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At least 19 records

Graft copolymers from poly(2,6-dimethylphenylene oxide) and pivalolactone

The copolyether-polyester system resulting from the anionic graft polymerization of pivalolactone onto poly(2,6-dimethylphenylene oxide) has been formulated with differing graft densities and graft segment lengths. Wide angle X-ray scattering studies on these materials indicated an increased crystalline order with increased PVL segments/graft for similarly annealed specimens and a decrease in such order with increasing carboxylation.

Bell, Vernon L.

Radio wave scattering in the outer heliosphere

Current models for the 2-3 kHz emissions observed by the Voyager spacecraft in the outer heliosphere involve 2f(p) radiation generated near the termination shock or the heliopause. Radio wave scattering by solar wind density irregularities strongly affects observed sources of f(p) and 2f(p) emission in the inner heliosphere and the characteristics of astrophysical sources. In particular, the angular size, brightness temperature, and time variability of the source are strongly affected by scattering, thereby having major implications for the inferred size, energy budget, time variability, location, and nature of the source if scattering is ignored. This paper addresses whether scattering is important for interpreting the Voyager 2-3 kHz emissions. Quantitative calculations (with and without diffraction) are performed for the angular broadening of an outer heliospheric source as a function of path length, radiation frequency relative to f(p) and the spectrum of density irregularities. The effects of scattering in both the solar wind and the heliosheath are considered. Predictions for radial gradients in the source's apparent angular size and in the source's modulation index are presented. The calculations are compared with observations and the results discussed. First estimates suggest that scattering plausibly dominates the observed source size. The observed trend in modulation index with heliocentric distance is consistent with scattering being important and the source being in the outer heliosphere. Additional arguments for scattering being important are summarized.

Cairns, Iver H.

Physical Models of Layered Polar Firn Brightness Temperatures from 0.5 to 2 GHz

We investigate physical effects influencing 0.5-2 GHz brightness temperatures of layered polar firn to support the Ultra Wide Band Software Defined Radiometer (UWBRAD) experiment to be conducted in Greenland and in Antarctica. We find that because ice particle grain sizes are very small compared to the 0.5-2 GHz wavelengths, volume scattering effects are small. Variations in firn density over cm- to m-length scales, however, cause significant effects. Both incoherent and coherent models are used to examine these effects. Incoherent models include a 'cloud model' that neglects any reflections internal to the ice sheet, and the DMRT-ML and MEMLS radiative transfer codes that are publicly available. The coherent model is based on the layered medium implementation of the fluctuation dissipation theorem for thermal microwave radiation from a medium having a nonuniform temperature. Density profiles are modeled using a stochastic approach, and model predictions are averaged over a large number of realizations to take into account an averaging over the radiometer footprint. Density profiles are described by combining a smooth average density profile with a spatially correlated random process to model density fluctuations. It is shown that coherent model results after ensemble averaging depend on the correlation lengths of the vertical density fluctuations. If the correlation length is moderate or long compared with the wavelength (approximately 0.6x longer or greater for Gaussian correlation function without regard for layer thinning due to compaction), coherent and incoherent model results are similar (within approximately 1 K). However, when the correlation length is short compared to the wavelength, coherent model results are significantly different from the incoherent model by several tens of kelvins. For a 10-cm correlation length, the differences are significant between 0.5 and 1.1 GHz, and less for 1.1-2 GHz. Model results are shown to be able to match the v-pol SMOS data closely and predict the h-pol data for small observation angles.

layered polar firn emission

Two-scale-factor universality near the critical point of fluids

Thermodynamic data from interferometric density profile studies and light-scattering experiments near the critical isochore of Xe, CO2 and SF6 provide a basis for examining the hypothesized two-scale-factor universality for the correlation function of fluids near the gas-liquid critical point. For the investigation, three-scale-factor universality is assumed, with Ising-like critical exponent values obtained through the renormalization group technique. The two thermodynamic scale factors are found from the density profiles, while the scale factor for the correlation length is obtained from the light-scattering data.

Sengers, J. V.

