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At least 19 records

Post-Release Survivorship in a New Population of Blanding's Turtles Established Using Headstarted and Directly Released Turtles

Blanding’s Turtles are facing a variety of anthropogenic threats that decrease population viability. We initiated a project to establish a new population of Blanding’s Turtles on a National Wildlife Refuge in Massachusetts using hatchlings obtained from a nearby robust donor population. We released 440 head-started individuals and 401 directly-released hatchlings between 2007–2013 and conducted multiple years of post-release monitoring via aquatic trapping to estimate survival. Between 2014–2021 we released an additional 824 head-started and 433 directly-released individuals and conducted one year of aquatic trapping in 2021 to estimate population size. First year post-release survival of head-started turtles was six times that of directly-released hatchlings (0.72 vs. 0.12, respectively), but annual survival of both groups was 0.78–0.90 in subsequent years. Only 19% of turtles released at <60 mm carapace length (CL) were subsequently recaptured compared to 60% of those released at ≥60 mm CL, supporting 60 mm CL as a target minimum release size. The mean population estimates using two different study designs were 164 and 202, with 91 individuals encountered. Now that turtles released early in the project are approaching reproductive maturity, we recommend resampling and expanding trapping efforts to include more wetlands to assess long-term survival, abundance, and distribution of Blanding’s Turtles in this newly established population. Furthermore, our results, combined with other evaluations of head-starting across the species’ range, add credence to the use of head-starting as a population recovery tool for Blanding’s Turtles.

59 BASIC BIOLOGICAL SCIENCES↗

The Seventeenth Data Release of the Sloan Digital Sky Surveys: Complete Release of MaNGA, MaStar, and APOGEE-2 Data

This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 survey that publicly releases infrared spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the subsurvey Time Domain Spectroscopic Survey data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey subsurvey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated value-added catalogs. This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper, Local Volume Mapper, and Black Hole Mapper surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

Impact of breech geometry and propellant flow on the release of large pellets for the ITER disruption mitigation system

Studies have been performed on the release mechanism for large pellets using high pressure gas in a shattered pellet injector. Typically, pellets are dislodged from the cryogenic surface and accelerated down a barrel using high pressure gas delivered by a fast-acting propellant valve. The pellets impact an angled surface which shatters the pellet into many small fragments before entering the plasma. This technique was initially demonstrated on DIII-D (Commaux et al 2016 Nucl. Fusion 56 046007) and is now deployed on JET, KSTAR, ASDEX-Upgrade, and other tokamaks around the world in support of ITER's disruption mitigation system design and physics basis. The large hydrogen, 28.5 mm diameter, 2 length-to-diameter ratio, pellets foreseen for ITER SPI operation have low material strength and low heat of sublimation, which cause the pellets to be fragile and highly reactive to the impact of warm propellant gas. Due to the size of the pellets, significantly more propellant gas is required to dislodge and accelerate them. This creates a potentially significant propellant gas removal issue as 2–6 bar-L of gas is expected to be required for release and speed control. The research presented in this paper is an in-depth exploration of the parameters that are keys to reliable pellet release and speed control. Computational fluid dynamics (CFD) modeling of propellant flows through various breech designs was conducted to determine the force generated on the back surface of a pellet. These simulations assumed the use of the ORNL designed flyer plate valve. CFD modeling combined with experimental measurements provide adequate insight to determine a path to an optimal valve and breech design for ITER SPI pellet release and speed control while minimizing propellant gas usage.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Conservative Release Fraction Correlation for Spray Releases

Washington River Protection Solutions, LLC (WRPS) is planning to conduct repairs in the Liquid Effluent Retention Facility (LERF), and prior to conducting this work they will re-evaluate the hazard category designation for LERF. As part of this evaluation, WRPS needs estimates of the release fraction of potential accidental sprays, because a spray release is a potential bounding accident. Pacific Northwest National Laboratory previously developed a conservative correlation for the cumulative generation rate (volume per time) of aerosol droplets less than or equal to specific sizes from spray releases as a function of the spray pressure, orifice area, and droplet diameter. To obtain release fraction estimates from the conservative generation rate correlation, the correlation needs to be recast by dividing the aerosol generation rate by the flow rate of a spray. In the current study, a conservative release fraction correlation was developed from the conservative aerosol generation rate correlation developed previously by dividing the generation rate correlation by the flow rate of a spray using an orifice flow rate equation and then this correlation was adjusted to be conservative. Test data were also extrapolated to a lower pressure than the lowest pressure tested (100 psig) for the spray data used for developing the previous conservative generation rate correlation. The new conservative release fraction correlation was then used to predict release fractions of respirable droplets (droplets = 10 µm) for four specific pipes that are part of LERF.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The 16th Data Release of the Sloan Digital Sky Surveys: First Release from the APOGEE-2 Southern Survey and Full Release of eBOSS Spectra

