Rashba anisotropy criterion correlates with the PST area and spin lifetime for two of the three proustites examined. Last, we show that a first-order effective SOC Hamiltonian, often used in two-dimensional systems, is insufficient to describe the PST state in all proustites, suggesting that higher order models are necessary to fully describe PSTs in bulk three-dimensional materials.

36 MATERIALS SCIENCE↗

Resolve instrument onboard the X-Ray Imaging and Spectroscopy Mission

We present an overview of the design and in-flight performance of the Resolve soft X-ray spectrometer on the X-Ray Imaging and Spectroscopy Mission that was successfully launched on September 7, 2023, on a JAXA H-IIA rocket from the Tanegashima Space Center of Japan. The instrument has a 36-pixel array of microcalorimeters, 35 of which are at the focus of a high-throughput grazing-incidence X-ray mirror. The instrument has achieved its required operational base temperature of 0.05 K and a spectral resolution of 4.5 eV (FWHM) at 6 keV. The cooling chain was designed to provide a lifetime of at least 3 years in orbit and operate with and without liquid helium to provide redundancy and the longest operational lifetime for the instrument. Early indications are that the cryogen lifetime may reach 6 years with a cryogen-free mode thereafter. A series of onboard X-ray calibration sources produces energy scale calibration lines simultaneously while observing celestial sources. The overall design and in-flight performance of Resolve are described.

Astronomy and AstroPhysics↗

Metal oxide barrier layers for terrestrial and space perovskite photovoltaics

Perovskite photovoltaics are attractive for both terrestrial and space applications. Although terrestrial conditions require durability against stressors such as moisture and partial shading, space poses different challenges: radiation, atomic oxygen, vacuum and high-temperature operation. Here we demonstrate a silicon oxide layer that hardens perovskite photovoltaics to critical space stressors. A 1-um-thick silicon oxide layer evaporated atop the device contacts blocks 0.05 MeV protons at fluences of 10 15 cm -2 without a loss in power conversion efficiency, which results in a device lifetime increase in low Earth orbit by x20 and in highly elliptical orbit by x30. Silicon-oxide-protected Cs 0.05 (MA 0.17 FA 0.83 ) 0.95 Pb(I 0.83 Br 0.17 ) 3 ) (MA, methylammonium; FA, formamidinium cation) and CsPbI 2 Br cells survive submergence in water and N,N-dimethylformamide. Furthermore, moisture tolerance of Sn-Pb and CsPbI 2 Br devices is boosted. Devices are also found to retain power conversion efficiencies on exposure to alpha irradiation and atomic oxygen. So, this barrier technology is a step towards lightweight packaging designs for both space and terrestrial applications.

14 SOLAR ENERGY↗

Systematic uncertainties in the measurement of the neutron lifetime using the Lunar Prospector neutron spectrometer

The lifetime of free neutrons measured in the laboratory has a longstanding disparity of ≈9 s. A space-based technique has recently been proposed to independently measure the neutron lifetime using interactions between the galactic cosmic rays and a low atmosphere planetary body. This technique has not produced competitive results yet due to constraints of nonoptimized data that contain large systematic errors. We use data from the neutron spectrometer on-board NASA's Lunar Prospector, and study two large systematics in the measurement of neutron lifetime: the lunar subsurface temperature and the lunar surface composition. We use the HeCd and HeSn neutron spectrometer data when the spacecraft was in a highly elliptical orbit during the orbit insertion period. We report the neutron lifetime using four different models that each have different choices of surface temperature and composition. The 5° [Prettyman et al ., J. Geophys. Res.: Planets 111, 2005JE002656 (2006)] and 2° [Wilson et al., Phys. Rev. C 104, 045501 (2021)] rebinned maps result in 777.6±11.7 s and 739.6±10.8 s, respectively. For the 20° map (Prettyman et al., 2006), constant equatorial and a latitude-dependent temperature model result in 738.6±10.8 s and 767.3±11.2 s, respectively. Increasing the complexities of the models accounting for the systematic effects increase the measured lifetime. However, the reported measurements are not competitive with the laboratory results due to large unaccounted systematics resulting from nonoptimized measurements and modeling assumptions. This work serves as a study of systematic uncertainties for future neutron lifetime measurements using the space-based technique. We estimate the effect on the lifetime from the choice of temperature model to be to be 28.7 ±15.5 s, and choice of compositional map (for 20° and 5° maps) to be 10.3 ±12.2 s.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Material erosion measurements and expected operational lifetime of a deployable photon sieve payload

