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Results for “shuttling effects”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Suppressing the Shuttle Effects with FeCo/SPAN Cathodes and High-Concentration Electrolytes for High-Performance Lithium–Sulfur Batteries

The shuttle effects and the sluggish redox kinetics are two of the main challenges in lithium–sulfur (Li–S) batteries, which significantly reduce the capacity of the batteries and restrict their commercialization. Herein, FeCo/sulfurized polyacrylonitrile (SPAN) is synthesized as a cathode material via the electrospinning technique and a further heat treatment. Synchrotron X-ray absorption spectroscopy confirmed the existence of Fe–S/Fe and Co–S bonds in FeCo/SPAN, which benefit the adsorptive and catalytic activities toward lithium polysulfides (LiPSs). Here, we further investigated the effect of electrolyte concentration in inhibiting the shuttle of LiPSs in Li–S batteries. Small-angle X-ray scattering (SAXS) reveals that more contact ion pairs are formed and fewer free solvent molecules exist with the increase of the electrolyte concentration, which can inhibit the dissolution and shuttle of LiPSs. Finally, the batteries assembled with high-concentration electrolytes (3 M LiTFSI in DOL/DME) exhibit a higher specific capacity retention compared to those assembled with low-concentration electrolytes. This work enriches the route to prepare Li–S batteries with the rational design of cathode materials and electrolytes.

25 ENERGY STORAGE↗
DOE OSTI2020

Unraveling Shuttle Effect and Suppression Strategy in Lithium/Sulfur Cells by In Situ/Operando X-ray Absorption Spectroscopic Characterization

The polysulfides shuttle effect represents a great challenge in achieving high capacity and long lifespan of lithium/sulfur (Li/S) cells. A comprehensive understanding of the shuttle-related sulfur speciation and diffusion process is vital for addressing this issue. Herein, we employed in situ/operando X-ray absorption spectroscopy (XAS) to trace the migration of polysulfides across the Li/S cells by precisely monitoring the sulfur chemical speciation at the cathodic electrolyte-separator and electrolyte-anode interfaces, respectively, in a real-time condition. After we adopted a shuttle-suppressing strategy by introducing an electrocatalytic layer of twinborn bismuth sulfide/bismuth oxide nanoclusters in a carbon matrix (BSOC), we found the Li/S cell showed greatly improved sulfur utilization and longer life span. The operando S K-edge XAS results revealed that the BSOC modification was bi-functional: trapping polysulfides and catalyzing conversion of sulfur species simultaneously. We elucidated that the polysulfide trapping-and-catalyzing effect of the BSOC electrocatalytic layer resulted in an effective lithium anode protection. Finally, our results could offer potential stratagem for designing more advanced Li/S cells.

25 ENERGY STORAGE↗
DOE OSTI2026

Mitigation of polysulfide shuttle effect in Li-S batteries through catalytic disproportionation reaction

Polysulfides are poorly retained within porous cathodes and readily diffuse into the electrolyte over time, leading to the well-known shuttle effect that undermines the reversibility of Li-S batteries. Here, in this study, we demonstrate that catalytic disproportionation of polysulfides provides an effective pathway to suppress this process by rapidly converting dissolved species into solid sulfur and sulfides, thereby preventing their migration into the electrolyte. Fundamentally, the sluggish kinetics of sulfur redox reactions are responsible for the accumulation and redistribution of soluble polysulfides in the bulk electrolyte. By accelerating these kinetics, catalyzed disproportionation not only confines sulfur within the conductive cathode matrix but also promotes the homogeneous precipitation of Li₂S₂/Li₂S, which enhances electrochemical reversibility and cycling stability. Using nitrogen-doped carbon (NC800) as a model catalyst, we reveal its ability to drive a pseudo-16-electron reduction pathway, leading to a single dominant Li₂S product and uniform deposition within the porous framework. In contrast, a non-catalytic carbon (KB) yields multiple polysulfide intermediates and heterogeneous deposition. The mechanistic insights provided here highlight the pivotal role of catalytic disproportionation in reshaping sulfur redox pathways and offer a rational strategy for mitigating polysulfide shuttling in practical Li-S pouch cells.

