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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Complete Initial Evaluation of Novel Complexants for Tc Holdback for Simplified Single Cycle Separations.

Management of technetium at the back end of nuclear fuel cycle is complicated by its unique physico-chemical character, but must be addressed to due to the environmental, storage and reprocessing challenges of this fission product. In a single-cycle scenario, the recovery and purification of uranium is particularly challenging due to the tendency of a pertechnetate anion to follow uranyl cation. This report summarizes initial studies directed towards finding the solution for technetium management. Two options for controlling technetium’s chemistry in solvent extraction scenarios were studied. Molecular recognition of pertechnetate by aqueous complexants based on guanidinium moieties was compared to redox manipulation of technetium using dihydrazide reagents. Solvent extraction, potentiometric and nuclear magnetic resonance spectroscopy studies were performed. The influence of guanidinium reagents on the liquid-liquid partitioning of technetium is less pronounced, relative to dihydrazides. Strong impact exerted by dihydrazides originates from the technetium-catalyzed decomposition of such compounds which reduces technetium to a tetravalent, non-extractable state. Although this route of technetium management is very effective the destruction of dihydrazides is undesirable. Guanidinium complexants show a more tempered influence on technetium. The effect on the liquid-liquid partitioning of pertechnetate is evident and likely guided by anion recognition due to ion-pair and hydrogen bond formation. Guanidiniums are stable in presence of technetium as evidenced by nuclear magnetic resonance studies. The steady state chemistry of guanidiniums identify this class of aqueous complexants as solid candidates for structure-function pertechnetate recognition studies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

Caspian Tern Management to Increase Survival of Juvenile Salmonids in the Columbia River Basin: Progress and Adaptive Management Considerations

Abstract Predation by Caspian terns Hydroprogne caspia is a factor limiting the recovery of some Endangered Species Act-listed populations of salmonids from the Columbia River basin, especially steelhead Oncorhynchus mykiss. This prompted the development and implementation of two separate management plans, one in the Columbia River estuary and the other in the Columbia Plateau region, to reduce the impact of Caspian tern predation on smolt survival. Caspian terns nesting at managed breeding colonies within the basin were relocated to alternative nesting islands created for terns outside the basin. Both plans were successful in significantly reducing smolt losses to Caspian terns nesting at managed sites; however, new developments have led to regression in smolt survival gains associated with tern management. Adaptive management to prevent terns at managed colonies from relocating to nest elsewhere in the basin and to improve nesting opportunities for Caspian terns outside the basin are needed to maximize the survival benefits to Endangered Species Act-listed salmonids from management. Adaptive management is also necessary to ensure the long-term viability of the Pacific Flyway population of Caspian terns, whose breeding population has declined by more than 50% since the two management plans were implemented.

Collis, Ken↗
DOE OSTI2021

Performance of CUDA Unified Memory in CMS Heterogeneous Pixel Reconstruction

The management of separate memory spaces of CPUs and GPUs brings an additional burden to the development of software for GPUs. To help with this, CUDA unified memory provides a single address space that can be accessed from both CPU and GPU. The automatic data transfer mechanism is based on page faults generated by the memory accesses. This mechanism has a performance cost, that can be with explicit memory prefetch requests. Various hints on the inteded usage of the memory regions can also be given to further improve the performance. The overall effect of unified memory compared to an explicit memory management can depend heavily on the application. In this paper we evaluate the performance impact of CUDA unified memory using the heterogeneous pixel reconstruction code from the CMS experiment as a realistic use case of a GPU-targeting HEP reconstruction software. We also compare the programming model using CUDA unified memory to the explicit management of separate CPU and GPU memory spaces.

Kortelainen, Matti J.↗
DOE OSTI2020

Identification and Quantification of Technetium Species in Hanford Waste Tank AN-102

