Transmission effects on plastic films irradiated with ultraviolet light, electrons, and protons
Transmission effects on plastic films irradiated with ultraviolet light in vacuum
Anagnostou, E.↗
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Hydrogen Crossover Flux through Two-Dimensional Nanomaterials
Energy storage and conversion devices require an ion-exchange membrane with high transmission of charge-balancing ions and separation of anode and cathode electrolytes/gases. This ensures optimum device performance. Most conventional membranes suffer huge cross-permeation resulting in low energy efficiency and material degradation. This work investigated hydrogen permeability and proton transmission through membrane electrode assemblies (MEAs) containing a monolayer of hexagonal boron nitride and single-layer and bi-layer graphene in a gas-phase small-scale cell and a liquid cell. Here we found that the hydrogen crossover flux through MEAs with 2D materials was inhibited by at least a factor of 5 compared to the one without. Single-layer graphene and boron nitride enabled high proton transmission, but bi-layer graphene inhibited proton conduction. Defect visualization of 2D materials revealed few atomic-scale defects in graphene. These findings suggest that a monolayer of 2D material may provide good selectivity for energy conversion and storage devices by blocking species crossover while allowing high proton transmission.
2D materials↗
Some experimental data on the nuclear cascade in thick absorbers
High energy proton transmission in solid absorbers
PROTON↗
Adjustable collimation for dark-field proton radiography contrast enhancement
A dark-field imaging condition established through pre- and post-object beam collimation has been tested for a variety of different settings at the proton radiography facility (pRad) at Los Alamos National Laboratory. This technique facilitates imaging of thin samples and materials with small areal density changes with 800 MeV protons that would otherwise appear nearly transparent for high energy protons. In the configuration that was examined, the pre-object (upstream) collimator is utilized to remove protons with large scattering angles prior to the target object. The post-object collimation entails a combination of a conventional collimator, which eliminates protons with large scattering angles after target interaction, and an inverse collimator. The inverse collimator removes unscattered protons traveling on the beam axis and those with smaller scattering angles up to a desired angle. This establishes a dark-field condition by permitting solely protons that exhibit scattering angles from target interaction within a designated range to contribute to the image. This study explores the potential of combining different sized collimators for pre- and post-object collimation. The objective is to optimize contrast for a range of samples with minimal areal density variations. A series of dark-field conditions are explored employing a remote-controlled collimator wheel and the contrast-to-noise ratio, spatial resolution, and proton transmission are compared for those combinations. It is found that the contrast-to-noise ratio can be substantially enhanced for thin samples and low areal density objects, thereby facilitating capturing high-contrast images of objects that were previously invisible to high energy protons.
43 PARTICLE ACCELERATORS↗
Experimental observations of exploding bridgewire detonator function
Exploding bridgewire detonators are an industry standard technology used for over 75 years and valued for their precise timing and safety characteristics. Despite widespread use, their functional mechanism remains controversial with both shock and non-shock mechanisms attributed. In this work, we re-examine bridgewire detonator function with a suite of modern diagnostics and compare these observations with the existing literature. Traditional detonator observations consisted of voltage applied to the bridgewire and time dependent current, integral response measurements such as case motion and more recently Schlieren imaging of the detonator surface. In this work, we add visible light emission, X-ray transmission, proton radiography, and temperature measurements during detonator function in addition to voltage, current, and function times. The addition of in-situ observations of light emission, temperature, and density gives us new insight into the mechanisms of explosive bridgewire detonator function. We see a distinct separation in time, location, symmetry, and velocity of bridgewire output and detonation onset. During the time between bridgewire burst and the initiation of detonation, we observe a temperature ramp in the input pellet. In this paper, we present the suite of measurements and comparisons with the literature on integral response measurements.
42 ENGINEERING↗
Geomagnetic transmission of solar energetic protons during the geomagnetic disturbances of October 1989
Orbit-averaged geomagnetic transmission measurements during the large solar energetic particle events of October 1989 are presented using proton data from the NOAA-10 and GOES-7 satellies. The measurements are compared to geomagnetic transmission calculations determined by tracing particle trajectories through the combination of the International Geomagnetic Reference Field (IGRF) model and the 1989 Tsyganenko magnetospheric magnetic field model. The effective 'ring current' parameter in the 1989 Tsyganenko model based on the Dst data. Results are compared to calculations employing only the IGRF and to a parameterization of geomagnetically quiet-time cutoff rigidities derived from Cosmos/intercosmos observations. The 3-hour orbit-averaged results have approximately 15% accuracy during the October 1989 events.
