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Effects of Al:Si and (Al + Na):Si ratios on the properties of the international simple glass, part I: Physical properties
Understanding composition-structure-property relationships of high-alumina nuclear waste glasses are important for vitrification of nuclear waste at the Hanford Site. Two series of glasses were designed, one with varying Al:Si ratios and the other with (Al+Na):Si ratios based on the International Simple Glass (ISG, a simplified nuclear waste model glass), with Al2O3 ranging from 0 to 23 mol % (0 to 32 wt. %). The glasses were synthesized and characterized using electron probe microanalysis, X-ray photoelectron spectroscopy, small angle X-ray scattering, high temperature oxide melt solution calorimetry, and infrared spectroscopy. Glasses were crystal free, and the lowest Na2O and Al2O3 glass formed an immiscible glass phase. Evolution of various properties - glass transition temperature, percentage of 4-coordinated B, enthalpy of glass formation - and infrared spectroscopy results indicate that structural effects differ based on the glass series.
On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB6 Single Crystals
Abstract not provided
Synthesis and Physical Properties of Phase-Engineered Transition Metal Dichalcogenide Monolayer Heterostructures
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Remotely sensed physical property estimation from powder contaminated surfaces
It is the intent of this paper to demonstrate the veracity of a method to estimate the total solid contaminant mass present on a sparsely coated surface encompassing a pixel from longwave infrared spectra. Sparsely coated surfaces create complex radiometry due to the interactions of electromagnetic energy between intimate materials. Current algorithms can be used on intimate mixtures to identify the abundances of materials in a pixel, but they cannot provide additional property information. Radiative transfer models can create mixture signatures, but only with a set of well-characterized physical parameters that are typically not known or are difficult to retrieve. Finally, the approach described here creates a parameter inversion model from a radiative transfer model and uses empirically measured mixture data to retrieve physical characteristics of the contaminated surface and derive a total contaminant mass present.
Doping effect on the physical properties of Ca 10 Pt 3 As 8 (Fe 2 As 2 ) 5 single crystals
Ca 10 Pt 3 As 8 (Fe 2 As 2 ) 5 is a unique parent compound for superconductivity, which consists of both semiconducting Pt 3 As 8 and metallic FeAs layers. We report the observation of superconductivity induced via chemical doping in either Ca site using rare-earth (RE) elements (RE = La, Gd) or Fe site using Pt. The interlayer distance and the normal-state physical properties of the doped system change correspondingly. The coupled changes include (1) superconducting transition temperature T c increases with increasing both doping concentration and interlayer distance, (2) our T c value is higher than previously reported maximum value for Pt doping in the Fe site, (3) both the normal-state in-plane resistivity and out-of-plane resistivity change from non-metallic to metallic behavior with increasing doping concentration and T c , and (4) the transverse in-plane magnetoresistance (MR ab ) changes from linear-field dependence to quadratic behavior upon increasing T c . For La-doped compound with the highest T c (~35 K), upper critical fields ($H_{c2}^{ab} , H_{c2}^c$), coherence lengths (ξ ab , ξ c ), and in-plane penetration depth (λ ab ) are estimated. Finally, we discuss the relationship between chemical doping, interlayer distance, and physical properties in this system.
Precursor routes to quaternary intermetallics: Synthesis, crystal structure, and physical properties of clathrate-II Cs{sub 8}Na{sub 16}Al{sub 24}Si{sub 112}
A new quaternary clathrate–II composition, Cs{sub 8}Na{sub 16}Al{sub 24}Si{sub 112}, was synthesized by kinetically controlled thermal decomposition (KCTD) employing both NaSi and NaAlSi as the precursors and CsCl as a reactive flux. The crystal structure and composition of Cs{sub 8}Na{sub 16}Al{sub 24}Si{sub 112} were investigated using both Rietveld refinement and elemental analysis, and the temperature dependent transport properties were investigated. Our results indicate that KCTD with multiple precursors is an effective method for the synthesis of multinary inorganic phases that are not easily accessible by traditional solid-state synthesis or crystal growth techniques. - Graphical abstract: Quaternary Cs{sub 8}Na{sub 16}Al{sub 24}S{sub 112} clathrate–II was synthesized for the first time by kinetically controlled thermal decomposition (KCTD) employing a NaSi+NaAlSi precursor mixture with CsCl as the reactive flux, and the structural and transport properties were investigated. Our approach demonstrates a new synthetic pathway for the synthesis of multinary inorganic compounds. This work reports the exploration of a new clathrate composition as this class of materials continues to be of interest for thermoelectrics and other energy-related applications.