Technetium-99 (Tc) generated from the fission of 235U and 239Pu in high yields is one of the most difficult contaminants to be addressed at the U.S. Department of Energy Hanford Site. In strongly alkaline solutions typifying Hanford tank waste, Tc exists as pertechnetate (TcO4-) (oxidation state VII) as well as in reduced forms (oxidation state < VII) collectively known as non-pertechnetate species. Designing strategies for effective Tc management, including separation and immobilization, necessitates understanding the molecular structure of the non- pertechnetate species and their identification in the actual tank waste samples, which would facilitate development of new treatment technologies effective for dissimilar Tc species. Toward this objective, a spectroscopic library of the Tc(I) [fac-Tc(CO)3]+ and Tc(IV, VII) compounds was generated using a range of techniques and applied to the characterization of the actual tank waste supernatant collected from the tank 241-AN-102 at Hanford, WA. A sample of the 241-AN-102 tank waste supernatant was processed to adjust Na concentration to about 5.6 M and remove 137Cs by spherical resorcinol-formaldehyde (sRF) ion exchange resin. Cesium-loaded sRF column was eluted with 0.5 M HNO3. As received AN-102, Cs-depleted AN-102 effluent, and sRF eluate fractions were comprehensively characterized for chemical composition and speciation of Tc using 99Tc nuclear magnetic resonance spectroscopy and X-ray absorption spectroscopy. It was demonstrated for the first time that non-pertechnetate Tc present in the 241-AN-102 tank waste is composed of several low-valent Tc species, including the Tc(I) [fac-Tc(CO)3]+ and Tc(IV) compounds. This is the second experimental observation of the [fac-Tc(CO)3]+ species in the Hanford tank waste and the first demonstration of multiple forms of non-pertechnetate species existing simultaneously in the waste, cumulatively highlighting their importance for the waste processing.

Low Activity Waste (LAW), High Level Waste, nuclea↗
DOE OSTI2021

Dynamic Process Intensification via Data-Driven Dynamic Optimization: Concept and Application to Ternary Distillation

Process intensification is a design philosophy aimed at making chemical processes safer and more efficient. Its implementation often results in significant modifications to the design and structure of the process, with several conventional unit operations occurring in the same physical device. Traditionally, process intensification has focused on steady-state operation. In our previous works, we introduced dynamic process intensification (DPI) as a new intensification paradigm based on operational changes for conventional or intensified units. DPI is predicated on switching operation between two auxiliary steady states selected via a steady-state optimization calculation that ensures that the system generates, on average and over time, the same products as in nominal steady-state operation, but with favorable economics. This paper extends the DPI concept and introduces a novel dynamic optimization-based DPI strategy (Do-DPI) that involves imposing a true cyclic operation rather than switching between two discrete states. We discuss its implementation using surrogate dynamic models learned via system identification. Here, an extensive case study concerning a ternary distillation column separating a canonical hydrocarbon mixture shows that Do-DPI can reduce energy use by more than 4% relative to steady-state operation, with no significant deviations in product quality and production rate.

42 ENGINEERING↗
DOE OSTI2025

Integrating vehicle trajectory planning and arterial traffic management to facilitate eco-approach and departure deployment

Eco-approach and departure (EAD) enable continuous vehicle motion in urban signalized corridors. Since such a motion can extend to the EAD vehicles’ followers, it makes EAD a promising technology to benefit the traffic flow where automated vehicles and conventional vehicles coexist. Most existing EAD studies envision an ideal setting that neglects real-world operational conditions such as lane changes, multi-movement intersection configuration, partially automated fleet, and/or limited traffic state awareness. This study aims to fill the gap by designing an EAD algorithm considering real-world traffic operation constraints. The proposed algorithm uses a model predictive controller to minimize vehicle speed reduction and variation based on the real-time traffic signal control plan and measured queues at the intersection. The required inputs are readily available at many modern intersections. We observed that the proposed controller’s performance might degrade because of lane-changing maneuvers and lead-left turn traffic signals. These observations motivated our development of a lane change management strategy and a signal control implementation strategy to facilitate the EAD implementation. The lane change management strategies separate the EAD operations and lane-changing maneuvers in time and space. The signal control implementation strategy applies lag-left turn signals to enable EAD operation for both the through and left-turn vehicles. Compared to the non-EAD case, our EAD approach produces 2.5% to 7.8% energy savings while keeping similar intersection mobility. Notably, this approach brings about 2.5% to 3.6% energy savings in a 2% CAV case. This result demonstrates the feasibility of deploying EAD at low connected automated vehicle penetration rates.

