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At least 19 records

More Than 40 yr of Potentially Induced Seismicity Close to the San Andreas Fault in San Ardo, Central California

Evidence for fluid–injection–induced seismicity is rare in California hydrocarbon basins, despite widespread injection close to seismically active faults. We investigate a potential case of injection–induced earthquakes associated with San Ardo oilfield operations that began in the early 1950s. The largest potentially induced events occurred in 1955 (M L 5.2) and 1985 (M w 4.5) within ~6 km from the oilfield. We analyze Synthetic Aperture Radar interferometric images acquired by Sentinel–1A/B satellites between 2016 and 2020 and find surface deformation of up to 1.5 cm/yr, indicating pressure–imbalance in parts of the oilfield. Fluid injection in San Ardo is concentrated within highly permeable rocks directly above the granitic basement at a depth of ~800 m. Seismicity predominantly occurs along basement faults at 6–13 km depths. Seismicity and wastewater disposal wells are spatially correlated to the north of the oilfield. Temporal correlations are observed over more than 40 yr with correlation coefficients of up to 0.71 for seismicity within a 24 km distance from the oilfield. Such large distances have not previously been observed in California but are similar to the large spatial footprint of injection in Oklahoma. Furthermore, the San Ardo seismicity shows anomalous clustering with earthquakes consistently occurring at close spatial proximity but long interevent times. Similar clustering has previously been reported in California geothermal fields and may be indicative of seismicity driven by long–term, spatially persistent external forcing.

58 GEOSCIENCES↗

Effects of soil particles and convective transport on dispersion and aggregation of nanoplastics via small-angle neutron scattering (SANS) and ultra SANS (USANS)

Terrestrial nanoplastics (NPs) pose a serious threat to agricultural food production systems due to the potential harm of soil-born micro- and macroorganisms that promote soil fertility and ability of NPs to adsorb onto and penetrate into vegetables and other crops. Very little is known about the dispersion, fate and transport of NPs in soils. This is because of the challenges of analyzing terrestrial NPs by conventional microscopic techniques due to the low concentrations of NPs and absence of optical transparency in these systems. Herein, we investigate the potential utility of small-angle neutron scattering (SANS) and Ultra SANS (USANS) to probe the agglomeration behavior of NPs prepared from polybutyrate adipate terephthalate, a prominent biodegradable plastic used in agricultural mulching, in the presence of vermiculite, an artificial soil. SANS with the contrast matching technique was used to study the aggregation of NPs co-dispersed with vermiculite in aqueous media. We determined the contrast match point for vermiculite was 66% D 2 O / 33% H 2 O. At this condition, the signal for vermiculite was ~50–100%-fold lower that obtained using neat H 2 O or D 2 O as solvent. According to SANS and USANS, smaller-sized NPs (50 nm) remained dispersed in water and did not undergo size reduction or self-agglomeration, nor formed agglomerates with vermiculite. Larger-sized NPs (300–1000 nm) formed self-agglomerates and agglomerates with vermiculite, demonstrating their significant adhesion with soil. However, employment of convective transport (simulated by ex situ stirring of the slurries prior to SANS and USANS analyses) reduced the self-agglomeration, demonstrating weak NP-NP interactions. Convective transport also led to size reduction of the larger-sized NPs. Therefore, this study demonstrates the potential utility of SANS and USANS with contrast matching technique for investigating behavior of terrestrial NPs in complex soil systems.

