Stochastic Reconstruction of Ablating Material Properties for Uncertainty Propagation in Material Response Simulations
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Thermal Protection Materials↗
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Investigation of material properties of thermoplastic and thermoset polymer materials at cryogenic temperatures using molecular dynamics
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Swapnil S. Bamane↗
Effect of Thermomechanical Processing on the Microstructure, Properties, and Work Behavior of a Ti50.5 Ni29.5 Pt20 High-Temperature Shape Memory Alloy
TiNiPt shape memory alloys are particularly promising for use as solid state actuators in environments up to 300 °C, due to a reasonable balance of proper ties, including acceptable work output. However, one of the challenges to commercializing a viable high-temperature shape memory alloy (HTSMA) is to establish the appropriate primary and secondary processing techniques for fabrication of the material in a required product form such as rod and wire. Consequently, a Ti 50.5 Ni 29.5 Pt 20 alloy was processed using several techniques including single- pass high-temperature extrusion, multiple-pass high-temperature extrusion, and cold drawing to produce bar stock, thin rod, and fine wire, respectively. The effects of heat treatment on the hardness, grain size, room temperature tensile properties, and transformation temperatures of hot- and cold-worked material were examined. Basic tensile properties as a function of temperature and the strain-temperature response of the alloy under constant load, for the determination of work output, were also investigated for various forms of the Ti 50.5 Ni 29.5 Pt 20 alloy, including fine wire.
Grain Size↗
Integrated Process-Structure-Property Simulations for Additive Manufacturing Using the Open-Source Materialite Package
The microstructure and properties of additively manufactured (AM) metals are strongly dependent on process conditions. Therefore, process-structure-property (PSP) simulations are a useful tool for exploring process parameter space, studying process variations, and quantifying uncertainty in material properties. However, integrating process-structure and structure-property simulations often involves connecting multiple software packages. Each package may use unique data structures and require substantial domain knowledge. This presentation demonstrates PSP simulation capabilities of Materialite, an open-source package developed at NASA Langley Research Center. Materialite simplifies model linkages by using a common data structure and model interface, enabling straightforward simulation across a PSP model chain. Physics-based models, including kinetic Monte Carlo and crystal plasticity, are implemented within the package. The model interface is also intended to simplify implementation of new models and enable integration with external simulation tools. Example use cases include uncertainty quantification with PSP models and GPU-accelerated powder bed fusion AM process models.
additive manufacturing↗
Satellite Material Contaminant Optical Properties
The Air Force Wright Research and Development Center and the Arnold Engineering Development Center are continuing a program for measuring optical effects of satellite material outgassing products on cryo-optic surfaces. Presented here are infrared (4000 to 700 cm -1 ) transmittance data for contaminant films condensed on a 77 K geranium window. From the transmittance data, the contaminant film refractive and absorptive indices (n, k) were derived using an analytical thin-film interference model with a nonlinear least-squares algorithm. To date 19 materials have been studied with the optical contents determined for 13 of those. The materials include adhesives, paints, composites, films, and lubricants. This program is continuing and properties for other materials will be available in the future.
B E Wood↗
Program to develop an inorganic separator for a high temperature silver-zinc battery Quarterly progress report, Oct. 29, 1965 - Jan. 29, 1966
Polyphenylene oxide case and cover mechanical properties determination, and component reliability tests for silver-zinc battery with inorganic separators
MECHANICAL PROPERTY↗
Metallurgical and Thermal Properties of 57Ni-40Ti-3Hf (wt%)
Selected properties of 57Ni-40Ti-3Hf (wt%) were measured to further develop this material for use in aerospace rolling-element bearings. The average grain size and microindentation hardness of the material at room temperature were 90 μm and 549 HV, respectively. From room temperature to 500 °C, electrical resistivity increased from 8.9×10–7 to 11.3×10–7 Ω⋅m, thermal expansion coefficients varied from 1.1×10–5 to 1.2×10–5 mm/mm⋅°C, specific heat increased from 0.44 to 0.53 W⋅sec/g⋅K, thermal diffusivity rose from approximately 0.003 to 0.005 cm2/sec and thermal conductivity increased from approximately 0.09 to 0.19 W/cm⋅K. The behavior of the material can be explained by well-known metallurgical theory. These results are expected to provide a basis for design and modeling of future aerospace components.
rule of mixtures↗
Design and fabrication of 100 ampere- hour nickel cadmium battery cells Final report
Design and electric characteristics of 100 A-h nickel-cadmium battery cells with active Adhydrode third electrode
NICKEL-CADMIUM BATTERY↗
Bend Properties of Sapphire Fibers at Elevated Temperatures: Bend Survivability - 1
The effect of temperature on the bend radius that a c-axis-oriented sapphire fiber can withstand was determined for fibers of various diameter. Bend stress rupture tests were performed for times of 1-100 h and temperatures of 300-1700 C. Fibers would survive the bend test undeformed, would fracture or would deform. The bend survival radius was determined to be the radius above which no fibers fractured or deformed for a given time-temperature treatment. It was found that the ability of fibers to withstand curvature decreases substantially with time and increasing temperature and that fibers of smaller diameter (46-83 micron) withstood smaller bend radii than would be expected from just a difference in fiber diameter when compared with the bend results of the fibers of large diameter (144 micron). This was probably due to different flaw populations, causing high temperature bend failure for the tested sapphire fibers of different diameters.