Arterial corridor management↗
DOE OSTI2026

Membranes for Lithium Recovery From Conventional and Unconventional Sources

Lithium has been deemed a critical mineral of national importance that finds uses in a wide range of applications, and its demand has been rising significantly in recent years. The urgency of meeting this demand requires lithium extraction from various aqueous sources such as continental brines, geothermal brines, seawater, produced water, and battery waste. While direct lithium extraction (DLE) technologies such as adsorption, ion exchange, and solvent extraction have emerged as possible solutions, membrane technologies are also being investigated for various sources and at different stages of the recovery process. Here, we analyze the application of membranes for pretreatment of lithium source waters, bring management, lithium/magnesium separation, lithium/sodium separation, and lithium hydroxide conversion, and evaluate performance metrics for critical lithium separations from the literature. We explore the potential of membranes at every stage of the recovery process and describe their current status and future prospects. We describe hypothetical process trains with integrated membrane technologies for each source type and address their feasibility and challenges. The potential energy and water impacts of membrane-integrated and conventional DLE processes are also critically considered alongside performance and selectivity metrics, and this is illustrated using examples and calculated from published technical reports. This paper thus provides a comprehensive overview of the application of membranes along every stage of the lithium recovery process, emphasizing the versatility and potential of membrane technologies for critical mineral recovery.

36 MATERIALS SCIENCE↗
DOE OSTI2021

An overview of bipolar plates in proton exchange membrane fuel cells

Bipolar plates are a crucial component of proton exchange membrane fuel cells. They are responsible for transporting reactant gases, carrying the current from the membrane electrode assembly to the end plates, providing heat and water management, and separating the individual cells. However, these plates also contribute to 80% of the fuel cell’s weight, 50% of its volume, and 40% of its cost, posing a barrier to the commercialization of fuel cells. This paper provides a comprehensive review of the materials and manufacturing processes used in the fabrication of bipolar plates as well as recent research conducted on the improvement of bipolar plate weight, volume, and cost through material selection and manufacturing methods. Additive manufacturing is highlighted in this work as an innovative manufacturing method to produce bipolar plates. Novel contributions in this paper include a detailed explanation of traditional manufacturing processes for metallic and graphitic-polymer bipolar plates as well as a cost comparison between additive and traditional manufacturing processes.

08 HYDROGEN↗
DOE OSTI2022

1972713

Energy-frontier particle accelerators are among the most exciting, complex, challenging, and expensive research instruments performing high precision measurements confirming the fundamentals of the physics and broadening new research horizons. Currently the highest energy machines (under design or commissioned), from multi-GeV to several TeV, (ILC, FCC, CLIC) capable of searching for the most basic building blocks of matter are either driven by circular or linear accelerators [1-6]. Here (see also [7,8]) we suggest a novel design of circular-linear accelerator based on the merging of the weakly emitting, low-energy storage rings and energy recovery linear accelerators. To enable the operation of such a system and in particular the energy recovery from spent, high-intensity beams the use of the dual-axis asymmetric cavities is suggested. Merging circular and linear systems, and applications of dual axes cavities, aims to resolve both scientific and societal challenges. The merge of the systems will allow: 1) maintain high beam quality, high luminosity, and high energy efficiency; 2) offer a ?flexible? energy management via ?separation? of the collider and storage rings operations; 3) attract private partners via use of the storage rings to drive the next generation of the photon factories. The concept presented can be potentially used to reach ultimate energy frontiers in high-energy physics as well as to drive next generation light sources. We note that the numbers which will be presented are for illustration purpose and can be improved further.

Konoplev, I.↗
DOE OSTI2023

High Inlet Temperature Combustor for Direct-Fired Supercritical Oxy-Combustion

It is envisioned that supercritical CO 2 (sCO 2 ) electric power plant efficiencies can exceed 52% with 99% carbon capture using direct-fired oxy-combustion. Such efficiencies would be competitive with Natural Gas Combined Cycles (NGCC) and operate with nearly zero carbon emissions. To achieve high plant efficiencies, turbine inlet conditions must approach 1,200 °C at 250 bar. Such conditions, while desirable from a systems perspective, exceed the current state of the art in turbine design and materials qualification. The team of Southwest Research Institute ® (SwRI ® ), Georgia Institute of Technology (Georgia Tech), Spectral Energies, LLC (Spectral), GE Global Research (GE-GRC), and the University of Central Florida (UCF) sought to demonstrate an intermediate step toward these high efficiency plants with the development of a 1 MWth, subscale direct-fired oxy-fuel combustor. The efforts focused largely on the development of an auto-ignition based combustion system capable of providing the targeted 1200 °C and the pilot-scale plant to operate the combustor. While the project was stopped short of the commissioning and demonstration work, the advances made in this effort will reduce risks associated with chemical kinetics, thermal management, water separation, flue gas cleanup, materials selection, and corrosion in future demonstration efforts for the direct-fired oxy-fuel combustion cycles. The following report documents the design, analysis, and installation efforts completed during the project periods of performance.

