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At least 19 records

Study of exothermic processes in shock ignited gases by the use of laser shear interferometry

Report on measurements of maximum exothermic power pulses attainable from a given chemical system. Experimental tests involved the use of a shock tube technique whereby the exothermic process of combustion was controlled by reflected shock, so that it occurred under virtually inviscid flow conditions, while the measurements were performed at a resolution commensurate with the actual rate of chemical reaction. Experimental observations were made by means of a novel method of laser shear interferometry - a cross-breed between holography and the conventional means for measuring refractive index fields, in that, on one hand, it was based on the exploitation of the phase coherence of the laser light beam, recording first a diffraction image of the wave fronts which, for the desired final result, had to be optically reconstructed, and, on the other, it yielded eventually either two-dimensional interferograms or schlieren photographs of the observed phenomena.

Meyer, J. W.↗

Study of exothermic processes in shock ignited gases by the use of laser shear interferometry.

The paper reports on the measurements of maximum exothermic power pulses attainable from a given chemical system. Experimental tests involved the use of a shock tube technique whereby the exothermic process of combustion was controlled by reflected shock so that it occurred under virtually inviscid flow conditions, the data having been obtained at a resolution commensurate with the actual rate of chemical reaction. Experimental observations were made by means of a novel method of laser shear interferometry. Chemical systems treated in this manner comprised of mixtures of stoichiometric hydrogen-oxygen with 80 and 90% argon, while the measurements covered the full permissible range of initial thermodynamic conditions.

Meyer, J. W.↗

Shock wave ignition of metal powders

The interaction between isolated metal particles and shock-induced flowfields is analyzed to characterize physical events and determine experimental feasibility for shock wave ignition studies. Emphasis is placed on incident shock wave phenomenon as opposed to reflected shock wave. A pre-ignition particle-flow interaction is hypothesized which presumes a vapor phase ignition reaction and an absence of significant vaporization prior to particle melting and erosion. Rapid vaporization of eroded mass is expected, with ignition reaction in the particle wakes. Experimental observation of the 6438-A Cd line and the 3721-A MgO band support the ignition mechanism hypothesized. Scattered cloud data are believed to substantiate the hypothesis that ignition delays could be correlated with predicted melting times.

Fox, T. W.↗

Validation of Multiphase CFD Predictions of the SLS Launch Environment against Artemis I Flight Data

NASA’s Space Launch System (SLS) is powered by four Aerojet-Rocketdyne RS-25 engines, previously referred to as Space Shuttle Main Engines (SSMEs), with two RSRMV solid rocket boosters (SRBs) derived from the Shuttle booster as seen in Fig. 1. Ignition and the start transient of the SRBs, each of which generate 3.6 million pounds of thrust, create a series of large magnitude pressure waves separate from launch acoustics that have the potential to damage the vehicle if unmitigated. This portion of the SLS launch environment consists of igniter shock (IS), ignition overpressure (IOP), and duct overpressure (DOP).

T. Rivord↗

Shock wave ignition of magnesium powders

The paper is concerned with magnesium powder ignition caused by the interaction of powder with incident shock wave-induced flows. Experimentally observed ignition delays are correlated with predicted times for particle melting and the onset of thermal erosion, and a good agreement is found between experiment and theory. Ignition delays were measured as functions of particle screening, cloud concentration, incident shock strength, initial pressure, and oxygen concentration (diluted with nitrogen). An expression for the Nusselt number in the Reynolds number range 0-10,000 and the Mach number range 0-6 is proposed. The expression, when applied to predict particle behavior, provides results in agreement with experimental data for M/Re less than 0.5.

Fox, T. W.↗

Mechanism of ignition in shock wave interactions with reactive liquid droplets

A detailed qualitative analysis of the processes leading to the explosive ignition of a reactive liquid droplet that is suspended in a gas-phase oxidizer and subjected to the passage of a shock wave, is presented. The interval of time between shock wave passage and ignition is described by identifying a two-stage process which consists of a period of relative reactive dormancy that is followed by a chemical induction period leading to the thermal explosion of reactant that has been stripped from the liquid drop, vaporized, and mixed with the gas-phase oxidizer. The results of first-order calculations based on this model are presented and compared with experimental data for diethlcyclohexane drops in oxygen.

Pierce, T. H.↗

Methane oxidation behind reflected shock waves: Ignition delay times measured by pressure and flame band emission

Ignition delay data were recorded for three methane-oxygen-argon mixtures (phi = 0.5, 1.0, 2.0) for the temperature range 1500 to 1920 K. Quiet pressure trances enabled us to obtain delay times for the start of the experimental pressure rise. These times were in good agreement with those obtained from the flame band emission at 3700 A. The data correlated well with the oxygen and methane dependence of Lifshitz, but showed a much stronger temperature dependence (phi = 0.5 delta E = 51.9, phi = 1.0 delta = 58.8, phi = 2.0 delta E = 58.7 Kcal). The effect of probe location on the delay time measurement was studied. It appears that the probe located 83 mm from the reflecting surface measured delay times which may not be related to the initial temperature and pressure. It was estimated that for a probe located 7 mm from the reflecting surface, the measured delay time would be about 10 microseconds too short, and it was suggested that delay times less than 100 microsecond should not be used. The ignition period was defined as the time interval between start of the experimental pressure rise and 50 percent of the ignition pressure. This time interval was measured for three gas mixtures and found to be similar (40 to 60 micro sec) for phi = 1.0 and 0.5 but much longer (100 to 120) microsecond for phi = 2.0. It was suggested that the ignition period would be very useful to the kinetic modeler in judging the agreement between experimental and calculated delay times.