59 BASIC BIOLOGICAL SCIENCES↗

Carbon ore, rare earth, and critical minerals (core-cm) assessment of san juan and raton coal basins: what is the future potential of coal in the san juan and raton basins, new mexico and colorado

This report summarizes results from the CORE-CM project in the San Juan and Raton basins of New Mexico and Colorado and ultimately begins to address what is the future of coal in the San Juan and Raton basins. The objective of this project was to determine the nonfuel carbon-based products (CBP), critical minerals, and rare earth elements (REE) potential in coal and related stratigraphic units in the San Juan and Raton basins and adjacent areas. This project delineated favorable geologic terrains and priority areas containing potential CBP, critical minerals, and REE deposits for the DOE mandate, which also is a priority of the NMBGMR and state of New Mexico. This project is important to the state because CBP, critical minerals, and REE resources must be identified before land use decisions are made by government officials. Future mining of CBP, critical minerals, and REE will directly benefit the economy of New Mexico. Furthermore, it is crucial to re-establish a domestic source of critical minerals and REE in the U.S. to help secure the nation’s clean energy future, to reduce the vulnerability of the U.S. to material shortages related to national defense, and to maintain our global technical and economic competitiveness. In addition to these benefits, students at New Mexico Institute of Mining and Technology (NMT) and San

01 COAL, LIGNITE, AND PEAT↗

ESAC (EQ-SANS Assisting Chatbot): Application of large language models and retrieval-augmented generation for enhanced user experience at EQ-SANS

Neutron scattering experiments have played vital roles in exploring materials properties in the past decades. While user interfaces have been improved over time, neutron scattering experiments still require specific knowledge or training by an expert due to the complexity of such advanced instrumentation and the limited number of experiments each person may perform each year. This paper introduces an innovative chatbot application that leverages Large Language Models(LLM) and Retrieval-Augmented Generation (RAG) technologies to significantly enhance the user experience at the EQ-SANS, a small-angle neutron scattering instrument at the Spallation Neutron Source of Oak Ridge National Laboratory. Through a user-centric design approach, the EQ-SANS Assisting Chatbot (ESAC) serves as an interactive reference for users, thereby facilitating the use of the instrument by visiting scientists. By bridging the gap between the users of EQ-SANS and the control systems required to perform their experiments, the ESAC sets a new standard for interactive learning and support for the scientific community using large-scale scientific facilities.

97 MATHEMATICS AND COMPUTING↗

Particle dynamics of nanoplastics suspended in water with soil microparticles: insights from small angle neutron scattering (SANS) and ultra-SANS

Small-angle neutron scattering (SANS) and ultra-SANS (USANS) were employed to understand the aggregation behavior and observe the size reduction for nanoplastics (NPs) formed from a biodegradable mulch film, and microparticles of vermiculite (V), an artificial soil, suspended in water in the presence of low convective shear (ex situ stirring) prior to measurements. Neutron contrast matching was employed to minimize the signal of V (by 100-fold) and thereby isolate the signal due to NPs in the neutron beam, as the contrast match point (CMP) for V (67 vol% deuteration of water) differed from that of NPs by more than 20%. The original NPs' size distribution was bimodal: <200 nm and 500–1200 nm, referred to as small and large NPs, i.e., SNPs and LNPs, respectively. In the absence of V, SNPs formed homoaggregates at higher concentrations that decreased with stirring time, while the size of LNPs remained unchanged. The presence of V at 2-fold lower concentration than NPs did not change the size of SNPs but reduced the size of LNPs by nearly 2-fold as stirring time increased. Because the size of SNPs and LNPs did not differ substantially between CMP and 100% D 2 O solvents, it is evident that SNPs and LNPs are mainly composed of NPs and not V. In conclusion, the results suggest that LNPs are susceptible to size reduction through collisions with soil microparticles via convection, yielding SNPs near soil–water interfaces within vadose zones.