The Sloan Digital Sky Surveys (SDSS) have been observing the skies from Apache Point Observatory (APO) since 1998 (using the 2.5m Sloan Foundation Telescope, Gunn et al. 2006) and from Las Campanas Observatory (LCO) since 2017 (using the du Pont 2.5m Telescope). Representing the fourth phase of SDSS, SDSS-IV (Blanton et al. 2017) consists of three main surveys; the Extended Baryon Oscillation Spectroscopic Survey (eBOSS; Dawson et al. 2016), Mapping Nearby Galaxies at APO (MaNGA; Bundy et al. 2015), and the APO Galactic Evolution Experiment 2 (APOGEE-2; Majewski et al. 2017). Within eBOSS, SDSS-IV has also conducted two smaller programs: the SPectroscopic IDentification of ERosita Sources (SPIDERS; Clerc et al. 2016; Dwelly et al. 2017) and the Time Domain Spectroscopic Survey (TDSS; Morganson et al. 2015). These programs have investigated a broad range of cosmological scales, including cosmology with large-scale structure in eBOSS, the population of quasars and variable or X-ray-emitting stars with TDSS and SPIDERS; nearby galaxies in MaNGA; and the Milky Way and its stars in APOGEE-2.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Uranium Attenuated by a Wetland 50 Years after Release into a Stream

: Wetlands have several important roles in the hydrological cycle, including maintaining water quality by removing surface and groundwater contaminants. Over time, the wetlands themselves can become contaminated, posing a secondary environmental threat. The objective of this study was to calculate the inventory of uranium (U) remaining in a wetland 50 years after the Fuel Fabrication Facility on the Savannah River Site located in South Carolina released 43.5 Mg of U into the nearby environment. Over 232 700 gamma spectra and their associated global positioning system (GPS) coordinates were collected and collated into a map of the contaminated land area. Five core samples were also collected that contained U concentrations as high as 14 099 mg/kg (background levels are about 2.7 mg/kg U). The contaminated area was 278 000 m2 , and it contained 36.2 Mg U, about 83% of the U released. About 80% of the U in the wetland was concentrated in a former beaver pond, a 73 000 m2 area (26% of the contaminated area). This contaminated wetland area was almost 2 km from the source, indicating that it comprised unique hydro-biogeochemical properties for immobilizing the released U. To the best of our knowledge, this is the first data-rich study to quantify the long-term effectiveness of a wetland to immobilize inorganic contaminants. Significant environmental changes to the system, such as those associated with hydrology, forest fires, or anthropogenic land use, may alter the complex hydro-biogeochemical interactions necessary for the long-term immobilization of the U.

Contaminant inventory↗

GEWEX SRB Release 4: Public Release

The NASA/GEWEX Surface Radiation Budget (SRB) project produces 3-hourly shortwave and longwave surface and top of atmosphere radiative fluxes for the 1983-nearpresent time period. Here we announce the public availability of the new Release 4 Integrated data product (R4-IP). R4-IP uses the newly recalibrated and processed ISCCP HXS product as its primary input for cloud and radiance data, replacing ISCCP DX with a ninefold increase in pixel count (10km instead of 30km). This version retains a 1°x1° resolution but benefits from a much larger number of samples per grid box than the SRB Release 3. ISCCP also provides an atmospheric temperature and moisture dataset known as nnHIRS which we use here, along with Seaflux and Landflux surface and near-surface meteorological parameters constituting an “Integrated Product” for energy and water cycle studies. In addition to the input data improvements, several important algorithm improvements have been made since Release 3. These include recalculated shortwave (SW or solar wavelengths) atmospheric transmissivities and reflectivities yielding a somewhat less transmissive atmosphere. Both SW and LW (longwave or thermal infrared) also include variable aerosol composition and radiative properties, allowing for the use of a detailed aerosol history from the Max Planck Institute Aerosol Climatology (MAC). Both LW and SW algorithms now produce pristine sky fluxes, allowing the aerosol flux effects to be quantified. For SW, ocean albedo and snow/ice albedo are improved from Release 3. Total solar irradiance is now variable, and reduced to an average of 1361 Wm-2. The radiative treatment of ice cloud is improved. For the LW, a climatological monthly varying spectral surface emissivity is added.Here we analyze the new SW SRB datasets, comparing them to the previous Release 3, BSRN and PMEL surface measurements. Validation results show improved agreement compared to Release 3. Comparisons to ERBE and CERES TOA and surface satellite datasets before and after overlap periods show the long-term agreement with radiometric uncertainty. Monthly anomalies at global and zonal regions show very good correlation with the shorter ERBE and CERES flux anomalies linking those to the longer term. The uncertainties are discussed and periods of potential issues in inputs and/or algorithms are identified.