Two Point Space-Time Correlation of Density Fluctuations Measured in High Velocity Free Jets

Two-point space-time correlations of air density fluctuations in unheated, fully-expanded free jets at Mach numbers M(sub j) = 0.95, 1.4, and 1.8 were measured using a Rayleigh scattering based diagnostic technique. The molecular scattered light from two small probe volumes of 1.03 mm length was measured for a completely non-intrusive means of determining the turbulent density fluctuations. The time series of density fluctuations were analyzed to estimate the integral length scale L in a moving frame of reference and the convective Mach number M(sub c) at different narrow Strouhal frequency (St) bands. It was observed that M(sub c) and the normalized moving frame length scale L*St/D, where D is the jet diameter, increased with Strouhal frequency before leveling off at the highest resolved frequency. Significant differences were observed between data obtained from the lip shear layer and the centerline of the jet. The wave number frequency transform of the correlation data demonstrated progressive increase in the radiative part of turbulence fluctuations with increasing jet Mach number.

Panda, Jayanta

The transfer of resonance-line radiation in static astrophysical media

An analytic solution is derived for the mean intensity of resonance-line radiation within an absorbing medium of large scattering optical depth but low density. The line profile, the mean number of scatterings before absorption or escape, the mean path length traveled, and the fraction of the photons which escape the medium are derived. Approximate methods are also developed which permit the treatment of media of intermediate optical depth, where scattering takes place in the Doppler core. Astrophysical applications include the absorption of H Ly-alpha radiation by stellar dust, the pumping of H2 Lyman band lines by H Ly-alpha and the Bowen fluorescence.

Neufeld, David A.

Calculations of the displacement damage and short-circuit current degradation in proton irradiated (AlGa)As-GaAs solar cells

A theoretical model for computing the displacement damage defect density and the short-circuit current (I sub sc) degradation in proton-irradiated (AlGa)As-GaAs p-n junction solar cells is presented. Assumptions were made with justification that the radiation induced displacement defects form an effective recombination center which controls the electron and hole lifetimes in the junction space charge region and in the n-GaAs active layer of the irradiated GaAs p-n junction cells. The degradation of I sub sc in the (AlGa)As layer was found to be negligible compared to the total degradation. In order to determine the I sub sc degradation, the displacement defect density, path length, range, reduced energy after penetrating a distance x, and the average number of displacements formed by one proton scattering event were first calculated. The I sub sc degradation was calculated by using the electron capture cross section in the p-diffused layer and the hole capture cross section in the n-base layer as well as the wavelength dependent absorption coefficients. Excellent agreement was found between the researchers calculated values and the measured I sub sc in the proton irradiated GaAs solar cells for proton energies of 100 KeV to 10 MeV and fluences from 10 to the 10th power p/square cm to 10 to the 12th power p/square cm.

Yeh, C. S.

A Concept for a High-Energy Gamma-ray Polarimeter

We present a concept for an imaging gamma-ray polarimeter operating from approx. 50 MeV to approx. 1 GeV. Such an instrument would be valuable for the study of high-energy pulsars, active galactic nuclei, supernova remnants, and gamma-ray bursts. The concept makes use of pixelized gas micro-well detectors, under development at Goddard Space Flight Center, to record the electron-positron tracks from pair-production events in a large gas volume. Pixelized micro-well detectors have the potential to form large-volume 3-D track imagers with approx. 100 micron (rms) position resolution at moderate cost. The combination of high spatial resolution and a continuous low-density gas medium permits many thousands of measurements per radiation length, allowing the particle tracks to be imaged accurately before multiple scattering masks their original directions. The polarization of the incoming radiation may then be determined from the azimuthal distribution of the electron-positron pairs. We have performed Geant4 simulations of these processes to estimate the polarization sensitivity as a function of instrument parameters and event selection criteria.

Bloser, P. F.

An Electrothermodynamic Model with Distributed Properties for Effective Permittivities of Sea Ice

This paper presents a model to calculate the temperature dependence of effective permittivities for sea ice, a heterogeneous medium containing multiphase scatterers. With the strong permittivity fluctuation approach the model accounts for the electrodynamic scattering effect together with the quasi-static characteristics of multiple species and subspecies of inhomogeneities with distributed orientations, sizes, and shapes. Because of a preferential direction in the orientation distribution, the medium is effectively anisotropic. The size distribution is described with a probability density function in terms of normalized volumetric sizes. Scatterer shapes are nonuniform and have a general ellipsoidal form characterized by arbitrary axial ratios of correlation lengths which are related to physical geometries of the scatterers. In this formulation, sea ice consisting of solid ice, liquid brine, and gaseous inclusions is modeled to derive effective permittivities with thermodynamic phase redistribution and structural metamorphism. Theoretical results are in good agreement with experimental data at the C band frequency of 4.8 GHz for saline ice undergoing warming and cooling cycles. A competitive effect between the increase of liquid brine and the shape rounding of ellipsoidal scatterers at increasing temperatures explains the trend observed in measured data. Sensitivities of effective permittivities to structural and physical parameters characterizing sea ice are also studied.