Boberg, P. R.↗
Proton-induced degradation of VUV transmission of LiF and MgF2
Proton-induced degradation of vacuum ultraviolet (VUV) transmittance of LiF and MgF2 was measured for 85- and 600-MeV protons for a fluence up to 2.8 x 10 to the 13th p/sq cm. Transmittances were measured from 105 to 210 nm. When the irradiation level for a given material is expressed in terms of absorbed energy per unit of volume of crystal, 85- and 600-MeV protons produce the same degradation. MgF2 is substantially more radiation resistant than LiF in the VUV. Irradiation of LiF with 1.8 x 10 to the 13th p/sq cm at 85 MeV changed the transmittance of the hydrogen Ly-alpha line at 121.6 nm from 55 to 23%. The corresponding change for MgF2 was from 52 to 42% for 2.8 x 10 to the 13th p/sq cm.
Reft, C. S.↗
A New Simultaneous Membrane Thickness and Catalyst Loading Measurement for Fuel Cell Proton-Exchange Assemblies by $\mathrm{IR}$ Transmission
Here, we present a study of mid-infrared (mid-IR) transmission through typical proton-exchange fuel cell and water electrolyzer catalyst-coated membrane materials, and the determination of membrane layer thickness, and catalyst layer loading, from the power of the transmitted beam. Measured membrane thicknesses lay in the range of 25-125 um, and catalyst areal loadings range from 0.05 to 0.35 mg/cm 2 . We show that the transmission spectrum correlated to membrane thickness and catalyst loading values separately, and also used a mathematical model to calculate both quantities simultaneously, from a single measurement of transmission. Measurements were carried out using a Fourier-transform infrared (FTIR) spectrometer, in specular transmission mode, in the wavelength range of 3-13 um (3333-770 cm -1 ). We discuss the potential application of this method to the development of roll-to-roll manufacturing full-area-scanning quality inspection of catalyst-coated membrane (CCM) materials.
30 DIRECT ENERGY CONVERSION↗
Photon generators and engines for laser power transmission
High power continuous and pulsed coherent radiation generation by gas lasers, discussing transmission by proton generators and transforming engines
Ahlstrom, H. G.↗
In Vitro Studies on Space Radiation-Induced Delayed Genetic Responses: Shielding Effects
Understanding the radiation risks involved in spaceflight is of considerable importance, especially with the long-term occupation of ISS and the planned crewed exploration missions. Several independent causes may contribute to the overall risk to astronauts exposed to the complex space environment, such as exposure to GCR as well as SPES. Protons and high-Z energetic particles comprise the GCR spectrum and may exert considerable biological effects even at low fluence. There are also considerable uncertainties associated with secondary particle effects (e.g. HZE fragments, neutrons etc.). The interaction of protons and high-LET particles with biological materials at all levels of biological organization needs to be investigated fully in order to establish a scientific basis for risk assessment. The results of these types of investigation will foster the development of appropriately directed countermeasures. In this study, we compared the biological responses to proton irradiation presented to the target cells as a monoenergetic beam of particles of complex composition delivered to cells outside or inside a tissue phantom head placed in the United States EVA space suit helmet. Measurements of chromosome aberrations, apoptosis, and the induction of key proteins were made in bone marrow from CBA/CaJ and C57BL/6 mice at early and late times post exposure to radiation at 0, 0.5, 1 and 2 Gy while inside or outside of the helmet. The data showed that proton irradiation induced transmissible chromosomal/genomic instability in haematopoietic stem cells in both strains of mice under both irradiation conditions and especially at low doses. Although differences were noted between the mouse strains in the degree and kinetics of transforming growth factor-beta 1 and tumor necrosis factor-alpha secretion, there were no significant differences observed in the level of the induced instability under either radiation condition, or for both strains of mice. Consequently, when normalized to physical dose, the monoenergetic proton field present inside the helmet-protected phantom produced equivalent biological responses, when compared to unshielded cells, as measured by the induction of delayed genetic effects in murine haematopoietic stem cells.