Nanoplastics↗

SANS quantification of bound water in water-soluble polymers across multiple concentration regimes

Contrast-variation small-angle neutron scattering (CV-SANS) is a widely used technique for quantifying hydration water in soft matter systems, but it is predominantly applied in the dilute regime or for systems with a well-defined structure factor. Here, CV-SANS was used to quantify the number of hydration water molecules associating with three water-soluble polymers with different critical solution temperatures and types of water–solute interactions in dilute, semidilute, and concentrated solution through the exploration of novel methods of data fitting and analysis. Multiple SANS fitting workflows with varying levels of model assumptions were evaluated and compared to give insight into SANS model selection. These fitting pathways ranged from general, model-free algorithms to more standard form and structure factor fitting. In addition, Monte Carlo bootstrapping was evaluated as a method to estimate parameter uncertainty through simulation of technical replicates. The most robust fitting workflow for dilute solutions was found to be form factor fitting without CV-SANS ( i.e. polymer in 100% D 2 O). For semidilute and concentrated solutions, while the model-free approach can be mathematically defined for CV-SANS data, the addition of a structure factor imposes physical constraints on the optimization problem, suggesting that the optimal fitting pathway should include appropriate form and structure factor models. The measured hydration numbers were consistent with the number of tightly bound water molecules associated with each monomer unit, and the concentration dependence of the hydration number was largely governed by the chemistry-specific interactions between water and polymer. Polymers with weaker water–polymer interactions ( i.e. those with fewer hydration water molecules) were found to have more bound water at higher concentrations than those with stronger water–polymer interactions due to the increase in the number of forced water–polymer contacts in the concentrated system. This SANS-based method to count hydration water molecules can be applied to polymers in any concentration regime, which will lead to improved understanding of water–polymer interactions and their impact on materials design.

36 MATERIALS SCIENCE↗

Uniformity and volume-representativity of consecutive submillimetre wafers of shale for SANS and USANS investigations

(Ultra) Small Angle Neutron Scattering (SANS/USANS) is a non-destructive technique suitable for characterization of porous structures from nano- to micro-pore size (1 nm to 20 μm), which has been widely used to characterize accessible and inaccessible porosity in tight unconventional hydrocarbon reservoirs (e.g., shales). Here, in this study, SANS and USANS are used to examine the degree of nano- to micropore uniformity of the rock body on sub-millimetre to centimetre scale. This study presents a test of the hypothesis of volume representativity of pore structure information measured by SANS and USANS for shale wafers (0.22–1 mm) cut from six North American unconventional shale cores of different maturities (New Albany Shale and Marcellus Shale). Experimental reproducibility of USANS is further investigated for two wafers measured using various acquisition times. All samples show that fluctuations of the relative intensity generally decrease from the USANS Q-range (pore size from around 200 nm to 20 μm) to most of the SANS Q-range (pore size from around 5 nm to 700 nm), and peaks in the SANS large-Q region (for pores smaller than about 5 nm). There is a positive correlation between the spatial fluctuation of the relative SANS intensity and the scattering power of shales. In addition, the scattering intensity and its fluctuations is larger for the less mature shale cores. Shale is known to be highly heterogenous and the hypothesis of uniformity does not apply at sub-millimetre scale even for samples that appear homogeneous at visual inspection. This study presents an approach to minimise the variation through sample selection, data interpretation methodology and instrumental reproducibility tests. The best values of the microstructural spatial uniformity for the apparently homogeneous sections of a core (i.e., the SANS and USANS intensity variation) is less than ±10%.

01 COAL, LIGNITE, AND PEAT↗

Equitable Strategies for Residential Building Energy Efficiency and Electrification in San José, California

Hotter summers, heat waves, wildfires, and droughts are already affecting San Jose residents, with historically marginalized communities impacted first and worst. The City of San Jose has ambitious goals to make the city climate-neutral by 2030 and serve as an example for cities to accelerate climate action around the world. Electrifying and decarbonizing residential buildings are important priorities to achieve San Jose's plans to reach carbon neutrality while enabling residents to live the "Good Life 2.0" - a vision that aligns with community-identified priorities of safety, health, freedom, community, and positive experiences. This technical assistance built upon the Electrify San Jose: Framework for Existing Building Electrification to identify actionable strategies to make single- and multi-family buildings both energy-efficient and all-electric. This report is intended to provide the San Jose Climate Smart team and their partners with relevant data, insights, and actionable analysis to aid in-depth and nuanced engagements with key stakeholders. In particular, the findings in this report highlight opportunities and challenges for San Jose City Council, residents, building owners, developers, financial institutions, and utility partners instrumental in building support and earning buy-in for energy efficiency and electrification upgrades in existing buildings.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Equitable Strategies for Residential Building Energy Efficiency and Electrification in San José, California [Slides]