Earth energy budget↗

GEWEX SRB Release 4: Public Release

The NASA/GEWEX Surface Radiation Budget (SRB) project produces 3-hourly shortwave and longwave surface and top of atmosphere radiative fluxes for the 1983-near present time period. Here we announce the public availability of the new Release 4 Integrated data product (R4-IP). R4-IP uses the newly recalibrated and processed ISCCP HXS product as its primary input for cloud and radiance data, replacing ISCCP DX with a ninefold increase in pixel count (10km instead of 30km). This version retains a 1°x1° resolution but benefits from a much larger number of samples per grid box than the SRB Release 3. ISCCP also provides an atmospheric temperature and moisture dataset known as nnHIRS which we use here, along with Seaflux and Landflux surface and near-surface meteorological parameters constituting an “Integrated Product” for energy and water cycle studies. In addition to the input data improvements, several important algorithm improvements have been made since Release 3. These include recalculated shortwave (SW or solar wavelengths) atmospheric transmissivities and reflectivities yielding a somewhat less transmissive atmosphere. Both SW and LW (longwave or thermal infrared) also include variable aerosol composition and radiative properties, allowing for the use of a detailed aerosol history from the Max Planck Institute Aerosol Climatology (MAC). Both LW and SW algorithms now produce pristine sky fluxes, allowing the aerosol flux effects to be quantified. For SW, ocean albedo and snow/ice albedo are improved from Release 3. Total solar irradiance is now variable, and reduced to an average of 1361 Wm-2. The radiative treatment of ice cloud is improved. For the LW, a climatological monthly varying spectral surface emissivity is added. Here we analyze the new SW SRB datasets, comparing them to the previous Release 3, BSRN and PMEL surface measurements. Validation results show improved agreement compared to Release 3. Comparisons to ERBE and CERES TOA and surface satellite datasets before and after overlap periods show the long-term agreement with radiometric uncertainty. Monthly anomalies at global and zonal regions show very good correlation with the shorter ERBE and CERES flux anomalies linking those to the longer term. The uncertainties are discussed and periods of potential issues in inputs and/or algorithms are identified.

Earth Radiation Budget↗

Photoinduced Carbon Dioxide Release via a Metastable Photoacid in a Nonaqueous Environment

Capturing and concentrating carbon dioxide (CO 2 ) from the atmosphere is an important modern scientific and technological challenge. CO 2 can be captured by forming a carbamate bond with amines, most notably monoethanolamine (MEA). Regenerating MEA by releasing the captured CO 2 requires heating the carbamate solution, which is energy-demanding and wasteful. Recently, photoacids were used to convert light input into pH change, which in turn released CO 2 from aqueous carbonate solutions. Here, we report a merocyanine photoacid that releases CO 2 from a non-aqueous carbamate solution of MEA, thereby extending the utility of this concept to a wider range of capture agents and environments. Based on the absorption spectra of the photoacid in the presence of acids and CO 2 , we show that the photoacid cycle and the CO 2 capture of MEA are two separate equilibria that are coupled to each other via protons. Then, we demonstrate that irradiating 405 nm light on the sample can induce release of CO 2 which we detect using an in-line mass spectrometer. This work highlights an alternative path for optimizing a photo-induced CO 2 capture and release system.

Amines↗

Probing the lattice structure of dynamically compressed and released single crystal iron through the alpha to epsilon phase transition