Nghiem, S. V.

Theory of waves incoherently scattered

Electromagnetic waves impinging upon a plasma at frequencies larger than the plasma frequency, suffer weak scattering. The scattering arises from the existence of electron density fluctuations. The received signal corresponds to a particular spatial Fourier component of the fluctuations, the wave vector of which is a function of the wavelength of the radiowave. Wavelengths short with respect to the Debye length of the medium relate to fluctuations due to non-interacting Maxwellian electrons, while larger wavelengths relate to fluctuations due to collective Coulomb interactions. In the latter case, the scattered signal exhibits a spectral distribution which is characteristic of the main properties of the electron and ion gases and, therefore, provides a powerful diagnosis of the state of the ionosphere.

Bauer, P.

Interstellar scattering of pulsar radiation. I - Scintillation

An investigation of the intensity fluctuations of 28 pulsars near 0.4 GHz indicates that spectra of interstellar scintillation are consistent with a Gaussian shape, that scintillation indices are near unity, and that the scintillation bandwidth depends linearly on dispersion measure. Observations at cm wavelengths show that the observer is in the near field of the scattering medium for objects with the lowest dispersion measures, and confirm the steep dependence of correlation bandwidth on dispersion measure found by Sutton (1971). The variations of scattering parameters with dispersion measure may indicate that the rms deviation of thermal electron density on the scale of 10 to the 11th cm grows with path length through the galaxy.

Backer, D. C.

Evaluation of Brightness Temperature Sensitivity to Snowpack Physical Properties Using Coupled Snow Physics and Microwave Radiative Transfer Models

There are multiple existing microwave radiative transfer models (RTMs) to simulate the brightness temperature (Tb) of snowpacks. It is still challenging to have consistent Tb responses from RTMs due to individual physical formulations of the snowpack scattering process. This article examines three of the widely-used multi-layer RTMs: 1) the microwave emission model of layered snowpacks (MEMLS); 2) the dense media radiative transfer based on the quasi-crystalline approximation (QCA) of Mie scattering of densely packed sticky spheres (DMRTQMS); and 3) the Helsinki University of Technology (HUT) model. Interestingly, these models yield slightly different Tb responses when driven by the same physical snowpack properties. Tb variations, dependent on the choice of RTMs, are then evaluated to improve the understanding of model differences in microwave emission from a snowpack. We first perform a sensitivity study of the Tb predictions from the three RTMs as a function of snow grain sizes, densities, and depths. While Tb from all three RTMs decreases with increasing snow grain sizes, it is found that a scaling factor is required to have the same amount of Tb attenuation for small grain sizes within the Rayleigh scattering regime. For larger grain sizes, however, a scaling coefficient is not enough to match the model outputs due to the different scattering assumptions of the RTMs. For a single snow layer with increasing snow depths and densities, all three RTMs exhibit Tb attenuations arising from the increase in path lengths and optical depths. Further evaluations are conducted by feeding the three RTMs with the output of a snow physics model driven by in situ weather forcing in a coupled simulation. Outputs of this coupled model include snowpack physical properties and Tbs. By using snow stratigraphy observations, another set of Tb simulation is also conducted with RTMs driven by in situ snowpit observations. The snow physics outputs from the coupled case are compared against in situ snow stratigraphy observations.

Do Hyuk Kang

Broadening and occultation of radio sources by comet Giacobini-Zinner as observed from ICE

During the encounter of the International Cometary Explorer (ICE) with comet P/Giacobini-Zinner, the radio astronomy experiment observed occultation and propagation effects on several distant radio sources. The observations of the partial occultation of the galactic radio source between 360 and 1000 kHz show that the three-dimensional large scale structure of the coma is consistent with the structure determined from in-situ measurements made along the encounter trajectory. In addition, these observations remove a previously existing ambiguity in the position of the galactic source. Between 110 and 360 kHz the earth source is broadened by scattering by the comet random density inhomogeneities. The amount of broadening indicates that the electron density fluctuations measured in situ by ICE along its trajectory (100 pct fluctuations with a scale length of 1000-2000 km over a path length of 100,000 km) exist with the same properties in the perpendicular direction.

