Search NASA⌕ Search

SEARCH · Search NASA

Results for “separator modification”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Size-Selective Nanoporous Atomically Thin Graphene Separators for Lithium–Sulfur Batteries

Lithium–sulfur batteries (LSBs) are extensively researched for their high energy densities but are hindered by the lithium polysulfide (LiPS) shuttling effect, which results in poor cyclability. A popular mitigation strategy is separator modification, where a LiPS trapping material is slurry-coated onto a conventional microporous polypropylene (PP) separator. This additional mass and volume unfortunately compromise the overall energy density of the LSB. This study aims to take a separator modification approach that avoids this issue. Nanoporous atomically thin membranes (NATMs) made of graphene are gaining attention for their scalable synthesis, tunable pore size, and negligible pore length. Herein, we apply a well-characterized graphene NATM for reasons similar to those of a size-selective interlayer in LSBs. The tailored pore size of ∼0.7–1.0 nm and atomic thinness facilitate the passage of Li + (solvated ionic diameters ∼0.54–1.26 nm) and blockage of larger LiPS (solvated ionic diameters ∼0.81–1.69 nm) without adding significant impedances or mass. The sulfur confinement is confirmed through scanning electron microscopy and energy-dispersive X-ray spectroscopy elemental analysis of the Li anode. An LSB with a NATM@PP separator shows virtually no capacity loss over 150 cycles, demonstrating efficacy of size-selective molecular sieving using NATMs in LSBs.

battery separator↗
DOE OSTI2025

Interphase Engineering Enabled by Using a Separator with Electrochemically Active Carbazole Polymers for Lithium-Ion Batteries

Separators are generally considered inert components in lithium-ion batteries. In the past, some electroactive polymers have been successfully applied in separator modifications for overcharge protection or as acid scavengers. This study highlights the first use of two “electroactive” carbazole polymers (copolymer 9-phenyl-9H-carbazole-phenyl [PCP] and poly(9-vinylcarbazole) [PVC]), which were each applied separately as coatings on the cathode-facing side of commercial Celgard 2325 separators, respectively, to enhance the cycling performance of 0.3Li 2 MnO 3 ·0.7LiMn 0.5 Ni 0.5 O 2 //graphite (LMR-NM//Gr) full cells through interphase engineering. The team observed an irreversible polymer oxidation process of the carbazole-functionalized polymers—occurring only during the first charge—for the modified separator cells, and the results were confirmed by dQ/dV analysis, cyclic voltammetry measurements, and nuclear magnetic resonance characterizations. During this oxidation, carbazole polymers participate in the process of interphase formation, contributing to the improved cycling performance of LMR-NM//Gr batteries. Particularly, oxidation takes place at voltages of ~4.0 and ~3.5 V when PCP and PVC are used as separator coatings, which is highly irreversible. Further postmortem examinations suggest that the improvements using these modified separators arise from the formation of higher-quality and more inorganic SEI, as well as the beneficial CEI enriched in LixPOyFz. These interphases effectively inhibit the crosstalk effect by reducing TM dissolution.

carbazole↗
DOE OSTI2024

In-situ ionothermal synthesis of nanoporous carbon/oxide composites: A new key to functional separators for stable lithium-sulfur batteries

Lithium-sulfur batteries (LSBs) with high energy density are promising for energy storage. However, conventional polypropylene-based separator cannot avoid polysulfides shuttling which impedes the practical application of LSBs. Herein, an in-situ ionothermal synthesis strategy that concurrently applies ionic liquid as the solvent, template and high-yield carbon source is proposed for the facile preparation of nanoporous carbon/oxide composite separator modifiers. The composites exhibit features of high polarity, self doping, oxygen vacancy, heteroatom doping, abundant defects and high electronic conductivity. Theoretical and experimental studies suggest that the composites can efficiently trap and convert polysulfides for high-performance LSBs. Indeed, in the composite-modified LSBs with next-generation roll-to-roll dry-processed high-loading sulfur cathodes, enhanced performance is achieved, revealing the effectiveness of the composites as functional materials towards separator modification. Therefore, the proposed strategy and its delivered nanoporous composites exhibit excellent versatility and practicality for high-performance LSBs.