In this work, experiments using broadband Laue x-ray diffraction (XRD) were used to examine the lattice structure of dynamically compressed [100]-oriented single crystal iron samples at the Dynamic Compression Sector at the Advanced Photon Source. These experiments used 1 μm thick iron single crystal samples sandwiched between a polyimide ablator and a polycarbonate window. A 100 J, 10 ns duration laser pulse incident on the polyimide ablator was used to shock compress the iron samples to initial stresses greater than 25 GPa, exceeding the ~13 GPa alpha (body-centered-cubic or bcc structure) to epsilon (hexagonal-close-packed or hcp structure) phase transition stress. XRD measurements were performed at various times relative to the shock wave entering the iron sample: early times, <~150 ps while the initial shock waves propagated through the iron; intermediate times, after the iron equilibrated with the ablator and window reaching a plateau stress state (12 or 17 GPa) lasting several nanoseconds; and late times, during uniaxial strain release. The early time measurements show that in <~150 ps, the high-pressure hcp phase is relaxed with a c/a ratio of 1.61, contrary to previous laser shock experiments where a c/a ratio of 1.7 was inferred. In the plateau stress state and partially released states, XRD measurements showed that the hcp structure retained a c/a ratio of 1.61 with no observable changes in the microstructure. Upon stress release at ~1 GPa/ns release rate, the reverse phase transition (hcp to bcc) to the original single crystal orientation (implying a transformation memory effect) was observed to reach completion somewhere between 13 and 11 GPa, indicating little stress hysteresis under rapid uniaxial strain release. A similar memory effect for the reverse hcp to bcc transformation has been previously observed under hydrostatic compression. However, the bcc/hcp orientation relationships differ somewhat between dynamic and static compression experiments, implying that the transformation pathway under uniaxial dynamic strain differs from the Burgers mechanism.

36 MATERIALS SCIENCE↗

Dispersible Colloid Facilitated Release of Organic Carbon From Two Contrasting Riparian Sediments

In aqueous systems, including groundwater, nano-colloids (1–100 nm diameter) and small colloids (<450 nm diameter) provide a vast store of surfaces to which organic carbon (OC) can sorb, precluding its normal bioavailability. Because nanomaterials are ubiquitous and abundant throughout Earth systems, it is reasonable that they would play a significant role in biogeochemical cycles. As such, mineral nano-colloids (MNC) and small colloids, formed through mineral weathering and precipitation processes, are both an unaccounted-for reservoir and unquantified vector for transport of OC and nutrients and contaminants within watersheds. Water extractions and leaching experiments were conducted under (1) aerobic (ambient) and (2) anaerobic (environmental chamber) conditions for each of two contrasting riparian sediments from (1) Columbia River, Washington and (2) Tims Branch, South Carolina. Water dispersible colloid-adsorbed OC was as high as 48% of OC for Tims Branch anaerobic batch water extraction and as low as 0% for Columbia River aerobic batch water extractions. Anaerobic leaching from column experiments yielded higher colloid and OC release rates. Transmission electron microscopy with electron dispersive spectroscopy mapping revealed organic carbon associated with aggregations of nano-particulate silicate minerals and Mossbauer identified nano-particulate goethite. This exploratory study demonstrates that mineral facilitated release of OC in riparian sediments is both significant and variable between locations.

Rod, Kenton A.↗

A quantitative study of retention and release of deuterium and tritium during irradiation of y-LiAlO2 pellets

This study reports on the quantification of deuterium in ion-irradiated gamma-LiAlO2 pellets as a function of dose and temperature. The gamma-LiAlO2 pellets were sequentially irradiated with He+ and D2+ ions to the same fluences of 5E16, 1E17 and 2E17 He++D+/cm2 at 188 K. Additional irradiation was performed to 1E17, 2E17 and 4E17 He++D+/cm2 at 573 K. A set of the pellets irradiated at 188 K was shipped and stored at low temperatures from 80 to 132 K and characterized using time-of-flight secondary ion mass spectrometry at ~173 K. The deuterium depth profiles show a Gaussian-like distribution in the low-temperature pellets. The total deuterium retention is found to be directly proportional to the ion fluence. About 27 at.% of the implanted deuterium atoms were released from the pellet irradiated to 2E17 He++D+/cm2 at 188 K during storage at room temperature for ~1 month. Retention of the trapped or bound deuterium during ion irradiation at 573 K increases initially with ion fluence and tends to saturate at a high fluence. The amount of the released deuterium is observed to be quantitatively consistent with that of the released tritium from similar standard pellets during neutron irradiation at 573 K.

Deuterium retention and release, ion irradiation, ↗

Controlled release of entrapped nanoparticles from thermoresponsive hydrogels with tunable network characteristics