25 ENERGY STORAGE↗
NASA NTRS1976

Engineering support for the Space Processing Application Rocket /SPAR/ project - Preparation for effective Shuttle utilization

Sounding rockets are being used in the Space Processing Program to develop the scientific, engineering, and management expertise to effectively use the Shuttle. An extensive vehicle selection study was necessary to optimize the payload weight, cost factors, and low-g time. The vehicle and subsystem development for each of the flight vehicles is described along with analyses and programmatic considerations peculiar to the Space Processing Program. Several early Space Processing payloads are described along with available flight results.

Ott, R. H.↗
NASA NTRS1971

Space shuttle: Effect of configuration changes on the directional characteristics of a GD/C booster Mach no. 1.2 - 4.96

Force tests on a 0.0035-scale model of the General Dynamics/Convair aerospace space shuttle B-15B-1 booster were conducted in the MSFC trisonic wind tunnel. The configuration has a low delta wing, all-movable delta-planform canard controls, and a single vertical tail. The test was devoted to investigating the effects of various configuration variables upon lateral-directional characteristics. These variables included wing dihedral, rudder flare, and body flap deflection. Yaw runs were made at angles of attack of 6, 10, 15, 25, 30, and 35 degrees. The Mach number range for this test was 1.20 to 4.96.

Brickey, J.↗
NASA NTRS1971

Space shuttle: Effect of orbiter/booster proximity interferences on the aerodynamic characteristics of the launch configuration during separation or abort maneuvers, M equals 0.6 - 1.38

The transonic phase of the 0.0088105-scale MSC orbiter booster separation test was conducted in the LTV 4-foot high speed wind tunnel, at Mach numbers of 0.6,0.9, 1.1, and 1.38. The purpose of this test was to define the effects of the orbiter/ booster proximity interference on the aerodynamic characteristics of the launch configuration during separation or abort maneuvers. Each model had both straight and delta wings available for variation of launch vehicle configuration concepts.

Romere, P. R.↗
NASA NTRS1991

Predicted rocket and shuttle effects on stratospheric ozone

The major chemical effluents of either solid- or liquid-fueled rockets that can potentially perturb stratospheric ozone include chlorine compounds (HCl), nitrogen compounds (NO(x)), and hydrogen compounds (H2 and H2O). Radicals (Cl, ClO, H, OH, HO2, NO, and NO2) formed directly or indirectly from rocket exhaust can cause the catalytic destruction of ozone. Other exhaust compounds that could presumably lead to ozone destruction either by direct reaction with ozone or by providing a surface for heterogeneous processes include the particulates Al2O3, ice, and soot. These topics are discussed in terms of the possible effects of rocket exhausts on stratospheric ozone.

Harwood, Robert S.↗
NASA NTRS1980

Proceedings of Shuttle Environmental Effects Program Review

Measurements of Titan exhaust cloud effluents are documented and compared, mesoscale and microphysical acid rain models are described, and a submesoscale model is proposed. Various instruments and facilities for measuring ice nuclei and other constituents of solid rocket motor exhaust effluents are discussed. Regional air quality monitoring and rain collection systems are described, and the ecological impact of solid rocket motor exhaust effluents is examined. The potential effect of space shuttle launches is estimated where data are adequate.

Potter, A. E.↗
NASA NTRS1983

Environmental effects of Shuttle launch and landing

The areas of concern were the toxic exhaust cloud produced by Shuttle launch, the effect of launch operations on the total ecology, and the sonic boom produced by Orbiter re-entry. Wet acidic dust fell from the exhaust cloud for about ten minutes after launch. The fallout was not entirely unexpected, but the intensity and duration was larger than anticipated. The fallout material is not considered a significant health hazard. Previously announced in STAR as N82-15729

Potter, A. E.↗
NASA NTRS1982

Shuttle contamination effects on ultraviolet coronagraphic observations

The ultraviolet light coronagraph being developed for Shuttle by the Harvard-Smithsonian Center for Astrophysics is described. Effects of Shuttle contaminants on ultraviolet coronagraphic observations are discussed and column densities for acceptable attenuation are provided which are generally applicable to high spectral resolution measurements in the 600 A - 1700 A spectral range.

Kohl, J. L.↗