25 ENERGY STORAGE↗
NASA NTRS1997

Enhancement of Nucleate Boiling Heat Flux on Macro/Micro-Structured Surfaces Cooled by Multiple Impinging Jets

An experimental investigation of nucleate boiling heat transfer from modified surfaces cooled by multiple in-line impinging circular jets is reported and found to agree with single jet results. A copper block is heated from the back by two electrical arcs, and cooled on the opposite side by three identical liquid jets of distilled water at subcoolings of 25 C 50 C and 77 C and Freon 113 at 24 C subcooling. Liquid flow rates are held constant at 5, 10, and 15 GPH for each of the three jets with jet velocities ranging from 1.4 m/s to 1 1.2 m/s and jet diameters from 0.95 mm to 2.2 mm. To increase the maximum heat flux (CHF) and heat removal rate, the boiling surface was modified by both macro and micro enhancements. Macro modification consists of machined radial grooves in the boiling surface arranged in an optimally designed pattern to allow better liquid distribution along the surface. These grooves also reduce splashing of liquid droplets, and provide 'channels' to sweep away bubbles. Micro modification was achieved by flame spraying metal powder on the boiling surface, creating a porous, sintered surface. With the addition of both micro and macro structured enhancements, maximum heat flux and nucleate boiling can be enhanced by more than 200%. Examination of each surface modification separately and together indicates that at lower superheats, the micro structure provides the enhanced heat transfer by providing more nucleation sites, while for higher superheats the macro structure allows better liquid distribution and bubble removal. A correlation is presented to account for liquid subcoolings and surface enhancements, in addition to the geometrical and fluid properties previously reported in the literature.

Kugler, Scott Lee↗
DOE OSTI2021

Nucleobase-Functionalized Poly(alkylthiophene)s: One-Pot, Sequential Direct Arylation Polymerization and Deprotection, and Surface Modification for Oil–Water Separations

Direct arylation polymerization (DArP) has emerged as an environmentally friendly, atom efficient method of synthesizing a variety of conjugated polymers. In this work, we report a one-pot approach consisting of DArP followed by Boc deprotection to synthesize a functional, surface-active adenine-containing poly(alkylthiophene). Careful control over the polymerization temperature enables the one-pot polymerization and deprotection strategy for synthesis, with quantitative (>99%) Boc deprotection achieved in 24 h. This temperature-controlled synthesis method reduces extra purification and isolation steps, which makes the total synthesis more efficient and practical, and allows higher molecular weight polymer to be made. We quantify the hydrogen bonding ability of the resulting adenine-containing polythiophene, T Ad -tT 4h , by 1 H NMR host–guest titration studies and analyze the results with the Benesi–Hildebrand model, yielding an association constant of 18.7 M –1 between alkylated thymine and T Ad -tT 4h . We demonstrate that T Ad -tT 4h robustly modifies the surface of cellulosic filter paper (CFP), and the modified cellulosic filter paper, CFP-T Ad -tT 4h , is an effective oil–water separatory filter with superhydrophobic properties (water contact angle (CA) ~151°). The utility of hydrogen bonding interactions between adenine and cellulose highlights the importance of side-chain engineering for creating functional materials.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Optimal Control Modification for Time-Scale Separated Systems

Recently a new optimal control modification has been introduced that can achieve robust adaptation with a large adaptive gain without incurring high-frequency oscillations as with the standard model-reference adaptive control. This modification is based on an optimal control formulation to minimize the L2 norm of the tracking error. The optimal control modification adaptive law results in a stable adaptation in the presence of a large adaptive gain. This study examines the optimal control modification adaptive law in the context of a system with a time scale separation resulting from a fast plant with a slow actuator. A singular perturbation analysis is performed to derive a modification to the adaptive law by transforming the original system into a reduced-order system in slow time. A model matching conditions in the transformed time coordinate results in an increase in the actuator command that effectively compensate for the slow actuator dynamics. Simulations demonstrate effectiveness of the method.

Adaptive Control↗
NASA NTRS1976

Modifications of the law of the wall and algebraic turbulence modelling for separated boundary layers

Various modifications of the conventional algebraic eddy viscosity turbulence model are investigated for application to separated flows. Friction velocity is defined in a way that avoids singular behavior at separation and reattachment but reverts to the conventional definition for flows with small pressure gradients. This leads to a modified law of the wall for separated flows. The effect on the calculated flow field of changes in the model that affect the eddy viscosity at various distances from the wall are determined by (1) switching from Prandtl's form to an inner layer formula due to Clauser at various distances from the wall, (2) varying the constant in the Van Driest damping factor, (3) using Clauser's inner layer formula all the way to the wall, and (4) applying a relaxation procedure in the evaluation of the constant in Clauser's inner layer formula. Numerical solutions of the compressible Navier-Stokes equations are used to determine the effects of the modifications. Experimental results from shock-induced separated flows at Mach numbers 2.93 and 8.45 are used for comparison. For these cases improved predictions of wall pressure distribution and positions of separation and reattachment are obtained from the relaxation version of the Clauser inner layer eddy viscosity formula.