03 NATURAL GAS↗
DOE OSTI2024

Water & Energy Interdependencies Across Economic Sectors of the United States

The motivation of the Integrated Water Power Resilience Project is to identify and develop opportunities for improving resilience in the water and power sectors through coordinated planning, investment, and operations and thereby provide benefits to power and water utilities, consumers, and the environment. Water and power systems are interdependent, subject to many of the same natural and manmade hazards, and are critical for the well-being of communities and society. Because of the interconnectedness of water and power systems, there are substantial economic, social, and environmental benefits to co-managing the market sectors for resilience instead of managing them separately. To support this initiative and future research in this area, a county level water and energy flow dataset was developed to build, calculate, and visualize interconnections in water and energy between various sectors. This report presents county and regional water and energy visualizations across nine economic sectors of the United States: agriculture, commercial, electricity generation, industrial, mining, public water supply, residential, transportation, and wastewater treatment.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2020

Removing the Cloak of Secrecy from Legacy Cleanup at Los Alamos national Laboratory - 20395

With the establishment in 2018 of the Los Alamos Legacy Cleanup Contract, the Department of Energy's (DOE) Environmental Management Los Alamos Field Office (EM-LA) and its contractor Newport News Nuclear BWXT Los Alamos (N3B) embarked on an expansive program to engage a broad range of local and regional stakeholders in the decision-making process for cleanup of legacy wastes (pre-1999) at the Los Alamos National Laboratory (LANL). From the inception of LANL during the Manhattan Project until the issuance of the new cleanup contract, the site was managed by a single management and operations (M and O) contactor whose main focus was national security. Segmenting from laboratory operations a separate cleanup contract managed by DoE's Office of Environmental Management (EM) brought new opportunities for the cleanup of legacy waste. That change likewise has opened new opportunities for engaging the community on legacy cleanup decisions. The new legacy cleanup contract - an unclassified contract - emphasizes public outreach, marking a cultural shift in how stakeholders in Los Alamos and throughout northern New Mexico are engaged. Without the constraints of classified work, EM-LA and N3B have increased the level of transparency with the public regarding cleanup activities. EM-LA and N3B have crafted an approach that best meets the values, priorities and needs of the neighboring communities by adapting the model successfully employed at Rocky Flats. Through enhanced stakeholder involvement, EM-LA will implement decisions that have considered broad input and deliver a safe and efficient cleanup of the site. EM-LA and N3B began the expanded stakeholder outreach program in January 2019, leading up to four Environmental Management Cleanup Forums held in the summer of 2019. EM-LA and N3B are now in the process of initiating a series of meetings with various stakeholder groups to determine their 'values' as they relate to cleanup using a novel approach that elicits and records values. The entire process is documented, ensuring that should questions arise about how, when and why decisions were made, they can be easily addressed. In addition to other public meetings to present cleanup scenarios and solicit active public involvement in cleanup decisions, the EM-LA and N3B approach involves discussions with stakeholders who want to explore specific technical issues and cleanup discussions in depth. EM-LA and N3B are also evaluating and implementing a variety of communications tools to help ensure the engagement plan sets the gold standard for transparency in legacy cleanup and stakeholder involvement. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

A Managed Tokens Service for Securely Keeping and Distributing Grid Tokens

Fermilab is transitioning authentication and authorization for grid operations to using bearer tokens based on the WLCG Common JWT (JSON Web Token) Profile. One of the functionalities that Fermilab experimenters rely on is the ability to automate batch job submission, which in turn depends on the ability to securely refresh and distribute the necessary credentials to experiment job submit points. Thus, with the transition to using tokens for grid operations, we needed to create a service that would obtain, refresh, and distribute tokens for experimenters’ use. This service would avoid the need for experimenters to be experts in obtaining their own tokens and would better protect the most sensitive long-lived credentials. Further, the service needed to be widely scalable, as we are currently keeping credentials active for approximately 15 experiments, each with 1-3 different credentials, and distributing those credentials to 2-20 submit points per experiment, with those numbers steadily increasing. To address these issues, we created and deployed a Managed Tokens service. The service is written in Go, taking advantage of that language’s native concurrency primitives to easily be able to scale operations as we onboard experiments. The service uses as its first credentials a set of kerberos keytabs, stored on the same secure machine that the Managed Tokens service runs on. These kerberos credentials allow the service to use htgettoken via condor_vault_storer to store vault tokens in the HTCondor credential managers (credds) that run on the batch system scheduler machines (HTCondor schedds); as well as downloading a local, shorter-lived copy of the vault token. The kerberos credentials are then also used to distribute copies of the locally-stored vault tokens to experiment submit points. When experimenters schedule jobs to be submitted, these distributed vault tokens are used to access a Hashicorp Vault instance (run separately from the Managed Tokens service), and previously-stored refresh tokens there are used to obtain the bearer token that is submitted with the job. We will discuss here the design of the Managed Tokens service, including elaborating on certain choices we made with regards to concurrent operations, configuration, monitoring, and deployment.