Hotter summers, heat waves, wildfires, and droughts are already affecting San Jose residents, with historically marginalized communities impacted first and worst. The City of San Jose has ambitious goals to make the city climate-neutral by 2030 and serve as an example for cities to accelerate climate action around the world. Electrifying and decarbonizing residential buildings are important priorities to achieve San Jose's plans to reach carbon neutrality while enabling residents to live the "Good Life 2.0" - a vision that aligns with community-identified priorities of safety, health, freedom, community, and positive experiences. This technical assistance built upon the Electrify San Jose: Framework for Existing Building Electrification to identify actionable strategies to make single- and multi-family buildings both energy-efficient and all-electric. This report is intended to provide the San Jose Climate Smart team and their partners with relevant data, insights, and actionable analysis to aid in-depth and nuanced engagements with key stakeholders. In particular, the findings in this report highlight opportunities and challenges for San Jose City Council, residents, building owners, developers, financial institutions, and utility partners instrumental in building support and earning buy-in for energy efficiency and electrification upgrades in existing buildings.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Travel Decision Survey - San Francisco - 2012

On behalf of the San Francisco Municipal Transportation Agency (SFMTA), Corey, Canapary & Galanis undertook a Travel Decision Survey within the City and County of San Francisco, as well the eight surrounding Bay Area counties of Alameda, Contra Costa, San Mateo, Marin, Santa Clara, Napa, Sonoma, and Solano. The primary goals of this study were to accurately assess mode share for trips within San Francisco (including trips to or from San Francisco, but excluding through trips) among city residents and residents of other Bay Area counties; provide additional trip details, including trip purpose information for each trip in the mode-share question series; and use the mode-share percentages collected on this survey in conjunction with total trip estimates provided by SFMTA to project the number of trips by mode on an average day in San Francisco.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Travel Decision Survey - San Francisco - 2013

On behalf of the San Francisco Municipal Transportation Agency (SFMTA), Corey, Canapary & Galanis undertook a Travel Decision Survey within the City and County of San Francisco, as well as the eight surrounding Bay Area counties of Alameda, Contra Costa, San Mateo, Marin, Santa Clara, Napa, Sonoma, and Solano. The primary goals of this study were to: 1. Assess percent mode share for travel in San Francisco for evaluation of the SFMTA Strategic Objective 2.3: Mode Share target of 50% non-private auto travel by FY 2018 with a 95% confidence level and margin of error ±5% or less. 2. Evaluate the above statement based on number of trips to, from, and within San Francisco by Bay Area residents. Trips by visitors to the Bay Area and for commercial purposes are not included. 3. Provide additional trip details, including trip purpose for each trip in the mode-share question series. 4. Collect demographic data on the population of Bay Area residents who travel to, from, and within San Francisco. 5. Collect data on travel behavior and opinions that support other SFMTA strategy and project evaluation needs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Travel Decision Survey - San Francisco - 2014

On behalf of the San Francisco Municipal Transportation Agency (SFMTA), Corey, Canapary & Galanis undertook a Travel Decision Survey within the City and County of San Francisco, as well as the eight surrounding Bay Area counties of Alameda, Contra Costa, San Mateo, Marin, Santa Clara, Napa, Sonoma, and Solano. The primary goals of this study were to: 1. Assess percent mode share for travel in San Francisco for evaluation of the SFMTA Strategic Objective 2.3: Mode Share target of 50% non-private auto travel by FY 2018 with a 95% confidence level and margin of error ±5% or less. 2. Evaluate the above statement based on number of trips to, from, and within San Francisco by Bay Area residents. Trips by visitors to the Bay Area and for commercial purposes are not included. 3. Provide additional trip details, including trip purpose for each trip in the mode-share question series. 4. Collect demographic data on the population of Bay Area residents who travel to, from, and within San Francisco. 5. Collect data on travel behavior and opinions that support other SFMTA strategy and project evaluation needs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Travel Decision Survey - San Francisco - 2015