Sapphire↗
Properties and Potential of Two (Ni,Pt)Ti Alloys for Use as High-Temperature Actuator Materials
The microstructure, transformation temperatures, basic tensile properties, shape memory behavior, and work output for two (Ni,Ti)Pt high-temperature shape memory alloys have been characterized. One was a Ni 30 Pt 20 Ti 50 alloy (referred to as 20Pt) with transformation temperatures above 230 °C and the other was a Ni 20 Pt 30 Ti 50 alloy (30Pt) with transformation temperatures above 530 °C. Both materials displayed shape memory behavior and were capable of 100% (no-load) strain recovery for strain levels up to their fracture limit (3-4%) when deformed at room temperature. For the 20Pt alloy, the tensile strength, modulus, and ductility dramatically increased when the material was tested just above the austenite finish (A f ) temperature. For the 30Pt alloy, a similar change in yield behavior at temperatures above the A f was not observed. In this case the strength of the austenite phase was at best comparable and generally much weaker than the martensite phase. A ductility minimum was also observed just below the A s temperature in this alloy. As a result of these differences in tensile behavior, the two alloys performed completely different when thermally cycled under constant load. The 20Pt alloy behaved similar to conventional binary NiTi alloys with work output due to the martensite-to-austenite transformation initially increasing with applied stress. The maximum work output measured in the 20Pt alloy was nearly 9 J/cm 3 and was limited by the tensile ductility of the material. In contrast, the martensite-to-austenite transformation in the 30Pt alloy was not capable of performing work against any bias load. The reason for this behavior was traced back to its basic mechanical properties, where the yield strength of the austenite phase was similar to or lower than that of the martensite phase, depending on temperature. Hence, the recovery or transformation strain for the 30Pt alloy under load was essentially zero, resulting in zero work output.
High-Temperature Shape Memory Alloy↗
Changes in Arctic and Antarctic Sea-Ice Properties and Processes
Although sea ice covers ~9% of the world’s oceans, its presence, and absence, vastly alter the energetic balance of Earth’s climate. Because of geographic differences, Arctic and Antarctic sea ice have different dominant properties and processes, which produce different responses to natural variability and anthropogenic change. In this Review, we survey changes in sea-ice properties and processes of the Arctic and Antarctic environments. In the Arctic, the melt season has lengthened by ~7.4 days decade −1 (1979-2024). There has been a corresponding decrease in winter sea-ice thickness (1.6 m mean total over 1980-2023), summer surface albedo (0.03 decade −1 over 1979-2020), and spring snow depth (2.5 cm decade −1 over 1954-2024). In comparison, corresponding changes in the Antarctic are small overall due to contrasting regional and temporal trends. From a dynamic perspective, sea-ice motion in both hemispheres has increased, with 0.63 cm s −1 decade −1 in the Arctic (1978-2024) and 0.69 cm s −1 decade −1 in the Antarctic (1982-2024), whereas trends in polynya occurrence differ by region. Future research should prioritize sea-ice observations that can inform how the climate system responds to natural variability and anthropogenic change, be standardized to increase uptake by the broader scientific community, and target process-oriented interactions to support model development.
Melinda A Webster↗
Properties of a Ni19.5Pd30Ti50.5 High-Temperature Shape Memory Alloy in Tension and Compression
Potential applications involving high-temperature shape memory alloys have been growing in recent years. Even in those cases where promising new alloys have been identified, the knowledge base for such materials contains gaps crucial to their maturation and implementation in actuator and other applications. We begin to address this issue by characterizing the mechanical behavior of a Ni 19.5 Pd 30 Ti 50.5 high-temperature shape memory alloy in both uniaxial tension and compression at various temperatures. Differences in the isothermal uniaxial deformation behavior were most notable at test temperatures below the martensite finish temperature. The elastic modulus of the material was very dependent on strain level; therefore, dynamic Young’s Modulus was determined as a function of temperature by an impulse excitation technique. More importantly, the performance of a thermally activated actuator material is dependent on the work output of the alloy. Consequently, the strain-temperature response of the Ni 19.5 Pd 30 Ti 50.5 alloy under various loads was determined in both tension and compression and the specific work output calculated and compared in both loading conditions. It was found that the transformation strain and thus, the specific work output were similar regardless of the loading condition. Also, in both tension and compression, the strain-temperature loops determined under constant load conditions did not close due to the fact that the transformation strain during cooling was always larger than the transformation strain during heating. This was apparently the result of permanent plastic deformation of the martensite phase with each cycle. Consequently, before this alloy can be used under cyclic actuation conditions, modification of the microstructure or composition would be required to increase the resistance of the alloy to plastic deformation by slip.