Kadhim, Munira A.↗
Proton flare and magnetic storm effect in the vicinity of the Earth
We have developed a model and associated computational procedure for estimating energetic proton exposures during a major solar proton event that occur in combination with a large magnetic storm. Transmission functions for solar protons are computed using geomagnetic vertical cutoff data for quiescent amd disturbed conditions. Predicted exposures in low altitude polar orbit are found to be orders of magnitude greater for severe magnetic storm conditions than are corresponding exposures in the absence of major disturbances. We examine the response scenario for the events of November 1960 as an example.
Nealy, J. E.↗
Simulation of the Charged Particle Deflection From the Sweeping Magnet Array in the Lunar Environment Heliospheric X-Ray Imager
The Lunar Environment heliospheric X-ray Imager (LEXI) is an instrument built to image x-rays from solar wind charge exchange in Earth’s magneto sheath. Monitoring the position of the magnetopause at the inner boundary of the magneto sheath allows us to understand how magnetic reconnection regulates how energy from the solar wind is deposited into Earth’s magnetosphere. LEXI is part of an upcoming lunar lander mission set to land in Mare Crisium. To repel unwanted charged particles, the instrument carries a permanent magnet array composed of 48 neodymium magnets. The array was designed to maximize charged particle deflection while minimizing stray magnetic fields, which could impact other instruments or spacecraft operation. A Runge–Kutta-based fully kinetic particle tracing model was created to evaluate the effectiveness of LEXI’s unique charged particle deflector array. Combined with the other particle suppression measures of the instrument, including physical structures and filters, the simulations show proton and electron transmission to the LEXI detector is expected to be sufficiently reduced to allow successful imaging. The flexible simulation model can be generalized to be used in examining the magnetic deflector array effectiveness of other instruments whose signals could be compromised by unwanted charged particle contamination.
Space environment effects↗
Product ion distributions using H 3 O + proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS): mechanisms, transmission effects, and instrument-to-instrument variability
Abstract. Proton-transfer-reaction mass spectrometry (PTR-MS) using hydronium ion (H3O+) ionization is widely used for the measurement of volatile organic compounds (VOCs) both indoors and outdoors. H3O+ ionization, as well as the associated chemistry in an ion–molecule reactor, is known to generate product ion distributions (PIDs) that include other product ions besides the proton-transfer product. We present a method, using gas-chromatography pre-separation, for quantifying PIDs from PTR-MS measurements of nearly 100 VOCs of different functional types including alcohols, ketones, aldehydes, acids, aromatics, organohalides, and alkenes. We characterize instrument configuration effects on PIDs and find that reactor reduced electric field strength (E/N), ion optic voltage gradients, and quadrupole settings have the strongest impact on measured PIDs. Through an interlaboratory comparison of PIDs measured from calibration cylinders, we characterized the variability of PID production from the same model of PTR-MS across seven participating laboratories. Product ion variability was generally smaller (e.g., < 20 %) for ions with larger contributions to the PIDs (e.g., > 0.30) but less predictable for product ions formed through O2+ and NO+ reactions. We present a publicly available library of H3O+ PTR-MS PIDs that will be updated periodically with user-provided data for the continued investigation into instrument-to-instrument variability of PIDs.
Link, Michael F. (ORCID:0000000218412455)↗
Production of zirconium-88 via proton irradiation of metallic yttrium and preparation of target for neutron transmission measurements at DICER
Abstract A process for the production of tens to hundreds of GBq amounts of zirconium-88 ( 88 Zr) using proton beams on yttrium was developed. For this purpose, yttrium metal targets (≈20 g) were irradiated in a ~16 to 34 MeV proton beam at a beam current of 100–200 µA at the Los Alamos Isotope Production Facility (IPF). The 88 Zr radionuclide was produced and separated from the yttrium targets using hydroxamate resin with an elution yield of 94(5)% (1σ). Liquid DCl solution in D 2 O was selected as a suitable 88 Zr sample matrix due to the high neutron transmission of deuterium compared to hydrogen and an even distribution of 88 Zr in the sample matrix. The separated 88 Zr was dissolved in DCl and 8 µL of the obtained solution was transferred to a tungsten sample can with a 1.2 mm diameter hole using a syringe and automated filling station inside a hot cell. Neutron transmission of the obtained 88 Zr sample was measured at the Device for Indirect Capture Experiments on Radionuclides (DICER).
