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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Performance of deformed steel fibers embedded in ultra-high performance concrete subjected to various pullout rates

Fiber-matrix bond properties are typically evaluated using a single-fiber pullout test. Such tests for ultra-high performance concrete (UHPC) are few in the literature and, in particular, those that focus on high pullout rates are exceedingly rare. In this research program, different types of high-strength steel fibers (twisted, straight and hooked) are embedded in two UHPC matrices with varying amounts of glass powder, which is a key ingredient of UPHC. The specimens are subjected to loading rates ranging from 0.018 mm/s (representing quasi-static loading) to 1800 mm/s (representing impact loading). Experimental results show that the pullout response of all of the fiber types exhibit progressively increasing rate sensitivity as the pullout speed increases and becomes significant during impact loading. It is most prominent in the smooth and twisted fibers and least in the hooked fibers. Additionally, scanning electron microscope studies are presented and used to explain the mechanism of rate enhancement from a microscopic perspective.

36 MATERIALS SCIENCE↗

Comparison of Gel Relaxation Times and End-Block Pullout Times in ABA Triblock Copolymer Networks

The gel relaxation times of two different poly[styrene-$b$-(ethylene-alt-propylene)-$b$-styrene] (SEPS) ABA triblock copolymers in squalane at various concentrations has been measured by rheology. These relaxation times were compared with the results of previous time-resolved small-angle neutron scattering (TR-SANS) experiments, which measured chain exchange kinetics in SEP diblock and SEPS triblock micelles in squalane. We report the gels relaxed up to four orders of magnitude faster than expected based on the chain exchange measurements of equivalent diblock polymers. By accounting for two factors—a bias toward shorter end-block lengths in the gel relaxation, and a reduction in the energy barrier to chain pullout caused by the triblock architecture—a model is constructed that reconciles the surprisingly short gel relaxation times with the chain exchange times measured via TR-SANS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Field study of group effects on the pullout capacity of “deep” helical piles in sand

This paper presents the results of a field load test program used to investigate group effects on the pullout capacity of single-helix “deep” helical piles/anchors in sand. The high tensile capacity and silent installation of helical piles has given them serious consideration as an alternative to conventional deep foundations and anchors for offshore renewable energy structures. New offshore applications may consider the use of groups of helical piles to resist structural loads. Group interaction effects are known to occur in helical piles, but there is a scarcity of field data on groups in sands under tensile loading. This study involved the installation and load testing of single-helix 152mm diameter round shaft piles and pile groups embedded in sand to depths of 12 and 18 helix diameters below the ground surface. The study was designed to explore the effects of close pile spacing, group configuration (i.e., number of piles), and soil strength (i.e., friction angle) as interpreted from cone penetration test (CPT) resistance. The results showed group efficiencies ranging from about 0.6 to 1.0 at a horizontal spacing of 2 to 3 times the helix diameter in sands with friction angles of about 39° to 44°. The data from this study may also be useful for validation of numerical models for analysis of helical pile group interactions.

Engineering↗

Failure Analysis of Three-Sheet Stackup Structure Made of Dissimilar High-Strength Steel

A three-sheet stackup structure consisting of B1500HS and B250P1 dissimilar high-strength steel was produced by resistance spot welding. The failure mode and energy absorption ability of two typical samples were investigated in typical loading state such as shear and cross-tension test. Moreover, the fracture characteristics were observed by scanning electron microscopy and the fracture process was analyzed based on the loading state. Results show two samples fracture in interfacial mode or pullout mode in shear test and fracture only in pullout mode in cross-tension test. Despite the different fracture modes, fractured sample shows ductile characteristics during mechanical tests. Compared with the sample fractured in interfacial mode, sample fractured in pullout mode has higher ultimate load and energy absorption ability in shear test. Moreover, sample absorbs more failure energy in cross-tension test than that in shear test because of the deformation of structure in cross-tension test. Both carbon equivalent and welding conditions affect the hardness of the fusion zone—a lower CE value leads to a softer HAZ which helps to promote pullout failure in the cross-tension test.

36 MATERIALS SCIENCE↗

The impact of core-shell nanotube structures on fracture in ceramic nanocomposites

Multi-wall carbon nanotubes (MWCNTs) can be used to create ceramic nanocomposites with improved fracture toughness. In the present work, atomic layer deposition (ALD) was employed to deposit thin oxide layers on MWCNTs. These core-shell structures were then used to create nanocomposites by using a polymer derived ceramic (PDC) to produce the matrix. Variations in both the initial MWCNT structure and the oxide layers led to substantial differences in fiber-pullout behavior. Single tube pullout tests also showed that the oxide coatings led to stronger bonding with the ceramic matrix. With high defect density MWCNTs, this led to shorter pull-out lengths which is consistent with the conventional understanding of fracture in ceramic matrix composites. However, with low defect density MWCNTs longer pullout lengths were observed with the oxide layers. To interpret the different trends that were observed, we believe that the ALD coatings should not be viewed simply as a means of altering the interfacial properties. Instead, the coated MWCNTs should be viewed as more complex core-shell fibers where both interface and internal properties can be controlled with the ALD layers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Influence of fiber inclination angle on bond-slip behavior of different alkali-activated composites under dynamic and quasi-static loadings