Bhat, Shreyas↗
DOE OSTI2026

OB200-DV-1 Treatability Testing: Final Results

The Hanford Site in Washington state previously generated plutonium for nuclear weapons. During operations, radionuclide byproducts and chemical process fluids were intentionally and/or unintentionally released to the subsurface, resulting in more than 800 contaminated waste sites across the Central Plateau, where historical chemical separations and waste management activities took place. As the Hanford Site mission transitioned from operations to site cleanup, remediation of the vadose zone and groundwater became a priority. However, given the depth of the unsaturated zone contamination above the groundwater, the unique nature of the waste, and the continuing impacts on groundwater quality, technologies needed to be identified and evaluated for in situ remediation in the deep vadose zone (DVZ). A laboratory treatability study has been completed to evaluate site-relevant effectiveness for nine in situ technologies that may be used to treat continuing sources of contaminants in specific areas of the Central Plateau waste sites that are grouped into the 200-DV-1 Operable Unit (OU). The 200-DV-1 OU was established in 2010 to address 43 Central Plateau waste sites with complex DVZ remediation challenges. Eight of these technologies were identified through a prescreening effort that evaluated remedial technologies potentially applicable to DVZ contamination in the Central Plateau . These eight technologies were selected for further study based on site specific knowledge gaps about their effectiveness. A ninth technology was added to the treatability study based on new information from separate laboratory investigations (conducted following the prescreening effort) demonstrating the technology’s potential effectiveness (see Section 1.2 for more information) and value for inclusion in the treatability study.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

HarDWR - Water Management Area (WMA) Shapefiles

For a detailed description of the database of which this record is only one part, please see the HarDWR meta-record. Borders of all Water Management Areas (WMAs) across the 11 Western-most states of the continental United States are available filtered through a single source. The legal name for this set of boundaries varies state-by-state. The data is provided as two compressed shapefiles. One, stateWMAs, contains data for all 11 states. For 10 of those states, Arizona being the exception, the polygons represent the legal management boundaries used by those states to manage their surface and groundwater resources respectively. Arizona is unique among this collection of states in that surface and groundwater resources are managed using two separate sets of boundaries. During our followup analysis, due to technical reasons we decided to focus on one set of boundaries, those for surface water. Due to this, the Arizona surface WMAs are included within stateWMAs. The Arizona groundwater WMAs are provided as the second file azGroundWMAs as a companion to the first file for completeness and general reference, although the boundaries were no longer referenced in the analysis (Grogan et al., in review) past a certain point. The columns for both shapefiles are: basinNum: the state provided unique numerical ID basinName: the state provided English name of the area, where applicable state: the state name uniID: a unique identifier we created by concatenating the state name, and underscore, and the state numerical ID