High-Temperature Shape Memory Alloy↗
Artemis Suit Material Optical Property Testing of Dust Exposed Fabrics
This paper highlights one aspect of NASA’s ongoing technology-infusion effort to design, fabricate, and test a next-generation outer shell fabric for a lunar Extravehicular Activity (EVA) space suit, a critical component of sustained lunar exploration. Managing thermal loads on the Moon is essential for astronaut safety and suit performance. The suit’s exterior fabric directly influences heat gain and loss through its optical properties: low solar absorptivity minimizes sunlight absorption, while high infrared emissivity aids radiative cooling. Lunar regolith complicates this balance. Its fine, abrasive particles possess unique optical behavior that can lower reflectivity and raise emissivity when embedded in or adhered to fabric surfaces, degrading thermal control and increasing the risk of overheating or cooling inefficiency. To quantify these effects, the Artemis Suit Materials (ASM) team measured solar absorptance and infrared emissivity of clean and dust-soiled Ortho Fabric, establishing beginning-of-life (BOL) and end-of-life (EOL) benchmarks. EOL conditions were simulated with a rotary tumbler abrasion process using lunar dust simulant and ceramic media to reproduce cumulative wear expected during surface operations. Tests also included unmodified fabrics and a fabric/film laminate system containing titanium dioxide to evaluate potential improvements in dust resistance and optical performance. Results from these evaluations provide critical insight into how lunar dust alters fabric thermal behavior and inform the design of bespoke suit materials that maintain required optical properties throughout mission life, supporting safe and effective long-duration EVA on the lunar surface.
Textile↗
Artemis Suit Material Optical Property Testing of Dust Exposed Fabrics
This paper highlights one aspect of NASA’s ongoing technology-infusion effort to design, fabricate, and test a next-generation outer shell fabric for a lunar Extravehicular Activity (EVA) space suit, a critical component of sustained lunar exploration. Managing thermal loads on the Moon is essential for astronaut safety and suit performance. The suit’s exterior fabric directly influences heat gain and loss through its optical properties: low solar absorptivity minimizes sunlight absorption, while high infrared emissivity aids radiative cooling. Lunar regolith complicates this balance. Its fine, abrasive particles possess unique optical behavior that can lower reflectivity and raise emissivity when embedded in or adhered to fabric surfaces, degrading thermal control and increasing the risk of overheating or cooling inefficiency. To quantify these effects, the Artemis Suit Materials (ASM) team measured solar absorptance and infrared emissivity of clean and dust-soiled Ortho Fabric, establishing beginning-of-life (BOL) and end-of-life (EOL) benchmarks. EOL conditions were simulated with a rotary tumbler abrasion process using lunar dust simulant and ceramic media to reproduce cumulative wear expected during surface operations. Tests also included unmodified fabrics and a fabric/film laminate system containing titanium dioxide to evaluate potential improvements in dust resistance and optical performance. Results from these evaluations provide critical insight into how lunar dust alters fabric thermal behavior and inform the design of bespoke suit materials that maintain required optical properties throughout mission life, supporting safe and effective long-duration EVA on the lunar surface.
space↗
Biobased Polybenzoxazine Derived from Furfurylamine and Piceol with Low Cure Temperature and Advanced Properties for Composite Matrices
A novel benzoxazine made from furfurylamine, paraformaldehyde, and piceol, Bz-FA-HA, is assessed for applications in fiber reinforced (FR) composites. Piceol is a biobased phenolic compound derived from the roots of Norwegian spruce trees and contains a methyl ketone group at the para position. Bz-FA-HA is a liquid at room temperature, has a viscosity of < 1 Pa.s at temperatures above 90 °C, and a Tonset of cure at 132 °C. The carbonyl is found to react with the furan ring, yielding a crosslinking reaction, when cured above 180 °C as indicated by differential scanning calorimetry and thermogravimetric analysis coupled with Fourier transform infrared spectroscopy. Poly(Bz-FA-HA) has a Tg > 350 °C, attributed to the crosslinking reaction. Furthermore, the storage modulus is > 3 GPa, regardless of cure temperature. Poly(Bz-FA-HA) has a char yield at 800 °C of 65.0 % (62.3 % at 1000 °C), and a Tonset of decomposition of 357 °C in nitrogen. The resulting carbon formed during pyrolysis shrinks during the carbonization reaction and scanning electron microscopy imaging shows a cross-section with micro cracks. The high processability, advanced mechanical properties, and exceptional char yield make it a promising candidate as the matrix for FR composites.