This study investigates the influence of inclination angle (0° and 45°) on the interfacial bond-slip behavior of macro steel fibers (straight, hooked end-deformed and length-deformed) and length-deformed polypropylene fibers reinforced in fly-ash and metakaolin based alkali-activated composites (AACs) under quasi-static and dynamic loadings. AACs demonstrate superior peak bond strength and toughness compared to cement composites regardless of fiber type and loading rate. Results also show that straight steel fiber exhibits a complete pullout in AACs. The amount of deformation of the fibers (deformation ratio) determined the failure type at different inclination angle and loading rate, thus governing the peak load and energy absorption. Depending on the fiber orientation, premature fiber rupture or matrix cracking is observed under dynamic loading in AACs due to matrix brittleness. The fiber failure modes in dynamic pullout are no different from those observed in the quasi-static pullout in AACs.

36 MATERIALS SCIENCE↗

ALFA Discrete Element Method (DEM) Simulations using PFC3D

Contains input scripts, background information, reduced data, and results associated with the discrete element method (DEM) simulations of interface shear tests, plate anchor pullout tests, and torpedo anchor installation and pullout tests, using the software PFC3D (v4.0).

16 TIDAL AND WAVE POWER↗

Microstructure and Interfacial Shear Strength in W/(Zr{sub 55}Cu{sub 30}Al{sub 10}Ni{sub 5}){sub 100−x}Nb{sub x} Composites

In the present study, (Zr{sub 55}Cu{sub 30}Al{sub 10}Ni{sub 5}){sub 100−x}Nb{sub (x=0,1,2,3)} bulk metallic glass matrix/tungsten wire composites were fabricated by a gas pressure infiltration process at temperature 950 °C for 5 min. Microstructural studies and mechanical behaviors of the materials have been investigated by scanning electron microscopy, transmission electron microscopy and pullout tests. The mechanical results showed that the interface shear strength in the composite sample with X = 2 increased more than twice compared to the composite sample with X = 0. Based on the microstructural results, the addition of two atomic percent Nb in the matrix composite causes an increase in the diffusion band thickness during the melt infiltration and change in the interface fracture mode as a result of pullout test.

36 MATERIALS SCIENCE↗

Intramedullary Unicortical Button and All-Suture Anchors Provide Similar Maximum Strength for Onlay Distal Biceps Tendon Repair

To evaluate the biomechanical profile of onlay distal biceps repair with an intramedullary unicortical button versus all-suture anchors under cyclic loading and maximal load to failure. Twenty paired fresh-frozen human cadaveric elbows were randomized to onlay distal biceps repair with either a single intramedullary button or with two 1.35-mm all-suture anchors. A 1.3-mm high tensile strength tape was used in a Krackow stitch to suture the tendons in both groups. Specimens and repair constructs were loaded for 3,000 cycles and then loaded to failure. Maximum load to failure, mode of failure, and construct elongation were recorded. Mean (± standard deviation) maximum load to failure for the unicortical intramedullary button and all-suture anchor repairs were 503.23 ± 141.77 N and 537.33 ± 262.13 N (P = .696), respectively. Mean maximum displacement after 3,000 cycles (± standard deviation) was 4.17 ± 2.05 mm in the button group and 2.06 ± 1.05 mm in the suture anchor group (P = .014). Mode of failure in the button group was suture tape rupture in 7 specimens, failure at the tendon–suture interface in 2 specimens, and button pullout in 1 specimen. Anchor pullout was the mode of failure in all suture anchor specimens. There were no tendon ruptures or radial tuberosity fractures in either group. In conclusion, this study demonstrates that onlay distal biceps repair with 2 all-suture anchors has similar maximum strength to repair with an intramedullary button and that both are viable options for fixation.

