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Unusual weathering products of oldhamite parentage in the Norton County enstatite achondrite

Oldhamite, CaS, is found only in enstatite chondrites and enstatite achondrites. During the course of a comprehensive study of Norton County, oldhamite was found in several polished thin sections of enstatite achondrite. Inspection of thousands of specimens of Norton County showed that occasionally white, pale-yellow and brown specks, generally a few millimeters in size, occur on their surfaces. X-ray powder analysis of these materials shows that they contain portlandite, Ca(OH)2, vaterite (CaCO3, hexagonal), calcite (CaCO3, trigonal), bassanite (CaSO4 1/2 H2O) and one unknown species. It is suggested that these minerals were produced by terrestrial weathering of oldhamite.

Okada, A.↗

Static compression of Ca(OH)2 at room temperature - Observations of amorphization and equation of state measurements to 10.7 GPa

X-ray diffraction measurements are reported for Ca(OH)2 portlandite as it is compressed to 37.6 GPa in the diamond cell at room temperature. Between 10.7 and 15.4 GPa crystalline Ca(OH)2 transforms to a glass, and on decompression the glass recrystallizes between 3.6 and 5.1 GPa. Below pressures of 10.7 GPa the elastic compression of crystalline Ca(OH)2 was measured. A finite strain analysis of these data shows that the isothermal bulk modulus and its pressure derivative are 37.8 + or - 1.8 GPa and 5.2 + or - 0.7 at zero pressure. The change in the unit cell dimensions indicates that the linear incompressibilities of Ca(OH)2 differ by a factor of three.

Meade, Charles↗