Spacecraft operating in low-Earth orbit are subjected to a number of hazardous environmental constituents that can lead to decreased system performance and reduced operational lifetimes. Due to their thermal, optical, and mechanical properties, polymers are used extensively in space systems; however they are particularly susceptible to material erosion and degradation as a result of exposure to the LEO environment. The focus of this research is to examine the material erosion and mass loss experienced by a custom Kaptonlike polyimide due to exposure in a simulated low-earth orbit environment. The deployable membrane telescope design discussed in this research is named Peregrine and is the scientific payload for FalconSat-7, a 3U cubesat designed and developed at the United States Air Force Academy (USAFA) for the purpose of demonstrating the capability of deployable membrane telescope technology on a nanosatellite platform. In addition to the polymer samples, chrome, silver and gold specimens will be examined to measure the oxidation rate and act as a control specimen, respectively. A magnetically filtered atomic oxygen plasma source has previously been developed and characterized for the purpose of simulating the low-Earth orbit environment. The plasma source can be operated at a variety of discharge currents and gas flow rates, of which the plasma parameters downstream of the source are dependent. The characteristics of the generated plasma were examined as a function of these operating parameters to optimize the production of O + ions with energy relevant to LEO applications. The erosion yield of the Kapton-like polyimide was experimentally determined to be 2.84 x 10 -24 cm 3 per atom which is in close agreement when compared to the on-orbit measurement for reaction efficiency of Kapton HN. We report the experimentally determined reaction rate for the Kapton-like polyimide was used to estimate the operational lifetime of the photon sieve during the solar conditions expected beginning in May 2019. The effective lifetime is estimated between 126 and 153 days.

36 MATERIALS SCIENCE↗

Photoionization from the Xe 4d orbitals of XeF 2

Here, we present a comparison of the photoionization dynamics of the 4d shell of XeF 2 from threshold to 250 eV to those of the prototypical 4d shell of atomic Xe. The new experimental data include spin–orbit and ligand-field-resolved partial cross sections, photoelectron angular distributions, branching fractions, and lifetime widths for the 4d-hole states. The spin–orbit branching fractions and angular distributions are remarkably similar to the corresponding distributions from atomic Xe across a broad energy interval that includes both the intense shape resonance in the f continuum and a Cooper minimum in the same channel. The angular distributions and branching fractions are also in reasonably good agreement with our first-principles theoretical calculations on XeF 2 . Data are also presented on the lifetime widths of the substate-resolved 4d-hole states of XeF 2 . While the trends in the widths are similar to those in the earlier experimental and theoretical work, the linewidths are considerably smaller than in the previous measurements, which may require some reinterpretation of the decay mechanism. Finally, we present new data and an analysis of the Auger electron spectra for ionization above the 4d thresholds and resonant Auger spectra for several pre-edge features.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Chemical bonding and Born charge in 1T-HfS 2

We combine infrared absorption and Raman scattering spectroscopies to explore the properties of the heavy transition metal dichalcogenide 1T-HfS 2 . We employ the LO–TO splitting of the E u vibrational mode along with a reevaluation of mode mass, unit cell volume, and dielectric constant to reveal the Born effective charge. We find $Z$$^{*}_{B}$ = 5.3e, in excellent agreement with complementary first-principles calculations. In addition to resolving the controversy over the nature of chemical bonding in this system, we decompose Born charge into polarizability and local charge. We find α = 5.07 Å 3 and Z* = 5.2e, respectively. Polar displacement-induced charge transfer from sulfur p to hafnium d is responsible for the enhanced Born charge compared to the nominal 4+ in hafnium. 1T-HfS 2 is thus an ionic crystal with strong and dynamic covalent effects. Taken together, our work places the vibrational properties of 1T-HfS 2 on a firm foundation and opens the door to understanding the properties of tubes and sheets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Strain engineering a persistent spin helix with infinite spin lifetime