Brabbs, T. A.↗

The carbon dioxide chaperon efficiency for the reaction H + O2 + M yields HO2 + M from ignition delay times behind reflected shock waves

Ignition delay times for stoichiometric hydrogen-oxygen in argon with and without carbon dioxide were measured behind reflected shock waves. A 20-reaction kinetic mechanism models the measured hydrogen-oxygen delay times over the temperature range 950 to 1300 K. The chaperon efficiency for carbon dioxide determined for the hydrogen-oxygen carbon dioxide mixture was 7.0. This value is in agreement with literature values but much less than a recent value obtained from flow tube experiments. Delay times measured behind a reflected shock wave were about 20% longer than those measured behind incident shock waves. The kinetic mechanism successfully modeled the high-pressure data of Skinner and the hydrogen-air data of Stack. It is suggested that the lowest temperature points for the hydrogen-air data of Slack are unreliable and that the 0.27-atm data may illustrate a case where vibrational relaxation of nitrogen is important. The reaction pathway HO2 yields H2O2 yields OH yields H was required to model the high-pressure data of Skinner. The successful modeling of the stoichiometric hydrogen-air data demonstrates the appropriateness of deriving kinetic models from data for gas mixtures highly diluted with argon. The technique of reducing a detailed kinetic mechanism to only the important reactions for a limited range of experimental data may render the mechanism useless for other test conditions.

Brabbs, Theodore A.↗

Controlled flow assembly

Incorporation of isolation valves in high pressure oxygen supply system prevents occurrence of shock ignition when valves are opened. Specifications of equipment show flow rates, pressure ratings, and service life. Illustration of equipment is provided.

Cohen, A. E.↗

The efficient calculation of chemically reacting flow

A semi-implicit finite volume formulation is used to study flows with chemical reactions. In this formulation the source terms resulting from the chemical reactions are treated implicitly and the resulting system of partial differential equations is solved using two time-stepping schemes. The first is based on the Runge-Kutta method while the second is based on an Adams predictor-corrector method. Results show that improvements in computational efficiency depend to a large extent on the manner in which the source term is treated. Further, analysis and computation indicate that the Runge-Kutta method is more efficient than the Adams methods. Finally, an adaptive time stepping scheme is developed to study problems involving shock ignition. Calculations for a hydrogen-air system agree well with other methods.

Eklund, D. R.↗

Liftoff Environments

A Launch Environment, or Liftoff Environment, fundamentally represents a source of loading during the hold-down or liftoff phase of a rocket launch. A launch vehicle is subjected to transient and oscillatory pressure loading on its exterior surfaces induced by engines and boosters during vehicle hold-down and liftoff. These pressure loads are a principal source of structural vibration which may result in the malfunction of vehicle components or the fatigue of exterior skin panels or component brackets. Additionally, the pressure loading gives rise to sound pressure levels inside the crew cabin which may impact the crew's health, safety, or ability to communicate. Liftoff Environments can have a significant impact on the launch vehicle or surrounding structures. For SLS, there are eight primary environments supported by the Liftoff Environments team. These are Liftoff Acoustics (LOA), Hold-down Acoustics (HDA), RS-25 Nozzle Flow Transient (NFT) Acoustics, Booster Ignition Overpressure (IOP) & Duct Overpressure (DOP), Igniter Shock, Core Stage Engine (CSE) Overpressure, Excess Hydrogen (H2) Pop, and Infrasonic Acoustics. These can be split generally into acoustics, which are sustained stationary events, and transients, which are short duration nonstationary events.

Matthew J Casiano↗

Ignition of SiH4-H2-O2-N2 behind reflected shock waves

The ignition of mixtures of silane, hydrogen, and oxygen diluted with nitrogen was studied in a chemical kinetic shock tube. Ignition delay time measurements were made behind reflected shock waves at pressures of 1.25 atm and 1.35 atm and temperatures ranging from approximately 800 K to 1050 K for two mixtures with silane-oxygen equivalence ratios of 1.0 and 0.5, respectively. Enhancement of the ignition by use of silane was observed experimentally by the failure of a similar mixture containing only hydrogen, oxygen, and nitrogen to ignite during the maximum test time available for these test conditions.

Mclain, A. G.↗

Ignition of magnesium powders in shock wave induced flows

Ignition of magnesium powders, resulting from an interaction with incident shock wave-induced flows, has been studied. A numerical analysis of particle dynamics and heating is presented and compared with experimental measurements. The induction period is strongly dependent on convective heat transfer and not on chemical reaction rate. Experimentally observed ignition delays were on the order of 100 microns and were inversely dependent on shock strength and initial pressure, directly dependent on particle size and cloud concentration, and independent of oxygen concentration down to 2.3 percent oxygen. Good agreement between experiment and theory was realized.

Fox, T. W.↗