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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Flash Cracking Reactor for Waste Plastic Processing

Conversion of waste plastic to energy is a growing problem that is especially acute in space exploration applications. Moreover, utilization of heavy hydrocarbon resources (wastes, waxes, etc.) as fuels and chemicals will be a growing need in the future. Existing technologies require a trade-off between product selectivity and feedstock conversion. The objective of this work was to maintain high plastic-to-fuel conversion without sacrificing the liquid yield. The developed technology accomplishes this goal with a combined understanding of thermodynamics, reaction rates, and mass transport to achieve high feed conversion without sacrificing product selectivity. The innovation requires a reaction vessel, hydrocarbon feed, gas feed, and pressure and temperature control equipment. Depending on the feedstock and desired product distribution, catalyst can be added. The reactor is heated to the desired tempera ture, pressurized to the desired pressure, and subject to a sweep flow at the optimized superficial velocity. Software developed under this project can be used to determine optimal values for these parameters. Product is vaporized, transferred to a receiver, and cooled to a liquid - a form suitable for long-term storage as a fuel or chemical. An important NASA application is the use of solar energy to convert waste plastic into a form that can be utilized during periods of low solar energy flux. Unlike previous work in this field, this innovation uses thermodynamic, mass transport, and reaction parameters to tune product distribution of pyrolysis cracking. Previous work in this field has used some of these variables, but never all in conjunction for process optimization. This method is useful for municipal waste incinerator operators and gas-to-liquids companies.

Timko, Michael T.↗
NASA NTRS2017

Effects of Adiabatic Heating on the High Strain Rate Deformation of Polymer Matrix Composites

Polymer matrix composites (PMCs) are increasingly being used in aerospace structures that are expected to experience complex dynamic loading conditions throughout their lifetime. As such, a detailed understanding of the high strain rate behavior of the constituents, particularly the strain rate, temperature, and pressure dependent polymer matrix, is paramount. In this paper, preliminary efforts in modeling experimentally observed temperature rises due to plastic deformation in PMCs subjected to dynamic loading are presented. To this end, an existing isothermal viscoplastic polymer constitutive formulation is extended to model adiabatic conditions by incorporating temperature dependent elastic properties and modifying the components of the inelastic strain rate tensor to explicitly depend on temperature. It is demonstrated that the modified polymer constitutive model is capable of capturing strain rate and temperature dependent yield as well as thermal softening associated with the conversion of plastic work to heat at high rates of strain. The modified constitutive model is then embedded within a strength of materials based micromechanics framework to investigate the manifestation of matrix thermal softening, due to the conversion of plastic work to heat, on the high strain rate response of a T700Epon 862 (T700E862) unidirectional composite. Adiabatic model predictions for high strain rate composite longitudinal tensile, transverse tensile, and in-plane shear loading are presented. Results show a substantial deviation from isothermal conditions; significant thermal softening is observed for matrix dominated deformation modes (transverse tension and in-plane shear), highlighting the importance of accounting for the conversion of plastic work to heat in the polymer matrix in the high strain rate analysis of PMC structures.

polymer matrix composites↗
NASA NTRS2020

An Improved Plastically Dilatant Unified Viscoplastic Constitutive Formulation for Multiscale Analysis of Polymer Matrix Composites Under High Strain Rate Loading