On behalf of the San Francisco Municipal Transportation Agency (SFMTA), Corey, Canapary & Galanis undertook a Travel Decision Survey within the City and County of San Francisco, as well as the eight surrounding Bay Area counties of Alameda, Contra Costa, San Mateo, Marin, Santa Clara, Napa, Sonoma, and Solano. The primary goals of this study were to: 1. Assess percent mode share for travel in San Francisco for evaluation of the SFMTA Strategic Objective 2.3: Mode Share target of 50% non-private auto travel by FY 2018 with a 95% confidence level and margin of error ±5% or less. 2. Evaluate the above statement based on number of trips to, from, and within San Francisco by Bay Area residents. Trips by visitors to the Bay Area and for commercial purposes are not included. 3. Provide additional trip details, including trip purpose for each trip in the mode-share question series. 4. Collect demographic data on the population of Bay Area residents who travel to, from, and within San Francisco. 5. Collect data on travel behavior and opinions that support other SFMTA strategy and project evaluation needs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Travel Decision Survey - San Francisco - 2017

On behalf of the San Francisco Municipal Transportation Agency (SFMTA), Corey, Canapary & Galanis undertook a Travel Decision Survey within the City and County of San Francisco, as well as the eight surrounding Bay Area counties of Alameda, Contra Costa, San Mateo, Marin, Santa Clara, Napa, Sonoma, and Solano. The primary goals of this study were to: 1. Assess percent mode share for travel in San Francisco for evaluation of the SFMTA Strategic Objective 2.3: Mode Share target of 50% non-private auto travel by FY 2018 with a 95% confidence level and margin of error ±5% or less. 2. Evaluate the above statement based on number of trips to, from, and within San Francisco by Bay Area residents. Trips by visitors to the Bay Area and for commercial purposes are not included. 3. Provide additional trip details, including trip purpose for each trip in the mode-share question series. 4. Collect demographic data on the population of Bay Area residents who travel to, from, and within San Francisco. 5. Collect data on travel behavior and opinions that support other SFMTA strategy and project evaluation needs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The air mycobiome is decoupled from the soil mycobiome in the California San Joaquin Valley

Abstract Dispersal is a key force in the assembly of fungal communities and the air is the dominant route of dispersal for most fungi. Understanding the dynamics of airborne fungi is important for determining their source and for helping to prevent fungal disease. This understanding is important in the San Joaquin Valley of California, which is home to 4.2 million people and where the airborne fungus Coccidioides is responsible for the most important fungal disease of otherwise healthy humans, coccidioidomycosis. The San Joaquin Valley is the most productive agricultural region in the United States, with the principal crops grown therein susceptible to fungal pathogens. Here, we characterize the fungal community in soil and air on undeveloped and agricultural land in the San Joaquin Valley using metabarcoding of the internal transcribed spacer 2 variable region of fungal rDNA. Using 1,002 individual samples, we report one of the most extensive studies of fungi sampled simultaneously from air and soil using modern sequencing techniques. We find that the air mycobiome in the San Joaquin Valley is distinct from the soil mycobiome, and that the assemblages of airborne fungi from sites as far apart as 160 km are far more similar to one another than to the fungal communities in nearby soils. Additionally, we present evidence that airborne fungi in the San Joaquin Valley are subject to dispersal limitation and cyclical intra‐annual patterns of community composition. Our findings are broadly applicable to understanding the dispersal of airborne fungi and the taxonomic structure of airborne fungal assemblages.

