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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Bench‐Scale Evaluation of Hydrothermal Processing Technology for Conversion of Wastewater Solids to Fuels: Marrone et al.

ABSTRACT: Hydrothermal Liquefaction (HTL) and Catalytic Hydrothermal Gasification (CHG) proof‐of‐concept bench‐scale tests were performed to assess the potential of hydrothermal treatment for handling municipal wastewater sludge. HTL tests were conducted at 300 to 350 °C and 20 MPa on three different feeds: primary sludge, secondary sludge, and digested solids. Corresponding CHG tests were conducted at 350 °C and 20 MPa on the HTL aqueous phase output using a ruthenium‐based catalyst. Biocrude yields ranged from 25 to 37%. Biocrude composition and quality were comparable to biocrudes generated from algae feeds. Subsequent hydrotreating of biocrude resulted in a product with comparable physical and chemical properties to crude oil. CHG product gas methane yields on a carbon basis ranged from 47 to 64%. Siloxane concentrations in the CHG product gas were below engine limits. The HTL‐CHG process resulted in a chemical oxygen demand (COD) reduction of > 99.9% and a reduction in residual solids for disposal of 94 to 99%.

Marrone, P. A.↗

Fed-batch hydrolysate addition and cell separation by settling in high cell density lignocellulosic ethanol fermentations on AFEX™ corn stover in the Rapid Bioconversion with Integrated recycling Technology process

Abstract The Rapid Bioconversion with Integrated recycling Technology (RaBIT) process uses enzyme and yeast recycling to improve cellulosic ethanol production economics. The previous versions of the RaBIT process exhibited decreased xylose consumption using cell recycle for a variety of different micro-organisms. Process changes were tested in an attempt to eliminate the xylose consumption decrease. Three different RaBIT process changes were evaluated in this work including (1) shortening the fermentation time, (2) fed-batch hydrolysate addition, and (3) selective cell recycling using a settling method. Shorting the RaBIT fermentation process to 11 h and introducing fed-batch hydrolysate addition eliminated any xylose consumption decrease over ten fermentation cycles; otherwise, decreased xylose consumption was apparent by the third cell recycle event. However, partial removal of yeast cells during recycle was not economical when compared to recycling all yeast cells.

Sarks, Cory↗

Review of the containerless processing technologies and facilities

Material processing techniques which can most fully utilize the advantages provided by space are related to containerless processing. An avoidance of physical contact between the melt and the walls of a container leads to an elimination of container-induced contamination and heterogeneous nucleation. Containerless processing facilities development by NASA will provide a basis for the performance of precursor experiments and processing technologies studies prior to Space Shuttle flights. Attention is given to acoustic containerless processing, electromagnetic containerless processing, electrostatic levitation technology, drop tubes, and the use of zero-G KC-135 aircraft flights for tests and training purposes.

Wang, T. G.↗

Plan for Developing TRISO Fuel Processing Technologies

This Plan demonstrates the availability of technologies for processing TRISO used nuclear fuel for waste management and actinide recovery purposes. These technologies are judged to be at a very low level of technology readiness and as such they constitute a fertile research area for the DOE-NE’s Office of Materials and Chemical Technologies. Strategies to mature the technologies to a point where they can reasonably be considered in engineering alternatives analyses typically involve laboratory-scale tests using fuel simulant to characterize process streams and demonstrate key engineering features. Several criteria are available to help selecting candidate technologies for further maturation

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Annual Report: Innovative Process Technologies (30 September 2013)

Innovative Process Technologies is concerned with the development of innovative cost-effective technologies that promote efficiency, environmental performance, availability of advanced energy systems, and the development of computational tools that shorten development timelines of advanced energy systems. The project is focused on five distinct research tasks: (1) Sensors and Controls, (2) Power Electronics and Energetic Materials, (3) Innovative Energy Concepts (IEC), (4) Computational Materials, and (5) Multiphase Flow.

20 FOSSIL-FUELED POWER PLANTS↗

Fabricating binary optics: An overview of binary optics process technology

A review of binary optics processing technology is presented. Pattern replication techniques have been optimized to generate high-quality efficient microoptics in visible and infrared materials. High resolution optical photolithography and precision alignment is used to fabricate maximally efficient fused silica diffractive microlenses at lambda = 633 nm. The degradation in optical efficiency of four-phase-level fused silica microlenses resulting from an intentional 0.35 micron translational error has been systematically measured as a function of lens speed (F/2 - F/60). Novel processes necessary for high sag refractive IR microoptics arrays, including deep anisotropic Si-etching, planarization of deep topography and multilayer resist techniques, are described. Initial results are presented for monolithic integration of photonic and microoptic systems.