Steinberg, J. L.

Neutral atmospheric models compatible with satellite orbital decay and incoherent scatter measurements

A correlation study was made of the variations of the exospheric temperature extrema with various combinations of the monthly mean and daily values of the 2800 MHz and Ca:2 solar indices. The phase and amplitude of the semi-annual component and the term dependent on Kp were found to remain almost the same for the maximum and minimum temperature. The term dependent on the 27 day component of the solar activity was found to be about four times as large for the diurnal maximum as for the minimum. Measurements at Arecibo have shown that temperature gradient changes at 125 km are consistent with the phase difference between the neutral temperature and density maxima. This is used to develop an empirical model which is compatible with both the satellite measurements and the available incoherent scatter measurements. A main feature of this model is that day length is included as a major model parameter.

Rohrbaugh, J. L.

The diffusive idealization of charged particle transport in random magnetic fields

The transport of charged particles diffusing in a random magnetic field parallel to a relatively large guiding field is presented. The same coefficient of diffusion is obtained by three methods. Two corrections must be added to the expression in which the diffusive flux is proportional to the gradient of the density. Explicit expressions are given for a characteristic time and a characteristic length which describe the corrections. The well known divergence of the coefficient of diffusion, which is implied by the quasilinear analysis of pitch angle scattering, does not occur if the scattering rate is finite at 90 deg pitch angle. This effect is illustrated by formulas which give the coefficient of diffusion when the quasilinear expression is perturbed by a variable amount of isotropic scattering.

Earl, J. A.

Rayleigh Scattering Diagnostic for Measurement of Velocity and Density Fluctuation Spectra

A new molecular Rayleigh scattering based flow diagnostic is used for the first time to measure the power spectrum of gas density and radial velocity component in the plumes of high speed jets. The technique is based on analyzing the Rayleigh scattered light with a Fabry-Perot interferometer used in the static, imaging mode. The PC based data acquisition system is capable of simultaneous sampling of velocity and density at rates to 100 kHz and data record lengths to 10 million. Velocity and density power spectra and velocity-density cross spectra are presented for a subsonic jet, an underexpanded screeching jet, and for Mach 1.4 and Mach 1.8 supersonic jets. Software and hardware interfaces were developed to allow computer control of all aspects of the experiment and data acquisition.

Seasholtz, Richard G.

Theory of anisotropic refractive scintillation - Application to stellar occultations by Neptune

A theory of refractive scintillation due to a thin phase-changing screen with an anisotropic power-law spectrum of phase fluctuations is presented. Scintillation theory for an isotropic medium is discussed, and anisotropy of the mean density and anisotropy in the scattering are discussed. The theory of refractive scintillation in an anisotropic medium is developed, deriving a general expression for the cross-correlation of flux variations at two points on the 'observer screen'. From this, estimates of the coherence lengths and amplitudes of flux variations are obtained for important parameter regimes. The application of the theory to the analysis of two occultations by Neptune is addressed. The projected dimensions of the occulting stars, a normalization constant to describe the phase fluctuations, and an anisotropy parameter are determined, and the theory is shown to agree well with observation. The significance of the theory for understanding of the physics of Neptune's atmosphere is discussed.

Narayan, Ramesh

A mathematical characterization of vegetation effect on microwave remote sensing from the Earth

In passive microwave remote sensing of the earth, a theoretical model that utilizes the radiative transfer equations was developed to account for the volume scattering effects of the vegetation canopy. Vegetation canopies such as alfalfa, sorghum, and corn are simulated by a layer of ellipsoidal scatterers and cylindrical structures. The ellipsoidal scatterers represent the leaves of vegetation and are randomly positioned and oriented. The orientation of ellipsoids is characterized by a probability density function of Eulerian angles of rotation. The cylindrical structures represent the stalks of vegetation and their radii are assumed to be much smaller than their lengths. The underlying soil is represented by a half-space medium with a homogeneous permittivity and uniform temperature profile. The radiative transfer quations are solved by a numerical method using a Gaussian quadrature formula to compute both the vertical and horizontal polarized brightness temperature as a function of observation angle. The theory was applied to the interpretation of experimental data obtained from sorghum covered fields near College Station, Texas.

Choe, Y.