Convective carbon dioxide dissolution in a closed porous medium at high-pressure real-gas conditions
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A real gas, upwind, parabolized Navier-Stokes (PNS) code has been developed to compute the three-dimensional hypersonic flow of equilibrium air around various body shapes. The new code is an extension of the upwind (perfect gas) PNS code of Lawrence et al. (1986). The upwind algorithm is based on Roe's (1981) flux-difference splitting scheme which has been modified to account for real gas effects using the nearly exact approach of Vinokur and Liu (1988). Simplified curve fits are employed to obtain the thermodynamic and transport properties of equilibrium air. The new code has been validated by computing the M-infinity = 25 laminar flow of air over cones at various angles of attack. The results of these computations are compared with the results from a conventional centrally-differenced, real gas PNS code and the previous axisymmetric, upwind, real gas code. The agreement is excellent in all cases.
A real gas, upwind, parabolized Navier-Stokes (PNS) code has been developed to compute the two-dimensional/axisymmetric hypersonic flow of equilibrium air around various body shapes. The new code is an extension of the upwind (perfect gas) PNS code of Lawrence, Tannehill and Chaussee. The upwind algorithm is based on Roe's flux-difference splitting scheme which has been modified to account for real gas effects. Simplified curve fits are used to obtain the thermodynamic and transport properties of equilibrium air. The new code has been validated by computing the hypersonic laminar flow of air over a flat plate, a wedge, a ramp, and a cone. The results of these computations are compared with the results from a conventional centrally-differenced, real gas, PNS code and the agreement is excellent, except in the vicinity of shock waves where the present code exhibits far superior shock capturing capabilities.
This paper presents a description of the changes and additions to the perfect gas PARC2D code to include chemical equilibrium effects, resulting in a code called PARCEQ2D. The work developed out of a need to have the capability of more accurately representing the flowfield surrounding the aeroassist flight experiment (AFE) vehicle. Use is made of the partition function of statistical mechanics in the evaluation of the thermochemical properties. This approach will allow the PARC code to be extended to thermal nonequilibrium when this task is undertaken in the future. The transport properties follow from formulae from the kinetic theory of gases. Results are presented for a two-dimensional AFE that compare perfect gas and real gas solutions at flight conditions, showing vast differences between the two cases.
Validation activities and facility types are discussed for six different flow codes: (1) perfect gas; (2) real gas; (3) nozzle/plume; (4) combustion; (5) thermochemical nonequilibrium; and (6) boundary layer and transition. All data and results are presented in viewgraph format.
Laminar, real gas hypersonic flowfields over a three dimensional configuration are computed using an unsteady, factored implicit scheme. Local chemical and thermodynamic properties are evaluated by an equilibrium composition method. Transport properties are obtained from individual species properties and application of a mixture rule. Numerical solutions are presented for an ideal gas and equilibrium air for free-stream Mach numbers of 13 and 15 and at various angles of attack. The effect of real gas is to decrease the shock-layer thickness resulting from decreased shock-layer temperatures and corresponding increased density. The combined effects of viscosity and real gas are to increase the subsonic layer near the wall.
High-temperature effects alter the physical and transport properties of a gas, air in particular, due to vibrational excitation and gas dissociation, and thus the chemical reactions have to be considered in order to compute the flow field. Linear stability of high-temperature boundary layers is investigated under the assumption of chemical equilibrium and this gas model is labeled here as real gas model. In this model, the system of stability equations remains of the same order as for the perfect gas and the effect of chemical reactions is introduced only through mean flow and gas property variations. Calculations are performed for Mach 10 and 15 boundary layers and the results indicate that real gas effects cause the first mode instability to stabilize while the second mode is made more unstable. It is also found that the second mode instability shifts to lower frequencies. There is a slight destabilizing influence of real gas on the Goertler instability as compared to the perfect gas results.
Real gas properties of helium which is used in electrically driven shock tubes
Critical issues concerning real gas effects in hypervelocity flows where the thermochemical nonequilibrium effects are pronounced, are described. Emphasis is on the development and validation of benchmark analysis tools. Approaches to develop and/or enhance phenomenological models, including test techniques to acquire databases, and incorporate them into computational flow field simulation codes are described. The performance characteristics of shock tubes, ballistic ranges and arc heated wind tunnels, state of the art diagnostics are included. The following aerothermodynamic phenomena are discussed: aerodynamic parameters, viscous interactions, turbulent transition, forebody heating/heat transfer, radiative heating, Lee-Base flows and low density real gas.