59 BASIC BIOLOGICAL SCIENCES↗

Scat Detection Dog Surveys for the San Joaquin Kit Fox on the Lawrence Livermore National Laboratory's Experimental Test Site (Site 300) and the Corral Hollow Ecological Reserve: 2020 Deployment

The San Joaquin kit fox (Vulpes macrotis mutica) historically occupied an extensive range in the San Joaquin Valley, California; however, their populations and habitat have since been significantly reduced by human impacts (United States Fish and Wildlife Service [USFWS] 1998). More than 95% of the potential habitat for kit foxes on the San Joaquin Valley floor has been converted to irrigated agriculture, urbanized, or industrialized lands. The San Joaquin kit fox was listed as endangered by the USFWS in 1967 and as threatened by the State of California in 1971. Records from local surveys, research projects, and incidental sightings indicate the present distribution of kit foxes extends from 1) southern Kern County north to Contra Costa, Alameda, and San Joaquin counties on the west side of the valley and to Stanislaus County on the east side; 2) into some of the larger, uncultivated valley-floor land parcels in Kern, Tulare, Kings, Fresno, Madera, and Merced counties; and 3) westward within 5 counties in the interior coastal range (USFWS 1998). Kit foxes have been denoted to occur in 3 geographically distinct core and several satellite populations in a heavily fragmented landscape, with the largest extant populations concentrated in the southern part of the range and smaller populations and isolated sightings in the central and northern portions (USFWS 1998, 2010).

54 ENVIRONMENTAL SCIENCES↗

San Juan Islands Tidal Energy Characterization

The San Juan Islands are an archipelago with multiple tidal channels that produce strong tidal currents that could be harnessed for electricity generation. At present, there is limited electrical generation on the islands, with power primarily provided by a subsea cable connection with the mainland. As part of the C-MIST program, NOAA's CO-OPS program collected ADCP data at 46 stations in the San Juan Islands and adjacent waterways, from April to August of 2017. PNNL has recently developed a 3-D tidal hydrodynamic model for tidal energy resource characterization and assessment in the Salish Sea (Yang et al. 2021). Several tidal channels in the San Juan Islands were identified as top hotspots for potential tidal energy extraction. However, due to the complex geometry and inter-connected waterways, tidal currents around San Juan Islands also exhibit strong spatial and temporal asymmetry. Therefore, it is important to analyze the NOAA ADCP data to define metrics relevant to tidal energy, and further refine PNNL's tidal hydrodynamic model to accurately simulate currents in small tidal channels and account for sharp bathymetry gradients. The outcome of this technical assistance will allow developers to identify the promising opportunities for tidal energy in the San Juan Islands.

16 TIDAL AND WAVE POWER↗

Preparation & shipping of ten neutron irradiated Eurofer97 steel variants to HFIR for SANS experiments

At ORNL, ten variants of Eurofer97 steel were irradiated in the high flux isotope reactor (HFIR) to ~2.94 – 3.24 dpa at 300 ± 30 °C, as part of the EUROfusion Lot-IV collaboration. The irradiations were performed in non-instrumented rabbit capsules in the flux trap region, which included SS-J3 type tensile samples and M4-CVN multi-notch bend bars. Their full set of microstructure and mechanical properties were previously reported in multiple previous publications. In this project, half-broken irradiated and nonirradiated SS-J3 tensile samples from ten alloys, code-named H, I, J, K, L, M, N, O, P and E, were prepared and shipped for facilitating small angle neutron scattering (SANS) experiments at the HFIR general purpose (GP)-SANS beam line. This report summarizes the completed tasks which included canister moves at the Irradiated Materials Examination and Testing (IMET) hot-cell facility to retrieve the samples from long-term storage, loading of the ten irradiated samples at IMET inside lead (Pb) piglets that were specifically provided by ORNL for SANS experiments and radiological shipment from IMET facility to the HFIR hot cells for performing SANS experiments. In addition to the irradiated samples, ten nonirradiated half-broken pieces from the Eurofer97 variants were also provided to HFIR for SANS.

36 MATERIALS SCIENCE↗