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Method to define minimum phase transfer function within bounded region of phase gain specifications at several discrete frequencies
Four-wave mixing (FWM) in gas-filled hollow-core capillaries, a nonlinear optical process that mixes signal and pump photon frequencies to generate idler frequency photons, offers a method for precise spectral phase transfer from signal to idler at ultrashort timescales and extreme powers. However, this regime is challenged by competing linear and nonlinear dynamics, leading to significant trade-offs between spectral phase transfer and conversion efficiency. Our computational investigation focuses on the upconversion of femtosecond pulses from the infrared (IR) to the ultraviolet (UV), a range notoriously difficult to manipulate. We explore an intermediate energy regime that strikes an optimal balance between FWM-mediated phase-transfer fidelity and nonlinear conversion efficiency. By adjusting the energy ratios and spectral phase profiles of the input signal, we achieve conversion efficiencies of approximately 5-15% while maintaining an effective quasi-linear spectral phase transfer. These findings will contribute to establishing first-principles and scaling laws essential for applications such as high-precision imaging, spectroscopy, quantum transduction, and distributed entangled interconnects, facilitating advanced control of ultrafast photonic and electronic wavepackets in quantum materials with unprecedented spatial and temporal precision.
Tributyl phosphate and N,N-di(2-ethylhexyl)isobutyramide (DEHiBA) are uranium-selective extractants that could be used to recover low-enriched uranium from commercial used nuclear fuel. The economic viability of liquid-liquid extraction processes for chemical separations depends on both thermodynamic and kinetic considerations. Here we used microfluidic droplet extraction to measure interfacial phase transfer rate constants for the extraction and stripping of Ce(IV), a non-radioactive actinide surrogate. The Damkohler numbers for each system were calculated and the phase transfer processes were determined to be diffusion-limited under all conditions, contrary to prior studies using constant interface stirred cells and single drop methods. A well-extracted 2:1 DEHiBA/Ce(IV) complex in the organic phase was determined from batch distribution studies, suggesting a different extraction mechanism for Ce(IV) compared with poorly extracted Pu(IV). Finally, phase disengagement rates were found to be rapid in both systems, in agreement with other studies.
A front-illuminated CCD of relative high quantum efficiency (QE) and high charge transfer efficiency (CTE) utilizes an open-phase region for receiving photons and two-phase gate regions (.phi..sub.1 and .phi..sub.2) for transferring electrons collected in one pixel to the next. The open-phase region is implanted with additional n-type elements (phosphorus) in order to increase the potential of the CCD channel in the open-phase region for collection of electrons and additionally implanted with concentrated and very shallow p-type elements (boron) to pin the surface of the n-channel in the open-phase region to OV, while gate region .phi..sub.1 and .phi..sub.2 are biased to -3.5V and driven to +10V by a two-phase transfer clock. The open pinned-phase (OPP) region thus permits two-phase transfer clocking and optimum reception of photons during the integration periods between transfer clock pulses.
Abstract Localized high‐concentration electrolytes (LHCEs) have attracted interest in alkali metal batteries due to the advantages of forming stable solid‐electrolyte interphases (SEIs) on anodes and good chemical/electrochemical stability. Herein, a new degradation mechanism is revealed for ether‐based LHCEs that questions their compatibility with alkali metal anodes (Li, Na, and K). Specifically, the ether solvent reacts with alkali metals to generate solvated electrons (e s − ) that attack hydrofluoroether co‐solvents to form a series of byproducts. The ether solvent essentially acts as a phase‐transfer reagent that continuously transfers electrons from solid‐phase metals into the solution phase, thus inhibiting the formation of stable SEI and leading to continuous alkali metal corrosion. Switching to an ester‐based solvating solvent or intercalation anodes such as graphite or molybdenum disulfide has been shown to avoid such a degradation mechanism due to the absence of e s − .
Abstract Localized high‐concentration electrolytes (LHCEs) have attracted interest in alkali metal batteries due to the advantages of forming stable solid‐electrolyte interphases (SEIs) on anodes and good chemical/electrochemical stability. Herein, a new degradation mechanism is revealed for ether‐based LHCEs that questions their compatibility with alkali metal anodes (Li, Na, and K). Specifically, the ether solvent reacts with alkali metals to generate solvated electrons (e s − ) that attack hydrofluoroether co‐solvents to form a series of byproducts. The ether solvent essentially acts as a phase‐transfer reagent that continuously transfers electrons from solid‐phase metals into the solution phase, thus inhibiting the formation of stable SEI and leading to continuous alkali metal corrosion. Switching to an ester‐based solvating solvent or intercalation anodes such as graphite or molybdenum disulfide has been shown to avoid such a degradation mechanism due to the absence of e s − .