Operando analysis of the molten Li|LLZO interface: Understanding how the physical properties of Li affect the critical current density
Not Available
Minimal Impacts of Microplastics on Soil Physical Properties under Environmentally Relevant Concentrations
Agricultural soils are a major reservoir of microplastics, and concerns have arisen about the impacts of microplastics on soil properties and functioning. In this report we measured the physical properties of a silt loam in response to the incorporation of polyester fibers and polypropylene granules over a wide range of concentrations. We further elucidated the underlying mechanisms through determining the role of microplastic shape and the baseline effects from the amendment of soil particles. The incorporation of microplastics into soil tended to increase contact angle and saturated hydraulic conductivity, decrease bulk density and water holding capacity, while did not affect aggregate stability. Polyester fibers affected soil physical properties more profoundly than polypropylene granules, due to the vastly different shape of fibers from that of soil particles. However, changes in soil properties were gradual, and significant changes did not occur until a high concentration of microplastics was reached (i.e., 0.5% w/w for polyester fibers and 2% w/w for polypropylene granules). Currently, microplastic concentrations in soils not heavily polluted with plastics are far below these concentrations, and results from this study suggest that microplastics at environmentally relevant concentrations have no significant effects on soil physical properties.
Evaluation of Hanford 200 West Area Tank Farms (241-S/241-SX-/241-U tank farms) Physical Properties Data for Use in Development of West Area Tank Treatment (WATT) Processing
With the recent acceptance of West Area Tank Treatment disposition alternative for 200 West Area tanks at the Hanford Site by the State of Washington and the U.S. Department of Energy, a review was initiated to identify the physical properties data available in the literature for the Hanford 241-S, 241-SX, and 241-U tank farms. The literature reviewed indicated that there is a relatively small set of useful data on physical properties of 200 West Area tanks, and the data that do exist are biased around a narrow range of tank samples. Much of the testing between the 1990s and mid-2010s was intended to support either enhanced sludge washing or feed delivery to the Pretreatment Facility at the Hanford Waste Treatment and Immobilization Plant. As such, some physical properties of 200 West Area samples were measured under conditions that are no longer relevant. Because of the distinctly different nature of many past processes at the 200 West Area compared to the 200 East Area, insight from waste testing in the 200 East Area waste should be used with caution, as there may be significantly different qualities in the physical properties data between these two areas (both in situ and as measured in laboratory analyses). Based on this assessment, there is a need to collect additional physical property data to support planning for 200 West Area retrievals.
Atomic Absorption Line Diagnostics for the Physical Properties of Red Supergiants
Red supergiants (RSGs) are evolved massive stars that represent extremes, in both their physical sizes and their cool temperatures, of the massive star population. The effective temperature (T {sub eff}) is the most critical physical property needed to place an RSG on the Hertzsprung–Russell Diagram, due to the stars’ cool temperatures and resulting large bolometric corrections. Several recent papers have examined the potential utility of atomic line equivalent widths (EWs) in cool supergiant (CSG) spectra for determining T {sub eff} and other physical properties and found strong correlations between Ti i and Fe i spectral features and T {sub eff} in earlier-type CSGs (G and early K) but poor correlations in M-type stars, a spectral subtype that makes up a significant fraction of RSGs. We have extended this work by measuring the EWs of Ti, Fe, and Ca lines in late K- and M-type RSGs in the Milky Way, Large Magellanic Cloud, and Small Magellanic Cloud, and compared these results to the predictions of the theoretical stellar LTE atmosphere models (MARCS) stellar atmosphere models. Our analyses show a poor correlation between T {sub eff} and the Fe i and Ti i lines in our observations (at odds with strong correlations predicted by stellar atmosphere models), but do find statistically significant correlations between T {sub eff} and the Ca ii triplet (CaT) features of Milky Way RSGs, suggesting that this could be a potential diagnostic tool for determining T {sub eff} in M-type supergiants. We also examine correlations between these spectral features and other physical properties of RSGs (including metallicity, surface gravity, and bolometric magnitude), and consider the underlying physics driving the evolution of atomic line spectra in RSGs.
Hybrid Organic Inorganic Perovskites: Physical Properties and Applications (in 4 Volumes)
This four-volume handbook gives a state-of-the-art overview of hybrid organic inorganic perovskites, both two dimensional (2D) and three dimensional (3D), from synthesis and characterization and simulation to optoelectronic devices (such as solar cells and light emitting diodes), spintronics devices and catalysis application. The editors, coming from academia and national laboratory, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 30 expert authors in 21 chapters, they construct the story of hybrid perovskite structural and optical properties, electronic and spintronic response, laser action, and catalysis from varied viewpoints: materials science, chemical engineering, and energy engineering. The four volumes are arranged according to the focus material properties. Volume 1 is focused on the material physical properties including structure, deposition characteristic and the structure of the electronic bands and excitons of these compounds. Volume 2 covers the hybrid perovskite optical properties including the ultrafast optical response, photoluminescence and laser action. Volume 3 contains the spin response of these compounds including application such as spin valves, photogalvanic effect, and magnetic response of light emitting diodes and solar cell devices. Finally, and highly relevant to tomorrow's energy challenges, volume 4 is focused on the physics and device properties of the most relevant applications of the hybrid perovskites, namely photovoltaic solar cells. The text contains many high-quality colorful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with the hybrid organic inorganic perovskites.