Polymer matrix composites are commonly used to fabricate energy-absorbing structures expected to experience impact loading. As such, a detailed understanding of the dynamic response of the constituent materials is necessary. Since the rate, temperature, and pressure dependence of carbon fiber reinforced polymer matrix composites are primarily manifestations of the rate, temperature, and pressure dependence of the polymer matrix, it is crucial that the constitutive behavior of the matrix be accurately characterized. In this work, an existing unified viscoplastic constitutive formulation is extended to ensure thermodynamic consistency and to more accurately account for the tension-compression asymmetry observed in the response of polymeric materials. A new plastic potential function is proposed, and elementary loading conditions are utilized to determine relations between model constants to ensure nonnegative plastic dissipation, a necessary thermodynamic requirement. Expressions for plastic Poisson’s ratios are derived and are bounded by enforcing nonnegative plastic dissipation. The model is calibrated against available experimental data from tests conducted over a range of strain rates, temperatures, and loading cases on a representative thermoset epoxy; good correlation between simulations and experimental data is obtained. Temperature rises due to the conversion of plastic work to heat are computed via the adiabatic heat energy equation. The viscoplastic polymer model is then used as a constitutive model in the generalized method of cells micromechanics theory to investigate the effects of matrix adiabatic heating on the high strain rate response of a unidirectional composite. The thermodynamic consistency of the model ensures plastic dissipation can only cause an increase in temperature. Simulation results indicate that significant thermal softening due to the conversion of plastic work to heat is observed in the composite for matrix dominated deformation modes.

Impact loading↗
NASA NTRS2010

Creating Methane from Plastics: Recycling at a Lunar Outpost

The high cost of re-supply from Earth demands resources to be utilized to the fullest extent for exploration missions. Recycling is a key technology that maximizes the available resources by converting waste products into useful commodities. One example of this is to convert crew member waste such as plastic packaging, food scraps, and human waste, into fuel. The ability to refuel on the lunar surface would reduce the vehicle mass during launch and provide excess payload capability. The goal of this project is to determine the feasibility of recycling waste into methane on the lunar outpost by performing engineering assessments and lab demonstrations of the technology. The first goal of the project was to determine how recycling could influence lunar exploration. Table I shows an estimation of the typical dried waste stream generated each day for a crew of four. Packaging waste accounts for nearly 86% of the dry waste stream and is a significant source of carbon on the lunar surface. This is important because methane (CH4) can be used as fuel and no other source of carbon is available on the lunar surface. With the initial assessment indicating there is sufficient resources in the waste stream to provide refueling capabilities, the project was designed to examine the conversion of plastics into methane.

Captain, Janine↗
NASA NTRS2014

Bacterial Degradation of Plastics

Plastics are not only a major component of societies on Earth but also those in Space. After use, plastics can accumulate and become difficult to recycle or reuse. Finding ways to degrade and recycle synthetic plastics would provide a way to reduce the upmass of Space Travel, create a closed-loop system of resources and even benefit life on Earth. The purpose of this project is to identify and characterize bacterial species that can degrade and recycle plastics. It has been suggested that bacteria can use plastics, like polyethylene and polystyrene, as a carbon source. These plastics are broken down into intermediary molecules which can then be used in the bacterium's metabolism. Environmental samples were collected from various locations rich in plastic waste. These samples are currently being used to culture bacteria in M9 minimal media containing polyethylene and polystyrene beads as the sole carbon source. High Performance Liquid Chromatography (HPLC), Scanning Electron Microscopy (SEM), and DNA sequencing are among the various methods that will be used identify and characterize bacteria that can degrade plastics. The results from these experiments will provide methods to reduce waste of plastics and ultimately improve sustainability for long-term space exploration.

plastic conversion↗
NASA NTRS2014

Characterization of Plastic Degrading Bacteria from Environmental Samples by Genetic and Biochemical Analysis

Plastic is the major waste-product during NASA space missions, recycling this waste-stream to produce other beneficial materials would decrease upmass. Bacterial called plastisomes have been demonstrated to metabolize non-biodegradable plastics such as polyethylene and polystyrene. Characterization and engineering of these bacteria, and their eventual incorporation as life support systems would enable space flight beyond lower earth orbit. We will utilize molecular techniques to identify and isolate the most productive plastisome. Environmental samples obtained from locations known to be rich in plastic will be cultured in a laboratory defined-media supplemented with plastic as the sole carbon source. Cultures will be monitored for growth over time. Ribosomal DNA will be amplified from cultures that exhibit growth using PCR. These amplified fragments will be sequenced to determine the identity of the consortia in the cultures. We will then perform bioinformatics analysis on the data to identify the plastisomes and generate phylogenetic trees. Morphological and physiological profile of the plastisomes will also be conducted by microscopy and biochemical tests. Our results would reveal a bacterial strain that can break down plastics efficiently. The implication for this project would not only benefit space exploration but also make a major impact towards sustainability development on Earth.