Benzoxazine↗
Magnetic and Dielectric Properties of Lunar Samples
The dielectric properties of lunar soil and rock samples show a systematic character when careful precautions are taken to ensure there is no moisture present during measurement. The dielectric constant (K) above 10 5 Hz is directly dependent on density according to the formula K = (1.93 ± 0.17) p where p is the density in g/cc. The dielectric loss tangent is only slightly dependent on density and has values less than 0.005 for typical soils and 0.005-0.03 for typical rocks. In addition to a density dependence, the loss tangent appears to be directly related to the metallic ilmenite content. These results are in good agreement with the results of the Surface Electrical Properties Experiment carried on Apollo 17. It showed a surface layer of dielectric constant 3.8 and a loss tangent of 0.008. This is presumed to be a layer of compact soil about 7 m thick, overlying a medium with a dielectric constant of roughly 7.5 and a loss tangent interpreted to be 0.035, The medium is presumed to be bedrock. These results are compatible with seismic results. The magnetic properties of lunar samples can be used to study the distribution of metallic and ferrous iron which shows systematic variations from soil-type to soil-type and a general tendency to increasing Fe°/Fe** distribution in the more highly rewelded breccias. The other magnetic characteristics can also be used to determine the distribution of grain sizes. There are a number of ways of interpreting the origin of the stable remanent magnetization in lunar samples, but several lines of evidence suggest that it is of thermal origin and was acquired at a time when the igneous rocks and breccias cooled from above 800°C in the presence of an ancient field.
D W Strangway↗
Material Properties and Modeling of Room Temperature Vulcanizing Silicone
Room Temperature Vulcanizing silicone (RTV) is a high-temperature adhesive that has successfully been used as a gap-filler between Thermal Protection System (TPS) tiles for heatshields on numerous missions. It is also used to bond instrumentation plugs such as temperature and pressure sensors into the heatshields. While RTV has been traditionally assumed to be a non-porous and non-ablating material, numerous experiments have shown that RTV pyrolyzes and becomes highly porous as it is heated. Heating RTV has also shown swelling, or intumescence, which can pose unique problems that lead to roughness induced boundary-layer transition, surface oxide formation and contamination of heat shield sensors. Therefore, it is crucial to understand and model the intumescence phenomenon of RTV. As data for RTV material properties is limited, the first step in modeling RTV is to collect material properties such as pyrolysis mass-loss, microstructure change, virgin and char porosity, etc. which was performed in our initial study. Additionally, thermomechanical properties such as Young’s modulus and Poisson ratio are required for modeling the intumescence of RTV, which were taken from literature and the coefficient of thermal expansion was collected using in-situ heating and Micro Computed Tomography (µ-CT) in previous studies. Finally, numerous other properties such as pyrolysis gas properties, virgin and char thermal conductivity and specific heat were compiled from previous experiments and literature into a material database that can be used for simulations. In Porous Material Analysis Toolbox based on OpenFOAM (PATO) [4], structural mechanics coupled with material response was used for simulating the intumescence of RTV as it is heated. However, since the permeability of the material is very low, the pyrolysis gas creates an internal pressure build-up as the material is being heated, significantly contributing to the deformation of the material. To correctly characterize this phenomenon, additional physics models were implemented into PATO's stress analysis solver, and results were compared with RTV dilatometry test data as a preliminary verification case. Future work will include experiments of RTV at the Plasmatron X facility and the in-situ heating cell with µ-CT, and improvement of simulation tools to more accurately model RTV intumescence.
PATO↗
Thermodynamic Properties of Uranium-Zirconium Carbide Solid Solutions with Oxygen
Uranium-zirconium carbide solid solutions are potential candidates for fuel in space nuclear reactors. To support development of advanced robust fuels for space applications, (U y Zr 1-y )C x O z solid solutions were synthesized via carbothermic reduction with uranium, carbon, and oxygen contents raging from y=0.05 – 0.3, x=0.95 – 0.98, and z = 0.02 – 0.07. These solid solutions were subsequently characterized by X-ray diffraction and elemental combustion analysis. High-temperature oxidative drop solution calorimetry in molten sodium molybdate solvent at 1073 K was employed to determine the formation, oxidation, and mixing enthalpies of (U y Zr 1-y )C x O z solid solutions, and thereby for evaluating their thermodynamic stability. The solid solutions are enthalpically less stable than the UC and ZrC end members. They also become less stable and more reactive towards oxidation with increasing uranium content. Incorporation of oxygen into solid solutions increases their solid solution-stability and improves their oxidation resistance.
Calorimetry↗