Effects of Recovery Conditions and Aggregation Mechanisms on the Chemical and Physical Properties of Hybrid Poplar and Corn Stover Lignins
Heterogeneity in the physical properties and processing behavior of lignins recovered from biorefining process streams can hinder their effective utilization and industrial valorization. This work investigates lignin recovery by acidification from alkaline pretreatment liquors of varying sources (corn stover and hybrid poplar), compositions, solid contents, and incubation temperatures prior to filtration. Recovered lignins were characterized for filtration performance, mass yield, chemical composition, particle size and morphology, and color. A transition temperature was identified corresponding to marked shifts in lignin physical properties and was a function of the solid content and liquor source. Filtration below this temperature yielded slow-filtering, dark, brittle lignins with smoother particle surfaces, whereas precipitation above this threshold yielded fast-filtering, lighter, powdery lignins with rougher particle surfaces. The impact of temperature and concentration on universal cluster aggregation mechanisms was proposed to explain the differences between lignin particle properties and filtration behavior.
Physical Properties of Hilti HIT-RE 500 V3 After Irradiation: Slant Shear, Tensile, Flexural, and Compressive
There are various applications in which epoxy adhesives may be used within hot-cell environments. These epoxies currently see limited use within hot cells since it is known that organics see degradation after small doses even as low as 50 kilogray (kGy). These losses in physical property strengths limit the use of these epoxies to non-structural applications. In modern construction, however, the use of epoxies to bond structural components such as rebar or threaded anchors is becoming increasingly prevalent. To employ these types of materials the Idaho National Laboratory (INL) has begun investigating the specific degradation properties of epoxies for use in structural applications in environments where radiation is present. Hilti HIT-RE 500 V3 is used extensively in new construction and renovation projects across the world. The INL has conducted various tests on this epoxy for low dose environments. These tests include tensile, flexural, compression, and slant shear tests following the American Society for Testing Material International (ASTM) standards D638, D790, D695, and C882/882M respectively. Two sample sets for each test were created where the baseline specimens were not irradiated, and another set was irradiated to an accumulated dose of approximately 50-60 kGy. All the samples were destructively tested and analyzed focusing on the change in physical properties, examples of these tests are shown in Figures 1-4. Tensile testing results indicate a 0.9% loss in maximum load capacity, a 0.5% loss in tensile stress at maximum load, a 1.4% loss in tensile strain at break, and a 15% decrease in modulus of elasticity. Flexural testing results display an increase in all the following: 12% in strain at maximum load, 10% in maximum load capacity, 5% in stress at maximum load, and 3% in young’s modulus. The compressive physical properties after irradiation display a 1% increase in maximum load, a 3% decrease in stress at yield, and a 5% decrease in modulus of elasticity. The maximum compressive stress saw no measurable change after irradiation. The slant shear specimens after irradiation displayed a 2% increase in maximum load capacity and maximum compressive stress. Though a structural analysis would have to be completed as is normal for building design the increases and decreases in the measured physical properties indicate that this material may be used for structural applications in low dose hot-cell environments without adhesive failure.
Standard methods for heat capacity measurements on a Quantum Design Physical Property Measurement System
The commercial availability of the Physical Property Measurement System (PPMS) by Quantum Design has significantly increased access to heat capacity measurements on a wide variety of materials. Although the PPMS can routinely measure the heat capacities of thermally conducting materials with high accuracy, specialized sample mounting techniques must be used for insulating powders, and the analysis of first order transitions also requires non-standard methods. The concern is that many users are not aware of these constraints when measuring the heat capacity of a diverse array of materials, and therefore, the heat capacity data reported in the literature can be unreliable. In this paper, we provide an extensive and critical review of the heat capacity data reported in the literature measured using the Quantum Design PPMS. The purpose is to provide a de facto standard for sample mounting and data analysis methods suitable for the reporting of accurate thermodynamic data.
Tailoring physical properties of crystals through synthetic temperature control: A case study for new polymorphic NbFeT e 2 phases
Growth parameters play a significant role in the crystal quality and physical properties of layered materials. Here we present a case study on a van der Waals magnetic NbFeTe 2 material. Two different types of polymorphic NbFeTe 2 phases, synthesized at different temperatures, display significantly different behaviors in crystal symmetry, electronic structure, electrical transport, and magnetism. While the phase synthesized at low temperature showing behavior consistent with previous reports, the new phase synthesized at high temperature, has completely different physical properties, such as metallic resistivity, long-range ferromagnetic order, anomalous Hall effect, negative magnetoresistance, and distinct electronic structures. Neutron diffraction reveals out-of-plane ferromagnetism below 70 K, consistent with the electrical transport and magnetic susceptibility studies. Finally, our work suggests that simply tuning synthetic parameters in a controlled manner could be an effective route to alter the physical properties of existing materials potentially unlocking new states of matter, or even discovering new materials.