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Influence of electrical field on the susceptibility of gallium nitride transistors to proton irradiation
Radiation susceptibility of electronic devices is commonly studied as a function of radiation energetics and device physics. Often overlooked is the presence or magnitude of the electrical field, which we hypothesize to play an influential role in low energy radiation. Accordingly, we present a comprehensive study of low-energy proton irradiation on gallium nitride high electron mobility transistors (HEMTs), turning the transistor ON or OFF during irradiation. Commercially available GaN HEMTs were exposed to 300 keV proton irradiation at fluences varying from 3.76 × 10 12 to 3.76 × 10 14 cm 2 , and the electrical performance was evaluated in terms of forward saturation current, transconductance, and threshold voltage. The results demonstrate that the presence of an electrical field makes it more susceptible to proton irradiation. The decrease of 12.4% in forward saturation and 19% in transconductance at the lowest fluence in ON mode suggests that both carrier density and mobility are reduced after irradiation. Additionally, a positive shift in threshold voltage (0.32 V and 0.09 V in ON and OFF mode, respectively) indicates the generation of acceptor-like traps due to proton bombardment. high-resolution transmission electron microscopy and energy dispersive x-ray spectroscopy analysis reveal significant defects introduction and atom intermixing near AlGaN/GaN interfaces and within the GaN layer after the highest irradiation dose employed in this study. According to in-situ Raman spectroscopy, defects caused by irradiation can lead to a rise in self-heating and a considerable increase in (∼750 times) thermoelastic stress in the GaN layer during device operation. The findings indicate device engineering or electrical biasing protocol must be employed to compensate for radiation-induced defects formed during proton irradiation to improve device durability and reliability.
gallium nitride↗
Shock Acceleration of Solar Energetic Protons: The First 10 Minutes
Proton acceleration at a parallel coronal shock is modeled with self-consistent Alfven wave excitation and shock transmission. 18 - 50 keV seed protons at 0.1% of plasma proton density are accelerated in 10 minutes to a power-law intensity spectrum rolling over at 300 MeV by a 2500km s-1 shock traveling outward from 3.5 solar radius, for typical coronal conditions and low ambient wave intensities. Interaction of high-energy protons of large pitch-angles with Alfven waves amplified by low-energy protons of small pitch angles is key to rapid acceleration. Shock acceleration is not significantly retarded by sunward streaming protons interacting with downstream waves. There is no significant second-order Fermi acceleration.
Ng, Chee K.↗
Stripping Foils at the RHIC Injectors: A History
Stripping foils are used throughout Collider-Accelerator Department to strip ions of unwanted electrons. This is done in stages throughout the complex to optimize the transmission of particles. For polarized protons, they are injected into the AGS Booster as H-, and then stripped to H+. For ions from the tandem source, there are two stripping foils: one at the center and the other at the end of the tandem. The tandem foils will not be covered in this document. For ions out of the EBIS source, there is no use of stripping foils upstream of injection into the Booster. All ions that are not fully stripped in Booster are stripped further in the Booster to AGS (BTA) transfer line stripping foil assembly. Finally, any ions that are not fully stripped in the AGS are either stripped in the AGS to RHIC transfer line stripping foil, or as they are being dumped in the AGS by the plunging stripping foil (PSF) dependent on the particles intensity and charge. The BTA foil is the workhorse of the complex, having to provide the desired charge state of ions as light as O, and as heavy as Uranium. Optimizing the stripping efficiency to the desired charge state, while minimizing the energy lost and emittance growth from transiting the foil, requires careful consideration of the foil materials and thicknesses. This paper serves an overview of stripping foils at C-AD, with a review of foils from the construction of the AGS Booster to now.
43 PARTICLE ACCELERATORS↗
Friction and Wear Properties of As-deposited and Carbon Ion-implanted Diamond Films
Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 ke V ion energy, resulting in a dose of 1.2310(exp 17) carbon ions/cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40 percent relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and were properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to 10(exp -8)mm(exp 3)/N-m) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4)mm(exp 3/N-m) in ultrahigh vacuum. The carbon ion implanation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, nondiamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine- and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7)mm(exp 3/N-m). Even in ultrahigh vacuum, the presence of the nondiamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6)mm(exp 3)/N-m. Thus, the carbon ion-implanted, fine-grain diamond films can be effectively used as wear-resistant, self-lubricating coatings not only in air and dry nitrogen, but also in ultrahigh vacuum. The wear mechanism of diamond films is that of small fragments chipping off the surface. The size of wear particles is related to the extent of wear rates.
Miyoshi, Kazuhisa↗