Stern, Margaret B.↗

Optimization and Diagnostics Code for Technological Processes: Radiochemical Production Simulator

A software-hardware complex with the possibility of simulating the functioning of technological processes with APCS in real and accelerated time is being developed as part of Project Breakthrough in order to determine the optimal operating regimes of the technological processes of the units in a closed nuclear fuel cycle. It makes possible monitoring and control functions and the visualization and archiving of the results of simulation, which makes it possible at the development stages of technologies to evaluate the degree of adherence to the requirements of the technological equipment, regulating organs and final-control mechanisms, measurement apparatus, and monitoring channels, to analyze the control and diagnostics algorithms, blocking and protection, and to make when necessary changes in the design being developed. The developed software-hardware complex is a stimulator that will make it possible not only to investigate process schemes with their corresponding algorithms but also to develop training complexes for the training and certification of service personnel.

42 ENGINEERING↗

A Fecal Processing Technology Trade Study for Water Recovery in Various Mission Duration Scenarios

To achieve long endurance human space missions such as a trip to Mars, a fully recycled or “closed loop” water system is almost essential. Even for shorter duration missions in Earth orbit, lunar orbit, or on the surface of the moon, recovering and recycling water from as many sources as possible may prove beneficial. One source of water that has not been exploited to date is human solid waste. Herein, a trade study is performed to evaluate the ability of several fecal processing technologies to recover >80% of the water content within the waste. Human solid waste (feces) contains approximately 75% water by mass, which upon quantification, translates to ~170 g of recoverable water per crewmember per day and can scale to values of ~680 kg for a crew of 4 persons on a 1,000-day long exploration mission. Several fecal processing technologies (i.e., steam reforming, vacuum drying, freeze-drying, pyrolysis, ultrasonic drying, etc.) are analyzed using an equivalent system mass (ESM) approach to assess and compare the estimated cost for recovering fecal water – in terms of mass, power, and volume equivalents – against the water recovery mass savings for each technology. Post-use volume is also used as a secondary metric for comparison to quantify the benefits of volume reduction resulting from the fecal drying process. From said analysis, clear patterns and benefits emerge that may prove helpful for future fecal processing technology development and application to space exploration missions.

Trade study↗

Directed-energy process technology efforts

A summary of directed-energy process technology for solar cells was presented. This technology is defined as directing energy or mass to specific areas on solar cells to produce a desired effect in contrast to exposing a cell to a thermal or mass flow environment. Some of these second generation processing techniques are: ion implantation; microwave-enhanced chemical vapor deposition; rapid thermal processing; and the use of lasers for cutting, assisting in metallization, assisting in deposition, and drive-in of liquid dopants. Advantages of directed energy techniques are: surface heating resulting in the bulk of the cell material being cooler and unchanged; better process control yields; better junction profiles, junction depths, and metal sintering; lower energy consumption during processing and smaller factory space requirements. These advantages should result in higher-efficiency cells at lower costs. The results of the numerous contracted efforts were presented as well as the application potentials of these new technologies.

Alexander, P.↗

Spacecraft on-board SAR processing technology

This paper provides an assessment of the on-board SAR processing technology for Eos-type missions. The proposed Eos SAR sensor and flight data system are introduced, and the SAR processing requirements are described. The SAR on-board SAR processor architecture selection is discussed, and a baseline processor architecture using a frequency-domain processor for range correlation and a modular fault-tolerant VLSI time-domain parallel array for azimuth correlation are described. The mass storage and VLSI technologies needed for implementing the proposed SAR processing are assessed. It is shown that acceptable processor power and mass characteristics should be feasible for Eos-type applications. A proposed development strategy for the on-board SAR processor is presented.

Liu, K. Y.↗

Overview of containerless processing technologies

Many of the experiments to be carried out in the Space Shuttle will require containerless processing techniques that will provide manipulation and control of weightless (molten) materials without physical contact with container walls or other holding devices. The variety of containerless processing technologies now being developed for space- and ground-based materials processing facilities is surveyed. It is shown how the utilization of air jets or high-intensity acoustic, electromagnetic, or electrostatic fields can produce forces that support and manipulate materials. Most of the present containerless research seeks to develop high-temperature systems capable of melting and resolidifying materials. An introduction to available NASA test facilities is provided.