60 APPLIED LIFE SCIENCES↗

Effect of nano-SiO{sub 2} particles and curing time on development of fiber-matrix bond properties and microstructure of ultra-high strength concrete

Bond properties between fibers and cementitious matrix have significant effect on the mechanical behavior of composite materials. In this study, the development of steel fiber-matrix interfacial bond properties in ultra-high strength concrete (UHSC) proportioned with nano-SiO{sub 2} varying between 0 and 2%, by mass of cementitious materials, was investigated. A statistical model relating either bond strength or pullout energy to curing time and nano-SiO{sub 2} content was proposed by using the response surface methodology. Mercury intrusion porosimetry (MIP) and backscatter scanning electron microscopy (BSEM) were used to characterize the microstructure of the matrix and the fiber-matrix interface, respectively. Micro-hardness around the embedded fiber and hydration products of the matrix were evaluated as well. Test results indicated that the optimal nano-SiO{sub 2} dosage was 1% in terms of the bond properties and the microstructure. The proposed quadratic model efficiently predicted the bond strength and pullout energy with consideration of curing time and nano-SiO{sub 2} content. The improvement in bond properties associated with nano-silica was correlated with denser matrix and/or interface and stronger bond and greater strength of hydration products based on microstructural analysis.

36 MATERIALS SCIENCE↗

On the use of limestone calcined clay cement (LC3) in high-strength strain-hardening cement-based composites (HS-SHCC)

Highlights: • Use of LC{sup 3} slightly reduces flowability and shortens the setting time of fresh matrices. • Highly polymerized C-A-S-H gel and abundant ettringite benefit flexural strength of LC{sup 3}-matrices. • Use of LC{sup 3} enhances the bond strength between fiber and high-strength matrix. • LC{sup 3}-based HS-SHCC yields similar flexural performance as the composite with Portland cement. High-strength strain-hardening cement-based composites (HS-SHCC) demonstrate excellent mechanical and durability properties. However, high cement content typical to HS-SHCC results not only in high carbon footprint, but also in excessive hydration heat and severe autogenous shrinkage. In this investigation, Limestone Calcined Clay Cement (LC{sup 3}) was used to produce sustainable HS-SHCC. The LC{sup 3} substitution resulted in higher energy consumption during mixing and in shorter setting times of the fresh, plain matrices. Although the LC{sup 3} substitution slightly reduced the compressive strength, the formation of highly polymerized C-A-S-H gel and abundant ettringite benefited the flexural strength of the plain matrices. Additionally, single-fiber pullout experiments showed that the use of LC{sup 3} led to increased fiber-matrix bond strength and pullout energy. Finally, the replacement of Portland cement by LC{sup 3} resulted in HS-SHCC with similar mechanical performance to the reference composite, indicating a high potential for using LC{sup 3} in high-performance cement-based composites.

36 MATERIALS SCIENCE↗

Concentration-Driven Slowdown of Chain-Exchange Kinetics in Block Copolymer Micelle Solutions

Here, we investigate the dependence of chain-exchange kinetics on polymer concentration for spherical micelles prepared from a polystyrene-b-poly(ethylene-alt-propylene) (SEP) diblock copolymer ( M n = 75 kDa, Ð = 1.05, and f PS = 0.18) in the PEP-selective solvent squalane. Solutions with concentrations of 15 vol% or more adopt a body-centered-cubic (BCC) packing of micelles, or a dense liquid-like packing (LLP), as confirmed by small-angle X-ray scattering. Concurrently, the mean aggregation number of the micelles grows steadily from about 60 in dilute solution to nearly 200 by 50 vol%. Time-resolved small-angle neutron scattering (TR-SANS) analysis reveals a monotonic and substantial (i.e., more than four orders of magnitude) decrease in the rate of chain exchange as the polymer concentration increases from 1 to 50 vol%. The TR-SANS relaxation functions are analyzed, taking into account both changes in contrast (due to chain exchange) and evolution in the structure factor (due to refinement of micelle packing). The activation energy for chain pullout is extracted using an established model and can be expressed as a linear function of polymer concentration, indicating that, in addition to the enthalpic barrier for extracting the core block, the evolution of micelle characteristics with increasing concentration imposes further constraints on chain exchange. Consistent with a theory of Halperin, these results suggest that the dominant factor reflects steric penalties during core block pullout arising from a reduced interfacial area per chain and associated increased corona crowding, due to the increase in aggregation number. The rate of exchange is independent of whether the micelles adopt a BCC or LLP arrangement, confirming that the rate-limiting step is extraction of the core block.

chemical structure↗

How Does the Rate of Chain Exchange Relate to Stress Relaxation in Triblock Copolymer Networks?