Economics↗
DOE OSTI2020

HarDWR - Water Management Area (WMA) Shapefiles

A dataset within the Harmonized Database of Western U.S. Water Rights (HarDWR). For a detailed description of the database, please see the meta-record v2.0. Changelog v2.0 - No changes v1.0 - Initial public release Description Borders of all Water Management Areas (WMAs) across the 11 western-most states of the coterminous United States are available filtered through a single source. The legal name for this set of boundaries varies state-by-state. The data is provided as two compressed shapefiles. One, stateWMAs, contains data for all 11 states. For 10 of those states, Arizona being the exception, the polygons represent the legal management boundaries used by those states to manage their surface and groundwater resources respectively. WMAs refer to the set of boundaries a particular state uses to manage its water resources. Each set of boundaries was collected from the states individually, and then merged into one spatial layer. The merging process included renaming some columns to enable merging with all other source layers, as well as removing columns deemed not required for followup analysis. The retained columns for each boundary are: basinNum - the state provided unique numerical ID; basinName - the state provided English name of the area, where applicable; state - the state name; and uniID - a unique identifier we created by concatenating the state name, and underscore, and the state numerical ID. Arizona is unique within this collection of states in that surface and groundwater resources are managed using two separate sets of boundaries. During our followup analysis (Grogan et al., in review) we decided to focus on one set of boundaries, those for surface water. This is due to the recommendation of our hydrologists that the surface water boundary set is a more realist representation of how water moves across the landscape, as a few of the groundwater boundaries are based on political and/or economic considerations. Therefore, the Arizona surface WMAs are included within stateWMAs. The Arizona groundwater WMAs are provided as a separate file, azGroundWMAs, as a companion to the first file for completeness and general reference. WMA spatial boundary data sources by state: Arizona: Arizona Surface Water Watersheds; Collected February, 2020; https://gisdata2016-11-18t150447874z-azwater.opendata.arcgis.com/datasets/surface-watershed/explore?location=34.158174%2C-111.970823%2C7.50 Arizona: Arizona Ground Water Basins; Collected February, 2020; https://gisdata2016-11-18t150447874z-azwater.opendata.arcgis.com/datasets/groundwater-basin-2/explore?location=34.158174%2C-111.970823%2C7.50 California: California CalWater 2.2.1; Collected February, 2020; https://www.mlml.calstate.edu/mpsl-mlml/data-center/data-entry-tools/data-tools/gis-shapefile-layers/ Colorado: Colorado Water District Boundaries; Collected February, 2020; https://www.colorado.gov/pacific/cdss/gis-data-category Idaho: Idaho Department of Water Resources (IDWR) Administrative Basins; Collected November, 2015; https://data-idwr.opendata.arcgis.com/datasets/fb0df7d688a04074bad92ca8ef74cc26_4/explore?location=45.018686%2C-113.862284%2C6.93 Montana: Collected June, 2019; Directly contacted Montana Department of Natural Resources and Conservation (DNRC) Office of Information Technology (OIT) Nevada: Nevada State Engineer Admin Basin Boundaries; Collected April, 2020 https://ndwr.maps.arcgis.com/apps/mapviewer/index.html?layers=1364d0c3a0284fa1bcd90f952b2b9f1c New Mexico: New Mexico Office of the State Engineer (OSE) Declared Groundwater Basins; Collected April, 2020 https://geospatialdata-ose.opendata.arcgis.com/datasets/ose-declared-groundwater-basins/explore?location=34.179783%2C-105.996542%2C7.51 Oregon: Oregon Water Resources Department (OWRD) Administrative Basins; Collected February, 2020; https://www.oregon.gov/OWRD/access_Data/Pages/Data.aspx Utah: Utah Adjudication Books; Collected April, 2020; https://opendata.gis.utah.gov/datasets/utahDNR::utah-adjudication-books/explore?location=39.497165%2C-111.587782%2C-1.00 Washington: Washington Water Resource Inventory Areas (WRIA); Collected June, 2017; https://ecology.wa.gov/Research-Data/Data-resources/Geographic-Information-Systems-GIS/Data Wyoming: Wyoming State Engineer's Office Board of Control Water Districts; Collected June, 2019; Directly contacted Wyoming State Engineer's Office

Economics↗
DOE OSTI2023

Moisture-driven CO 2 pump for direct air capture

Direct Air Capture, the chemical separation of carbon dioxide (CO 2 ) from air, is considered a necessary approach to generate negative carbon emissions and in turn limit global warming, though energetic and monetary costs must continue to decline to meet the needed gigaton scale. The promise of energy-efficient and continuous carbon dioxide membrane separation has only recently been investigated with the development of facilitated chemical transport and novel electrochemically driven methods. This work demonstrates the potential for continuous pumping of CO 2 from air using commercial anion exchange membranes driven solely by a water vapor gradient. A reactive transport model that couples ionic transport with moisture sensitive bicarbonate chemistry in charged polymers, also termed moisture swing sorption, was developed alongside experimentally measured equilibrium and transport properties of CO 2 and water vapor in Fumasep FAA-3 to determine the mass transport limits of such a system. The results show that the commercial membrane is kinetically limited by the moisture sensitive chemistry, enabling a CO 2 current of 1.1 μmol/m 2 • s. In diffusion limited materials, a CO 2 pumping flux can reach 11 μmol/m 2 • s in and peak performance is expected with a dry air relative humidity around 50% pumping into a saturated water vapor permeate. In all configurations, water loss becomes the major cost in such a separation and must be managed through optimal polymer design or water recovery mechanisms. The work demonstrates the applicability of a new driving force, the evaporation of water, to meet the energetic demand of CO 2 separation from air.

36 MATERIALS SCIENCE↗