plastic conversion↗
NASA NTRS1980

Continuous coal processing method

A coal pump is provided in which solid coal is heated in the barrel of an extruder under pressure to a temperature at which the coal assumes plastic properties. The coal is continuously extruded, without static zones, using, for example, screw extrusion preferably without venting through a reduced diameter die to form a dispersed spray. As a result, the dispersed coal may be continuously injected into vessels or combustors at any pressure up to the maximum pressure developed in the extrusion device. The coal may be premixed with other materials such as desulfurization aids or reducible metal ores so that reactions occur, during or after conversion to its plastic state. Alternatively, the coal may be processed and caused to react after extrusion, through the die, with, for example, liquid oxidizers, whereby a coal reactor is provided.

Ryason, P. R.↗
NASA NTRS2011

Fiber-Optic Magnetic-Field-Strength Measurement System for Lightning Detection

A fiber-optic sensor system is designed to measure magnetic fields associated with a lightning stroke. Field vector magnitudes are detected and processed for multiple locations. Since physical limitations prevent the sensor elements from being located in close proximity to highly conductive materials such as aluminum, the copper wire sensor elements (3) are located inside a 4-cubic-in. (.66-cubic-cm) plastic housing sensor head and connected to a fiber-optic conversion module by shielded cabling, which is limited to the shortest length feasible. The signal path between the conversion module and the avionics unit which processes the signals are fiber optic, providing enhanced immunity from electromagnetic radiation incident in the vicinity of the measurements. The sensors are passive, lightweight, and much smaller than commercial B-dot sensors in the configuration which measures a three-dimensional magnetic field. The system is expandable, and provides a standard-format output signal for downstream processing. Inside of the sensor head, three small search coils, each having a few turns on a circular form, are mounted orthogonally inside the non-metallic housing. The fiber-optic conversion module comprises three interferometers, one for each search coil. Each interferometer has a high bandwidth optical phase modulator that impresses the signal received from its search coil onto its output. The output of each interferometer travels by fiber optic cable to the avionics unit, and the search coil signal is recovered by an optical phase demodulator. The output of each demodulator is fed to an analog-to-digital converter, whose sampling rate is determined by the maximum expected rate of rise and peak signal magnitude. The output of the digital processor is a faithful reproduction of the coil response to the incident magnetic field. This information is provided in a standard output format on a 50-ohm port that can be connected to any number of data collection and processing instruments and/or systems. The measurement of magnetic fields using fiber-optic signal processing is novel because it eliminates limitations of a traditional B-dot system. These limitations include the distance from the sensor to the measurement device, the potential for the signal to degrade or be corrupted by EMI from lightning, and the size and weight of the sensor and associated plate.

Gurecki, Jay↗
NASA NTRS1968

The role of energy in deformation

Necking, yield, and plastic flow in electrical analogs of mechanical systems with respect to energy conversion effects on mechanical behavior of various materials

Gruntfest, I. J.↗
NASA NTRS2001

Gamma Ray Large Area Space Telescope (GLAST) Balloon Flight Engineering Model: Overview