Persistent spin textures (PSTs) in solid-state materials arise from a unidirectional spin-orbit field in momentum space and offer a route to deliver long carrier spin lifetimes sought for future quantum microelectronic devices. Nonetheless, few three-dimensional materials are known to host PSTs owing to crystal symmetry and chemical requirements. There are even fewer examples demonstrated experimentally. Here we report that high-quality persistent spin textures can be obtained in the polar point groups containing an odd number of mirror operations. We use representation theory analysis and electronic structure calculations to formulate general discovery principles to identify PSTs hidden in known complex ternary layered and perovskite structures with large electric polarizations. We then show some of these materials exhibit PSTs without requiring any special crystalline symmetries. This finding removes the limitation imposed by mirror-symmetry protected PSTs that has limited compound discovery. Our general design approach enables the pursuit of persistent spin helices in materials exhibiting the C 3 v crystal class adopted by many quantum materials exhibiting large Rashba coefficients.

36 MATERIALS SCIENCE↗

Measuring autoionization decay lifetimes of optically forbidden inner valence excited states in neon atoms with attosecond noncollinear four-wave-mixing spectroscopy

Attosecond noncollinear four-wave-mixing spectroscopy with one attosecond extreme ultraviolet (XUV) pulse and two few-cycle near-infrared (NIR) pulses was used to measure the autoionization decay lifetimes of inner valence electronic excitations in neon atoms. After a 43-48-eV XUV photon excites a 2s electron into the 2s2p 6 (np) Rydberg series, broadband NIR pulses couple the 2s2p 6 3p XUV-bright state to neighboring 2s2p 6 3s and 2s2p 6 3d XUV-dark states. Controllable delays of one or both NIR pulses with respect to the attosecond XUV pulse reveal the temporal evolution of either the dark or bright states, respectively. Experimental lifetimes for the 3s, 3p, and 3d states are measured to be 7±2, 48±8, and 427±40 fs, respectively, with 95% confidence. Accompanying calculations with two independent ab initio theoretical methods, newstock and astra, verify the findings. The results support the expected trend that the autoionization lifetime should be longer for states that have a smaller penetration in the radial region of the 2s core hole, which in this case is for the higher angular momentum Rydberg orbitals. In conclusion, the underlying theory thus links the lifetime results to electron correlation and provides an assessment of the direct and exchange terms in the autoionization process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ultra-short-period Planets Are Stable against Tidal Inspiral

It has been unambiguously shown both in individual systems and at the population level that hot Jupiters experience tidal inspiral before the end of their host stars’ main-sequence lifetimes. Ultra-short-period (USP) planets have orbital periods P < 1 day, rocky compositions, and are expected to experience tidal decay on similar timescales to hot Jupiters if the efficiency of tidal dissipation inside their host stars parameterized as Q{sub ∗}{sup ′} is independent of P and/or secondary mass M {sub p}. Any difference between the two classes of systems would reveal that a model with constant Q{sub ∗}{sup ′} is insufficient. If USP planets experience tidal inspiral, then USP planet systems will be relatively young compared to similar stars without USP planets. Because it is a proxy for relative age, we calculate the Galactic velocity dispersions of USP planet candidate host and non-host stars using data from Gaia Data Release 2 supplemented with ground-based radial velocities. We find that main-sequence USP planet candidate host stars have kinematics consistent with similar stars in the Kepler field without observed USP planets. This indicates that USP planet hosts have similar ages to field stars and that USP planets do not experience tidal inspiral during the main-sequence lifetimes of their host stars. The survival of USP planets requires that Q{sub ∗}{sup ′} ≳ 10{sup 7} at P ≈ 0.7 day and M{sub p}≈2.6 M{sub ⊕}. This result demands that Q{sub ∗}{sup ′} depend on the orbital period and/or mass of the secondary in the range 0.5 day≲P≲5 days and 1 M{sub ⊕}≲M{sub p}≲1000 M{sub ⊕}.

79 ASTRONOMY AND ASTROPHYSICS↗