Barmatz, M.↗

The Effect of Chemical Composition and Processing Technology on the Microstructure, Texture and Earing Behavior of DR Tinplate

The influence of alloying elements and processing technology on the microstructure, crystallographic texture and earing propensity has been investigated in two kinds of DR tinplate differing in Ti content: steel A, no Ti addition, and steel B 0.015% added. The cementite distribution, second-phase particles and the content of dissolved carbon and nitrogen atoms were obtained by SEM, TEM and XPS, respectively. Since the two steels develop both a partial 〈110〉//RD fiber and a {111}//ND fiber, the relative intensities of the several vital texture components seem to differ visibly. There are three types of strengthening mechanisms involved here: strengthening by grain size reduction, solution strengthening and strain hardening. That the tensile strength of steel B is greater than A implies the third mode plays a dominant role in the strength increasing for the DR tinplate. The crystallographic texture of materials not only results in a “preferential orientation” of the mechanical property, but also takes the primary responsibility for ears forming during drawing. Increasing the second cold-rolled reduction is not favorable to reduce the ear height, but this situation seems to be ameliorable. The average ears height of steel B is smaller than that of A, which demonstrated a low level of solute atoms and an ideal texture characteristic before deformation could alleviate the adverse effect caused by an elevated second cold reduction.

36 MATERIALS SCIENCE↗

Review of allanite: Properties, occurrence and mineral processing technologies

Allanite is commonly encountered as an accessory rare-earth silicate mineral in association with minerals such as garnet, biotite, and feldspar. It is distributed globally and occurs in igneous formations such as granites, pegmatites, and syenites, as well as in various metamorphic rocks such as schist, gneiss, and amphibolite. Moreover, it can be found in mineral veins formed through hydrothermal activity. While allanite has not yet been extensively utilized for the production of rare-earth elements, recent discoveries of high-grade rare-earth-rich allanite deposits in Wyoming, USA, highlight its economic potential. However, despite ongoing research on the mineralogy and processing of rare-earth minerals, allanite has not received widespread attention in mineral processing. To achieve economical extraction of rare-earth elements from allanite in the future, systematic studies on processing techniques (e.g., density separation, magnetic separation, flotation, leaching) are imperative to fully unlock the potential of allanite as a rare-earth element source. To pave the way for future investigation of allanite and address the unique processing challenges, this review article aims to comprehensively summarize previous studies, encompassing properties, occurrences, and processing technologies of allanite.

42 ENGINEERING↗

Advanced optical sensing and processing technologies for the distributed control of large flexible spacecraft

The objective was to examine state-of-the-art optical sensing and processing technology applied to control the motion of flexible spacecraft. Proposed large flexible space systems, such an optical telescopes and antennas, will require control over vast surfaces. Most likely distributed control will be necessary involving many sensors to accurately measure the surface. A similarly large number of actuators must act upon the system. The used technical approach included reviewing proposed NASA missions to assess system needs and requirements. A candidate mission was chosen as a baseline study spacecraft for comparison of conventional and optical control components. Control system requirements of the baseline system were used for designing both a control system containing current off-the-shelf components and a system utilizing electro-optical devices for sensing and processing. State-of-the-art surveys of conventional sensor, actuator, and processor technologies were performed. A technology development plan is presented that presents a logical, effective way to develop and integrate advancing technologies.

Williams, G. M.↗

Evaluation of Brine Processing Technologies for Spacecraft Wastewater

Brine drying systems may be used in spaceflight. There are several advantages to using brine processing technologies for long-duration human missions including a reduction in resupply requirements and achieving high water recovery ratios. The objective of this project was to evaluate four technologies for the drying of spacecraft water recycling system brine byproducts. The technologies tested were NASA's Forward Osmosis Brine Drying (FOBD), Paragon's Ionomer Water Processor (IWP), NASA's Brine Evaporation Bag (BEB) System, and UMPQUA's Ultrasonic Brine Dewatering System (UBDS). The purpose of this work was to evaluate the hardware using feed streams composed of brines similar to those generated on board the International Space Station (ISS) and future exploration missions. The brine formulations used for testing were the ISS Alternate Pretreatment and Solution 2 (Alt Pretreat). The brines were generated using the Wiped-film Rotating-disk (WFRD) evaporator, which is a vapor compression distillation system that is used to simulate the function of the ISS Urine Processor Assembly (UPA). Each system was evaluated based on the results from testing and Equivalent System Mass (ESM) calculations. A Quality Function Deployment (QFD) matrix was also developed as a method to compare the different technologies based on customer and engineering requirements.

recycling↗

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

space processing↗