The Gamma Ray Large Area Space Telescope (GLAST) Large Area Telescope (LAT) is a pair-production high-energy (greater than 20 MeV) gamma-ray telescope being built by an international partnership of astrophysicists and particle physicists for a satellite launch in 2006, designed to study a wide variety of high-energy astrophysical phenomena. As part of the development effort, the collaboration has built a Balloon Flight Engineering Model (BFEM) for flight on a high-altitude scientific balloon. The BFEM is approximately the size of one of the 16 GLAST-LAT towers and contains all the components of the full instrument: plastic scintillator anticoincidence system (ACD), high-Z foil/Si strip pair-conversion tracker (TKR), CsI hodoscopic calorimeter (CAL), triggering and data acquisition electronics (DAQ), commanding system, power distribution, telemetry, real-time data display, and ground data processing system. The principal goal of the balloon flight was to demonstrate the performance of this instrument configuration under conditions similar to those expected in orbit. Results from a balloon flight from Palestine, Texas, on August 4, 2001, show that the BFEM successfully obtained gamma-ray data in this high-background environment.

Thompson, D. J.↗
NASA NTRS1994

Chemical recycling of scrap composites

There are no well-developed technologies for recycling composite materials other than grinding to produce fillers. New approaches are needed to reclaim these valuable resources. Chemical or tertiary recycling, conversion of polymers into low molecular weight hydrocarbons for reuse as chemicals or fuels, is emerging as the most practical means for obtaining value from waste plastics and composites. Adherent Technologies is exploring a low-temperature catalytic process for recycling plastics and composites. Laboratory results show that all types of plastics, thermosets as well as thermoplastics, can be converted in high yields to valuable hydrocarbon products. This novel catalytic process runs at 200 C, conversion times are rapid, the process is closed and, thus, nonpolluting, and no highly toxic gas or liquid products have been observed so no negative environmental impact will result from its implementation. Tests on reclamation of composite materials show that epoxy, imide, and engineering thermoplastic matrices can be converted to low molecular weight hydrocarbons leaving behind the reinforcing fibers for reuse as composite reinforcements in secondary, lower-performance applications. Chemical recycling is also a means to dispose of sensitive or classified organic materials without incineration and provides a means to eliminate or reduce mixed hazardous wastes containing organic materials.

Allred, Ronald E.↗
NASA NTRS1994

Flexible Solar Cells

Solar cell "modules" are plastic strips coated with thin films of photovoltaic silicon that collect solar energy for instant conversion into electricity. Lasers divide the thin film coating into smaller cells to build up voltage. Developed by Iowa Thin Film Technologies under NASA and DOE grants, the modules are used as electrical supply for advertising displays, battery rechargers for recreational vehicles, and to power model airplanes. The company is planning other applications both in consumer goods and as a power source in underdeveloped countries.

Source record↗
NASA NTRS1984

Development and testing of Parabolic Dish Concentrator No. 1

Parabolic Dish Concentrator No. 1 (PDC-1) is a 12-m-diameter prototype concentrator with low life-cycle costs for use with thermal-to-electric energy conversion devices. The concentrator assembly features panels made of a resin transfer molded balsa core/fiberglass sandwich with plastic reflective film as the reflective surface and a ribbed framework to hold the panels in place. The concentrator assembly tracks in azimuth and elevation on a base frame riding on a circular track. It is shown that the panels do not exhibit the proper parabolic contour. However, thermal gradients were discovered in the panels with daily temperature changes. The PDC-1 has sufficient optical quality to operate satisfactorily in a dish-electric system. The PDC-1 development provides the impetus for creating innovative optical testing methods and valuable information for use in designing and fabricating concentrators of future dish-electric systems.

Dennison, E. W.↗
NASA NTRS1977

Nuclear Science Symposium, 23rd, Scintillation and Semiconductor Counter Symposium, 15th, and Nuclear Power Systems Symposium, 8th, New Orleans, La., October 20-22, 1976, Proceedings

The volume includes papers on semiconductor radiation detectors of various types, components of radiation detection and dosimetric systems, digital and microprocessor equipment in nuclear industry and science, and a wide variety of applications of nuclear radiation detectors. Semiconductor detectors of X-rays, gamma radiation, heavy ions, neutrons, and other nuclear particles, plastic scintillator arrays, drift chambers, spark wire chambers, and radiation dosimeter systems are reported on. Digital and analog conversion systems, digital data and control systems, microprocessors, and their uses in scientific research and nuclear power plants are discussed. Large-area imaging and biomedical nucleonic instrumentation, nuclear power plant safeguards, reactor instrumentation, nuclear power plant instrumentation, space instrumentation, and environmental instrumentation are dealt with. Individual items are announced in this issue.