Thermoresponsive hydrogels have been studied intensively for creating smart drug carriers and controlled drug delivery. Understanding the drug release kinetics and corresponding transport mechanisms of nanoparticles (NPs) in a thermoresponsive hydrogel network is the key to the successful design of smart drug delivery systems. Here, we construct a mesoscopic model of rigid NPs entrapped in a hydrogel network in an aqueous solution, where the hydrogel network is formed by cross-linked semiflexible polymers of thermoresponsive poly(N-isopropylacrylamide) (PNIPAM). By varying the temperature crossing the lower critical solution temperature of PNIPAM, we can significantly change the hydrogel network characteristics. We systematically investigate how the matrix porosity and the nanoparticle size affect the transport kinetics of NPs at different temperatures. Quantitative results on the mean-squared displacement and the van Hove displacement distributions of NPs show that all NPs entrapped in the smart hydrogels undergo subdiffusion at both low and high temperatures. For a coil state, the transport of NPs in the hydrogels can be enhanced by decreasing the matrix porosity of the polymer network and NPs' size. However, when the solution temperature is increased above the critical temperature, the hydrogel network collapses following the coil-to-globule transition, with the NPs tightly trapped in some local regions inside the hydrogels. Consequently, the NP diffusion coefficient can be reduced by two orders of magnitude, or the diffusion processes can even be completely stopped. These findings provide new insights for designing controlled drug release from stimuli-responsive hydrogels, including autonomously switch on/off drug release in response to physical and chemical stimuli.

42 ENGINEERING↗

Release mechanism for releasing and reattaching experiments on the Space Shuttle

The release mechanism (REM) unlatches an experiment so that it can be moved about inside and outside the shuttle bay by the remote manipulator system (RMS), and then reattaches it to the REM base. Operated from the crew compartment after the RMS has been attached to the experiment, the REM releases the experiment by an electric motor driving a gear train and linkage which extracts four pins from holes in four plates. Electrical connectors on the REM are disengaged by the mechanical action of the structural pins retracting from the plates. When the REM releases the experiment, an unlatched indicator is actuated in the crew compartment, and then the experiment can be moved by using the RMS. To reattach the experiment to the REM, the RMS places the experiment with REM attachment angles against the flat, smooth surface of the REM; then the RMS moves the experiment into position for latchup. Actuation of an electric motor drives the four pins into the four holes in the plates. When fully latched, a switch actuated by the motion of the linkage, shuts the electric motor off and gives an indication to the crew compartment that the REM is latched.

Clark, A. V.↗

Probing the magnetosphere using chemical releases from the Combined Release and Radiation Effects Satellite

An overview is presented of the chemical release experiments from NASA's Combined Release and Radiation Effects Satellite (CRRES) program. Preliminary results are given for the CRRES investigations of (1) stimulated electron and ion precipitation, (2) ion transport in the magnetotail, (3) critical ionization velocity, (4) field line tracing and parallel acceleration, (5) diamagnetic cavity formation and collapse, and (6) plasma instabilities. The chemical vapor properties from a thermite release mechanism are also briefly described.

Bernhardt, P. A.↗

Improved PARE (Pressurized Airborne Release Equipment) for Damage Ratio, Airborne Release Fraction and Respirable Fraction Testing (Version 4)

This paper describes an improved version of the PARE (Pressurized Airborne Release Equipment) system (Sutter 1983a and Sutter 1983b and Ballinger et al 1987) for powder venting testing. This effort seeks to improve the accuracy of risk estimation for the venting of pressurized powders and the venting of gases through pressurized powders. This includes experimental measurement for estimating DR (damage ratio), ARF (airborne release fraction) and RF (respirable fraction) quantities. The present study was performed to address previously indicated problematic factors (i.e. noted gaps) (US DOE 1994).

42 ENGINEERING↗

An Experimental and Numerical Investigation to Characterize the Low-Temperature Heat Release in Stoichiometric and Lean Combustion

This work reports on an experimental and modeling study on the low-temperature heat release (LTHR) characteristics for three RON 90 binary blends (n-heptane blended with isooctane, toluene and ethanol) in a Cooperative Fuel Research (CFR) engine at lean and stoichiometric conditions that are representative of homogeneous charge compression ignition (HCCI) and spark-ignition (SI) end-gas combustion conditions, respectively. An analysis of the end-gas temperature-pressure (T-P) trajectories was performed to identify the intake conditions leading to similar T-P trajectories between the two lambdas for each fuel blend. A heat release analysis was then conducted for the identified cases, where fuel-to-fuel differences in LTHR were identified and found to be sensitive to the operating condition. Simulations were conducted for these cases using a recently updated chemical kinetic model and a 0-D engine model, where good qualitative and reasonable quantitative agreements in LTHR were obtained. Sensitivity analysis was also performed directly on the rates of LTHR, to understand the controlling chemical reactions of LTHR, providing further insights into the fuel-to-fuel differences. The results demonstrate the significant promoting effect of n-heptane on LTHR rates, while inhibiting effects were seen for ethanol and toluene. Also highlighted was the importance of H atom abstraction reactions from the chemistry of each fuel component, which could lead to contradictory fuel behavior depending on the locations of the H site of the abstraction reaction due to the different ensuing pathways for the primary fuel radicals.

LTHR, RON 90 binary blends, sensitivity analysis↗