Real gas corrections to gas flow computations for sonic nozzles
Real gas mass flow rate computation through sonic nozzle
This paper presents a computational study of real-gas effects on the mean flow and temporal stability of heptane/nitrogen and oxygen/hydrogen mixing layers at supercritical pressures. These layers consist of two counterflowing free streams of different composition, temperature, and density. As in related prior studies reported in NASA Tech Briefs, the governing conservation equations were the Navier-Stokes equations of compressible flow plus equations for the conservation of total energy and of chemical- species masses. In these equations, the expressions for heat fluxes and chemical-species mass fluxes were derived from fluctuation-dissipation theory and incorporate Soret and Dufour effects. Similarity equations for the streamwise velocity, temperature, and mass fractions were derived as approximations to the governing equations. Similarity profiles showed important real-gas, non-ideal-mixture effects, particularly for temperature, in departing from the error-function profile, which is the similarity solution for incompressible flow. The temperature behavior was attributed to real-gas thermodynamics and variations in Schmidt and Prandtl numbers. Temporal linear inviscid stability analyses were performed using the similarity and error-function profiles as the mean flow. For the similarity profiles, the growth rates were found to be larger and the wavelengths of highest instability shorter, relative to those of the errorfunction profiles and to those obtained from incompressible-flow stability analysis. The range of unstable wavelengths was found to be larger for the similarity profiles than for the error-function profiles
A theoretical study was performed addressing the degree of applicability or inapplicability, to a real gas, of the occasionally stated belief that for an ideal gas, incompressibility is synonymous with a zero or very low Mach number. The measure of compressibility used in this study is the magnitude of the divergence of the flow velocity vector [V(bar) (raised dot) u (where u is the flow velocity)]. The study involves a mathematical derivation that begins with the governing equations of flow and involves consideration of equations of state, thermodynamics, and fluxes of heat, mass, and the affected molecular species. The derivation leads to an equation for the volume integral of (V(bar) (raised dot) u)(sup 2) that indicates contributions of several thermodynamic, hydrodynamic, and species-flux effects to compressibility and reveals differences between real and ideal gases. An analysis of the equation leads to the conclusion that for a real gas, incompressibility is not synonymous with zero or very small Mach number. Therefore, it is further concluded, the contributions to compressibility revealed by the derived equation should be taken into account in simulations of real-gas flows.
Preflight estimates of the hypersonic aerodynamic characteristics of the Shuttle orbiter were based on a diverse series of research studies using state of the art techniques developed by basic research in the 60's and 70's. Real-gas viscous calculations on simple shapes that were used to evaluate correlation parameters indicated that real-gas effects reduce aerodynamic forces and moments. Inviscid calculations on winged lifting shapes indicated reduced forces and a slight nose-up pitch resulted because of real-gas effects. Analysis of the extensive wind tunnel data base indicated viscous correlation parameters provided the most appropriate extrapolation technique for estimating flight aerodynamics. Variations because of changes in the ratio of specific heats, which was the only available experimental tool for evaluating real-gas effects, indicated that reduced loads and nose-up pitching moments would occur at high altitudes and Mach numbers but that the values would not exceed the tolerances and variations established about the aerodynamic design data book values derived from viscous correlations. During STS-1, nose-up pitching moments exceeded the established variations.
Numerical codes were developed to calculate the two dimensional flow field which results when supersonic flow encounters double wedge configurations whose angles are such that a type 4 pattern occurs. The flow field model included the shock interaction phenomena for a delta wing orbiter. Two numerical codes were developed, one which used the perfect gas relations and a second which incorporated a Mollier table to define equilibrium air properties. The two codes were used to generate theoretical surface pressure and heat transfer distributions for velocities from 3,821 feet per second to an entry condition of 25,000 feet per second.
Air flow in a hypersonic nozzle causes real gas effects due to reaction among the species constituting air. Such reactions may be in chemical equilibrium or in chemical nonequilibrium. Here using the CSCM upwind scheme for the compressible Navier-Stokes equations, the real gas flowfield in an arcjet nozzle is computed for both the equilibrium case and the nonequilibrium case. A hypersonic nozzle flow arising from a pebble bed heated plenum is also computed for the equilibrium situation. Between the equilibrium cases, the chemistry is treated by two different schemes and comments are made as to computational complexity. For the nonequilibrium case, a full set of seventeen reactions and full implicit coupling of five species with gasdynamics is employed to compute the flowfield. For all cases considered here the gas is assumed to be a calorically imperfect mixture of ideal gases in thermal equilibrium.
A four month feasibility study of a hypersonic real-gas free flight test facility for NASA Langley Research Center (LARC) was performed. The feasibility of using a high-energy electromagnetic launcher (EML) to accelerate complex models (lifting and nonlifting) in the hypersonic, real-gas facility was examined. Issues addressed include: design and performance of the accelerator; design and performance of the power supply; design and operation of the sabot and payload during acceleration and separation; effects of high current, magnetic fields, temperature, and stress on the sabot and payload; and survivability of payload instrumentation during acceleration, flight, and soft catch.
A straightforward procedure has been developed to quickly determine an inviscid design of a hypersonic wind tunnel nozzle when the test crash is both calorically and thermally imperfect. This real gas procedure divides the nozzle into four distinct parts: subsonic, throat to conical, conical, and turning flow regions. The design process is greatly simplified by treating the imperfect gas effects only in the source flow region. This simplification can be justified for a large class of hypersonic wind tunnel nozzle design problems. The final nozzle design is obtained either by doing a classical boundary layer correction or by using this inviscid design as the starting point for a viscous design optimization based on computational fluid dynamics. An example of a real gas nozzle design is used to illustrate the method. The accuracy of the real gas design procedure is shown to compare favorably with an ideal gas design based on computed flow field solutions.