The relationship between macroscopic stress relaxation and molecular-level chain exchange in triblock copolymer micelles has been explored using rheology and time-resolved small-angle neutron scattering (TR-SANS), marking the first measurements of chain exchange in concentrated triblock networks. It has long been assumed in models of transient or thermoreversible networks that the time scales for these two processes are equal. Experimentally, we find that stress relaxation occurs many orders-of-magnitude faster than chain exchange. This difference is quantitatively explained by modest dispersity in the core block that results in a slight asymmetry within any given nominally symmetric triblock. For stress relaxation to occur, only the shorter chain must pull out, while chain exchange is slowed due to the requirement of the eventual pullout of the longer block. The pullout time is extremely sensitive to the length of the core block. This mechanism is supported by measurements with an intentionally asymmetric triblock copolymer, which displays an even larger difference between the stress relaxation and chain exchange rates. These results establish a quantitative molecular-level picture of the chain dynamics associated with stress relaxation in triblock copolymer networks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Use of polypropylene fibers coated with nano-silica particles into a cementitious mortar

Fiber reinforced cementitious composite (FRCC) materials have been widely used during last decades in order to overcome some of traditional cementitious materials issues: brittle behaviour, fire resistance, cover spalling, impact strength. For composite materials, fiber/matrix bond plays an important role because by increasing fiber/matrix interactions is possible to increase the behaviour of the entire material. In this study, in order to improve fiber to matrix adhesion, two chemical treatments of polypropylene fibers were investigated: alkaline hydrolysis and nano-silica sol-gel particles deposition. Treatmtents effect on fibers morphology and mechanical properties was investigated by scanning electron microscopy (SEM) and tensile tests. SEM investigations report the presence of spherical nano-silica particles on fiber surface, in the case of sol-gel process, while alkaline hydrolysis leads to an increase of fibers roughness. Both treatments have negligible influence on fibers mechanical properties confirming the possibility of their use in a cementitious mortar. Pullout tests were carried out considering three embedded length of fibers in mortar samples (10, 20 and 30 mm, respectively) showing an increase of pullout energy for treated fibers. The influence on fiber reinforced mortar mechanical properties was investigated by three-point flexural tests on prismatic specimens considering two fibers length (15 and 30 mm) and two fibers volume fractions (0.50 and 1.00 %). A general increase of flexural strength over the reference mix was achieved and an overall better behaviour is recognizable for mortars containing treated fibers.

36 MATERIALS SCIENCE↗

Mechanical and Corrosion Assessment of Friction Self-Piercing Rivet Joint of Carbon Fiber-Reinforced Polymer and Magnesium Alloy AZ31B

In the present work, thermoset carbon fiber–reinforced polymer (CFRP) was spot joined to magnesium alloy AZ31B by a friction self-piercing riveting (F-SPR) process. Lap shear tensile and cross-tension testing were used to evaluate the mechanical joint performance. An average lap shear tensile load of 5.18 kN was achieved, while an average of 2.81 kN was found from cross-tension testing. All F-SPR samples showed a pullout of AZ31B after mechanical testing, indicating good mechanical interlocking between the steel rivet and AZ31B. Corrosion potential was measured for each material to establish the galvanic corrosion characteristics. As expected, AZ31B was found to be the most active, while thermoset CFRP was the most noble. The steel rivet fell between the AZ31B (active) and the thermoset CFRP (noble). Salt fog corrosion testing (ASTM B-117) was performed to evaluate the corrosion performance of the uncoated F-SPR joint. With up to 200 h of exposure, the post-corroded F-SPR joint integrity retained 81.2% of the pre-exposure F-SPR joint strength with AZ31B pullout failure mode. From cross-sectional analysis of the F-SPR joint, extensive corrosion of AZ31B was observed at the joint and other exposure areas. However, steel rivet was not significantly corroded due to sacrificial anode effect by which AZ31B corroded first in the galvanic couple.

36 MATERIALS SCIENCE↗

Characterization of Static Performance and Failure of Resistance Spot Welds of High-Strength and Press-Hardened Steels

The static performances and failure characteristics of resistance spot welds (RSW) of steel sheets were studied in this work. Both similar and dissimilar joints of press-hardened steel grade 22MnB5 and as-rolled high-strength steel grade 1000 were examined. From metallographic analyses and micro-hardness measurements, it was shown that the microstructures of base metal (BM), heat affected zone (HAZ) and fusion zone of steel joints were noticeably different. In particular, the HAZ close to BM or subcritical HAZ (SCHAZ) of 22MnB5 steel exhibited greatly decreased hardness due to occurring tempered martensite, in which carbide precipitation was clearly observed. Furthermore, tensile shear test and cross-tension test of the welded steel sheets were carried out. The determined maximum loads, energy absorbability and corresponding failure mechanisms were analyzed and compared. The RSW samples of similar steel grade 1000 provided the highest load-carrying capacity and absorbed energy in both tests. Due to the large hardness difference and soft zone in weldment of dissimilar steel specimen, failure loads and static absorbed energies were deteriorated up to 17 and 68%, respectively. The observed fracture occurrences of all investigated joints were pullout failure mode, in which BM and HAZ were the crack initiation sites of grades 1000 steel and 22MnB5 steel, respectively. The SCHAZ of welded boron steel considerably caused the failure onset in tension shear test, but seemed to have negligible effect on cross-tension test.

36 MATERIALS SCIENCE↗