A new DSN RF system is being developed that transmits at X-band and receive at both X-band and S-band. End-to-end tests are planned to measure the phase stability of this system. Equations for the phase transfer functions between the error sources in the system and the X-band and S-band Doppler extractor outputs are derived. This analysis considers both test modes, using a test translator, and actual spacecraft tracking where the spacecraft is at some distance from the DSN station. The results indicate that the proposed end-to-end tests will not accurately reflect the error that occurs during actual spacecraft tracking.
An alternative to having a primary frequency standard on board a spacecraft is to phase lock a simple oscillator on the spacecraft to a microwave tone transimitted from the ground.
An alternative to having a primary frequency standard on board a spacecraft is to phase lock a simple oscillator on the spacecraft to a microwave tone transmitted from the ground. The received tone is transponded and rebroadcast to the ground. The round trip phase is measured, and used to correct for effects on time scales longer than the round trip light travel time. This method is used with the TDRSS relay satellites, and will be used for the Japanese space VLBI mission VSOP. There are several sources of error introduced by this process. The most important error source is a loss of the on board standard for all times that the satellite is out of contact with a ground tracking station. The fractional loss will be greater than 10% for almost any orbit, even with a network of several ground tracking stations, and it will be considerably worse for a low earth orbit. Only a geostationary orbit can eliminate this problem. Another error source is connected to the previous one. Round trip phase tracking can remove, after the fact, link effects during a tracking pass on time scales greater than the round trip light travel time. However, there will be a jump in the spacecraft clock when multiple passes are connected (e.g. when the spacecraft is reacquired after passing out of sight). These jumps will be equal in magnitude (except for a geometrical factor) to the accuracy with which the spacecraft orbit is known. With a GPS receiver and GPS-like beacon on a spacecraft, the orbit can be known to a few cm, giving timing jumps on the order of 100 picoseconds. Even with a geostationary orbit, these jumps would occur any time the link was interrupted due to mechanical or electrical problems.
NASA Special Level POD demonstration tests are typically performed on flat plates of a single material containing fatigue cracks with aspect rations between 0.3 and 0.5. In many cases, the inspectors that pass the demonstration tests use (transfer) the NDE technique to inspect different materials and part geometries and for varying types of flaws. The objective of the task is to investigate several of the factors that may influence the transferability of POD demonstration tests. An existing set of 30 6061-T6 aluminum crack panels will be used to create parts with a square tube and pocket type geometries. These same aluminum crack panels were used in a study of the effect of penetrant sensitivity level on POD. Hence, we should be able to directly compare the POD for flat panels versus larger parts with more complex geometries.
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Phase change paint tests of a Rockwell International .00593-scale space shuttle orbiter were conducted in the Langley Research Center's Variable Density Wind Tunnel. The test objectives were to determine the effects of various wing/underbody configurations on the aerodynamic heating rates and boundary layer transition during simulated entry conditions. Several models were constructed. Each varied from the other in either wing cuff radius, airfoil thickness, or wing-fuselage underbody blending. Two ventral fins were glued to the fuselage underside of one model to test the interference heating effects. Simulated Mach 8 entry data were obtained for each configuration at angles of attack ranging from 25 to 40 deg, and a Reynolds number variation of one million to eight million. Elevon, bodyflap, and rudder flare deflections were tested. Oil flow visualization and Schlieren photographs were obtained to aid in reducing the phase change paint data as well as to observe the flow patterns peculiar to each configuration.
Tests were conducted in a hypersonic wind tunnel using various truncated space shuttle orbiter configurations in an attempt to establish the optimum model size for other tests examining body shock-wing leading edge interference effects. The tests were conducted at Mach number 8 using the phase change paint technique. A test description, tabulated data, and tracings of isotherms made from photographs taken during the test are presented.
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A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes a plurality of independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.
A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes several independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.
Direct numerical simulations of fluid flow, heat transfer, and phase changes are presented. The simulations are made possible by a recently developed finite difference/front tracking method based on the one-field formulation of the governing equations where a single set of conservation equations is written for all the phases involved. The conservation equations are solved on a fixed rectangular grid, but the phase boundaries are kept sharp by tracking them explicitly by a moving grid of lower dimension. The method is discussed and applications to boiling heat transfer and the solidification of drops colliding with a wall are shown.
The Two-phase Heat Transfer International Topical Team consists of researchers and members from various space agencies including ESA, JAXA, CSA, and RSA. This presentation included descriptions various fluid experiments either being conducted by or planned by NASA for the International Space Station in the areas of two-phase flow, flow boiling, capillary flow, and crygenic fluid storage.