Wagner, L. J.↗
NASA NTRS2022

Methane Bioreactor System Offers Sustainable Plastic Alternative for Earth and Space

Mango Materials partnered with the Colorado School of Mines on NASA STTR awards to adapt a bioreactor system to convert methane into bioplastic for low-gravity environments. In space, methane from carbon dioxide conversion systems and waste treatment can be used to 3D print objects and provide polymers for construction and regolith binding. On Earth, the system can convert methane—a greenhouse gas—into environmentally conscious bioplastic. Mango Materials received $6 million through NASA CCRPP, including funds from fashion investors seeking alternatives to plastic-based textiles.

SBIR/STTR↗
NASA NTRS1983

Pyroelectric conversion in space: A conceptual design study

Pyroelectric conversion is potentially a very lightweight means of providing electrical power generation in space. Two conceptualized systems approaches for the direct conversion of heat (from sunlight) into electrical energy using the pyroelectric effect of a new class of polar polymers were evaluated. Both of the approaches involved large area thin sheets of plastic which are thermally cycled by radiative input and output of thermal energy. The systems studied are expected to eventually achieve efficiencies of the order of 8% and may deliver as much as one half kilowatt per kilogram. In addition to potentially very high specific power, the pyroelectric conversion approaches outlined appear to offer low cost per watt in the form of an easily deployed, flexible, strong, electrically ""self-healing'', and high voltage sheet. This study assessed several potential problems such as plasma interactions and radiation degradation and suggests approaches to overcome them. The fundamental technological issues for space pyroelectric conversion are: (1) demonstration of the conversion cycle with the proposed class of polymers, (2) achievement of improved dielectric strength of the material, (3) demonstration of acceptable plasma power losses for low altitude, and (4) establishment of reasonable lifetime for the pyroelectric material in the space environment. Recommendations include an experimental demonstration of the pyroelectric conversion cycle followed by studies to improve the dielectric strength of the polymer and basic studies to discover additional pyroelectric materials.

Olsen, R. B.↗
NASA NTRS2012

FAST Mast Structural Response to Axial Loading: Modeling and Verification

The International Space Station s solar array wing mast shadowing problem is the focus of this paper. A building-block approach to modeling and analysis is pursued for the primary structural components of the solar array wing mast structure. Starting with an ANSYS (Registered Trademark) finite element model, a verified MSC.Nastran (Trademark) model is established for a single longeron. This finite element model translation requires the conversion of several modeling and analysis features for the two structural analysis tools to produce comparable results for the single-longeron configuration. The model is then reconciled using test data. The resulting MSC.Nastran (Trademark) model is then extended to a single-bay configuration and verified using single-bay test data. Conversion of the MSC. Nastran (Trademark) single-bay model to Abaqus (Trademark) is also performed to simulate the elastic-plastic longeron buckling response of the single bay prior to folding.

Knight, Norman F., Jr.↗
NASA NTRS1990

The development of physically based micro-mechanics - Based on the characteristic tip field of dislocation pileup

Based on the analytical solution by Eshelby et al. (1951) and the numerical calculations by Chou and Li (1969) and Armstrong et al. (1962), it is shown that the force, F, on the locked leading dislocation of a discrete dislocation pileup is capable of characterizing uniquely the stress, strain, and displacement field at the tip of the pileup, including the positions of the discrete mobile dislocations next to the leading dislocation. Conversely, the positions of the mobile dislocations can be used to measure F. The F thus measured can be used to study micro-plastic deformation and micro-fractures at grain boundaries or any other dislocation barriers.

Gao, Q.↗