Baldwin, B. S.↗
NASA NTRS2010

Optimal Control Modification Adaptive Law for Time-Scale Separated Systems

Recently a new optimal control modification has been introduced that can achieve robust adaptation with a large adaptive gain without incurring high-frequency oscillations as with the standard model-reference adaptive control. This modification is based on an optimal control formulation to minimize the L2 norm of the tracking error. The optimal control modification adaptive law results in a stable adaptation in the presence of a large adaptive gain. This study examines the optimal control modification adaptive law in the context of a system with a time scale separation resulting from a fast plant with a slow actuator. A singular perturbation analysis is performed to derive a modification to the adaptive law by transforming the original system into a reduced-order system in slow time. A model matching conditions in the transformed time coordinate results in an increase in the actuator command that effectively compensate for the slow actuator dynamics. Simulations demonstrate effectiveness of the method.

Nguyen, Nhan T.↗
NASA NTRS1977

Study report on modification of the long term circulatory model for the simulation of bed rest

Modifications were made of the circulatory, fluid, and electrolyte control model which was based on the model of Guyton. The modifications included separate leg compartments and the addition of gravity dependency. It was found that these modifications allowed for more accurate bed rest simulation by simulating changes in the orthostatic gradient and simulating the response to the fluid shifts associated with bed rest.

Leonard, J. I.↗
DOE OSTI2024

Modification of ZIF‐8 Membranes for Gas Separation Using X‐ray Radiation

Here, we report an X-ray radiation-induced modification of the structure and gas permeation behavior of ZIF-8 membranes. With 300 min irradiation time, CO 2 permeance decreases by only 9 %, while N 2 and CH 4 permeances reduce by 75 and 65 %, respectively, leading to 3.7- and 2.6-fold enhancements in ideal selectivity for CO 2 /N 2 and CO 2 /CH 4 .

ZIF-8 membranes↗
NASA NTRS1979

An experimental investigation of (UF-235)6 fission nuclear-pumped lasers

A UF6 handling system was designed for use in conjunction with the existing nuclear-pumped laser vacuum system at a nuclear reactor laboratory to perform the experiments described above. A modification to separate the gas fill system from the vacuum system and thus greatly reduce its volume is described as well as operating procedures for the first controlled nuclear pumping experiments with UF6 vapor contained in the laser cell.

Miley, G. H.↗
NASA NTRS1981

Computation of separated flows by a vortex-tracing algorithm

Numerical solutions for two-dimensional, time-dependent, separated flows around bodies are obtained, using a new version of the vortex method. This method provides an efficient representation of flows involving large regions of separation. The modifications incorporated in the new version, which improve its accuracy, versatility, and computing speed, are described. The computer cost is only of the order of the 3/2 power on N, instead of N-squared, for each step with N vortices. Arbitrary shapes can be treated; a conformal mapping is not required. Special attention is paid to the viscous character of the solution and to the accurate computation of the pressure distribution at the body surface. The vortex solution for the outer flow is coupled to an inner solution for the attached part of the boundary layer. Numerical results are presented for several bluff bodies exhibiting dependence on Reynolds number, for stationary airfoils under steady or transient conditions and for oscillating airfoils, including dynamic stalls. These results are compared with other available results, analytical or experimental, and demonstrate the enhanced reliability and accuracy of the improved method.

Spalart, P. R.↗
DOE OSTI2024

Modification of ZIF‐8 Membranes for Gas Separation Using X‐ray Radiation

Abstract We report an X‐ray radiation‐induced modification of the structure and gas permeation behavior of ZIF‐8 membranes. With 300 min irradiation time, CO 2 permeance decreases by only 9 %, while N 2 and CH 4 permeances reduce by 75 and 65 %, respectively, leading to 3.7‐ and 2.6‐fold enhancements in ideal selectivity for CO 2 /N 2 and CO 2 /CH 4 .

Lee, Dennis T.↗
DOE OSTI2024

Biomass Attributes and Attribute Modifications Affecting Systems and Methods to Separate and Fractionate

Chemical and physical heterogeneity in biomass feedstocks such as agricultural or forestry residues is due to substantial differences in plant tissue types. These differences can contribute significant challenges to handling, preprocessing, and conversion in biorefining processes. An understanding of this chemical and physical heterogeneity can be used to inform fractionation technologies that could facilitate more streamlined processing and potentially be employed to yield multiple co-product streams for a single feedstock. In this chapter, the motivation and scope of biomass fractionation is first outlined. Physical and chemical properties of biomass feedstocks, along with their distribution and diversity within plants, are next discussed with respect to how these differences can be exploited in a fractionation process. A summary of some of the key physical principles that allow for fractionation is next covered along with how these physical principles are exploited in equipment designs. Examples from the literature are briefly discussed that highlight how these approaches can be employed to achieve processing objectives. Several case studies on physical fractionation of corn stover and forestry residues are presented that illustrate how integrated fractionation processes could be employed. Lastly, prospects and potential economic drivers for adoption of biomass fractionation technologies are discussed.

09 BIOMASS FUELS↗